CN218710884U - Water electrolysis hydrogen production system utilizing ultrasonic field - Google Patents
Water electrolysis hydrogen production system utilizing ultrasonic field Download PDFInfo
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- CN218710884U CN218710884U CN202222491740.2U CN202222491740U CN218710884U CN 218710884 U CN218710884 U CN 218710884U CN 202222491740 U CN202222491740 U CN 202222491740U CN 218710884 U CN218710884 U CN 218710884U
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- cooling
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- cooling water
- water
- electrolytic
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- 229910001868 water Inorganic materials 0.000 title claims abstract description 51
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 37
- 239000001257 hydrogen Substances 0.000 title claims abstract description 37
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 37
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000005868 electrolysis reaction Methods 0.000 title abstract description 9
- 239000000498 cooling water Substances 0.000 claims abstract description 65
- 238000001816 cooling Methods 0.000 claims abstract description 40
- 238000006243 chemical reaction Methods 0.000 claims description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 9
- 239000001301 oxygen Substances 0.000 claims description 9
- 229910052760 oxygen Inorganic materials 0.000 claims description 9
- 238000010248 power generation Methods 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 3
- 238000003487 electrochemical reaction Methods 0.000 abstract description 6
- 238000002604 ultrasonography Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 239000003792 electrolyte Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 230000036632 reaction speed Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model discloses an utilize ultrasonic field's electrolytic water hydrogen manufacturing system, include: the device comprises a power supply system, a control system, an ultrasonic wave generation system, an electrolytic bath system and a cooling circulation system. In such a way, the utility model relates to an utilize electrolysis water hydrogen production system of ultrasonic field, on the one hand, through ultrasonic transducer to the specific frequency signal that ultrasonic generator produced transform to form ultrasonic field and produce cavitation bubble, realized the cleanness of electrode surface, improved electrochemical reaction rate; on one hand, the temperature of the cooling water tank and the temperature of the electrolytic bath are transmitted to a control system by a sensor and are adjusted, so that the temperature of the electrolytic water in the electrolytic bath is ensured, and the electrolytic performance of the electrolytic bath is ensured; on the other hand, the electrolytic bath, the ultrasonic generator, the cooling circulating pump and the like are controlled by the control system, so that the automation control degree is high, the operation is convenient, and the risk of artificial regulation is reduced.
Description
Technical Field
The utility model relates to the technical field of hydrogen production by water electrolysis, in particular to a hydrogen production system by water electrolysis utilizing an ultrasonic field.
Background
Under the target background of 'double carbon', with the release of long-term planning in the development of the hydrogen energy industry, the hydrogen energy rises to the strategic position of national energy. The wind power and the photovoltaic power generation are utilized to electrolyze water to produce hydrogen, intermittent renewable energy sources are converted into hydrogen energy, and the cross-region and cross-time optimal configuration of various energy sources can be realized. However, in the process of producing hydrogen by electrolyzing water, hydrogen and oxygen are generated and then gathered near the electrode plate. When the bubbles are adhered to the surface of the electrode plate, the impedance on the electrode plate is increased, higher overpotential is caused, and meanwhile, the effective contact area between the electrode plate and the electrolyte is reduced; when gas collects in the electrolyte, the gas phase concentration in the electrolyte increases and also affects the conductivity of the solution. These problems all contribute to an increase in the power consumption of the electrolysis process.
Cavitation bubbles are formed in the presence of an ultrasonic field, the surface of the electrode is cleaned, the bubbles on the surface of the electrode disappear, and the surface area of the electrode is increased, so that the electrochemical reaction rate is increased, and the hydrogen yield is increased. Therefore, the existence of the ultrasonic field has important significance for reducing the energy consumption of water electrolysis, improving the utilization efficiency of electric energy and further reducing the hydrogen production cost.
SUMMERY OF THE UTILITY MODEL
The utility model discloses the main technical problem who solves provides an utilize ultrasonic field's electrolytic water hydrogen manufacturing system, has advantages such as reliable performance height, efficient, accurate control, has extensive market prospect in electrolytic water hydrogen manufacturing's application and popularization simultaneously.
