CN87107328A - Acaricidal composition - Google Patents
Acaricidal composition Download PDFInfo
- Publication number
- CN87107328A CN87107328A CN87107328.5A CN87107328A CN87107328A CN 87107328 A CN87107328 A CN 87107328A CN 87107328 A CN87107328 A CN 87107328A CN 87107328 A CN87107328 A CN 87107328A
- Authority
- CN
- China
- Prior art keywords
- mite
- miticide
- composition
- present
- ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 23
- 230000000895 acaricidal effect Effects 0.000 title abstract description 17
- -1 2, 2, 3, 3-tetramethylcyclopropanecarboxylic acid alpha-cyano-3-phenoxybenzyl ester Chemical class 0.000 claims abstract description 17
- 239000000642 acaricide Substances 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 14
- 238000009736 wetting Methods 0.000 claims description 12
- 239000004480 active ingredient Substances 0.000 claims description 11
- FOCVUCIESVLUNU-UHFFFAOYSA-N Thiotepa Chemical compound C1CN1P(N1CC1)(=S)N1CC1 FOCVUCIESVLUNU-UHFFFAOYSA-N 0.000 claims description 4
- 230000009969 flowable effect Effects 0.000 claims description 4
- 229960001196 thiotepa Drugs 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- 239000008187 granular material Substances 0.000 claims description 2
- 125000003047 N-acetyl group Chemical group 0.000 claims 2
- 239000000470 constituent Substances 0.000 claims 2
- 150000002148 esters Chemical class 0.000 description 16
- 241000488581 Panonychus citri Species 0.000 description 11
- 239000007921 spray Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- 239000003814 drug Substances 0.000 description 10
- 241001672694 Citrus reticulata Species 0.000 description 9
- 241000238631 Hexapoda Species 0.000 description 9
- 241001454293 Tetranychus urticae Species 0.000 description 9
- 241000510091 Quadrula quadrula Species 0.000 description 8
- 230000000694 effects Effects 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 5
- 238000005507 spraying Methods 0.000 description 5
- 235000013311 vegetables Nutrition 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 4
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 4
- 235000013601 eggs Nutrition 0.000 description 4
- 230000000749 insecticidal effect Effects 0.000 description 4
- 231100000572 poisoning Toxicity 0.000 description 4
- 230000000607 poisoning effect Effects 0.000 description 4
- 230000003449 preventive effect Effects 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 241000238876 Acari Species 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 241000985245 Spodoptera litura Species 0.000 description 3
- 244000269722 Thea sinensis Species 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 3
- 238000010413 gardening Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000003071 parasitic effect Effects 0.000 description 3
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 241001124076 Aphididae Species 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 241001465754 Metazoa Species 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 150000003973 alkyl amines Chemical class 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 2
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- UOAMTSKGCBMZTC-UHFFFAOYSA-N dicofol Chemical compound C=1C=C(Cl)C=CC=1C(C(Cl)(Cl)Cl)(O)C1=CC=C(Cl)C=C1 UOAMTSKGCBMZTC-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000002147 killing effect Effects 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- 230000003129 miticidal effect Effects 0.000 description 2
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- 239000002728 pyrethroid Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- JECYNCQXXKQDJN-UHFFFAOYSA-N 2-(2-methylhexan-2-yloxymethyl)oxirane Chemical compound CCCCC(C)(C)OCC1CO1 JECYNCQXXKQDJN-UHFFFAOYSA-N 0.000 description 1
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 241000251468 Actinopterygii Species 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 241000272639 Brachycaudus mimeuri Species 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 235000009024 Ceanothus sanguineus Nutrition 0.000 description 1
- 241000426497 Chilo suppressalis Species 0.000 description 1
- 229920002101 Chitin Polymers 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 240000008067 Cucumis sativus Species 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 206010018498 Goitre Diseases 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 240000003553 Leptospermum scoparium Species 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 235000015459 Lycium barbarum Nutrition 0.000 description 1
- 240000000233 Melia azedarach Species 0.000 description 1
- 241000257159 Musca domestica Species 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-O N,N,N-trimethylglycinium Chemical class C[N+](C)(C)CC(O)=O KWIUHFFTVRNATP-UHFFFAOYSA-O 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- 241000500437 Plutella xylostella Species 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000006004 Quartz sand Substances 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical class [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- OWZREIFADZCYQD-UHFFFAOYSA-N [cyano-(3-phenoxyphenyl)methyl] 3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane-1-carboxylate Chemical class CC1(C)C(C=C(Br)Br)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 OWZREIFADZCYQD-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000005667 attractant Substances 0.000 description 1
