CN2912783Y - Complete equipment system for simulating synthesis and decomposition of natural gas hydrate and reaction kettle - Google Patents
Complete equipment system for simulating synthesis and decomposition of natural gas hydrate and reaction kettle Download PDFInfo
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- CN2912783Y CN2912783Y CN200520075644.3U CN200520075644U CN2912783Y CN 2912783 Y CN2912783 Y CN 2912783Y CN 200520075644 U CN200520075644 U CN 200520075644U CN 2912783 Y CN2912783 Y CN 2912783Y
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- NMJORVOYSJLJGU-UHFFFAOYSA-N methane clathrate Chemical group C.C.C.C.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O.O NMJORVOYSJLJGU-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000006243 chemical reaction Methods 0.000 title claims description 38
- 238000000354 decomposition reaction Methods 0.000 title abstract description 19
- 230000015572 biosynthetic process Effects 0.000 title abstract description 17
- 238000003786 synthesis reaction Methods 0.000 title abstract 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 56
- 238000004088 simulation Methods 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000003345 natural gas Substances 0.000 claims abstract description 21
- 230000000007 visual effect Effects 0.000 claims abstract description 17
- 238000005057 refrigeration Methods 0.000 claims abstract description 13
- 238000009826 distribution Methods 0.000 claims abstract description 10
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- 206010045178 Tunnel vision Diseases 0.000 claims description 11
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- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
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- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The utility model relates to a seabed natural gas hydrate simulated synthesis and decomposition complete sets system, still relate to this seabed natural gas hydrate simulated synthesis and the reation kettle who decomposes in the complete sets system simultaneously, belong to the mechanical engineering field, the core part reation kettle of this system can bear pressure and temperature of 3000 meters depth of water, visual degree is high, the volume is great, simultaneously the system cost is relatively lower, the control means is abundant, pressure boost and pressurize are convenient fast, the formation and the decomposition of this equipment system to natural gas hydrate in the sea water and the real seabed silt all can carry out simulated synthesis and decomposition analysis, play important guiding role to seabed natural gas hydrate's reserves, exploration; the utility model discloses a complete sets system, including simulation natural gas distribution system, natural gas high pressure boost system, reation kettle, refrigeration and bath temperature control system and parameter control platform and computer data acquisition system, still be equipped with magnetic stirring system, reation kettle is the visual reation kettle of high pressure.
Description
Technical field
The utility model relate to the simulation of a kind of hydrate synthetic with resolve into the complete equipment system, more specifically to the simulation of a kind of sea bed gas hydrate synthetic with resolve into the complete equipment system, also relate to this sea bed gas hydrate simulation simultaneously and synthesize and the reactor that resolves in the complete equipment system, belong to mechanical engineering field.
Background technology
Gas hydrates are huge strategic eco-friendly power sources of reserves after coal and oil, are described as the laurel of 21 century new forms of energy, this shows national governments and the scientific and technological expert attention to it.Though than later, the investigation of the ocean gas hydrate carried out of China Geological Survey Bureau has in recent years obtained the progress that attracts people's attention to the investigation of gas hydrates and research starting in China.Gas hydrates simulated experiment technology is the basic technology that gas hydrates are reconnoitred research, and minority developed country has set up their synthetic and decomposition experimental system of gas hydrates simulation, and exports to China.The core reaction device of early test device adopts stainless steel pressing pressure reactor usually, uses the back to find to exist a lot of weak points.Comprise the equipment heaviness, relatively not high, the visual degree of bearing capacity poor (can't observe its internal-response), analyzing and testing means few, easily produce seawater stress corrosion cracking (SCC) etc.In recent years, released modern visual high-pressure fluid test macro in the world, this device mainly comprises reactor, constant temperature air bath, stirring and volume adjustment means, pressure and temperature measurement mechanism and control system etc.Reactor is the bright sapphire still of the full impregnated of a variable volume, and the variable volume scope is 13.6～100cm
3, maximum working pressure can reach 40MPa, and operating temperature range is-20～120 ℃.Material can mix by agitator or circulating pump in the reactor.Temperature in the reactor is measured by RTD, and precision is ± 0.1K that the pressure precision is the determination of pressure sensor of 0.06% (being 24kPa).With distilled water reactor is cleaned 2 times before each experimental system test, purge with experimental gas then, vacuumize at last, in reactor, inject an amount of distilled water and experiment hydrocarbons.The experiment method therefor is generally the constant temperature and pressure search method, and the formation/decomposition of hydrate is determined by perusal.The temperature of the control device adjusting air bath of system makes temperature of reaction kettle stably be in setting value at first by experiment when the experiment beginning, by agitator combined experiments fluid, increases the gas-liquid contact area, reduces hydrate and forms induction time.Regulate pressure by position of piston in the change reactor simultaneously, the pressure that improves in the reactor generates hydrate.From operating position,, concrete not enough as follows though this series products has had outstanding improvement at the control of visual, parameter, aspect such as corrosion-resistant, but still exists many weak points that can't overcome:
1) be subjected to restrictions such as cost, manufacturing process, volume is too small, uses comparatively difficulty at aspects such as natural gas hydrate gas storage ability and THERMAL STABILITY;
2) can't simulate the formation and the decomposition of gas hydrates in the silt of true seabed, therefore can't be, explored directive function to the reserves of sea bed gas hydrate;
3) owing to when differentiating the formation of hydrate/decompositions, adopt perusal, cause reacting the uncertainty that critical point is judged, the researching and analysing synchronously of the association reaction parameter after the while also can't experimentize to image;
4) real-time monitoring means deficiency lacks support to the repeatability of analog result, determine and the checking of reaction condition;
5) can't carry out reactor and open fast, synthetic hydrate can't take out fast and burn, analyzes or further research;
6) lack real time data and image analysis software support, experimental implementation and interpretation are limited.
