CS196496B1 - Glass bath for manufacturing frits and glazes - Google Patents
Glass bath for manufacturing frits and glazes Download PDFInfo
- Publication number
- CS196496B1 CS196496B1 CS682078A CS682078A CS196496B1 CS 196496 B1 CS196496 B1 CS 196496B1 CS 682078 A CS682078 A CS 682078A CS 682078 A CS682078 A CS 682078A CS 196496 B1 CS196496 B1 CS 196496B1
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- oxide
- weight
- glazes
- frits
- prepared
- Prior art date
Links
- 238000004519 manufacturing process Methods 0.000 title description 3
- 239000011521 glass Substances 0.000 title description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 20
- 239000010453 quartz Substances 0.000 claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004579 marble Substances 0.000 claims description 6
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 239000010451 perlite Substances 0.000 claims description 5
- 235000019362 perlite Nutrition 0.000 claims description 5
- 239000000377 silicon dioxide Substances 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011787 zinc oxide Substances 0.000 claims description 4
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 2
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000292 calcium oxide Substances 0.000 claims description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000000395 magnesium oxide Substances 0.000 claims description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims description 2
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 2
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 2
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims description 2
- 229910001950 potassium oxide Inorganic materials 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 2
- 229910001948 sodium oxide Inorganic materials 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 235000012239 silicon dioxide Nutrition 0.000 claims 2
- 238000005299 abrasion Methods 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 6
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 5
- 239000004327 boric acid Substances 0.000 description 5
- 239000010433 feldspar Substances 0.000 description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 description 3
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 235000011181 potassium carbonates Nutrition 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000735284 Irena Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000011182 sodium carbonates Nutrition 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Landscapes
- Glass Compositions (AREA)
Description
ČESKOSLOVENSKASOCIALISTICKÁREPUBLIKA( 1» )CZECHOSLOVAKCASOCIALISTREPUBLIC (1 »)
POPIS VYNÁLEZU |«*«<>DESCRIPTION OF THE INVENTION
K AUTORSKÉMU OSVĚDČENI (61) (23) Výstavní priorita(22) Přihlášeno 20 10 78(21) PV 6820-78 (31) Int O.’ C 04 B 41/00// C 03 C 5/00TO THE CERTIFICATE OF CERTIFICATE (61) (23) Exhibition Priority (22) Registered 20 10 78 (21) PV 6820-78 (31) Int O. 'C 04 B 41/00 // C 03 C 5/00
ÚŘAD PRO VYNÁLEZYA OBJEVY (40) Zveřejnčno 29 06 79(45) Vydáno Q1 3 g2OFFICIAL OFFICE AND DISCOVERY (40) Published 29 06 79 (45) Published Q1 3 g2
Autor vynálezu ŠOLC LIBOR RNDr.CSc.,STARÁ PAKAVLČEK JOSEF ing.Author of the invention ŠOLC LIBOR RNDr.CSc., STARÁ PAKAVLČEK JOSEF ing.
BLECHOVÁ IRENA,TURNOV (54) Kmen pro výrobu frit a glazur 1BLECHOVA IRENA, TURNOV (54) Frit and Glazing Strain 1
Vynález se týká kmene pro výrobu frit a glazur, nebo přesněji složení tohoto kmeneThe invention relates to a strain for producing frits and glazes, or more precisely to the composition of this strain
Frity a z nich připravovaná glazury pre glazování dlaždic a obkladaček se vyrábějítavením kmene, sestávajícího z křemene, živců, boraxu, kyseliny boritě, mramoru, dolo-mitu a přísad kysličníků zirkonu, zinku, olova a uhličitanu sodného a draselného. Pod-statnou součástí těchto kmenů je křemen a živce. I když křemen a živce jsou nerosty v přírodě hojně rozěířené, jsou požadavky najejich jakost jako základní suroviny pro výrobu frit tak vysoké, Že vhodný křemen aživce jsou surovinami poměrně vzácnými a proto i značně nákladnými. Jevilo se protoúčelným nalézt takové složení kmene, která by tuto ekonomickou nevýhodu podstatně sní-žilo. Cíle bylo dosaženo tímto vynálezem kmene pro výrobu frit a glazur, sestávajícíhoze směsi tvořené 15 až 30 % hmotnostními křemene, 10 až 30 % hmotnostními kyseliny bo-řit é a/nebo 2 až 15 % hmotnostními boraxu, 10 až 15 % hmotnostními mramoru, 2 až 15 %hmotnostními kaolinu, 2 až 15 % hmotnostními křemičitanu