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- XIWFQDBQMCDYJT-UHFFFAOYSA-M benzyl-dimethyl-tridecylazanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 XIWFQDBQMCDYJT-UHFFFAOYSA-M 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000152 carbamate pesticide Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000005018 casein Substances 0.000 description 1
- BECPQYXYKAMYBN-UHFFFAOYSA-N casein, tech. Chemical compound NCCCCC(C(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(CC(C)C)N=C(O)C(CCC(O)=O)N=C(O)C(CC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(C(C)O)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=N)N=C(O)C(CCC(O)=O)N=C(O)C(CCC(O)=O)N=C(O)C(COP(O)(O)=O)N=C(O)C(CCC(O)=N)N=C(O)C(N)CC1=CC=CC=C1 BECPQYXYKAMYBN-UHFFFAOYSA-N 0.000 description 1
- 235000021240 caseins Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000031902 chemoattractant activity Effects 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910052570 clay Inorganic materials 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000002657 fibrous material Substances 0.000 description 1
- 239000000915 fish venom Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229920000550 glycopolymer Polymers 0.000 description 1
- 201000003872 goiter Diseases 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 231100000731 ichthyotoxin Toxicity 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 150000002825 nitriles Chemical class 0.000 description 1
- 150000002903 organophosphorus compounds Chemical class 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 238000010010 raising Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- YZHUMGUJCQRKBT-UHFFFAOYSA-M sodium chlorate Chemical compound [Na+].[O-]Cl(=O)=O YZHUMGUJCQRKBT-UHFFFAOYSA-M 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 235000014347 soups Nutrition 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 235000012222 talc Nutrition 0.000 description 1
- 235000013616 tea Nutrition 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940032912 zephiran Drugs 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
An acaricidal composition comprising 2, 2, 3, 3-tetramethylcyclopropanecarboxylic acid alpha-cyano-3-phenoxybenzyl ester and O, S-dimethyl N-acetyl thiophosphate as effective components.
Description
The present invention relates to the miticide composition of a novelty, it can prevent and treat various harming the crops and the mite class of horticultural crop effectively, as two spotted spider mite, and false spider mite, instep line mite, goitre mite etc.More specifically have a talk about; the present invention relates to one and it is characterized in that containing effective composition 2,2,3; 4-Tetramethylcycloprop-ne-ne carboxylic acid alpha-cyano-3-phenoxybenzyl ester (to call branch Piao Ju ester in the following text) and O, the miticide composition of S-dimethyl-N-acetyl group thio-phosphamide (to call orthen in the following text).Miticide composition of the present invention can be effectively used to farmland and gardening.
Divide Piao Ju ester, one of active ingredient of the present invention, be a synthetic pyrethrins series desinsection, kill the mite compound, both can prevent and treat being an impediment to healthy insect, also can prevent and treat the insect on agricultural and the gardening.Known this compound itself just can be used for preventing and treating the insect that is an impediment to health, and as housefly, northern house, Germany flies Lian etc., and the insect that is harmful to crops and horticultural crop.As striped rice borer, prodenia litura, black peach aphid, Tetranychus cinnabarinus etc. (Japanese patent application publication No. 5450/1976).
Orthen is another active ingredient that the present invention adopts, according to " agricultural chemicals handbook " version in 1985, and Japanese plant protection on January 30, association P.73-74(1986; company publishes), about the update reader of agricultural chemicals, P.1(publish by soft science company; 1982, March 25) etc., known orthen has interior absorption and high insecticidal activity; can prevent and treat vegetable-crop pest-insect; as prodenia litura, diamond-back moth etc., and mandarin orange pest; as aphid, thrips etc.; orthen is very weak to the activity of mite class; therefore be very low as acaricidal preventive effect; the miticide of many routines; in direct preventive effect, interior absorption, aspects such as gasification property are all fine; they are killing mite spectrum, residual activity, ichthyotoxin and always satisfied to the aspects such as toxicity of warm blooded animal.And, because many acaricidal long-term uses have caused having produced these acaricidal high resistant mites in many places.Particularly for insect fruit tree, vegetables, tea, flowers and see the mite class taste on the tree, ordinary maple leaf mite for example, Tetranychus cinnabarinus, tetranychus telarius (T.Kanzawa), the tangerine Panonychus citri, the elm Panonychus citri, the many foods of example fall the line mite and have observed acaricidal obvious resistance.Therefore, many miticides are losing the use value to these mite classes.