Summary of the invention
The purpose of this utility model is to solve above-mentioned the deficiencies in the prior art and problem, pressure and temperature, visual degree height that a kind of core component can bear 3000 meters depth of waters is provided, volume is big, cost is relatively low, monitoring means are abundant, supercharging and pressurize sea bed gas hydrate simulation quickly and easily are synthetic and has resolved into the complete equipment system.This device systems is to the formation of gas hydrates in the silt of in the seawater and true seabed and decompose and all can simulate synthetic and decomposition analysis, therefore to the reserves of sea bed gas hydrate, explored important directive function.
Another purpose of the present utility model be also provide the simulation of a kind of sea bed gas hydrate synthetic with resolve into the reactor that uses in the complete equipment system, this reactor structure bearing capacity is strong, stress corrosion under the frivolous and sea water resistance, and can simulate the formation and the decomposition of gas hydrates in the silt of true seabed, therefore to the reserves of sea bed gas hydrate, explored directive function.
The utility model is achieved through the following technical solutions:
Sea bed gas hydrate simulation of the present utility model is synthesized and the complete set of equipments system that decomposes, include simulation natural gas air distribution system, natural gas high pressure pressure charging system, reactor, refrigeration and bath temperature control system and parameter console and computer data acquisition system, the magnetic agitation system also is housed, simulation natural gas air distribution system is connected with natural gas high pressure pressure charging system by pipeline, natural gas high pressure pressure charging system is connected with reactor by pipeline again, refrigeration and bath temperature control system are connected with reactor by pipeline, computer data acquisition system is connected with reactor and parameter console by circuit, and described reactor is a high pressure visual reaction kettle.
The spherical reactor that the high pressure visual reaction kettle of the utility model system is processed into for the mode that hollows out with titanium alloy monobloc forging part inside, it at the bottom of the still platform structure, offer 4 tubulose visor holes and the tubulose visor is installed respectively in the equatorial positions of reactor spheroid, 90 ° of the location intervals in each hole, the top of reactor spheroid also has 1 tubulose visor hole and the tubulose visor is installed, the shell ring and the reaction kettle body of tubulose visor are integrated, the endoporus of shell ring is that cylinder adds trapezium structure, shell ring is the top of shell ring from the size maximum of reaction kettle body distal-most end internal diameter; Shell ring mid portion internal diameter size is placed in the middle, is the middle part of shell ring; The internal diameter minimum of shell ring and reaction kettle body coupling part, be the bottom, shell ring bottom internal diameter is identical with tubulose visor hole internal diameter, shell ring is equipped with the cylindrical, massive bulletproof glass in the middle part, the twice Composition spacer is housed on the bulletproof glass both ends of the surface, the O RunddichtringO is equipped with in the bulletproof glass side, and shell ring top compresses sealing by pressure head; The diameter of described cylindrical, massive bulletproof glass is less than the internal diameter at tunnel vision lens barrel joint middle part and greater than visor hole internal diameter, and the diameter dimension of cylindrical, massive bulletproof glass is than the little 1～2mm of internal diameter at tunnel vision lens barrel joint middle part; The shell ring lower length is greater than the thickness of reaction kettle body, and shell ring top is identical with the middle part external diameter, and the shell ring lower outer diameter is less than the external diameter at top or middle part; Described pressure head is that hollow cylinder adds trapezium structure, all be processed with nipple simultaneously, its external screw-thread joint is connected with the shell ring internal thread, is used for compressing bulletproof glass and pad, pressure head internal whorl joint is connected with micro-camera device, and carries out water seal by compress gasket; Described tubulose visor outer end is provided with the interface of optical fiber shooting under water, by mouthful installation high-precision micro optical fiber camera head that is threaded that the tubulose visor outside is offered, note down all audio and video files and import Computer Storage and analysis by the output line connection DVR of micro-camera device; After taking out bulletproof glass in the described tunnel vision lens barrel joint ultrasonic probe can be installed, probe adopts the arc contact surface screw thread to compress sealing and probe side O type circle self-tightening sealing, and the ultrasonic listening output line can connect computer and carry out data acquisition; Described natural gas high pressure pressure charging system adopts the mode of gas drive gas boosting; Described magnetic agitation system comprises and is placed on the rare earth magnetic steel of installing on the magnetic beans stirrer and the outer lower motor output shaft of reactor in the reactor, and holes probe is equipped with and by parameter console control rotating speed in the motor shaft outside; Described refrigeration and bath temperature control system adopt the mode that reactor immerses the salt bath temperature controlling groove to control reaction temperature, and the bath body of wall includes double-layer foamed dose composite board by stainless steel materials and makes.
