CN87102224A - 利用逸出石油气进行深孔三元采油的方法 - Google Patents
利用逸出石油气进行深孔三元采油的方法 Download PDFInfo
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- CN87102224A CN87102224A CN87102224.9A CN87102224A CN87102224A CN 87102224 A CN87102224 A CN 87102224A CN 87102224 A CN87102224 A CN 87102224A CN 87102224 A CN87102224 A CN 87102224A
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- 238000000034 method Methods 0.000 title abstract description 11
- 239000007789 gas Substances 0.000 claims abstract description 31
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000010438 heat treatment Methods 0.000 claims abstract description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000001257 hydrogen Substances 0.000 claims abstract description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 4
- 239000002918 waste heat Substances 0.000 claims abstract description 3
- 239000000203 mixture Substances 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- 238000011084 recovery Methods 0.000 claims description 3
- 238000005336 cracking Methods 0.000 claims description 2
- 238000005553 drilling Methods 0.000 claims description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 6
- 239000002737 fuel gas Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000002485 combustion reaction Methods 0.000 description 4
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000001307 helium Substances 0.000 description 2
- 229910052734 helium Inorganic materials 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 238000013022 venting Methods 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 150000002371 helium Chemical class 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000003129 oil well Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/32—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air
- C01B3/34—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of gaseous or liquid organic compounds with gasifying agents, e.g. water, carbon dioxide, air by reaction of hydrocarbons with gasifying agents
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/16—Enhanced recovery methods for obtaining hydrocarbons
- E21B43/24—Enhanced recovery methods for obtaining hydrocarbons using heat, e.g. steam injection
-
- E—FIXED CONSTRUCTIONS
- E21—EARTH OR ROCK DRILLING; MINING
- E21B—EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- E21B43/00—Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells
- E21B43/34—Arrangements for separating materials produced by the well
- E21B43/40—Separation associated with re-injection of separated materials
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Geology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Mining & Mineral Resources (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Physics & Mathematics (AREA)
- Environmental & Geological Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Fluid Mechanics (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Industrial Gases (AREA)
Abstract
本发明涉及利用逸出的石油气进行三元采油的方法，对于邻近油田的炼油厂将会有特殊的意义。用已知方法引入热水或蒸汽所采的石油还含有所谓的石油气，其中大部分是由甲烷和其他可燃气体组成。按本发明，这种气体可用一个由高温反应器加热的转化炉转化为氢，并用该反应器的余热生产蒸汽。
Description
本发明涉及利用逸出的石油气进行三元采油（die tertiaeren Oelgewinnung）的方法。对于邻近油田的炼油厂来说，本发明具有特殊的意义。
众所周知，按常规方法用深井泵采尽的油田经引入蒸汽或热水后可以进一步再利用，其主要原因是温度的升高使存在地下的石油的粘滞度降低，而且还用水来取代油。根据该方法，在已经用一般方法采尽的油田里，除了可采得所需石油外，还释放出含烃的气体，这些气体至今为止都是采取放气烧掉或通过燃烧来获得热量。仅仅为了将蒸汽引入已经开采过的油田而生产蒸汽，耗资耗能都极其可观。烧去颇有价值的原料仅仅用于生产只能用一次的蒸汽，从国民经济观点以及从环境保护考虑，都是不适宜的，而且技术上也有问题。