In order to solve the technical problem, the utility model discloses a technical scheme be:
provided is a system for producing hydrogen by electrolyzing water using an ultrasonic field, comprising: the device comprises a power supply system, a control system, an ultrasonic wave generation system, an electrolytic bath system and a cooling circulation system, wherein the power supply system, the ultrasonic wave generation system, the electrolytic bath system and the cooling circulation control system are all connected with the control system,
the ultrasonic wave generating system comprises an ultrasonic wave generator and an ultrasonic wave transducer, the ultrasonic wave transducer connected with the ultrasonic wave generator is arranged in the cooling water tank to convert frequency signals generated by the ultrasonic wave generator so as to form an ultrasonic wave field and cavitation bubbles for cleaning electrodes,
the cooling circulation system comprises a cooling water tank, a cooling water circulation pump, a cooling water inlet, a cooling water outlet and a temperature sensor, wherein the cooling water tank is used for storing cooling circulation water, the electrolytic tank and the temperature sensor are arranged in the cooling water tank, so that the electrolytic tank is immersed in the cooling circulation water, the cooling water inlet is arranged at the lower part of the cooling water tank, the cooling water circulation pump is connected with the cooling water inlet so as to send the cooling circulation water discharged from the cooling water outlet and cooled and/or the cooling circulation water in other external equipment into the cooling water tank, and the cooling water outlet is arranged at the upper part of the cooling water tank so as to draw out the cooling circulation water in the cooling water tank, so that the circulation use of the cooling circulation water is controlled.
In a preferred embodiment of the present invention, the power supply system employs a renewable energy power generation system.
In a preferred embodiment of the present invention, the cooling water circulation pump is connected to the cooling water outlet through a circulation cooling pipe.
In a preferred embodiment of the present invention, the electrolytic cell system comprises an electrolytic cell, electrodes, reaction chambers, an oxygen collecting port, and a hydrogen collecting port, wherein the reaction chambers are disposed on the upper portion of the electrolytic cell, one of the oxygen collecting port is disposed on the upper portion of the reaction chamber, and the hydrogen collecting port is disposed on the upper portion of the other reaction chamber.
In a preferred embodiment of the present invention, the oxygen collecting port and the hydrogen collecting port are located above the cooling circulation water.
In a preferred embodiment of the invention, the operating temperature in the electrolytic cell is 60-80 ℃.
In a preferred embodiment of the present invention, the ultrasonic signal transmitted from the ultrasonic generator is greater than or equal to 20kHz.
The utility model has the advantages that: on one hand, the ultrasonic transducer is used for converting a specific frequency signal generated by the ultrasonic generator to form an ultrasonic field and generate cavitation bubbles, so that the surface of the electrode is cleaned, and the electrochemical reaction rate is improved; on one hand, the temperature of the cooling water tank and the electrolytic tank is transmitted to a control system by a sensor and is adjusted, so that the temperature of the electrolytic water in the electrolytic tank is ensured, and the electrolytic performance of the electrolytic tank is ensured; on the other hand, the electrolytic bath, the ultrasonic generator, the cooling circulating pump and the like are controlled by the control system, so that the automatic control degree is high, the operation is convenient, and the risk of artificial regulation is reduced.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the drawings used in the description of the embodiments are briefly introduced below, and it is obvious that the drawings in the following description are only some embodiments of the present invention, and for those skilled in the art, other drawings can be obtained without inventive work, wherein:
fig. 1 is a schematic structural diagram of a preferred embodiment of the system for producing hydrogen by electrolyzing water using an ultrasonic field according to the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be described clearly and completely below, and it should be apparent that the described embodiments are only some embodiments of the present invention, but not all embodiments. Based on the embodiments in the present invention, all other embodiments obtained by a person skilled in the art without creative efforts belong to the protection scope of the present invention.
Referring to fig. 1, an embodiment of the present invention includes:
a system for producing hydrogen by electrolyzing water by using an ultrasonic field comprises a power supply system 1, a control system 2, an ultrasonic generation system, an electrolytic bath system and a cooling circulation system.
The electrolytic cell system can adopt a commonly used electrolytic cell structure and mainly comprises an electrolytic cell 11, an electrode 12, two reaction bins, an oxygen collecting port 13 and a hydrogen collecting port 14, wherein the two reaction bins are oppositely arranged on the upper part of the electrolytic cell, one of the two reaction bins is provided with one oxygen collecting port, and the other reaction bin is provided with one hydrogen collecting port.
The ultrasonic wave generating system comprises an ultrasonic wave generator 5 and an ultrasonic wave transducer 6, and the ultrasonic wave transducer connected with the ultrasonic wave generator is arranged in the cooling water tank.