The reactor that uses in the complete set of equipments system that sea bed gas hydrate simulation of the present utility model is synthesized and decomposed is high pressure visual reaction kettle, it is the spherical reactor that is processed into the mode that titanium alloy monobloc forging part inside hollows out, it at the bottom of the still platform structure, offer 4 tubulose visor holes and the tubulose visor is installed respectively in the equatorial positions of reactor spheroid, 90 ° of the location intervals in each hole, the top of reactor spheroid also has 1 tubulose visor hole and the tubulose visor is installed, the shell ring and the reaction kettle body of tubulose visor are integrated, the endoporus of shell ring is that cylinder adds trapezium structure, shell ring is the top of shell ring from the size maximum of reaction kettle body distal-most end internal diameter; Shell ring mid portion internal diameter size is placed in the middle, is the middle part of shell ring; The internal diameter minimum of shell ring and reaction kettle body coupling part, be the bottom, shell ring bottom internal diameter is identical with tubulose visor hole internal diameter, shell ring is equipped with the cylindrical, massive bulletproof glass in the middle part, the twice Composition spacer is housed on the bulletproof glass both ends of the surface, the O RunddichtringO is equipped with in the bulletproof glass side, and shell ring top compresses sealing by pressure head; The diameter of described cylindrical, massive bulletproof glass is less than the internal diameter at tunnel vision lens barrel joint middle part and greater than visor hole internal diameter, and the diameter dimension of cylindrical, massive bulletproof glass is than the little 1～2mm of internal diameter at tunnel vision lens barrel joint middle part; The shell ring lower length is greater than the thickness of reaction kettle body, and shell ring top is identical with the middle part external diameter, and the shell ring lower outer diameter is less than the external diameter at top or middle part; Described pressure head is that hollow cylinder adds trapezium structure, all be processed with nipple simultaneously, its external screw-thread joint is connected with the shell ring internal thread, is used for compressing bulletproof glass and pad, pressure head internal whorl joint is connected with micro-camera device, and carries out water seal by compress gasket.
The beneficial effects of the utility model are as follows:
1) reactor can bear the pressure and temperature of 3000 meters depth of waters, can simulate the pressure and temperature of 3000 meters following depth of waters, does not produce stress corrosion simultaneously under high pressure and the effect of seawater medium;
2) the visual degree height of system not only can directly be observed the phase transformation situation in the high-pressure installation, the researching and analysing synchronously of the association reaction parameter after also can experimentizing to image simultaneously;
3) system response still volume is bigger, can reach 1000ml, can simulate the formation and the decomposition of gas hydrates in the silt of true seabed;
4) system cost is relatively low;
5) right judgement all can be made to the formation and the decomposition critical point of (obstructed light, visual poor) gas hydrates in the seawater and in the silt of seabed by system, and Ji Lu above-mentioned signal can amplify further research of do simultaneously;
6) He Cheng hydrate can take out fast and burn, analyzes or further research;
7) system possesses real time data and image analysis software support;
8) supercharging of natural gas high pressure pressure charging system and pressurize are quick and convenient;
9) the magnetic agitation system can make things convenient for the stepless speed regulation of stirrer in the realization response still;
10) refrigeration and bath temperature control system adopt the mode that reactor immerses the salt bath temperature controlling groove to control reaction temperature, temperature-controlled precision (temperature fluctuation)≤± 0.1 ℃, and bath insulation is simultaneously adopted double-layer foamed dose, and heat insulation effect is fine;
11) this device systems is to the formation of gas hydrates in the silt of in the seawater and true seabed with decompose and all can simulate synthetic and decomposition analysis, therefore to the reserves of sea bed gas hydrate, explored important directive function.