On the other hand, as mentioned above, be the Insecticidal and acaricidal agent of a pyrethroid series as the branch Piao Ju ester of one of active ingredient of the present invention, even itself is also effective to mite., the acaricidal activity comparison lepidoptera pest (as prodenia litura) of branch Piao Ju ester and the insecticidal activity of Zhu's wing order insect (as the machine aphid) are low, therefore, when using dosage is enough to kill these insects, can't kill the mite class.The result is, when adopting when dividing the Piao Ju ester to come extremely mite, just needing increases consumption, brought toxicity thus again and to the problem of environment adverse effect.
Therefore, be badly in need of the miticide of a kind of novelty of exploitation, it has efficiently for the mite class that has increased resistance owing to the conventional miticide of use when hanging down consumption, and low toxicity, and environment is seldom had adverse effect.
Purpose of the present invention just provides a kind of miticide that satisfies the novelty of this demand.
In light of this situation, the present invention has adopted all cpds to make extensive studies, found that, the miticide of forming as active ingredient with minute Piao Ju ester and orthen is for ordinary maple leaf mite, the tangerine Panonychus citri, tetranychus telarius (T.Kanzawa), side are eaten instep line mite etc. more all good control efficiency.
Secondly, also will make specific description for acaricidal compound method of the present invention and use.
In order to produce miticide of the present invention, can be with active ingredient of the present invention and appropriate carriers and adjuvant, as surfactant, binding agent, stabilizing agents etc. mix, and the mixture of gained is processed into wetting powder, missible oil, liquor, flowable, pulvis, unit's drift pulvis, granula subtilis or the like.
Content of effective in these preparations, for wetting powder, missible oil, liquor and flowable are in 1～90%(weight) scope in; For pulvis, do not have drift pulvis and granula subtilis, in 0.5～5%(weight) scope in; For granule, in 1～10%(weight) scope in.In this case, dividing the Piao Ju ester and the ratio of orthen is 1: 1 to 1: 100, preferably 1: 1 to 1: 50.
The carrier that can adopt in miticide of the present invention is normally used arbitrary solid or liquid-carrier in the chemicals in agricultural chemicals and gardening, does not have concrete restriction.
For example, solid carrier comprises mineral powder (for example high Cen soil, bentonite, clay, montmorillonite, talcum, diatomite, mica, quartz sand, ammonium sulfate, urea), the plant powder is (for example, bean powder, flour, sawdust, tobacco end, starch, crystalline vegetable fiber material), alumina, silicate, glycopolymers, polymolecularity silicate, paraffin etc.
Liquid-carrier comprises water, alcohols (methyl alcohol for example, ethanol, normal propyl alcohol, isopropyl alcohol, n-butanol, ethylene glycol, phenmethylol), aromatic hydrocarbons (benzene for example, toluene, dimethylbenzene, ethylbenzene, chlorobenzene, isopropylbenzene, the first naphthalene), halogenated hydrocarbons (chloroform for example, carbon tetrachloride, carrene, dichloroethane, Arcton 11, dicholorodifluoromethane), ethers (ether for example, oxirane, dioxane, oxolane), ketone (acetone for example, MEK, cyclohexanone, methyl iso-butyl ketone (MIBK)), ester class (for example, ethyl acetate, butyl acetate, the acetate glycol ester, pentyl acetate), nitrile (acetonitrile for example, propionitrile, acrylonitrile), sulfoxide (for example dimethyl sulfoxide (DMSO)), alcohol ether (for example glycol monoethyl ether, ethylene glycol monoethyl ether), fat or alicyclic (n-hexane for example, cyclohexane), industrial gasoline (for example benzinum, naphtha) and petroleum cuts (paraffin for example, kerosene, light oil).
At preparation missible oil, wetting powder, during preparations such as flowable, in order to improve emulsification, dispersion, dissolving, wetting, luminous, lubricated, effects such as Zhan Zhe can adopt surfactant ((or emulsifier).Provide such surfactant below, but be not limited thereto.
Nonionic:
The polyoxyethylene alkyl ether,
The polyoxyethylene Arrcostab,
Polyoxyethylene sorbitan Arrcostab,
The sorbitan Arrcostab, etc.
