CN86104010A - Colouring of natural marble and products thereof - Google Patents
Colouring of natural marble and products thereof Download PDFInfo
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- CN86104010A CN86104010A CN86104010.4A CN86104010A CN86104010A CN 86104010 A CN86104010 A CN 86104010A CN 86104010 A CN86104010 A CN 86104010A CN 86104010 A CN86104010 A CN 86104010A
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- natural marble
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Abstract
The present invention is colouring of natural marble and products thereof.A kind of preparation method that belongs to extraordinary pattern in the decorative art field or picture.
But invention is to select the solution of photoactive substance to be impregnated in the micropore of natural marble by itself and reducing agent, and chemical reaction takes place therein.Thereby obtain the atrament of not oxidation by air under stable, water insoluble, the normal temperature.This material does not corrode the natural marble matrix, and the painted depth is adjustable, and painted thickness can be controlled.Therefore, can be the natural marble deep processing senior building ornament or other art work.As natural marble mural painting, upright stone tablet, plaque etc.
Description
The present invention is colouring of natural marble and products thereof.A kind of preparation method that belongs to extraordinary pattern in the decorative art field or picture.
At present, two kinds of methods are arranged when making building and ornament materials or other art work with marble, the one, abandon with the natural vein of natural marble and to gather; The one, intend natural marble figue as the artificial emmarble face mould of usefulness as described in U.S. Patent number 3341396 documents and make.Abandon with the natural vein of natural marble and to gather predetermined pattern, the time-consuming material that takes, very uneconomical.The artificial marble decorative cover can only be simulated simple natural marble figue, and makes complicated.Want with above-mentioned two kinds of methods abandon exactly gather or make complicated layout, expert of calligraphy and painting's works are impossible.
Task of the present invention is to seek a kind of chemical method, for natural marble black.Can remedy the deficiency of apolegamy natural marble natural vein like this.For example select for use the natural marble plate to do the indoor decoration mural painting, when the natural marble plate each other joining place abandon and gather the black decorative pattern and make it continuously very at need, just can be that natural marble plate part is painted with method of the present invention, natural vein with the simulation natural marble, keep whole wall decorative pattern continuous, harmony reaches the requirement on attractive in appearance.Can be that natural marble black with method of the present invention perhaps at all.Various layouts, expert of calligraphy and painting's works are produced on the natural marble surface, do the flawless finish handicraft or the art work on architectural or other industry, as natural marble mural painting, upright stone tablet, plaque etc.So just, can be transformed into senior building art or other art work to natural marble by being used for the common building ornament materials, its economic benefit increases greatly.
Selected painted chemical substance is wanted can infiltrate, be diffused in the micropore of natural marble, and chemical reaction can take place therein.Chemical reaction product, promptly coloring material must be can oxidation by air under stable, water insoluble, the normal temperature, more can not corrode the natural marble matrix.Dyed layer thickness can be controlled, and the painted depth is adjustable.
For solving this task, but select the solution of photoactive substance for use, with finger or other instrument, as things such as pen, brush dip in this solution by the requirement coated of layout or painting and calligraphy through shaped natural marble surface.Allow it to the infiltration of natural marble internal capillary, diffusion.The quality difference of natural marble, solution is to the speed difference of its internal capillary infiltration, diffusion; Solution is longer to the time of the infiltration of natural marble internal capillary, diffusion, and natural marble surface colour layer is thicker; Solution is denseer, and the natural marble surface colour is darker.Wait to reach the infiltration layer thickness of pre-provisioning request, the remaining solution in natural marble surface is sopped up with blotting paper.Then, but in the natural marble surface that scribbles photoactive substance solution coated reducing agent again, as organic reducing agent aldehydes, alcohols etc.Reductant solution is to natural marble internal capillary infiltration, diffusion, but and with the solution generation chemical reaction of photoactive substance, colored particles is separated out, and retains in the micropore of natural marble.Water is rinsed the natural marble colored surface well and it is moved to sensitization under the high light, but promptly develops the color at the position of solution that scribbles photoactive substance and reducing agent.
Certainly, the present invention also can be applicable to other stone material, pottery, brick, cement products etc.
But be that example specifies method of the present invention with silver salt solution in the photoactive substance solution below.