Description of drawings
Fig. 1 is a system architecture schematic diagram of the present utility model
Fig. 2 is the reactor structure front view of the utility model system
Fig. 3 is the reactor structure vertical view of the utility model system
Fig. 4 is the work relationship schematic diagram of each subsystem of the present utility model
Each part description among the figure: 1, stop valve, 2, air gauge, 3, the gas boosting pump, 4, air compressor machine, 5, NaCl solution, 6, the fluid charge pump, 7, thermometer, 8, computer acquisition system, 9, receive gas cylinder, 10, gas vent, 11, reactor, 12, magnetic stirring apparatus, 13, visor, 14, compressor, 15, needle-valve, 16, the distribution bottle, 17, the gas component gas cylinder, 18, the interface fairlead, 19, magnetic beans stirrer, 20, kettle, 21, thermocouple, 22, bulletproof glass, 23, shell ring, 24, the O RunddichtringO, 25, Composition spacer, 26, pressure head, 27, the liquid phase mouth, 28, gauge port, 29, the gas phase mouth, 30, temperature-measuring port, 31, relief valve port
The specific embodiment
Embodiment
Synthetic and the decomposition simulation experiment study of gas hydrates cryogenic high pressure test complete set of equipments system-specific Yu Haiyang gas hydrates of the present utility model, this system is developed for the first time by domestic unit on the basis of at home and abroad investigating.As shown in the figure, it is by reactor, refrigeration and bath temperature control system, magnetic agitation system, parameter console and computer data acquisition system, simulation natural gas air distribution system, natural gas high pressure pressure charging system totally six sub-system assembles.Its course of work or principle are: analog gas is after the air distribution system distribution, in input reactor after the supercharging of natural gas high pressure pressure charging system, reactor places the salt bath of bath temperature control system to carry out temperature control, carry out stirring reaction control by magnetic agitation system and parameter console simultaneously, the acoustics of running parameter in the course of reaction such as temperature, pressure and monitoring in real time and optical signalling are by computer data acquisition system collection and real-time analysis.
The reactor 11 of the utility model system is a high pressure visual reaction kettle, internal diameter is 125mm, it is the spherical reactor that is processed into the mode that titanium alloy monobloc forging part inside hollows out, be platform structure at the bottom of the still, such structure bearing capacity is strong, the stress corrosion under the light and handy and sea water resistance, the design pressure of reactor is 30MPa (can simulate the pressure condition of the 3000 meters depth of waters in seabed), design temperature is-10 ℃, and volume is 1000ml, and working media is seawater, natural gas and sediment.Offering 4 tubulose visor holes and diameter is installed respectively in the equatorial positions of reactor spheroid is 20mm tubulose visor 13,90 ° of the location intervals in each hole, the top of reactor spheroid also has 1 tubulose visor hole and the tubulose visor is installed, the shell ring 23 and the reaction kettle body of tubulose visor are integrated, weld together, the shell ring material is a titanium alloy, the endoporus of shell ring is that cylinder adds trapezium structure, the length of shell ring is 80mm, internal diameter has three kinds of different sizes, shell ring is the top of shell ring from the size maximum of reaction kettle body distal-most end internal diameter; The top internal diameter is 56mm, and shell ring mid portion internal diameter size is placed in the middle, is the middle part of shell ring; The middle part internal diameter is 46mm, and the length at middle part is 36mm; Shell ring overlaps with reaction kettle body and the internal diameter minimum of extension, is the bottom; Shell ring bottom internal diameter and the identical 20mm of tubulose visor hole internal diameter, the external diameter of shell ring bottom is 62mm, the identical 73mm that is in shell ring middle part with the top external diameter, shell ring is equipped with cylindrical, massive bulletproof glass 22 in the middle part, the thickness of cylindrical, massive bulletproof glass 22 is 36mm, diameter is 44mm, when guaranteeing sealing intensity, also can realize logical light like this, can the high pressure of anti-30MPa, twice Composition spacer 25 is housed on the bulletproof glass both ends of the surface, O RunddichtringO 24 is equipped with in the bulletproof glass side, and shell ring 23 tops compress sealing by pressure head 26, and pressure head 25 adds trapezium structure for hollow cylinder, can guarantee inner logical light like this, all be processed with nipple simultaneously, its external screw-thread joint is connected with the shell ring internal thread, is used for compressing bulletproof