Anionic:
The benzene sulfonamide acid esters,
Sulfonation succinic acid Arrcostab,
The alkyl sodium sulfate ester,
The polyoxyethylene alkyl sulfate,
Aromatic yl sulphonate, etc.
Cationic:
Alkylamine:
(for example, lauryl amine, stearyl trimethyl ammonium chloride, zephiran), the polyoxyethylene alkylamine, etc.
Amphoteric type:
Carboxylic acids (for example betaine class),
Sulfuric acid ester, etc.
Except these surfactants, also can adopt various auxiliary agents, polyvinyl alcohol for example, carboxymethyl cellulose, gum Arabic, polyvinyl acetate, gelatin, casein, Sodium Alginate, bassora gum etc.Also can add an amount of stabilizing agent, as antioxidant, UV absorbers etc.
Miticide of the present invention also can with other miticide, various insecticides (pyrethroid insectide for example, organic phosphate insecticide, carbamate pesticide, the chitin synthesis inhibitor agent), attractant, repellant, bactericide, weed killer herbicide, plant growth regulator, the use that is mixed such as fertilizer, using with like this can enlarge the acaricidal scope of application of the present invention (comprising the disease of being prevented and treated, the kind of insect, application process, spraying time).
The using method of miticide composition of the present invention is as follows: although using dosage is different with the generation quantity of mite, generally be/10 ares of 0.5～50 grams, preferably 1～10 gram is/10 ares, in the quantity of active ingredient, promptly divides the total amount of Piao Ju ester and orthen; When miticide is wetting powder or missible oil, dilute with water during use, in mite breeding period, the amount of liquid medicine that imposes on crop is 100～400 liters/10 ares.
Miticide of the present invention is for ordinary maple leaf mite, tetranychus telarius (T.Kanzawa), tangerine Panonychus citri, side are eaten the control of instep line mite etc. more, use separately with every kind of active ingredient, and reach the situation that these mites evil prevented and treated fully and compared synergistic effect, that is to say that dividing the Piao Ju ester is 100ppm or when lower at working concentration, generally is low to the preventive effect of mite class, orthen is when common working concentration scope (250-500ppm), and acaricidal activity is also low., when two components were all mixed use with the concentration that shows low acaricidal activity, this mixture had shown the unexpected high acaricidal activity to mite adult and ovum immediately, and residual activity has also obtained reinforcement.Think that this is to have strengthened the result of potential separately acaricidal activity owing to dividing Piao Ju ester and two components of orthen to act synergistically mutually.In addition, these two components also will never be owing to this using with damaged to the original excellent insecticidal activity of other insect.
To further specify the present invention by following examples, but the mixing active ingredients ratio, the kind of auxiliary agent and quantity etc. are not limited to the situation of these examples certainly.In these examples, all " part " number averages refer to weight.
Example 1 wetting powder
With 20 parts of branch Piao Ju esters, 20 parts of orthen, 5 parts of sodium alkyl benzene sulfonates, 2 parts of sodium lignin sulfonates, 5 parts of hard charcoals and 48 parts of clays mix, and grinding promptly gets wetting powder.
Example 2
With 10 parts of branch Piao Ju esters, 30 parts of orthen, 5 parts of sodium lauryl sulfates, 2 parts of sodium naphthalene sulfonate/formalin condensation products, 5 parts of hard charcoals and 48 parts of clays mix, and grind promptly to get wetting powder.
Example 3 missible oil
With 5 parts of branch Piao Ju esters, 10 parts of orthen, 5 parts of polyoxyethylene nonylplenyl ethers, 40 parts of acetonitriles and 40 parts of dimethylbenzene blend together solution, promptly get missible oil.
Use together and divide the miticide of the present invention of Piao Ju ester and orthen to show fabulous miticidal effect, this effect has never seen when using these two kinds of components separately, the mite class of being prevented and treated parasitizes fruit tree, vegetables, tea, the ordinary maple leaf mite on the tree, Tetranychus cinnabarinus are tasted in flowers and sight, tetranychus telarius (T.Kanzawa), the tangerine Panonychus citri, the elm Panonychus citri, side is shared the meal instep line mite etc.
At first, every kind of active ingredient of miticide of the present invention and independent use is compared, and parasitizes mite class on crops and the horticultural crop in control, ordinary maple leaf mite for example, and the tangerine Panonychus citri during tetranychus telarius (T.Kanzawa) etc., shows the control efficiency of synergy.In addition, the very fast appearance of preventive effect, and last till the acaricidal action that produces high synergy.As a result, in addition when being used alone effective ingredient invalid fully mite, by using with of two kinds of effective ingredients, can fully promptly prevent and treat these mite classes, and can continue segment length's time.
