CN85108710B - Process and equipment for light burning magnesite in ebullating calciner - Google Patents

Process and equipment for light burning magnesite in ebullating calciner Download PDF

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CN85108710B
CN85108710B CN85108710A CN85108710A CN85108710B CN 85108710 B CN85108710 B CN 85108710B CN 85108710 A CN85108710 A CN 85108710A CN 85108710 A CN85108710 A CN 85108710A CN 85108710 B CN85108710 B CN 85108710B
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China
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fluidizing furnace
flue gas
furnace
light
ore
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CN85108710A
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CN85108710A (en
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王岳南
吕士魁
迟兆宏
靳明月
由振祥
徐中文
赵海鹏
叶甫祥
李扬仪
林钦铭
王勇
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Liaoning Magnesium Mine Company Ministry Of Metallurgy
MAANSHAN MINE INST MINISTRY OF METALLURGICAL INDUSTRY
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Liaoning Magnesium Mine Company Ministry Of Metallurgy
MAANSHAN MINE INST MINISTRY OF METALLURGICAL INDUSTRY
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Application filed by Liaoning Magnesium Mine Company Ministry Of Metallurgy, MAANSHAN MINE INST MINISTRY OF METALLURGICAL INDUSTRY filed Critical Liaoning Magnesium Mine Company Ministry Of Metallurgy
Priority to CN85108710A priority Critical patent/CN85108710B/en
Publication of CN85108710A publication Critical patent/CN85108710A/en
Publication of CN85108710B publication Critical patent/CN85108710B/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/40Production or processing of lime, e.g. limestone regeneration of lime in pulp and sugar mills

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Abstract

The present invention relates to a method and a device for producing soft burning magnesium oxide, particularly to a method and a device for producing soft burning magnesium oxide through the soft burning of magnesite ore by a fluidized bed furnace. The soft burning magnesium oxide with low burning loss, high activity, thin and uniform granularity and high quality is prepared by putting the magnesite ore with granularity of 0 to 25mm in a fluidized bed furnace through drying, heating, decomposition, burst, airflow milling and separation; therefore, the technique is simplified, and the grade of the magnesium oxide of the product is increased. The production device comprises a fluidized bed furnace, a material discharging screw, a smoke gas and air heat exchanger, a cyclonic dust collector, a multiclone dust collector, a cloth bag or an electric dust collector, a hopper, a negative pressure conveying and cooling system, an exhaust fan, etc.

Description

The method and apparatus of fluidizing furnace light-calcined magnesite stone
The present invention relates to a kind of method and apparatus of producing light calcined magnesia, particularly a kind of method and apparatus of producing light calcined magnesia with fluidizing furnace light-calcined magnesite stone.With granularity is that the giobertite of 0~25mm places in the fluidizing furnace, drying, heating, decomposition, explosion, air-flow is levigate, after the sorting, obtain burning lower, active high, fine size and high-quality light calcined magnesia has uniformly been simplified technology, improved the grade of product.
The product that the present invention produced is light calcined magnesia (claiming magnesia again), and this product can further be processed into magnesia, as basic refractory.Also can make multiple material of construction, and make the papermaking packing material.
Hot-work to magnisite stone at present generally has two kinds of methods.First one-step calcination, promptly
Magnisite MgCO 3
Figure 85108710_IMG1
Reburned magnesia sand MgO+CO 2↑ it two is two step calcinings, promptly
Magnisite MgCO 3
Figure 85108710_IMG2
Light calcined magnesia MgO+CO 2
Figure 85108710_IMG3
Reburned magnesia sand MgO
For a long time, China produces the light calcined magnesia reverberatory furnace.It is the bulk raw ore of 25~100mm that but reverberatory furnace can only use granularity, and when mining the output granularity account for 40~45% less than the ore of 25mm, this part fine ore can not utilize substantially and pile up.Resource, land occupation had both been wasted, again contaminate environment.Once produced light calcined magnesia with rotary kiln, ring kiln for handling fine ore, but product percent of pass is lower, the energy consumption height.
The method that states such as West Germany, the U.S., Japan produce light calcined magnesia is a multiple bedded furnace, and this furnace structure complexity needs with more high-temperature steel, and operating rate is low, and the maintenance condition is poor, and unit surface throughput is low.
Above-mentioned reverberatory furnace, rotary kiln, ring kiln, multiple bedded furnace etc. are when light-burned magnisite stone, all be to go into stove with massive ore, the block light calcined magnesia of output, and departments such as fire-resistant, building materials, light industry need with light calcined magnesia all require granularity less than 120 μ m, therefore need further to pulverize with equipment such as Raymond mills, increase cargo handling operation, consumed the energy.Block giobertite is gone into stove, the block light calcined magnesia of output, and quality product is often uneven, in general forms surperficial burning easily, the center underburnt, therefore remaining the burning subtracts up to 3~8%, brings adverse consequences for next step operation.
Austria adopts shower furnace to handle the particulate giobertite, the outer decomposition technique of the stove of similar cement industry, its particulate giobertite is flotation concentrate or the prior levigated raw ore of granularity below 150 μ m, even, the remaining light calcined magnesia that reduces in 1% that burns of output quality after shower furnace is handled.Still need two subjobs but ore grinding, mill burn in advance.
MgO, CaO, AL in the method light-calcined magnesite stone products obtained therefroms such as above-mentioned reverberatory furnace, rotary kiln, multiple bedded furnace, shower furnace 2O 3, SiO 2, Fe 2O 3Deng composition, can only decide with the composition of raw ore, in the stove useful composition magnesium oxide MgO there is not inrichment, to useless composition AL 2O 2, SiO 2, Fe 2O 3Deng also there not being discarded function.
The light-burned method and apparatus that the purpose of this invention is to provide a kind of giobertite is to obtain uniform in quality, the remaining high-quality light calcined magnesia that lowers that burns.And can be with fine grinding job delete or the simplification before light-burned, after light-burned.Make the grade of useful composition MgO in the light-burned product improve impurity composition AL 2O 3, SiO 2, Fe 2O 3Reduce etc. grade.According to product to CaO/SiO 2Requirement, it is adjusted to proper proportion.
Technical process of the present invention and device are seen Fig. 1.Granularity is that the giobertite of 0~25mm is added in the fluidizing furnace (2) continuously by self-conveyor feed (1), ore is seethed with excitement by hot blast in the fluidizing furnace (by the roots blower supply and by the flue gas-air heat exchanger heating) and the flue gas that fuel combustion produces, ore is dried in stove, heating, decompose, explosion, air-flow is levigate, sorting, generate to burn and lower, active high, the light calcined magnesia of fine size, take furnace roof out of with the rising flue gas, through flue gas-air heat exchanger (3), cyclone (4), multiclone collector (5), cloth bag or dust precipitator (6), fine powder and flue gas are separated, fine powder combines in hopper (7), deliver to finished bin by negative-pressure conveying system (8), enter atmosphere by induced-draft fan (9) and chimney (10) after the gas cleaning.
Emit the partly interior material of stove by the load displacing screw (11) of fluidizing furnace bottom, can get rid of indissoluble impurity component in the ore, improve the content of magnesium oxide MgO in the furnace roof product, play the effect of hot sorting mined material.
In raw ore,, can adjust CaO/SiO in the product with addition of an amount of high calcium ore of certain particle size 2Ratio, satisfy the composition requirement of reburned magnesia sand.
Fluidizing furnace is up big and down small upright empty stove, and the bottom is provided with grid distributor, and the good oil-fired burner of several atomizing effects is arranged on the grid distributor.
Parameters such as the temperature of whole technology, pressure, air quantity, oil mass, feeding quantity all concentrate on master control room, show, write down and regulate with instrument.
Main technologic parameters of the present invention and product quality indicator are:
(1) light roasting temperature is 800~900 ℃
(2) ebullated bed operation wind speed 2~3 meter per seconds
(3) quality product
MgO content 80~97.5%(decides according to the grade of going into the stove ore);
Burning subtracts about 1%;
Granularity-74 μ m>99%-40 μ m>90%;
(4) 164 kilograms/ton of product oil consumption per ton (calorific value is about 9500 kilocalories/kilogram).

