CO5040072A1 - Procedimiento y compuestos intermediarios para la prepara- cion de compuestos de fluorolefina plaguicidas - Google Patents
Procedimiento y compuestos intermediarios para la prepara- cion de compuestos de fluorolefina plaguicidasInfo
- Publication number
- CO5040072A1 CO5040072A1 CO98034403A CO98034403A CO5040072A1 CO 5040072 A1 CO5040072 A1 CO 5040072A1 CO 98034403 A CO98034403 A CO 98034403A CO 98034403 A CO98034403 A CO 98034403A CO 5040072 A1 CO5040072 A1 CO 5040072A1
- Authority
- CO
- Colombia
- Prior art keywords
- groups
- compound
- alkyl
- haloalkyl
- independently selected
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
- C07C43/29—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing halogen
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C43/00—Ethers; Compounds having groups, groups or groups
- C07C43/02—Ethers
- C07C43/257—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings
- C07C43/295—Ethers having an ether-oxygen atom bound to carbon atoms both belonging to six-membered aromatic rings containing hydroxy or O-metal groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/64—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings
- C07C59/66—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings
- C07C59/68—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings the non-carboxylic part of the ether containing six-membered aromatic rings the oxygen atom of the ether group being bound to a non-condensed six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C59/00—Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O—metal, —CHO, keto, ether, groups, groups, or groups
- C07C59/40—Unsaturated compounds
- C07C59/58—Unsaturated compounds containing ether groups, groups, groups, or groups
- C07C59/72—Unsaturated compounds containing ether groups, groups, groups, or groups containing six-membered aromatic rings and other rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/732—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids of unsaturated hydroxy carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/734—Ethers
- C07C69/736—Ethers the hydroxy group of the ester being etherified with a hydroxy compound having the hydroxy group bound to a carbon atom of a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/66—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
- C07C69/73—Esters of carboxylic acids having esterified carboxylic groups bound to acyclic carbon atoms and having any of the groups OH, O—metal, —CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety of unsaturated acids
- C07C69/738—Esters of keto-carboxylic acids or aldehydo-carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/02—Systems containing only non-condensed rings with a three-membered ring
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Oxygen Or Sulfur (AREA)
- Pyridine Compounds (AREA)
Abstract
Un procedimiento para la preparación de un compuesto defluorolefina que tiene la fórmula estructural Ien la cual R es hidrógeno o alquilo C1 -C4 , y R1 es alquilo C1 -C4 , haloaquilo C1 -C4 , o ciclopropilo, o R y R1 se toma conjuntamente con el átomo de carbono al cual están unidos para formar un grupo ciclopropilo;Ar es fenilo opcionalmente substituido con hasta tres grupos independientemente seleccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 , o grupos haloalcoxi C1 -C4 , o 1- ó 2- naftiloopcionalmente substituido con hasta tres grupos independientemente seleccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 , o grupos haloalcoxi C1 -C4 ;Ar1 es fenoxifenilo opcionalmente substituido con hasta cinco grupos independientemente selecccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 , o grupos haloalcoxi C1 -C4 ;bifenilo opcionalmente substituido con hasta cinco grupos independientemente seleccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 , ó grupos haloalcoxi C1 -C4 , bencilfenilo opcionalmente sustituido con hasta cinco grupos independientemente seleccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 o grupos haloalcoxi C1 -C4 ; obenzoilfenilo opcionalmente substituido con hasta cinco grupos independientemente seleccionados