CN2635679Y - Ultrasonic wave electrochemistry electrolytic tank - Google Patents

Ultrasonic wave electrochemistry electrolytic tank Download PDF

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Publication number
CN2635679Y
CN2635679Y CN 03232261 CN03232261U CN2635679Y CN 2635679 Y CN2635679 Y CN 2635679Y CN 03232261 CN03232261 CN 03232261 CN 03232261 U CN03232261 U CN 03232261U CN 2635679 Y CN2635679 Y CN 2635679Y
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CN
China
Prior art keywords
ultrasonic
ultrasonic wave
generator
electrochemical cell
cell body
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN 03232261
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Chinese (zh)
Inventor
罗耀明
戴迎春
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East China University of Science and Technology
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East China University of Science and Technology
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Publication date
Application filed by East China University of Science and Technology filed Critical East China University of Science and Technology
Priority to CN 03232261 priority Critical patent/CN2635679Y/en
Application granted granted Critical
Publication of CN2635679Y publication Critical patent/CN2635679Y/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The utility model relates to an ultrasonic electrochemical electrolytic cell, which comprises a container, an anode, a cathode and an ion exchange membrane, wherein, the ion exchange membrane is arranged in the middle of the container, which separates the container into cathode chamber and anode chamber. The anode is arranged in the anode chamber and the cathode is arranged in the cathode chamber. The utility model is characterized in that an ultrasonic generator is arranged on the container wall and a bubble generator is arranged at the bottom of the electrolytic cell. The arrangement of the ultrasonic generator and the bubble generator in the electrolytic cell can not only activate the activity of the electrolysis medium to improve the electrochemical yield, but also keep the surface of the ion exchange membrane hard to be polluted to make the ion transfer freely. The surface of the electrodes is not easy to be polluted due to the ultrasonic energy. Therefore, the electrochemical rate of the electrolytic cell can be raised by15 percent to 20 percent compared with the prior art.

Description

A kind of ultrasonic wave electrochemical cell
Technical field
The utility model relates to a kind of electrolyzer, specifically, relates to a kind of electrochemical cell with ultrasonic generator.
Background technology
Electrolyzer is a kind of chemical industry equipment, has in the chemical industry field very to use widely.At present, industrial electrolyzer commonly used generally comprises cell body, is arranged on the anode in the cell body, negative electrode, parts such as ionic membrane.There is some weak point in the electrolyzer of this routine, and the electrochemistry productive rate is low, active easy decline of electrolytic medium, and ionic membrane surface quilt is obstructed so that ionic moves easily, and electrode surface is also contaminated easily, has influenced electrolytic efficiency.
Summary of the invention
The utility model technical issues that need to address are to design a kind of ultrasonic wave electrochemical cell, to overcome the above-mentioned defective that prior art exists.
The technical solution of the utility model:
A kind of ultrasonic wave electrochemical cell, comprise the cell body, anode, negative electrode and the ionic membrane that are provided with the circulating liquid entrance and exit, said ionic membrane is arranged on the cell body middle part, cell body is divided into cathode cavity and anode cavities, anode is arranged in the anode cavities, negative electrode is arranged in the utmost point chamber, it is characterized in that, is provided with ultrasonic generator on the cell body wall.
Further, be provided with the bubble generator that is connected with the circulating liquid inlet at bottom of electrolytic tank, circulating liquid enters electrolyzer by bubble generator, can produce bubble, improves electrolytic efficiency.
By above-mentioned disclosed technical scheme as seen, because electrolyzer of the present utility model is provided with ultrasonic generator and bubble generator in cell body, not only can activate the activity of electrolytic medium, improve the electrochemistry productive rate, and the ionic membrane surface is difficult for contaminatedly, and ion can be moved swimmingly, and electrode surface is also owing to the reason of ultrasonic energy is difficult for contaminated, therefore, the comparable prior art of the electrochemistry productive rate of electrolyzer of the present utility model improves 15%~20%.
Description of drawings
Fig. 1 is a structural representation of the present utility model.
Fig. 2 is a tube shape bubble generator structural representation.
Fig. 3 is discoid bubble generator structural representation.
Embodiment
Referring to Fig. 1, electrolyzer of the present utility model, comprise the cell body 4, anode 2, negative electrode 9 and the ionic membrane 3 that are provided with the circulating liquid entrance and exit, said ionic membrane 3 is arranged on cell body 4 middle parts, cell body 4 is divided into cathode cavity 401 and anode cavities 402, anode 2 is arranged in the anode cavities 402, negative electrode 9 is arranged in the cathode cavity 401, be provided with one or more ultrasonic generators on the cell body wall, the ultrasonic wave of its generation can directly act on electrolytic medium, ionic membrane 3 and anode 2, the negative electrode 9 in the cell body 4;
Said ultrasonic generator is commercially available conventional ultrasound generating unit, comprise ultrasonic generator 7 with its ultrasonic transducer 8 that is connected by cable, ultrasonic generator can be directly installed on the cell body wall, can preferably ultrasonic transducer 7 be installed on the cell body wall, be connected with the independent ultrasonic generator 8 that is provided with by cable 1, can select the ultrasonic generator of ultrasonic frequency in 10~60 kilohertz range for use.
By Fig. 1 simultaneously as seen, the utility model is provided with the bubble generator 5 that is connected with the circulating liquid inlet at bottom of electrolytic tank, as seen from Figure 2, said bubble generator 5 comprises the disk that is provided with many row's apertures 501, the bottom of disk is connected by the inlet of the circulating liquid on pipe and the cell body (4), and circulating liquid enters electrolyzer by aperture 501, can produce bubble, make electrolytic medium produce fluctuation, improve electrolytic efficiency.
Fig. 3 is the bubble generator of another kind of structure, comprise the semicircle disk-like object that is provided with a plurality of apertures 501, the bottom of semicircle disk-like object is connected by the inlet of the circulating liquid on pipe and the cell body (4), circulating liquid enters electrolyzer by the aperture on the semicircle disk-like object 501, produce bubble, make electrolytic medium produce fluctuation, improve electrolytic efficiency.
According to the utility model, preferably adopt flat or net like anode and or/negative electrode;
According to the utility model, preferably adopt flat ionic membrane.

