CN87100231B - The method for making fibre with antibiotic and anti-stink - Google Patents
The method for making fibre with antibiotic and anti-stink Download PDFInfo
- Publication number
- CN87100231B CN87100231B CN87100231A CN87100231A CN87100231B CN 87100231 B CN87100231 B CN 87100231B CN 87100231 A CN87100231 A CN 87100231A CN 87100231 A CN87100231 A CN 87100231A CN 87100231 B CN87100231 B CN 87100231B
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- China
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- fabric
- fibre fabric
- bacilli
- fiber
- antibiotic
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Abstract
The present invention relates to an antiseptic deodorant fibre fabric and a preparation method thereof, which belongs to modification for orlon. The fibre fabric is obtained by that orlon is chemically treated into a composite fibre combining copper ions and amine-group compounds. The fibre fabric has high temperature resistance, wash resistance, no toxicity, no stimulation and no allergic reaction to people, and safe application to the skin; the fibre fabric also has antiseptic effect on staphylococcus aureus (penicillin sensitive strains), staphylococcus (resistant organisms), staphylococcus albus, monilia albicans, hay bacilli, colibacilli, pseudomonas aeruginosa, dysentery bacilli, bacilli enteritidis and bacilli typhi. The fibre fabric can be applied to antiseptic deodorant underwear, socks, insoles, uppers, sanitary articles for women, and working clothes for pharmaceutical industry, food industry, catering trade, hospitals and kindergartens.
Description
The present invention is a kind of antibiotic deodorant fabric and manufacturing technique thereof, belongs to fiber is carried out modification processing and Application Areas.
On the used textiles of people's daily life, all speckle with many microorganisms.Under suitable condition, they are breeding rapidly, produces mycelia and forms mildew, and the sanitation performance of used for textiles is worsened.Underwear, socks, shoe-pad etc. are in the process of taking, and with suitable microbial growth of temperature formation, breeding and the corrupt condition of sweat and skin, the result can produce stench; Though the medical fabric after high-temperature sterilization is aseptic, bacterium on the in use very fast meeting propagated sensation.Therefore, all begin both at home and abroad to have paid attention to research to the antibacterial textile deodorization.
According to Japan " process technology " Vol17, No.7 report, handle acrylic fiber with cupric salt and sulfur-containing compound and can stop the growth of staphylococcus aureus and hay bacillus, have the antibiotic effect of deodorization, also there is similar report to come out later on.Yet the antibacterial effect of this acrylic fibers-copper sulfide compound only limits to that staphylococcus aureus, hay bacillus, Escherichia coli, the thread tinea alba bacterium of skin etc. are had better sterilizing ability for four kinds.
The objective of the invention is to propose a kind of antibacterial range and expand antibiotic odourproof fiber and manufacturing technique to ten bacterial classifications such as staphylococcus aureus (blue or green quick), staphylococcus aureus (resistance), staphylococcus albus, Candida albicans, hay bacillus, Escherichia coli, Pseudomonas aeruginosa, shigella dysenteriae, bacillus enteritidis, typhoid bacilluses.And be applied to socks, shoe-pad, upper of a shoe liner, backing etc.
Technical essential of the present invention is: connect copper ion and Viride Nitens 4C simultaneously by chemical reaction on acrylic fiber
23H
25N
+ 2Group makes fibre modification
Wherein the compound of copper ion and acrylic fibers is (CN) to realize by the cyano group in the acrylic fibers.Reaction equation:
C
23H
25N
+ 2Be with acrylic fiber in the 3rd monomer in alkene sodium sulfonate or itaconic acid list sodium salt compound.Reaction equation:
Structure behind the fiber by modification of acrylics is:
Owing on acrylic fibers, connect copper ion and C simultaneously
23H
25N
+ 2Group shows synergy to killing and wounding of bacterium, has improved antibacterial ability, thereby makes original modifying orlon for having the antibacterial deodourizing effect, and makes antibacterial range expansion.
Manufacturing technique of the present invention is:
Prescription: acrylic fibers: copper sulphate: sodium thiosulfate: Viride Nitens 4 dyestuffs=1: (0.05～0.5): (0.01～0.1): (0.001～0.01)
Method: by the aqueous solution of above-mentioned formulated copper sulphate and sodium thiosulfate, acrylic fiber is put into earlier, control bath raio 1: (50～200), temperature remain on 40～80 ℃.0.5 after～1 hour fiber or fabric are taken out, clean, and then add Viride Nitens 4, and with pH regulator 3～4,60～100 ℃ of temperature after 0.5～1 hour, are cleaned, are dried.
The present invention is widely used, and can be used to make shoe-pad, socks, interior outerwear trousers and the bedding of antibacterial deodourizing, also can be used to weave antibiotic interior decoration fabric, carpet.
Compare prior art, the present invention has following advantage:
1, antibacterial range expands to staphylococcus aureus (blue or green quick), staphylococcus aureus (resistance), staphylococcus albus, Candida albicans, hay bacillus, Escherichia coli, Pseudomonas aeruginosa, shigella dysenteriae, bacillus enteritidis, typhoid bacillus etc.(seeing attached list 1)
2, antibiotic speed is fast, in 30 minutes effect can take place.
3, after measured, the present invention is to human body avirulence, non-stimulated, nothing allergy.
4, in addition, washability of the present invention is good, through 60 washings, and positive and negative 1000 frictions, antibacterial effect does not still subtract, and can anti-130 ℃ of high temperature, and cost is low.
5. the present invention not only can be used for people's dress, food industry, also can even do not adopt other medical procedure, can make wound quicken intact healing as the shallow table wound dressing of slight wound in medical treatment, and repeatedly clinic trial has shown this point.