Select the liquor argenti nitratis ophthalmicus of two equivalents for use, at normal temperatures, be processed on the marmorean polishing plate face of Snow Flower White that is of a size of 300mm * 300mm * 20mm (long * wide * thick), dip in this solution handwriting with writing brush, allow the solution freedom to about one hour of the infiltration of Snow Flower White marble internal capillary, diffusion, the thickness of diffusion layer can reach about 1.5mm.Then, sop up the residual liquid of marble surface with blotting paper.The reducing agent of selecting for use in this example is the formalin in the organic reducing agent.For reaching the reduction purpose better, formaldehyde is alkalized with NaOH.The weight ratio of three kinds of compositions is in NaOH, formaldehyde, the water mixed liquid: NaOH accounts for 10～15%; Formaldehyde accounts for 25～30%; Water accounts for 55～65%.Dip in this solution with writing brush and write former writing again one time, allow this solution freely infiltrate, to spread to Snow Flower White marble internal capillary at the Snow Flower White marble surface place with two equivalent liquor argenti nitratis ophthalmicus handwritings.Chemical reaction takes place in this solution and liquor argenti nitratis ophthalmicus in the marmorean micropore of Snow Flower White, reaction equation is as follows:
Subsequently, abundant reaction in Snow Flower White marble internal capillary finishes when formaldehyde and silver nitrate, and silver particles is separated out, and retains among the marble internal capillary.Water is rinsed the marble surface residue well, dries, and it is moved under the sunlight, and blackness handwriting promptly shows.
By above-mentioned same quadrat method, can make the pattern or the simulation natural marble figue of various artificial designs directly at natural marble surface drawing.
Claims (7)
1, a kind of colouring of natural marble.Natural marble can be made into different shape through processing, and surface grinding is characterized in that:
(1) but the solution of photoactive substance is coated in the natural marble surface of polishing;
(2) but in the natural marble surface that scribbles photoactive substance solution coated reducing agent again.
2, press the method for claim 1, but it is characterized in that the solution of photoactive substance is a kind of silver salt solution.
3, by the method for claim 1, it is characterized in that reducing agent is a kind of organic reducing agent.
4, press the method for claim 1-3, but it is characterized in that the silver salt solution of photoactive substance is a liquor argenti nitratis ophthalmicus, reducing agent is a formaldehyde.
5, the painted natural marble of producing by the method for claim 1 is characterized in that the dyed layer thickness of natural marble can be controlled.
6, the painted natural marble of producing by the method for claim 1 is characterized in that the painted depth of natural marble is adjustable.
7, the painted natural marble of producing by the method for claim 1, it is characterized in that its surface colour formed can be the various patterns or the natural marble figue of writing, picture or artificial design.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86104010A CN1006619B (en) | 1986-06-16 | 1986-06-16 | Colouring of natural marble and its product |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN86104010A CN1006619B (en) | 1986-06-16 | 1986-06-16 | Colouring of natural marble and its product |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86104010A true CN86104010A (en) | 1987-12-30 |
| CN1006619B CN1006619B (en) | 1990-01-31 |
Family
ID=4802283
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86104010A Expired CN1006619B (en) | 1986-06-16 | 1986-06-16 | Colouring of natural marble and its product |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1006619B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2782025A1 (en) * | 1998-08-07 | 2000-02-11 | Edmonde Goulesque | Process for the in-depth coloration of a hard rock substrate, such as granite, comprises the application of a saturated silver nitrate solution containing a dye and color development by exposure to UV radiation |
| CN105383197A (en) * | 2015-10-12 | 2016-03-09 | 佛山市蓝海石英石材有限公司 | Printing method for quartz stone |
-
1986
- 1986-06-16 CN CN86104010A patent/CN1006619B/en not_active Expired
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2782025A1 (en) * | 1998-08-07 | 2000-02-11 | Edmonde Goulesque | Process for the in-depth coloration of a hard rock substrate, such as granite, comprises the application of a saturated silver nitrate solution containing a dye and color development by exposure to UV radiation |
| CN105383197A (en) * | 2015-10-12 | 2016-03-09 | 佛山市蓝海石英石材有限公司 | Printing method for quartz stone |
| CN105383197B (en) * | 2015-10-12 | 2018-11-02 | 佛山市蓝海石英石材有限公司 | A kind of printing process of quartz |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1006619B (en) | 1990-01-31 |
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| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| C14 | Grant of patent or utility model | ||
| C19 | Lapse of patent right due to non-payment of the annual fee |