CN86101965A - Process for making non-radioactive luminous colored glaze - Google Patents

Process for making non-radioactive luminous colored glaze Download PDF

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Publication number
CN86101965A
CN86101965A CN 86101965 CN86101965A CN86101965A CN 86101965 A CN86101965 A CN 86101965A CN 86101965 CN86101965 CN 86101965 CN 86101965 A CN86101965 A CN 86101965A CN 86101965 A CN86101965 A CN 86101965A
Authority
CN
China
Prior art keywords
glaze
luminous
night
ceramic glaze
ceramic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 86101965
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Chinese (zh)
Inventor
李绍荣
张金铎
杨平
张有生
李兆臣
冯敏
陆杰
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
YINGKOU FLUORESCENT MATERIALS FACTORY
Original Assignee
YINGKOU FLUORESCENT MATERIALS FACTORY
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by YINGKOU FLUORESCENT MATERIALS FACTORY filed Critical YINGKOU FLUORESCENT MATERIALS FACTORY
Priority to CN 86101965 priority Critical patent/CN86101965A/en
Publication of CN86101965A publication Critical patent/CN86101965A/en
Pending legal-status Critical Current

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Abstract

The present invention is manufacturing technology, performance and the application thereof of non-radioactive luminous colored ceramic glaze.
The low-temperature glaze of forming with regulation with the zinc of mixing rare earth, cadmium or alkaline earth sulfide luminescent powder mixes, and through the luminous ceramic glaze of 700～850 ℃ of manufacturings, is that the photochromic bonded new ceramics of ideal is decorated and the night-mark(ing) material.
The pottery made from luminous glaze, except that having general ceramic glaze performance, still have "dead", send out characteristics such as colorama, brightness height, time of persistence be long.In the dark or send night colored gorgeous photochromicly, twilight sunset keeps being used for industry, daily and craft artistic pottery and porcelain more than two hours after visible light or uviolizing.

Description

Process for making non-radioactive luminous colored glaze
The invention relates to the manufacturing technology of "dead" luminous ceramic glaze, characteristic and other application.
The used luminescent powder of the present invention is for mixing rare earth material Er +++: Ga +++With with Cu ++(copper) activated sulfide luminescent material stores energy absorption under visible light, uviolizing, stop irradiation after, discharge with the form of light.In the dark or send colorama night, twilight sunset keeps more than two hours.
The used ceramic glaze of the present invention is formed content range:
SiO 240～50% Al 2O 34～5.5%
H 3BO 330～40% CaCO 30.1～0.2%
ZnO 2～3.6% K 2CO 32～3%
Na 2CO 310～15% ZrO 20.05～0.15%
1100～1350 ℃ of material firing temperatures, fusion and the low melting point glaze made, this glaze and the luminescent powder formed noctilucence glaze behind blackening that is mixed, have acid-alkali-corrosive-resisting, wear-resisting wiping, condition of surface is smooth, chemical stability good, luminosity is high, time of persistence is long, "dead", can send redness, orange, lemon yellow, yellowish green orchid is green is characteristics such as colorama.
The colorful noctilucent ceramic glaze that the present invention makes can be used for industrial ceramics, domestic ceramics, architectural pottery and craft artistic pottery and porcelain etc.Can be in the dark after visible light or uviolizing or send night bright and colourful photochromicly, be photochromic bonded china ornament of ideal and sign device.
Embodiment:
The compound method of A, low-temperature glaze
By following ratio of components, take by weighing various raw materials:
SiO 245.53 gram Al 2O 34.65 gram
H 3BO 333.98 gram CaCO 30.14 gram
ZnO 2.94 gram K 2CO 32.39 gram
Na 2CO 313.24 gram ZrO 0.08 gram
To prepare burden and drop in the ball grinder, put on the ball mill ball milling 4～6 hours, take out in pack into bique ware or the crucible, place 1200～1350 ℃ of heating and meltings, and take out to pour in the cold water and scrap sieving for standby after grinding.
B: the manufacture method of noctilucence glaze
Get above-mentioned low-temperature glaze 100 weight parts and luminescent powder 30 weight parts that pass through 180 mesh sieves, mix, water glass melt furnishing paste uses for coating ceramic.
C: the method for cooking of Noctilucent ceramics goods
The uniform luminous glaze slip of modulated is stuck with paste, by the design requirements pattern, be applied to or be printed on the ceramic form surface, behind the oven drying at low temperature, putting into kiln burns till under 700～850 ℃ of temperature, taking-up can form slick luminous glaze layer on ceramic surface, after visible light or uviolizing, in the dark or send colorama night.