Below the invention will be further elaborated by four examples:
Example 1:
1 gram acrylic fiber (39 bifilar) is placed on 100 milliliters and contains in 0.2 gram copper sulphate and the 0.1 gram sodium thiosulfate solution; bath raio 1: 100～200; be warmed up to 70～80 ℃; be incubated 1 hour; thoroughly clean the back and add 0.15% Viride Nitens 4, add HOAc and regulate pH3～4,70～80 ℃ of temperature; be incubated 1 hour are cleaned and dried.
Example 2:
1 gram acrylic fibers cloth is placed on 50 milliliters and contains in 0.2 copper sulphate, 0.1 gram sodium thiosulfate and the 0.01 gram sodium-chloride water solution; bath raio 1: 50～100; 70～80 ℃ of insulations 1 hour heat up; after thoroughly cleaning, add 0.15% Viride Nitens 4, add HOAc; regulate pH3～4; 70～80 ℃ of temperature, be incubated 1 hour, clean and dry.
Example 3:
1 gram 40% nitrile-cotton blended fiber (39 bifilar) is placed on 100 milliliters and contains in 0.1 gram copper sulphate and the 0.05 gram sodium thiosulfate solution; bath raio 1: 100～200 heats up 60～70 ℃; be incubated 1 hour; after thoroughly cleaning, add 0.1% Viride Nitens 4, add HOAc; make pH3～4; 60～70 ℃ of temperature, be incubated 1 hour, clean and dry.
Example 4:
1 gram 40% nitrile-cotton blended cloth, be placed on 50 milliliters and contain 0.1 gram copper sulphate, 0.05 in gram sodium thiosulfate and the 0.01 gram sodium-chloride water solution, bath raio 1: 50～100 heats up 60～70 ℃, be incubated 1 hour, clean the back and add 0.1% Viride Nitens 4, adding HOAc, to make pH be 3～4,60～70 ℃ of temperature, be incubated 1 hour, clean and dry.
Japan's SS-N Sang Telun antibiotic fabric and the present invention's contrast
Claims (10)
1, a kind of antibiotic deodorant fabric, base are characterised in that it is a complex copper ion on the first monomer acrylonitrile of acrylic fiber, compound C on the 3rd monomer itaconic acid or sodium allylsulfonate
23H
25N
+ 2Group, structural formula is:
2, by the manufacture method of the described antibiotic deodorant fabric of claim 1, it is characterized in that the acrylic fiber fabric is put into the solution that fills copper sulphate, sodium thiosulfate, temperature is 40～60 ℃.
3, by the manufacture method of the described antibiotic deodorant fabric of claim 2, it is characterized in that the fabric after handling through the first step is put into the solution that fills Viride Nitens 4 again, temperature is 80～100 ℃.
4, by the manufacture method of the described antibiotic deodorant fabric of claim 2, it is characterized in that it is by acrylic fiber: copper sulphate: sodium thiosulfate: Viride Nitens 4 dyestuffs=1: (0.05～0.5): (0.01～0.1): (0.001～0.01) prescription.
5, the shoe-pad of being made of the described antibiotic odourproof fiber of claim 1.
6, the socks of being made of the described antibiotic odourproof fiber of claim 1.
7, the interior outerwear trousers of being made of the described antibacterial deodourizing fabric of claim 1.
8, the bed of being made of the described antibacterial deodourizing fabric of claim 1 is gone up fabric.
9, the interior decoration fabric of being made of the described antibiotic odourproof fiber of claim 1.
10, the carpet of being knitted with the described antibiotic odourproof fiber of claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87100231A CN87100231B (en) | 1987-02-17 | 1987-02-17 | The method for making fibre with antibiotic and anti-stink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN87100231A CN87100231B (en) | 1987-02-17 | 1987-02-17 | The method for making fibre with antibiotic and anti-stink |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN87100231A CN87100231A (en) | 1987-11-18 |
| CN87100231B true CN87100231B (en) | 1987-12-16 |
Family
ID=4812774
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN87100231A Expired CN87100231B (en) | 1987-02-17 | 1987-02-17 | The method for making fibre with antibiotic and anti-stink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN87100231B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7179530B2 (en) | 2001-12-03 | 2007-02-20 | Rebac Gmbh | Antimicrobial composite material |
| CN1329584C (en) * | 2000-04-24 | 2007-08-01 | 韦尔豪泽公司 | Method for producing cellulose fiber having improved biostability |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057807C (en) * | 1996-08-29 | 2000-10-25 | 舒军 | Prodn process of physically antiseptic non-woven fabric |
| CN1102183C (en) * | 2000-06-05 | 2003-02-26 | 上海兰格科技发展有限公司 | Textile with mite-killing and anti-biotic function and its producing method |
| CN104257008A (en) * | 2014-10-21 | 2015-01-07 | 常熟市任阳工艺鞋厂 | Novel antibacterial shoe-pad |
| CN104963191B (en) * | 2015-07-22 | 2016-04-20 | 湖南莎丽袜业股份有限公司 | Two step method prepares copper ion fiber and socks |
| US9956123B2 (en) * | 2016-03-02 | 2018-05-01 | Alphal Engineering Technology Group, Inc. | Anti-microbial balanced weave wearable undergarment and process therefore |
-
1987
- 1987-02-17 CN CN87100231A patent/CN87100231B/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1329584C (en) * | 2000-04-24 | 2007-08-01 | 韦尔豪泽公司 | Method for producing cellulose fiber having improved biostability |
| US7179530B2 (en) | 2001-12-03 | 2007-02-20 | Rebac Gmbh | Antimicrobial composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN87100231A (en) | 1987-11-18 |
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