Claims (4)

1, a kind of method of producing light calcined magnesia, particularly a kind of method of producing light calcined magnesia with fluidizing furnace light-calcined magnesite stone, it is characterized in that giobertite adds in the fluidizing furnace by screw feeder continuously, ore is seethed with excitement by the flue gas of hot blast in the fluidizing furnace and fuel combustion generation, ore is dried in stove, heating, decompose, explosion, air-flow is levigate, fine-grained light calcined magnesia is taken furnace roof out of with the rising flue gas, through flue gas-air heat exchanger, cyclone, multiclone collector, cloth bag or dust precipitator, fine powder and flue gas are separated, fine powder combines in hopper, deliver to finished bin by negative-pressure conveying system, and the capable again sorting of indissoluble impurity component.
2, method according to claim 1 is characterized in that described sorting is the hot sorting in fluidizing furnace, gets rid of the impurity component indissoluble in the ore, that particle is bigger in the fluidizing furnace bottom by load displacing screw, thereby improves the content of magnesia in the product.
3, method according to claim 1 is characterized in that also will allocating in the described giobertite an amount of high calcium mineral, to adjust the CaO/Sio of product 2Ratio.
4, a kind of device with fluidizing furnace light-calcined magnesite stone production light calcined magnesia is characterized in that this device comprises fluidizing furnace, load displacing screw, flue gas-air heat exchanger, cyclone, multiclone collector, cloth bag or dust precipitator, hopper, negative pressure transportation cooling system, induced-draft fan.
CN85108710A 1985-12-02 1985-12-02 Process and equipment for light burning magnesite in ebullating calciner Expired CN85108710B (en)

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CN85108710A CN85108710B (en) 1985-12-02 1985-12-02 Process and equipment for light burning magnesite in ebullating calciner

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CN85108710A CN85108710B (en) 1985-12-02 1985-12-02 Process and equipment for light burning magnesite in ebullating calciner

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CN85108710B true CN85108710B (en) 1988-05-25

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108118142A (en) * 2017-12-29 2018-06-05 营口益嘉镁业科技有限公司 A kind of suspension flash decomposes and homogenizing processing technique

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100396799C (en) * 2005-09-20 2008-06-25 孟宪民 Synthetic adding ball and its preparing method
CN100462449C (en) * 2006-12-20 2009-02-18 辽宁科技大学 Magnesite hot enriching process
CN102653459B (en) * 2011-03-01 2014-05-21 辽宁科技大学 Thermoselect method and device for light roasting magnesium oxide
CN105734272B (en) * 2016-02-22 2017-06-23 北京科技大学 A kind of mechanical dynamic suspends with one-step baking beneficiation method and device
CN109136539B (en) * 2018-07-05 2020-06-23 沈阳化工大学 Integrated process of fluidized bed two-stage gasification and flash light burning magnesite
CN109320107A (en) * 2018-10-26 2019-02-12 辽宁科技大学 Suspension-boiling multithread state combination preparation high activity light calcined magnesia method
CN111484045B (en) * 2020-04-23 2022-09-13 海城三岩矿业有限公司 Multistage remelting purification method for fused magnesia

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108118142A (en) * 2017-12-29 2018-06-05 营口益嘉镁业科技有限公司 A kind of suspension flash decomposes and homogenizing processing technique

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