The cooling circulation system comprises a cooling water tank 3 for storing cooling circulation water 4, a cooling water circulating pump 7, a cooling water inlet 8, a cooling water outlet 9 and a temperature sensor 10, wherein the electrolytic tank and the temperature sensor are arranged in the cooling water tank, so that the electrolytic tank is directly immersed into the cooling circulation water, the cooling water inlet is arranged at the lower part of the cooling water tank, the cooling water circulating pump is connected with the cooling water inlet to send the cooling circulation water into the cooling water tank through the cooling water inlet, and the cooling water outlet is arranged at the upper part of the cooling water tank to pump out the cooling circulation water in the cooling water tank, so that the circulation use of the cooling circulation water is controlled.
During cooling operation, the cooling circulating water 4 enters the cooling water tank 3 through the cooling water inlet 8 by the cooling water circulating pump 7 and flows out of the cooling water tank 3 through the cooling water outlet 9, the cooling water circulating pump inlet is connected with the cooling water outlet and/or external circulating water, and the temperature sensor 10 and the cooling water circulating pump 7 in the cooling water tank 3 are both connected with the control system 2. When the temperature of cooling circulating water in the cooling water tank (or the running temperature of the electrolytic bath) is lower than 60 ℃, stopping running the circulating pump, and waiting for the temperature rise of the system; when the temperature of the cooling circulating water in the cooling water tank (or the operation temperature of the electrolytic tank) is gradually increased to 80 ℃, the circulating pump is started, and the cooling circulating water takes away the redundant heat, so that the electrolytic tank is ensured to operate at the stable optimal operation temperature (60-80 ℃), and the electrolytic performance of the electrolytic tank is ensured.
The ultrasonic wave generation system, the electrolytic cell system and the cooling circulation control system are all connected with the control system and used for receiving and transmitting feedback signals, so that the electrolytic cell, the ultrasonic generator, the cooling circulation pump and the like are controlled by the control system, the degree of automation control is high, the operation is convenient, and the risk of artificial regulation and control is reduced.
In actual operation, in order to conveniently evaluate and evaluate the hydrogen production process link of the electrolyzed water, the control system sends start-stop signals to the ultrasonic generator in due time through program setting, and in addition, the control system monitors the temperature of the electrolytic cell and adjusts the temperature through controlling the circulating pump, thereby being beneficial to the stable operation of the system and improving the efficiency of the electrolytic cell.
The control system is connected with the electric power supply system to obtain energy supply.
Further preferably, the power supply system employs a renewable energy power generation system.
The working principle of the water electrolysis hydrogen production system utilizing the ultrasonic field comprises: the control system analyzes according to the volt-ampere characteristic curve of the operation of the electrolytic bath, and feeds back the analysis result to the ultrasonic generator so as to control the ultrasonic generator to send ultrasonic signals with specific frequency of 20 kHz-hundreds of kHz; the ultrasonic transducer 6 arranged in the cooling water tank 3 is used for converting a specific frequency signal generated by the ultrasonic generator to form an ultrasonic field, the ultrasonic field is transmitted to the electrolytic tank 11 by taking cooling circulating water 4 as a medium, cavitation bubbles are formed in the electrolytic tank 11 due to the existence of the ultrasonic field, and the surface of the electrode 12 is cleaned to eliminate the bubbles on the surface of the electrode, so that the surface area of the electrode is increased, the electrochemical reaction rate is increased, and the stable operation of the electrolytic tank is maintained and balanced; the generated gas is discharged from the oxygen gas collecting port 13 and the hydrogen gas collecting port 14, respectively, and is collected and stored by the gas-liquid separation device.
The utility model relates to an utilize electrolysis water hydrogen manufacturing system of ultrasonic field's beneficial effect is:
(1) Introducing ultrasound in the electrochemical reaction process, cleaning the surface of the electrode by using the cavitation action of the ultrasound, keeping the activity of the electrode, expelling micro bubbles on the surface of the electrode by using the cavitation action and the degassing action of the ultrasound by using the cavitation of the ultrasound, improving the actual surface area of the surface of the electrode and increasing the reaction speed;
(2) The mass transfer process in the electrochemical reaction is enhanced by utilizing the cavitation effect of the ultrasound and the subsequent micro-jet effect, the reaction speed is improved, the tank voltage is reduced, and the energy consumption is saved;
(3) The temperature sensor is used for feeding back the temperature in real time, so that accurate heat exchange can be realized, and the temperature of the electrolytic cell can be controlled.