de átomos de halógeno, grupos alquilo C1 -C4 , grupos haloalquilo C1 -C4 , grupos alcoxi C1 -C4 o grupos haloalcoxi C1 -C4 ;y la configuración de los grupos ArCRR1 - y - CH2 Ar1 alrededor del doble enlace es - 2 -predominantemente mutuamente trans, cuyo procedimiento comprende:a) Fluorar un compuesto de butanoato de 4-aril-3-oxo-2-(bencilo substituido) que tiene la fórmula estructural II en la cual R2 es alquilo C1 -C6 y Ar, Ar1 , R y R1 son tal como se han descrito más arriha en presencia de una primera base para formar un compuesto de butanoato de 4-aril-2 flúor-3-oxo-2-(bencilo substituido) que tiene la fórmula estructural IIIen la cual Ar, Ar1 , R, R1 , y R2 son tal como se han descrito precedentemente;b) reducir el compuesto de fórmula III para formar un compuesto de butanoato de 4-aril-2-flúor-3-hidroxi-2-(bencilo substituido) que tienen la fórmula estructural IVen la cual Ar, Ar1 , R, R1 y R2 son tal como se han descrito precedentemente y la configuración de los grupos ArCRR1 CH(OH)- y - CF(CO2 R2 )CH2 Ar1 unidos al enlace rotulado "a" es predominantemente R,S o S,R o una mezcla de los mismos;c) saponificar el compuesto de fórmula IV para formar un compuesto de ácido 4-aril-2-flúor-3-hidroxi-2-butanoico (bencilo substituido) que tiene la fórmula estructural Vdonde Ar, Ar1 , R y R1 son tal como se han descrito más arriba y la configuración de los grupos ArCRR1 CH(OH)- y - CF(CO2 R2 )CH2 Ar1 unidos al enlace rotulado "a" es predominantemente R,S o S,R o una mezcla de los mismos; yd) hacer reaccionar el compuesto de fórmula V con un compuesto de haluro de sulfonilo y una segunda base.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US5016697P | 1997-06-19 | 1997-06-19 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CO5040072A1 true CO5040072A1 (es) | 2001-05-29 |
Family
ID=21963709
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CO98034403A CO5040072A1 (es) | 1997-06-19 | 1998-06-17 | Procedimiento y compuestos intermediarios para la prepara- cion de compuestos de fluorolefina plaguicidas |
Country Status (31)
| Country | Link |
|---|---|
| US (1) | US5973190A (es) |
| EP (1) | EP0885867B1 (es) |
| JP (1) | JPH11147857A (es) |
| KR (1) | KR100522107B1 (es) |
| CN (1) | CN1138735C (es) |
| AR (1) | AR013003A1 (es) |
| AT (1) | ATE207457T1 (es) |
| AU (1) | AU724762B2 (es) |
| BG (1) | BG102563A (es) |
| BR (1) | BR9802017A (es) |
| CA (1) | CA2240886A1 (es) |
| CO (1) | CO5040072A1 (es) |
| CZ (1) | CZ188698A3 (es) |
| DE (1) | DE69802140T2 (es) |
| DK (1) | DK0885867T3 (es) |
| ES (1) | ES2166590T3 (es) |
| GE (1) | GEP20022795B (es) |
| HU (1) | HU220279B (es) |
| ID (1) | ID20465A (es) |
| IL (1) | IL124924A (es) |
| MD (1) | MD980145A (es) |
| NO (1) | NO309263B1 (es) |
| NZ (1) | NZ330695A (es) |
| PL (1) | PL326881A1 (es) |
| RU (1) | RU2193022C2 (es) |
| SG (1) | SG66481A1 (es) |
| SK (1) | SK84798A3 (es) |
| TR (1) | TR199801109A3 (es) |
| TW (1) | TW457228B (es) |
| YU (1) | YU26598A (es) |
| ZA (1) | ZA985387B (es) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL154438A0 (en) * | 2000-09-12 | 2003-09-17 | Basf Ag | Process and intermediate compounds for the preparation of pesticidal fluoroolefin compounds |
| KR102245731B1 (ko) | 2020-10-26 | 2021-04-28 | 주식회사 삼정오디세이 | 샤프트 및 이의 제조방법 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9219612D0 (en) * | 1992-09-16 | 1992-10-28 | Khambay Bhupinder P S | Pesticidal fluoroolefins |
| GB9408605D0 (en) * | 1994-04-29 | 1994-06-22 | British Tech Group | Pesticidal fluoroolefins |
| GB9522144D0 (en) * | 1995-10-30 | 1996-01-03 | British Tech Group | Control of whitefly |
-
1998
- 1998-06-11 GE GEAP19984341A patent/GEP20022795B/en unknown
- 1998-06-15 IL IL12492498A patent/IL124924A/en not_active IP Right Cessation
- 1998-06-16 NZ NZ330695A patent/NZ330695A/xx unknown
- 1998-06-16 DK DK98304738T patent/DK0885867T3/da active
- 1998-06-16 EP EP98304738A patent/EP0885867B1/en not_active Expired - Lifetime
- 1998-06-16 ES ES98304738T patent/ES2166590T3/es not_active Expired - Lifetime
- 1998-06-16 AT AT98304738T patent/ATE207457T1/de not_active IP Right Cessation
- 1998-06-16 TR TR1998/01109A patent/TR199801109A3/tr unknown