The second, miticide of the present invention even for tangible acaricidal action also being arranged owing to using many organic synthesis miticides to produce drug-fast mite class.
The 3rd, because miticide of the present invention just demonstrates miticidal effect under low consumption, can not influence fish and warm blooded animal, therefore, do not worry causing environmental pollution.
The 4th, miticide of the present invention is to crops, and horticultural crop does not have poisoning.
The 5th, miticide of the present invention all has killing effect to larva and adult, as mentioned above, as long as spraying once, just shows residual action, and is therefore different with conventional miticide, do not need to repeat spraying.
Because miticide of the present invention has above-mentioned characteristic, so it can be used for fruit tree, tea, vegetables, vegetable gardens such as tree are tasted in flowers and sight, as control ordinary maple leaf mite, Tetranychus cinnabarinus, tetranychus telarius (T.Kanzawa), the tangerine Panonychus citri, the elm Panonychus citri, side is eaten the effectively miticide of instep line mite etc. more.
By following test examples acaricidal effect and the purposes that present invention will be further described.
The control efficiency test of 1 pair of ordinary maple leaf mite of test examples
Put 50 ordinary maple leaf mite female adult worm in plantation on the 7-8 of the glass greenhouse cucumber plant of leaf phase, these mites are the raisings through constant generations, and organophosphorus compounds and dicofol have been produced resistance, and their are laid eggs after being moved and growing.Grow, lay eggs back three days moving, will be diluted with water to the concentration of predesignating according to the wetting powder of the present invention of example 1 preparation, and spray with 100 liters/10 ares dose with manual sprayer.Behind spray medicine eve and spray medicine 3,7,14,30 days, measure parasitic female adult worm number and poisoning situation, and calculate control rate (%).Every kind of testing liquid repeats the design of 3 sub-districts and carries out according to every sub-district 3 strain plants.The results are shown in table 1.
Control rate in the test examples (%) calculates by following equation:
Control rate (%)=(1-(Tb/Ta)/(Cb/Ca)) * 100
In the formula
Ca is in the sub-district of being untreated, the mite number before the spray medicine
Cb is in the sub-district of being untreated, the mite number behind the spray medicine
Ta is handling the sub-district, the mite number before the spray medicine
Tb is handling the sub-district, the mite number behind the spray medicine
Test examples 2
The control efficiency test of tangerine Panonychus citri
In the citrus garden of the ripe initial stage of Okitsu, observe existing a large amount of tangerine Panonychus citri harm.To be diluted with water to according to the wetting powder of the present invention of example 2 preparation and give fixed concentration, and be to spray with 300 liters/10 ares soup with power driven sprayer.At spraying eve, with spraying back 3,7,14 and 30 days, statistics parasitic female adult worm number on optional 100 blades of every tree, and observation poisoning situation drew control rate (%) thus.
Each test is by 1 tree in every sub-district, and repeat 5 sub-districts.Calculate average control rate (%) and the results are shown in table 2
Test examples 3
The control efficiency test of tetranychus telarius (T.Kanzawa)
On the tea tree of planting in the plastic basin of 15 centimetres of diameters, put 30 female tetranychus telarius adults, this adult is through continuous propagating and breeding, and organo-tin compound and dicofol are had the mite class of resistance, and adult moves and grows the back and make it lay eggs.Move grew, lay eggs three days after, will be diluted with water to the fixed concentration of giving according to the wetting powder of the present invention of example 1 preparation, and spray with 300 liters/10 ares amount of liquid medicine with power driven sprayer.Behind spray medicine eve and spray medicine 3,7,14 and 30 days, detect parasitic female adult worm number and poisoning situation, obtain control rate (%).
Each test is carried out with every sub-district 3 basins.Calculate average control (%).The results are shown in table 3.
Claims (6)
1, a kind of miticide composition, said composition contains active ingredient 2,2,3,3-Tetramethylcycloprop-ne-ne carboxylic acid alpha-cyano-3-phenoxybenzyl ester and O, S-dimethyl N-acetyl group thio-phosphamide.
When 2, the miticide composition of claim 1, said composition were made wetting powder, missible oil, liquor or flowable, it was to be 1～90%(weight that active ingredient contains).
3, the miticide composition of claim 1, said composition is made pulvis, when not having drift pulvis or granula subtilis, active constituent content is 0.5～5%(weight).