glass and pad; Pressure head internal whorl joint is connected with micro-camera device, and carries out water seal by compress gasket.Micro-camera device just can be under water links together with reactor and has immersed the response situation of taking reactor in the salt bath like this, the sealing of light wave path realizes the sealing of triple different types, through measuring, pretightning force is little, and torque spanner moment reaches 80N.M and gets final product; Tubulose visor outer end is provided with the interface of optical fiber shooting under water, by mouthful installation high-precision micro optical fiber camera head that is threaded that the outer Side of tubulose visor offers, note down all audio and video files and import Computer Storage and analysis by the output line connection DVR of micro-camera device; After taking out bulletproof glass in the tunnel vision lens barrel joint ultrasonic probe can be installed, probe adopts the arc contact surface screw thread to compress sealing and probe side O type circle self-tightening sealing, the ultrasonic listening output line can connect computer and carry out data acquisition, the sound wave path is realized the sealing of double different types, under water pressure test condition (37.5MPa), digital display pressure keeps not descending in 1 hour in the still, proves that the sealing of this equipment is reliable; This kettle visor is offered, is had children outside the state plan aspect such as ripple probe connection and all belongs to technological gap, has far exceeded the scope of pertinent regulations technical specification (as GB150 standard and other domestic and international relevant specifications) in the world.Glass visor light wave path and sound wave path are installed simultaneously, and the interface of optical fiber shooting under water with ultrasonic probe (directly contacting with medium in the still) has been reserved in design, can be used for monitoring the synthetic of gas hydrates and decompose and direct situation of change of observing in the still, to (obstructed light in the silt of simulation seabed, visual poor) formation and the decomposition of gas hydrates monitor, seal pretightning force little (easy to operate and prevent glass pressure break) in addition, sealing is reliable, and convenient disassembly, synthetic hydrate can take out fast and burn, analyze or further research.
Magnetic agitation of the present utility model system comprises the rare earth magnetic steel of installing on the magnetic beans stirrer 19 installed on the Polycondensation Reactor and Esterification Reactor platform structure and the reactor 11 outer lower motor output shafts, the motor shaft outside is equipped with holes probe and is controlled rotating speed by the parameter console, when motor rotates, holes probe receives signal, deliver to digital rotating speed instrument and directly show stirrer rotating speed in the still, by regulating the rotational speed regulation knob, reach the stepless speed regulation of stirrer in the still, for unlikely too much weakening magnetic force, need shorten magnetic circuit as far as possible, because kettle is interior outer spherical, stressed effect is good, and the intensity of selected materials titanium alloy is also very high, therefore the still wall is thinner, through test, mixing effect is good, best results when 1100r/min.In addition, kettle also is provided with liquid phase mouth 27, gauge port 28, gas phase mouth 29, temperature-measuring port 30, relief valve port 31, is used for thermometric, pressure measurement and the turnover of other materials.
Natural gas high pressure pressure charging system of the present utility model adopts the mode of gas drive gas boosting, by air compressor machine 4 gas-powered, utilize the mechanical type gas distributing valve that pulsometer is turned round continuously, utilize piston two ends size area difference, low-pressure air driven plunger large tracts of land end, piston small size end output gases at high pressure.Pulsometer work is rapid, stops when reaching pressure set points.Do not have electric spark, can be used safely in inflammable, explosive gas (as natural gas etc.).Through on-the-spot test, the simulation natural gas boosting of 2.6MPa in the gas cylinder is only needed 102 minutes to 37.5MPa.After arriving the pressure target position, this moment, energy consumption was very little, and empty calory produces, no part movement.Therefore after pressure balance was broken, pulsometer was started working automatically and is reached next balance, was very beneficial for reacting the pressurize of gas reactor again, can finish efficiently, pressurization cheaply.Through after each component high-pure gas proportioning of air distribution system, import reactor after the quick supercharging of mist process high pressure pressure charging system.Traditional compressor noise and energy consumption are big, and pressure ratio is not high.