Claims (10)

1. ultrasonic wave electrochemical cell, comprise the cell body (4), anode (2), negative electrode (9) and the ionic membrane (3) that are provided with the circulating liquid entrance and exit, said ionic membrane (3) is arranged on cell body (4) middle part, cell body (4) is divided into cathode cavity (401) and anode cavities (402), it is characterized in that, on the cell body wall, be provided with ultrasonic generator.
2. ultrasonic wave electrochemical cell according to claim 1, it is characterized in that, said ultrasonic generator comprise ultrasonic generator (8) with its ultrasonic transducer (7) that is connected by cable (1), ultrasonic transducer (7) is installed on the cell body wall, is connected with the independent ultrasonic generator (8) that is provided with by cable (1).
3. ultrasonic wave electrochemical cell according to claim 1 is characterized in that, the ultrasonic frequency of ultrasonic generator is 10~60 kilo hertzs.
4. ultrasonic wave electrochemical cell according to claim 2 is characterized in that, the ultrasonic frequency of ultrasonic generator is 10~60 kilo hertzs.
5. ultrasonic wave electrochemical cell according to claim 1 is characterized in that, bottom of electrolytic tank is provided with the bubble generator (5) that is connected with the circulating liquid inlet.
6. ultrasonic wave electrochemical cell according to claim 5 is characterized in that, said bubble generator (5) comprises the disks that are provided with many row's apertures (501), and the bottom of disk enters the mouth by pipe and circulating liquid on the cell body (4) and is connected.
7. ultrasonic wave electrochemical cell according to claim 5, it is characterized in that, said bubble generator (5) comprises the semicircle disk-like object that is provided with aperture (501), and the bottom of semicircle disk-like object is connected by the inlet of the circulating liquid on pipe and the cell body (4).
8. according to each described ultrasonic wave electrochemical cell of claim 1~7, it is characterized in that, adopt the anode and/or the negative electrode of flat or net like.
9. according to each described ultrasonic wave electrochemical cell of claim 1~7, it is characterized in that, adopt flat ionic membrane.
10. ultrasonic wave electrochemical cell according to claim 8 is characterized in that, adopts flat ionic membrane.
CN 03232261 2003-06-17 2003-06-17 Ultrasonic wave electrochemistry electrolytic tank Expired - Fee Related CN2635679Y (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 03232261 CN2635679Y (en) 2003-06-17 2003-06-17 Ultrasonic wave electrochemistry electrolytic tank

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 03232261 CN2635679Y (en) 2003-06-17 2003-06-17 Ultrasonic wave electrochemistry electrolytic tank

Publications (1)

Publication Number Publication Date
CN2635679Y true CN2635679Y (en) 2004-08-25

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 03232261 Expired - Fee Related CN2635679Y (en) 2003-06-17 2003-06-17 Ultrasonic wave electrochemistry electrolytic tank

Country Status (1)

Country Link
CN (1) CN2635679Y (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101005886B (en) * 2005-06-13 2012-07-18 株式会社Omsi Process for producing solution having carbon dioxide dissolved therein, apparatus therefor and carbonated water
CN103920954A (en) * 2014-03-31 2014-07-16 青岛科技大学 Clamp for ultrasonic disturbance electrolyte micro-hole electrolytic machining
CN108048864A (en) * 2017-12-26 2018-05-18 扬州大学 Common cathode ultrasonic electrochemical device
CN114481169A (en) * 2021-12-31 2022-05-13 湖北葛化华祥化学有限公司 Ion membrane electrolysis system
CN114990571A (en) * 2022-05-25 2022-09-02 中国联合重型燃气轮机技术有限公司 Water electrolysis device

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101005886B (en) * 2005-06-13 2012-07-18 株式会社Omsi Process for producing solution having carbon dioxide dissolved therein, apparatus therefor and carbonated water
CN103920954A (en) * 2014-03-31 2014-07-16 青岛科技大学 Clamp for ultrasonic disturbance electrolyte micro-hole electrolytic machining
CN103920954B (en) * 2014-03-31 2017-01-11 青岛科技大学 Clamp for ultrasonic disturbance electrolyte micro-hole electrolytic machining
CN108048864A (en) * 2017-12-26 2018-05-18 扬州大学 Common cathode ultrasonic electrochemical device
CN108048864B (en) * 2017-12-26 2019-10-25 扬州大学 Common cathode ultrasonic electrochemical device
CN114481169A (en) * 2021-12-31 2022-05-13 湖北葛化华祥化学有限公司 Ion membrane electrolysis system
CN114990571A (en) * 2022-05-25 2022-09-02 中国联合重型燃气轮机技术有限公司 Water electrolysis device
CN114990571B (en) * 2022-05-25 2024-06-25 中国联合重型燃气轮机技术有限公司 Water electrolysis device

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C19 Lapse of patent right due to non-payment of the annual fee
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