本发明的任务在于通过合理地三元采油和将逸出的石油气用作宝贵的原料，从而避免上述缺点。
解决这项任务的方法是：采用将蒸汽引入油井并排放和分离所得的油-气-水混合物的方法来进行油井采油，其特征为用由高温反应器加热的转化炉将分离得到的气体转化为氢并用高温反应器的余热产生蒸汽，其部份蒸汽用于汽轮机发电，部份蒸汽用于三元采油，部份蒸汽供给转化炉。气体冷却的高温反应器，如同1986年3月“原子能经济”（“Atomwirtschaft”）第157～159页上所介绍的模拟反应堆一样，也有过程加热所具有的温度可供使用，它足以使甲烷转化。此时脱离转化炉的反应器冷却气体的温度还很高，能够产生高压和相应温度的水蒸汽，它正是三元采油所需要的。在这种情况下，用高温反应器的核反应产生的蒸汽并不是用上限温度，而核反应的气体裂化并不能用在下限温度范围所产生的热量。这两者如此不同的方法的结合在经济上是非常有利的，从整体来看是可观的。通过燃烧一部分石油气去转化另一部分石油气，这种利用石油气的热法首先是非常可理解的，但这不仅从国民经济观点而且从环境保护角度来看，都是不适宜的，何况还存在技术上的问题。通过直接燃烧石油气来加热转化炉时，由于含硫物的腐蚀，所以是不可实施的。实施本发明所需的石油气脱硫难免也需要增加特殊的费用，这些费用对于生产仅作为燃烧的气体而言虽属不合理，但对随后的气体的利用而言则是合理的，因为脱硫过的石油气是非常宝贵的产物。根据模拟原理，本文优先建议的气体冷却高温反应器的另一个优点是可用性高。当带有钢锭状燃烧元件的气体冷却高温反应器和带有正常距离的燃烧棒的压水反应器更换燃烧元件时，必须停止仪器的运转。模拟反应堆在连续运转时，可从下面取出燃烧元件，从上面加入燃烧元件，所以可以长期运转。这种观点对于油田和炼油厂的连续运转具有特殊的意义。
附图是以图解式说明的流程图。
在有大量深井钻孔的油田1中插有蒸汽管2，与其相邻的出口管3将石油、水和溶于油中的气体的混合物向上输至气体分离器4，再由气体分离器4将石油和水的混合物引向水分离器5，气体引向脱硫器6和分离器23，经预热器7与水蒸汽一起进入转化炉8。在供热的条件下，转化炉所转化的气体先进入预热器7，接着在蒸汽发生器9中冷却;在转换器10中，气体中所含CO与水蒸汽转化为CO2和氢;从转换器10中排放出来的气体混合物在洗涤器11中与CO2分离并在低温气体分离器12中与甲烷和其他含烃气体分离，这些含烃气体又重新供作脱硫器6后的气 流。转化炉8所需高温热量由气体冷却的高温反应器13经过一个封闭的氦循环14的热量供应，该氦循环14在转化炉8的出口还可加热蒸汽发生器15并由鼓风机16又再引向反应器13。在蒸汽发生器15中加热的蒸汽可以直接通过蒸汽管2加热油田，比较适宜的是中间连接一个换热器17，使对水质要求很高的仪器部件都能很好地接受处理过的净化水，而对水质要求较低的引入油田的蒸汽则可用供水泵18取自净水装置19，该净水装置19又利用从水分离器5排出的水。按需要的量、压力和温度，本方法所需蒸汽量部份直接取自蒸汽发生器9和15或根据汽轮机20的工作效率而定。21是放气22（不是循环供应）的备用供给装置。
在分离器23中分离高级碳氢化合物（C4以上），供作特殊的用处。
Claims (1)
1、将蒸汽引入深井钻孔，排放和分离逸出的油-气-水混合物，其特征在于用由高温反应器(13)加热的裂化炉(8)将气体转化为氢并用高温反应器(13)的余热产生蒸汽，其中部份蒸汽用于汽轮机(20)发电，部份蒸汽用于三元采油，部份蒸汽供给转化炉(8)。
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19863609253 DE3609253A1 (de) | 1986-03-19 | 1986-03-19 | Verfahren zur tertiaeren oelgewinnung aus tiefbohrloechern mit verwertung des austretenden erdoelgases |
| DEP2609253.3 | 1986-03-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87102224A true CN87102224A (zh) | 1987-09-30 |
| CN1007280B CN1007280B (zh) | 1990-03-21 |
Family
ID=6296769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87102224A Expired CN1007280B (zh) | 1986-03-19 | 1987-03-19 | 利用逸出石油气进行深孔三元采油的方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US4930574A (zh) |
| EP (1) | EP0298965B1 (zh) |
| JP (1) | JPH01501877A (zh) |
| CN (1) | CN1007280B (zh) |
| CA (1) | CA1278511C (zh) |
| DE (2) | DE3609253A1 (zh) |
| MX (1) | MX168462B (zh) |
| SU (1) | SU1729300A3 (zh) |
| WO (1) | WO1987005658A1 (zh) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103573405A (zh) * | 2012-08-01 | 2014-02-12 | 张吉林 | 注空气采油废气燃烧发电工艺 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5335728A (en) * | 1992-07-31 | 1994-08-09 | Strahan Ronald L | Method and apparatus for disposing of water at gas wells |
| US6273897B1 (en) | 2000-02-29 | 2001-08-14 | Ethicon, Inc. | Surgical bettress and surgical stapling apparatus |
| US20070062704A1 (en) * | 2005-09-21 | 2007-03-22 | Smith David R | Method and system for enhancing hydrocarbon production from a hydrocarbon well |
| CA2643214C (en) * | 2006-02-24 | 2016-04-12 | Shale And Sands Oil Recovery Llc | Method and system for extraction of hydrocarbons from oil sands |
| EP2010755A4 (en) | 2006-04-21 | 2016-02-24 | Shell Int Research | HEATING SEQUENCE OF MULTIPLE LAYERS IN A FORMATION CONTAINING HYDROCARBONS |
| GB0612092D0 (en) * | 2006-06-20 | 2006-07-26 | Johnson Matthey Plc | Oxygen removal |