The above-mentioned only be the embodiment of the utility model, not consequently the restriction the patent scope of the utility model, all utilize the equivalent structure or equivalent flow transform that the content of the specification was done, or directly or indirectly use in other relevant technical field, all the same reason is included in the patent protection scope of the utility model.
Claims (7)
1. An electrolytic water hydrogen production system using an ultrasonic field, comprising: the device comprises a power supply system, a control system, an ultrasonic wave generation system, an electrolytic bath system and a cooling circulation system, wherein the power supply system, the ultrasonic wave generation system, the electrolytic bath system and the cooling circulation control system are all connected with the control system,
the ultrasonic wave generating system comprises an ultrasonic generator and an ultrasonic transducer, the ultrasonic transducer connected with the ultrasonic generator is arranged in the cooling water tank to convert frequency signals generated by the ultrasonic generator so as to form an ultrasonic field and cavitation bubbles for cleaning electrodes,
the cooling circulation system comprises a cooling water tank, a cooling water circulation pump, a cooling water inlet, a cooling water outlet and a temperature sensor, wherein the cooling water tank is used for storing cooling circulation water, the electrolytic tank and the temperature sensor are arranged in the cooling water tank, so that the electrolytic tank is immersed in the cooling circulation water, the cooling water inlet is arranged at the lower part of the cooling water tank, the cooling water circulation pump is connected with the cooling water inlet so as to send the cooling circulation water discharged from the cooling water outlet and cooled and/or the cooling circulation water in other external equipment into the cooling water tank, and the cooling water outlet is arranged at the upper part of the cooling water tank so as to draw out the cooling circulation water in the cooling water tank, so that the circulation use of the cooling circulation water is controlled.
2. The system for producing hydrogen by electrolyzing water using an ultrasonic field as claimed in claim 1, wherein the power supply system employs a renewable energy power generation system.
3. The system for producing hydrogen by electrolyzing water using an ultrasonic field as set forth in claim 1, wherein the cooling water circulating pump is connected to the cooling water outlet through a circulating cooling pipe.
4. The system for producing hydrogen by electrolyzing water by using an ultrasonic field according to claim 1, wherein the electrolytic cell system comprises an electrolytic cell, electrodes, reaction chambers, an oxygen collecting port, and a hydrogen collecting port, two reaction chambers for mounting and placing electrodes are oppositely arranged on the upper part of the electrolytic cell, one of the reaction chambers is provided with the oxygen collecting port on the upper part, and the other reaction chamber is provided with the hydrogen collecting port on the upper part.
5. The system for producing hydrogen by electrolyzing water using an ultrasonic field as set forth in claim 4, wherein said oxygen collecting port and said hydrogen collecting port are located above the cooling circulation water.
6. The system for producing hydrogen by electrolyzing water using ultrasonic field as claimed in claim 1, wherein the operation temperature in the electrolytic bath is 60-80 ℃.
7. The system for producing hydrogen by electrolyzing water using an ultrasonic field as claimed in claim 1, wherein the ultrasonic signal transmitted from the ultrasonic generator is 20kHz or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202222491740.2U CN218710884U (en) | 2022-09-21 | 2022-09-21 | Water electrolysis hydrogen production system utilizing ultrasonic field |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202222491740.2U CN218710884U (en) | 2022-09-21 | 2022-09-21 | Water electrolysis hydrogen production system utilizing ultrasonic field |
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| CN218710884U true CN218710884U (en) | 2023-03-24 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115287680A (en) * | 2022-09-21 | 2022-11-04 | 中能(江苏苏州)氢能源科技有限公司 | Water electrolysis hydrogen production system utilizing ultrasonic field |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN115287680A (en) * | 2022-09-21 | 2022-11-04 | 中能(江苏苏州)氢能源科技有限公司 | Water electrolysis hydrogen production system utilizing ultrasonic field |
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20240116 Address after: 735000, No. 8 Xinglong Road, Nanyuan, Economic and Technological Development Zone, Suzhou District, Jiuquan City, Gansu Province Patentee after: Gansu Qingqiji Zhongneng Hydrogen Energy Technology Co.,Ltd. Address before: 215000 Room 214, 23 Blocks, Zhongbei District, No. 99 Jinjihu Avenue, Suzhou Industrial Park, Jiangsu Province Patentee before: China Energy (Jiangsu Suzhou) Hydrogen Energy Technology Co.,Ltd. |