Claims (1)

  1. The present invention is characterised in that used luminescent material is "dead", and mixing rare earth material is Er +++.Ga +++Be 10 of matrix weight -5～10 -7.Gu +++10 -3～10 -5Luminous colour powder.
    Ceramic glaze compositing range of the present invention is:
    SiO 240～50% Al 2O 34～5.5%
    H 3BO 330～40% CaCO 30.1～0.2%
    ZnO 2～3.6% K 2CO 32～3%
    Na 2CO 310～15% ZrO 20.05～0.15%
    1200～1350 ℃ of melt temperatures, prepared glaze maturing temperature is 700～850 ℃, chemical reaction does not take place being lower than 850 ℃ of temperature in glaze and luminescent powder, does not reduce luminescent properties.Luminous glaze is applied to the ceramic batch surface, forms the Vitrea luminous glaze layer of uniform surface after 700～850 ℃ of maturations, constitutes the Noctilucent ceramics goods.
CN 86101965 1986-03-20 1986-03-20 Process for making non-radioactive luminous colored glaze Pending CN86101965A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 86101965 CN86101965A (en) 1986-03-20 1986-03-20 Process for making non-radioactive luminous colored glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 86101965 CN86101965A (en) 1986-03-20 1986-03-20 Process for making non-radioactive luminous colored glaze

Publications (1)

Publication Number Publication Date
CN86101965A true CN86101965A (en) 1987-09-30

Family

ID=4801568

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 86101965 Pending CN86101965A (en) 1986-03-20 1986-03-20 Process for making non-radioactive luminous colored glaze

Country Status (1)

Country Link
CN (1) CN86101965A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062538C (en) * 1998-06-26 2001-02-28 山东伦博实业集团有限公司 Energy accumulating luminous glaze and its preparing technology
US8030834B2 (en) 2004-10-11 2011-10-04 Samsung Sdi Co., Ltd. Flat display device, plasma device panel and field emission containing phosphor coated with a heat-resistant material
CN102898185A (en) * 2012-11-06 2013-01-30 淄博泰如工业新材料有限公司 Production process of luminous ceramic product
CN102910824A (en) * 2012-11-06 2013-02-06 淄博泰如工业新材料有限公司 Formula and process for manufacturing noctilucent glaze material
CN104513066A (en) * 2013-09-30 2015-04-15 佛山市柯林瓷砖护理用品有限公司 Low temperature ceramic glaze manufacturing method
CN104789222A (en) * 2015-03-20 2015-07-22 淄博泰如工业新材料有限公司 Special energy source luminescent material and production process thereof
CN113545575A (en) * 2021-08-13 2021-10-26 广东顺德周大福珠宝制造有限公司 Jewelry and surface treatment method thereof

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1062538C (en) * 1998-06-26 2001-02-28 山东伦博实业集团有限公司 Energy accumulating luminous glaze and its preparing technology
US8030834B2 (en) 2004-10-11 2011-10-04 Samsung Sdi Co., Ltd. Flat display device, plasma device panel and field emission containing phosphor coated with a heat-resistant material
CN102898185A (en) * 2012-11-06 2013-01-30 淄博泰如工业新材料有限公司 Production process of luminous ceramic product
CN102910824A (en) * 2012-11-06 2013-02-06 淄博泰如工业新材料有限公司 Formula and process for manufacturing noctilucent glaze material
CN102898185B (en) * 2012-11-06 2014-12-10 淄博泰如工业新材料有限公司 Production process of luminous ceramic product
CN104513066A (en) * 2013-09-30 2015-04-15 佛山市柯林瓷砖护理用品有限公司 Low temperature ceramic glaze manufacturing method
CN104513066B (en) * 2013-09-30 2017-02-08 佛山市克里普斯科技有限公司 Low temperature ceramic glaze manufacturing method
CN104789222A (en) * 2015-03-20 2015-07-22 淄博泰如工业新材料有限公司 Special energy source luminescent material and production process thereof
CN113545575A (en) * 2021-08-13 2021-10-26 广东顺德周大福珠宝制造有限公司 Jewelry and surface treatment method thereof

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