| RU2460871C2 (ru) * | 2006-10-20 | 2012-09-10 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. | СПОСОБ ТЕРМИЧЕСКОЙ ОБРАБОТКИ in situ С ИСПОЛЬЗОВАНИЕМ НАГРЕВАТЕЛЬНОЙ СИСТЕМЫ С ЗАМКНУТЫМ КОНТУРОМ |
| WO2010030263A1 (en) * | 2008-09-15 | 2010-03-18 | Denyse Claire Dubrucq | Harvesting hydrocarbons from coal, shale, peat and landfill seams |
| US9062525B2 (en) * | 2011-07-07 | 2015-06-23 | Single Buoy Moorings, Inc. | Offshore heavy oil production |
| RU190546U1 (ru) * | 2019-03-29 | 2019-07-03 | Оксана Викторовна Давыдова | Утилизирующая попутный нефтяной газ энергетическая установка для выработки пара, подаваемого в нагнетательные скважины |
| CN114215601B (zh) * | 2021-12-31 | 2024-01-26 | 北京派创石油技术服务有限公司 | 利用废弃油井制造氢气的方法 |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3237692A (en) * | 1963-02-28 | 1966-03-01 | Shell Oil Co | Use of low-grade steam containing dissolved salts in an oil production method |
| US3237689A (en) * | 1963-04-29 | 1966-03-01 | Clarence I Justheim | Distillation of underground deposits of solid carbonaceous materials in situ |
| US3493050A (en) * | 1967-01-30 | 1970-02-03 | Kork Kelley | Method and apparatus for removing water and the like from gas wells |
| US3844349A (en) * | 1973-01-26 | 1974-10-29 | Mobil Oil Corp | Petroleum production by steam injection |
| US3881550A (en) * | 1973-05-24 | 1975-05-06 | Parsons Co Ralph M | In situ recovery of hydrocarbons from tar sands |
| US4007786A (en) * | 1975-07-28 | 1977-02-15 | Texaco Inc. | Secondary recovery of oil by steam stimulation plus the production of electrical energy and mechanical power |
| US4098339A (en) * | 1976-06-21 | 1978-07-04 | Mobil Oil Corporation | Utilization of low BTU natural gas |
| US4043393A (en) * | 1976-07-29 | 1977-08-23 | Fisher Sidney T | Extraction from underground coal deposits |
| DE2724833A1 (de) * | 1977-06-02 | 1979-03-01 | Ght Hochtemperaturreak Tech | Kohlevergasung mit kernenergie |
| US4171017A (en) * | 1978-03-30 | 1979-10-16 | Institute Of Gas Technology | Method of gas production from geopressurized geothermal brines |
-
1986
- 1986-03-19 DE DE19863609253 patent/DE3609253A1/de not_active Withdrawn
-
1987
- 1987-03-02 DE DE8787901373T patent/DE3769146D1/de not_active Expired - Fee Related
- 1987-03-02 JP JP62502120A patent/JPH01501877A/ja active Pending
- 1987-03-02 US US07/273,817 patent/US4930574A/en not_active Expired - Fee Related
- 1987-03-02 EP EP87901373A patent/EP0298965B1/de not_active Expired - Lifetime
- 1987-03-02 WO PCT/DE1987/000086 patent/WO1987005658A1/de active IP Right Grant
- 1987-03-17 CA CA000532189A patent/CA1278511C/en not_active Expired - Fee Related
- 1987-03-19 MX MX005624A patent/MX168462B/es unknown
- 1987-03-19 CN CN87102224A patent/CN1007280B/zh not_active Expired
-
1988
- 1988-09-16 SU SU884356451A patent/SU1729300A3/ru active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103573405A (zh) * | 2012-08-01 | 2014-02-12 | 张吉林 | 注空气采油废气燃烧发电工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA1278511C (en) | 1991-01-02 |
| WO1987005658A1 (en) | 1987-09-24 |
| JPH01501877A (ja) | 1989-06-29 |
| DE3609253A1 (de) | 1987-09-24 |
| MX168462B (es) | 1993-05-26 |
| EP0298965A1 (de) | 1989-01-18 |
| US4930574A (en) | 1990-06-05 |
| CN1007280B (zh) | 1990-03-21 |
| DE3769146D1 (de) | 1991-05-08 |
| SU1729300A3 (ru) | 1992-04-23 |
| EP0298965B1 (de) | 1991-04-03 |
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