- 1998-06-16 CZ CZ981886A patent/CZ188698A3/cs unknown
- 1998-06-16 DE DE69802140T patent/DE69802140T2/de not_active Expired - Fee Related
- 1998-06-16 JP JP10183280A patent/JPH11147857A/ja not_active Ceased
- 1998-06-17 CA CA002240886A patent/CA2240886A1/en not_active Abandoned
- 1998-06-17 CO CO98034403A patent/CO5040072A1/es unknown
- 1998-06-17 SG SG1998001445A patent/SG66481A1/en unknown
- 1998-06-17 KR KR1019980022709A patent/KR100522107B1/ko not_active IP Right Cessation
- 1998-06-17 BR BR9802017A patent/BR9802017A/pt not_active Application Discontinuation
- 1998-06-18 NO NO982811A patent/NO309263B1/no not_active IP Right Cessation
- 1998-06-18 PL PL98326881A patent/PL326881A1/xx unknown
- 1998-06-18 AU AU71968/98A patent/AU724762B2/en not_active Ceased
- 1998-06-18 ID IDP980888A patent/ID20465A/id unknown
- 1998-06-18 AR ARP980102917A patent/AR013003A1/es unknown
- 1998-06-18 YU YU26598A patent/YU26598A/sr unknown
- 1998-06-18 RU RU98111641/04A patent/RU2193022C2/ru not_active IP Right Cessation
- 1998-06-18 US US09/099,101 patent/US5973190A/en not_active Expired - Fee Related
- 1998-06-18 MD MD98-0145A patent/MD980145A/ro unknown
- 1998-06-18 CN CNB981149324A patent/CN1138735C/zh not_active Expired - Fee Related
- 1998-06-18 HU HU9801375A patent/HU220279B/hu not_active IP Right Cessation
- 1998-06-18 SK SK847-98A patent/SK84798A3/sk unknown
- 1998-06-19 TW TW087109826A patent/TW457228B/zh not_active IP Right Cessation
- 1998-06-19 BG BG102563A patent/BG102563A/xx unknown
- 1998-06-19 ZA ZA9805387A patent/ZA985387B/xx unknown
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| ES2180981T3 (es) | Procedimiento para la preparacion de una sal de magnesio de un heterociclo de sulfinilo sustituido. | |
| PA8546601A1 (es) | Nuevos derivados de indol con afinidad por el receptor 5-ht6 | |
| CO6150159A2 (es) | Compuestos de heteroarilo utiles como inhibidores de enzimas de activacion e1 | |
| EA200201141A1 (ru) | Производные тропана, полезные для терапии | |
| PE31691A1 (es) | Procedimiento para la preparacion de nuevos compuestos fungicidas | |
| AR046394A1 (es) | Derivados de quinolinas y quinazolinas, metodo de preparacion de los mismos y composiciones farmaceuticas que los contienen. | |
| AR065524A1 (es) | Diaminopirimidinas como fungicidas | |
| PE20050130A1 (es) | Compuestos organicos | |
| CO5540302A2 (es) | Heteroarilos multiciclicos con quinuclidinas para el tratamiento de enfermedades | |
| AR057071A1 (es) | Producto de combinacion que comprende arilpirazoles sustituidos | |
| PA8547901A1 (es) | Derivados de 4-piperacinilindol con afinidad receptora de 5-ht6 | |
| ES2194844T3 (es) | Antagonistas del receptor de aminoacidos excitadores. | |
| PE20051147A1 (es) | Compuestos de heteroaril y fenilsulfamoilo sustituidos | |
| PE2799A1 (es) | Lactamas e imidas heterociclicas de aralquilo y aralquilideno | |
| PE20121534A1 (es) | Nuevos maitansinoides y el uso de dichos maitansinoides para preparar conjugados con un anticuerpo | |
| CO4970728A1 (es) | 2-aminopiridinas que contienen sustituyentes de anillos condensados | |
| AR048213A1 (es) | 1-(4-mono-y di-halometilsulfonilfenil)-2-acilamino-fluorpropanoles analogos al florfenicol | |
| AR039698A1 (es) | Agonistas de los receptores cannabinoides | |
| CO5150149A1 (es) | Composiciones farmaceuticas derivadas de quinolina | |
| AR061973A1 (es) | Compuesto de 2-arilindol sustituido en la posicion 5, composicion farmaceutica que lo comprende, compuestos intermedios y procedimiento para la preparacion de los mismos | |
| AR004706A1 (es) | Un compuesto derivado de benzoxazina y pirido-oxazina utiles como antimicrobianos, composicion farmaceutica que lo contienen, un metodo para preparar dichos compuestos e intermediarios utiles para dicho metodo. | |
| ES2191611T3 (es) | Compuesto bajo forma de isomero geometrico u optico puro o de mezcla de tales isomeros. | |
| ES2038678T3 (es) | Procedimiento para la preparacion de n-(2-alquil-3-mercapto-glutaril)-alfamino-acidos. | |
| TW200604185A (en) | Chemical compounds | |
| CO5040072A1 (es) | Procedimiento y compuestos intermediarios para la prepara- cion de compuestos de fluorolefina plaguicidas |