zirkoničitého, 1 až 5 % hmot-nostními kysličníku zinečnatého, 1 až 5 # hmotnostními uhličitanu draselného, 2 až 15 %hmotnostními uhličitanu sodného, jehož podstata spočívá v tom, že obsahuje 30 až 60 %hmotnostních přírodního perlitu o oxidickém složení v % hmotnostních: 196 496 IBS *98 kysličník křemičitý 67,36 až 69,82 kysličník hlinitý 13,90 až 16,16 kysličník železitý 1,48 až 1,94 kysličník titaničitý 0,15 až 0,90 kysličník vápenatý 1,34 až 2,01 kysličník hořečnatý 0,64 až 1,20 kysličník sodný 2,20 až 3,50 kysličník draselný 4,60 až 5,40 ztráta žíháním 3,12 až 4,10 .t je jakostní a levná surovina a úspššnš na] živce a část křemene. Delší část křemene lze popřípadě nahradit jakostním sklářskýmpiskem. Příklady I. Podle vynálezu byl připraven kmen o složení v hmotnostních %: perlit 48,80 borax 8,17 kyselina boritá 12,55 uhličitan vápenatý 12,15 (mramor) kysličník křemičitý 15,34 (křemen) kysličník zinečnatý 2,99 Z tohoto kmene byla připravena frita tavením při 1350 až 1450 °C po dobu 4 hodin II. Podle vynálezu byl připraven kmen o složení v hmotnostních %: perlit 33,20 křemičitan zirkoničitý 10,58 borax 12,86 kyselina boritá 12,73 uhličitan vápenatý 10,61 (mramor) kysličník křemičitý 19,22 (křemen) kysličník zinečnatý 0,80 Z kmene byla připravena frita tavením při 1350 až 1450 °C po dobu 4 hodin HI. Podle vynálezu byl připraven kmen o složení v hmotnostních %: perlit 44,86 kyselina boritá 25,73 kysličník křemičitý 14,75 (křemen) uhličitan vápenatý 2,01 (mramor) křemičitan zirkoničitý 9,75 kaolin 2,90Frits and glazes prepared therefrom for glazing tiles and tiles with the production of a strain consisting of quartz, feldspar, borax, boric acid, marble, dolomite and additives of zirconium, zinc, lead and sodium and potassium carbonates. A substantial part of these strains is quartz and feldspar. Although quartz and feldspars are widely spread in nature, the requirements of their quality as the basic raw material for frit production are so high that suitable quartzites are relatively rare and therefore very expensive. It appeared purposeful to find a strain of the strain that would significantly reduce this economic disadvantage. The object was achieved by the present invention of a frit and glaze strain consisting of a mixture of 15 to 30% by weight of quartz, 10 to 30% by weight of boric acid and / or 2 to 15% by weight of borax, 10 to 15% by weight of marble, 2 up to 15% by weight of kaolin, 2 to 15% by weight of zirconium silicate, 1 to 5% by weight of zinc oxide, 1 to 5% by weight of potassium carbonate, 2 to 15% by weight of sodium carbonate; 60% by weight of natural perlite with an oxide composition in% by weight: 196 496 IBS * 98 silica 67,36 to 69,82 alumina 13,90 to 16,16 ferric oxide 1,48 to 1,94 titanium dioxide 0,15 to 0.90 calcium oxide 1.34 to 2.01 magnesium oxide 0.64 to 1.20 sodium oxide 2.20 to 3.50 potassium oxide 4.60 to 5.40 ignition loss 3.12 to 4.10. is quality and cheap raw material and feldspar success and quartz. The longer part of the quartz can be replaced by a quality glass sheet. Examples I. According to the invention, a strain was prepared in% by weight: perlite 48.80 borax 8.17 boric acid 12.55 calcium carbonate 12.15 (marble) silica 15.34 (quartz) zinc oxide 2.99 From this the frit was prepared by melting at 1350-1450 ° C for 4 hours II. According to the invention, a strain was prepared in% by weight: perlite 33.20 zirconium silicate 10.58 borax 12.86 boric acid 12.73 calcium carbonate 10.61 (marble) silica 19.22 (quartz) zinc oxide 0.80 Frit was prepared from the strain by melting at 1350-1450 ° C for 4 hours HI. According to the invention, a strain was prepared in% by weight: perlite 44.86 boric acid 25.73 silica 14.75 (quartz) calcium carbonate 2.01 (marble) zirconium silicate 9.75 kaolin 2.90
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS682078A CS196496B1 (en) | 1978-10-20 | 1978-10-20 | Glass bath for manufacturing frits and glazes |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CS682078A CS196496B1 (en) | 1978-10-20 | 1978-10-20 | Glass bath for manufacturing frits and glazes |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CS196496B1 true CS196496B1 (en) | 1980-03-31 |
Family
ID=5416108
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS682078A CS196496B1 (en) | 1978-10-20 | 1978-10-20 | Glass bath for manufacturing frits and glazes |
Country Status (1)
| Country | Link |
|---|---|
| CS (1) | CS196496B1 (en) |
-
1978
- 1978-10-20 CS CS682078A patent/CS196496B1/en unknown
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