Refrigeration of the present utility model and bath temperature control system adopt the mode that reactor immerses the salt bath temperature controlling groove to control reaction temperature, and the power of compressor 14 is 0.735KW, and cold-producing medium is R502, evaporating temperature :-55 ℃.Refrigerating medium is CaCl
2, add 34.6kgCaCl in every 100kg water
2T=-31.2 ℃ of its setting temperature.This salt bath volume is 133L, presses 110L water preparation NaCl solution.Refrigeration wants the moving flow of regulating nozzle (choke valve) of armrest to realize.Flow is little, enters the just few of evaporimeter, and the evaporation heat absorption is just few, and the salt liquid temp just can fall, and that perhaps falls is very slow, and the mouth of pipe temperature difference that pass in and out evaporimeter this moment is bigger.Even the exit has heating phenomenon (because of there not being the evaporation heat absorption).Flow is big, and the cold-producing medium that enters evaporimeter is many, and refrigeration is accelerated, and it is also fast to lower the temperature.When flow was suitable, the temperature of importing and exporting the mouth of pipe was close.Simultaneity factor is provided with stirring arm in temperature controlling groove, to strengthen heat exchange effect.Native system is tested the accuracy of temperature control of this system by the actual measurement reactor temperature, experimental result shows, this refrigeration system reaches designing requirement, through 2～3 hours, reduce to-10 ℃ by 25 ℃, temperature-controlled precision (temperature fluctuation)≤± 0.1 ℃, the bath body of wall includes double-layer foamed dose composite board by stainless steel materials and makes the heat insulation effect ideal.
Parameter console of the present utility model and computer data acquisition system mainly realize the control of bath cryogenic temperature, and temperature in the kettle shows, the control of still inner suspension magnetic beans speed of agitator, and the still internal pressure shows, start calendar scheduling function.Simultaneously, unified to gather and do instantaneous pattern analysis by computer after the inside and outside temperature and pressure digital display data of reactor are unified to be converted to electric current and voltage data, optical fiber image pickup signal that obtains from reactor and monitoring ultrasonic signal are also gathered and instantaneous pattern analysis by computer.
The test example
System of the present utility model has carried out the test of methane pressure (P)-temperature (T) condition in pure water.Test used methane and derive from Nanjing special gas factory, purity 〉=99.9%.Used water is the distilled water through 3 distillations.Earlier autoclave is cleaned up with 3 distilled water, inject 3 distilled water about 250mL then, again autoclave and whole high-pressure duct system are vacuumized, till not having bubble substantially in the water, wash autoclave and pipeline 3 times with methane gas then.According to the experiment needs, is that the methane gas of 8.36MPa is input in the autoclave by booster pump with pressure, starts magnetic stirring apparatus, makes methane gas fully dissolve in the water, when the pressure in the still under the same temperature no longer descends, represent that promptly the solution gas in the water reaches capacity.In experiment each time, the pressure in the autoclave remains unchanged substantially, and the generation and the decomposition of hydrate controlled in experiment by the lifting of temperature.When temperature dropped to 283.21K, hydrate generated in a large number, and this time percent of pass integrated value reduces suddenly, but the temperature of this moment has been lower than the equilibrium temperature under this pressure, and found through experiments, and the speed of this temperature value and magnetic agitation has much relations.Therefore, this temperature can not be as the temperature that balances each other of hydrate.The temperature of the system that raises subsequently, when temperature is raised to 284.79K, light percent of pass integrated value begins to rise, and this shows that hydrate begins to decompose, and accurately reads the temperature value of this flex point, i.e. the temperature that balances each other of hydrate formation under the pressure for this reason.Pressure (p)-temperature (T) data and the disclosed data in literature that experiment showed, the methane gas hydrate balance formation condition that is obtained by the utility model device systems are more identical, the results are shown in Table 1.
The pressure (p) of the decomposition of hydrate of table 1 methane in pure water-temperature (T) data determination
| p/MPa | ?8.36 | ?7.30 | ?6.14 | ?5.28 | ?4.85 | ?4.25 | ?3.97 | ?3.35 | ?3.07 |
| T/K | ?284.79 | ?283.62 | ?281.96 | ?280.37 | ?279.62 | ?278.13 | ?277.40 | ?275.53 | ?274.34 |
Because the 1000mL autoclave of the utility model system is easy to open, once took out the gas hydrates that generate in the still fast 3 times in the process of the test, and ignition combustion.Simultaneously, in the autoclave of the utility model system, use ultrasonic technique to survey the generation and the decomposition of gas hydrates in the unconsolidated sediment.Though some gas hydrates laboratory applications is crossed the supersonic sounding technology, also there is not ripe result's report abroad.In the experimentation, measure and real time record velocity of longitudinal wave, first wave amplitude and 3 parameters of reception dominant frequency.On experimental result, parameters,acoustic also changes according to certain rule in the formation of hydrate and decomposable process.Experimental result shows, raise suddenly when hydrate generates the time-frequency spectrum amplitude in a large number, and this spectral magnitude reduces suddenly during decomposition of hydrate, and this is because the result who has nothing in common with each other for the decay of hydrate in the received spectrum.Therefore, surveying the process that gas hydrates form in the marine sediment by the variation of ultrasonic wave dominant frequency will be highly effective means.