4, the miticide composition of claim 1, active constituent content was 1～10%(weight when said composition was made granule).
5, the miticide composition of claim 1, wherein 2,2,3,3-Tetramethylcycloprop-ne-ne carboxylic acid alpha-cyano-3-phenoxybenzyl ester and O, the mixing ratio of S-dimethyl N-acetyl group thio-phosphamide is 1: 1～1: 100.
6, the miticide composition of claim 5, wherein 2,2,3,3-Tetramethylcycloprop-ne-ne carboxylic acid alpha-cyano-3-phenoxybenzyl ester and O, the mixing ratio of S-dimethyl-N-acetyl group thio-phosphamide is 1: 1 to 1: 50.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP61291501A JPH0618766B2 (en) | 1986-12-09 | 1986-12-09 | Acaricide composition |
| JP291501/86 | 1986-12-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87107328A true CN87107328A (en) | 1988-06-22 |
| CN1020659C CN1020659C (en) | 1993-05-19 |
Family
ID=17769698
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87107328A Expired - Fee Related CN1020659C (en) | 1986-12-09 | 1987-12-09 | Acaricidal composition |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPH0618766B2 (en) |
| KR (1) | KR950009523B1 (en) |
| CN (1) | CN1020659C (en) |
| MY (1) | MY102265A (en) |
| PH (1) | PH23862A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2813993B2 (en) * | 1989-10-06 | 1998-10-22 | 株式会社トモノアグリカ | Acaricide composition |
-
1986
- 1986-12-09 JP JP61291501A patent/JPH0618766B2/en not_active Expired - Lifetime
-
1987
- 1987-12-08 MY MYPI87003166A patent/MY102265A/en unknown
- 1987-12-09 KR KR1019870014030A patent/KR950009523B1/en not_active IP Right Cessation
- 1987-12-09 CN CN87107328A patent/CN1020659C/en not_active Expired - Fee Related
- 1987-12-09 PH PH36192A patent/PH23862A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| KR950009523B1 (en) | 1995-08-23 |
| JPH0618766B2 (en) | 1994-03-16 |
| JPS63145206A (en) | 1988-06-17 |
| PH23862A (en) | 1989-11-23 |
| KR880006986A (en) | 1988-08-26 |
| CN1020659C (en) | 1993-05-19 |
| MY102265A (en) | 1992-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20110229589A1 (en) | Insect and plant disease control compositions and methods of use thereof | |
| TW529906B (en) | Method for protecting surfaces from arthropod infestation | |
| CN1111477A (en) | Synergistic composition | |
| US20070287631A1 (en) | Agricultural or Horticultural Additive | |
| JP2018530602A (en) | Pyrethrin-rich insecticide | |
| Alzoubi et al. | Effects of sublethal dose of different pesticides on the two-spotted spider mite" Tetranychus urticae Koch" and its predatory mites under greenhouse conditions | |
| CN1221173C (en) | Pesticidal composition | |
| CN104904741B (en) | A kind of Pesticidal combination and the method for controlling harmful organism | |
| CN1020659C (en) | Acaricidal composition | |
| WO2011151766A2 (en) | Insect and plant disease control compositions and methods of use thereof | |
| KR100985669B1 (en) | Insecticide composition | |
| CN103749521B (en) | A kind of Pesticidal combination | |
| CN104904719B (en) | A kind of Pesticidal combination and its method for controlling harmful organism | |
| CN1033356C (en) | Acaricidal composition | |
| CN105475346B (en) | A kind of Pesticidal combination | |
| CN104904742A (en) | Insect disinfestation composition and pest control method | |
| CN108782573A (en) | The miticide composition and its application of D- limonenes and rotenone | |
| RU2150829C1 (en) | Insecticide-acaricide preparation | |
| CN116035019A (en) | Pesticide composition of paichongding and preparation method thereof | |
| CN1918997A (en) | Complex miticide composition | |
| CN1274532A (en) | Tar-acetic acid composite emulsion as multipurpose pesticide | |
| CN105432656B (en) | A kind of Pesticidal combination | |
| JP2832538B2 (en) | Acaricidal composition | |
| CN105557721B (en) | A kind of Pesticidal combination | |
| JPS59219206A (en) | Novel composition showing synergistic activity as agricultural insecticide, repellent and tickicide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| C15 | Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993) | ||
| C19 | Lapse of patent right due to non-payment of the annual fee |