Claims (9)
1, a kind of sea bed gas hydrate simulation is synthesized and the complete set of equipments system that decomposes, include simulation natural gas air distribution system, reactor, refrigeration and bath temperature control system and parameter console and computer data acquisition system, it is characterized in that also being equipped with magnetic agitation system and natural gas high pressure pressure charging system, simulation natural gas air distribution system is connected with natural gas high pressure pressure charging system by pipeline, natural gas high pressure pressure charging system is connected with reactor by pipeline again, refrigeration and bath temperature control system are connected with reactor by pipeline, computer data acquisition system is connected with reactor and parameter console by circuit, and described reactor is a high pressure visual reaction kettle.
2, sea bed gas hydrate simulation according to claim 1 is synthesized and the complete set of equipments system that decomposes, it is characterized in that the spherical reactor that described high pressure visual reaction kettle is processed into for the mode that hollows out with titanium alloy monobloc forging part inside, it at the bottom of the still platform structure, offer 4 tubulose visor holes and the tubulose visor is installed respectively in the equatorial positions of reactor spheroid, 90 ° of the location intervals in each hole, the top of reactor spheroid also has 1 tubulose visor hole and the tubulose visor is installed, the shell ring and the reaction kettle body of tubulose visor are integrated, the endoporus of shell ring is that cylinder adds trapezium structure, shell ring is the top of shell ring from the size maximum of reaction kettle body distal-most end internal diameter; Shell ring mid portion internal diameter size is placed in the middle, is the middle part of shell ring; The internal diameter minimum of shell ring and reaction kettle body coupling part, be the bottom, shell ring bottom internal diameter is identical with tubulose visor hole internal diameter, shell ring is equipped with the cylindrical, massive bulletproof glass in the middle part, the twice Composition spacer is housed on the bulletproof glass both ends of the surface, the O RunddichtringO is equipped with in the bulletproof glass side, and shell ring top compresses sealing by pressure head.
3, sea bed gas hydrate simulation according to claim 2 is synthesized and the complete set of equipments system that decomposes, the diameter that it is characterized in that described cylindrical, massive bulletproof glass is less than the internal diameter at tunnel vision lens barrel joint middle part and greater than visor hole internal diameter, and the diameter dimension of cylindrical, massive bulletproof glass is than the little 1～2mm of internal diameter at tunnel vision lens barrel joint middle part; The shell ring lower length is greater than the thickness of reaction kettle body, and shell ring top is identical with the middle part external diameter, and the shell ring lower outer diameter is less than the external diameter at top or middle part; Described pressure head is that hollow cylinder adds trapezium structure, all be processed with nipple simultaneously, its external screw-thread joint is connected with the shell ring internal thread, is used for compressing bulletproof glass and pad, pressure head internal whorl joint is connected with micro-camera device, and carries out water seal by compress gasket.
4, sea bed gas hydrate simulation according to claim 2 is synthesized and the complete set of equipments system that decomposes, it is characterized in that described tubulose visor outer end is provided with the interface of optical fiber shooting under water, by mouthful installation high-precision micro optical fiber camera head that is threaded that the tubulose visor outside is offered, note down all audio and video files and import Computer Storage and analysis by the output line connection DVR of micro-camera device.
5, synthesize and the complete set of equipments system that decomposes according to claim 2 or 4 described sea bed gas hydrate simulations, after it is characterized in that taking out bulletproof glass in the described tunnel vision lens barrel joint ultrasonic probe can be installed, probe adopts the arc contact surface screw thread to compress sealing and probe side O type circle self-tightening sealing, and the ultrasonic listening output line can connect computer and carry out data acquisition.
6, sea bed gas hydrate simulation according to claim 1 is synthesized and the complete set of equipments system that decomposes, it is characterized in that described magnetic agitation system comprises is placed on the rare earth magnetic steel of installing on the magnetic beans stirrer and the outer lower motor output shaft of reactor in the reactor, and holes probe is equipped with and by parameter console control rotating speed in the motor shaft outside.
7, sea bed gas hydrate according to claim 1 simulation synthetic with the complete set of equipments system that decomposes, the bath body of wall that it is characterized in that described refrigeration and bath temperature control system includes double-layer foamed dose composite board by stainless steel materials and makes.
8, the reactor that uses in the complete set of equipments system that a kind of above-mentioned sea bed gas hydrate simulation is synthesized and decomposed is characterized in that described reactor is a high pressure visual reaction kettle.
9, reactor according to claim 8, it is characterized in that the spherical reactor that described high pressure visual reaction kettle is processed into for the mode that hollows out with titanium alloy monobloc forging part inside, it at the bottom of the still platform structure, offer 4 tubulose visor holes and the tubulose visor is installed respectively in the equatorial positions of reactor spheroid, 90 ° of the location intervals in each hole, the top of reactor spheroid also has 1 tubulose visor hole and the tubulose visor is installed, the shell ring and the reaction kettle body of tubulose visor are integrated, the endoporus of shell ring is that cylinder adds trapezium structure, shell ring is the top of shell ring from the size maximum of reaction kettle body distal-most end internal diameter; Shell ring mid portion internal diameter size is placed in the middle, is the middle part of shell ring; Shell ring overlaps with reaction kettle body and the internal diameter minimum of extension, be the bottom, shell ring bottom internal diameter is identical with tubulose visor hole internal diameter, shell ring is equipped with the cylindrical, massive bulletproof glass in the middle part, the twice Composition spacer is housed on the bulletproof glass both ends of the surface, the O RunddichtringO is equipped with in the bulletproof glass side, wherein the diameter of cylindrical, massive bulletproof glass is less than the internal diameter at tunnel vision lens barrel joint middle part and greater than visor hole internal diameter, the diameter dimension of cylindrical, massive bulletproof glass is than the little 1～2mm of internal diameter at tunnel vision lens barrel joint middle part, the shell ring lower length is greater than the thickness of reaction kettle body, shell ring top is identical with the middle part external diameter, and the shell ring lower outer diameter is less than the external diameter at top or middle part; Shell ring top compresses sealing by pressure head, described pressure head is that hollow cylinder adds trapezium structure, all be processed with nipple simultaneously, its external screw-thread joint is connected with the shell ring internal thread, be used for compressing bulletproof glass and pad, pressure head internal whorl joint is connected with micro-camera device, and carries out water seal by compress gasket.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102125815A (en) * | 2010-12-31 | 2011-07-20 | 中国科学院广州能源研究所 | High-pressure experimental system for simulating leakage type natural gas hydrate formation/decomposition |
| CN102435573A (en) * | 2011-08-31 | 2012-05-02 | 陕西师范大学 | High-pressure in-situ infrared spectroscopy apparatus for monitoring supercritical system on line |
| CN101701955B (en) * | 2009-10-27 | 2013-04-03 | 中国科学院力学研究所 | Experimental device and experimental method for simulating obvious stratum damage resulted from hydrate decomposition |
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| CN106268561A (en) * | 2015-06-12 | 2017-01-04 | 中国石油化工股份有限公司 | Gas hydrate generating means |
| CN105004849A (en) * | 2015-08-14 | 2015-10-28 | 西南石油大学 | Laboratory experiment device and method for solid fluidization exploitation of gas hydrate |
| CN109162708A (en) * | 2018-08-14 | 2019-01-08 | 山东科技大学 | Reservoir parameter multidimensional monitoring device in a kind of simulating hydrate recovery process |
| CN112226258A (en) * | 2020-10-12 | 2021-01-15 | 黑龙江科技大学 | NGH decomposition device and constant-temperature decomposition system for gas station |
| CN112226258B (en) * | 2020-10-12 | 2021-07-09 | 黑龙江科技大学 | NGH decomposition device and constant-temperature decomposition system for gas station |
| CN116726857A (en) * | 2023-08-14 | 2023-09-12 | 烟台百川汇通科技有限公司 | Reaction kettle for preparing anthraquinone hydrogenation catalyst |
| CN116726857B (en) * | 2023-08-14 | 2023-10-10 | 烟台百川汇通科技有限公司 | Reaction kettle for manufacturing anthraquinone hydrogenation catalyst |
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Effective date of abandoning: 20091021 |
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| AV01 | Patent right actively abandoned |
Effective date of abandoning: 20091021 |
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| C25 | Abandonment of patent right or utility model to avoid double patenting |