CN220759162U - Throttling type gas hydrate generation device - Google Patents

Throttling type gas hydrate generation device Download PDF

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Publication number
CN220759162U
CN220759162U CN202321677182.7U CN202321677182U CN220759162U CN 220759162 U CN220759162 U CN 220759162U CN 202321677182 U CN202321677182 U CN 202321677182U CN 220759162 U CN220759162 U CN 220759162U
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gas
pipe section
reaction kettle
laval nozzle
pressure reaction
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徐慧
俞恺雯
杨德良
蔡海霞
郑颖
杨梦祺
詹梦兰
李钰清
雷舒颖
王树立
姚景
吴茶水
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Quanzhou Vocational And Technical University
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Quanzhou Vocational And Technical University
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Abstract

The utility model belongs to the technical field of gas hydrates, and particularly relates to a throttling type gas hydrate preparation device. The reaction device comprises a high-pressure reaction kettle and an atomization nozzle arranged in the high-pressure reaction kettle; the gas-liquid conveying device comprises a gas storage bottle, a supersonic cyclone separation device arranged between the high-pressure reaction kettle and the gas storage bottle and a gas booster pump connected with the gas storage bottle, wherein one end of the gas booster pump is also connected with an air compressor; the cooling device comprises a first Laval nozzle connected to the gas cylinder. The water bath refrigeration equipment is replaced by the Laval nozzle, so that the effects of saving equipment cost, reducing energy consumption and simplifying operation are achieved.

Description

Throttling type gas hydrate generation device
Technical Field
The utility model belongs to the technical field of gas hydrates, and particularly relates to a throttling type gas hydrate production device.
Background
Gas hydrate is a non-stoichiometric, ice-like clathrate formed by host (water) and guest (gas) molecules at low temperature and high pressure. The gases that may form the hydrates include methane, ethane, propane, CO2, H2S, and the like. With the continuous and deep research of gas hydrate technology, the research and application of technologies based on gas hydrate characteristics, such as carbon dioxide capturing and sealing, sea water desalination and mixed gas separation, natural gas storage and transportation, and the like, have been increasingly focused. However, in the industrial production and application process, the bottleneck of the related technology application based on hydrate generation is mainly that the requirement of the generation condition is high, the generation speed is slow, the induction time is long, the gas storage density is low, and the like. The key problem solved at present is to improve the generation rate and efficiency of the hydrate. The current methods of enhancing hydrate formation fall into two broad categories: chemical physical strengthening and mechanical strengthening. The chemical physical strengthening is mainly to add an accelerator to promote the generation of hydrate, and the accelerator comprises a thermodynamic accelerator and a kinetic accelerator. The mechanical strengthening method mainly comprises stirring method, bubbling method, spraying method, external field method, etc. The mechanical strengthening mainly increases the gas-liquid contact area and rapidly dissipates heat generated in the hydration reaction. At present, the stirring method has the disadvantages of large energy consumption, low gas storage density, easy abrasion and the like, is rarely used alone in industry, but is applied to most of static hydrate generation experimental devices; by adopting ultrasonic atomization, the gas-liquid contact area is increased, and the hydrate generation speed can be improved, but the ultrasonic atomizer added by the experimental system not only increases the investment cost, but also increases the operation cost required by the experiment.
Hydrate formation mainly includes two processes, nucleation and growth. Nucleation refers to the process of forming stable hydrate nuclei reaching a critical dimension when the solution is in a supercooled state or a supersaturated state, and entering a stable growth stage of the hydrate after the nuclei reach a certain critical dimension. Nucleation generally involves an induction period of time during which the nuclei are formed, with greater randomness and instability. In addition, in the process of generating the hydrate, a hydrate film can be formed to prevent gas from entering the water phase and the hydrate phase and prevent the generation of the hydrate. The conditions for hydrate formation are severe, which is also a difficulty for industrial application. In the experiment of generating the hydrate, a certain time is required to be spent for cooling, so that the condition of generating the hydrate is achieved, and the condition also means that energy is consumed for cooling and heat preservation. Therefore, there is a need for a device that accelerates hydrate formation under conditions that allow rapid cooling without the need for additional heat transfer media and that reduce intermediate energy consumption and that are in sufficient contact with water to rapidly achieve hydrate formation.
Disclosure of Invention
The utility model discloses a throttling type gas hydrate generation device, which mainly solves the problems of long time consumption and high generation condition requirements of the existing hydrate generation.
In order to achieve the purpose, the utility model provides a throttling type gas hydrate generation device which is characterized by comprising a gas-liquid conveying device, a cooling device, a reaction device and a monitoring device, wherein the reaction device comprises a high-pressure reaction kettle and an atomization nozzle arranged in the high-pressure reaction kettle; the gas-liquid conveying device comprises a gas storage bottle, a supersonic cyclone separation device arranged between the high-pressure reaction kettle and the gas storage bottle and a gas booster pump connected with the gas storage bottle, wherein one end of the gas booster pump is also connected with an air compressor; the cooling device comprises a first Laval nozzle connected to the gas cylinder.
Preferably, an observation window is formed in the high-pressure reaction kettle, and the high-pressure reaction kettle is further connected with a vacuum pump.
Preferably, the monitoring device comprises a sensor connected with the high-pressure reaction kettle, a high-fiber camera device connected with the high-pressure reaction kettle and a data collector connected with the sensor, wherein the data collector is connected with a computer, and the sensor is used for measuring the pressure and the temperature in the high-pressure reaction kettle.
Preferably, the diameter of the first Laval nozzle in the cooling device is d, the first Laval nozzle is divided into a convergent pipe section and a divergent pipe section, the minimum diameter of the convergent pipe section and the divergent pipe section is 0.35d, the length of the divergent pipe section is longer than that of the pipe section, and the throat diameter of the first Laval nozzle is 0.2 d-0.6 d.
Preferably, a second Laval nozzle is arranged in the supersonic cyclone separation device, the inner diameter of a pipeline of the second Laval nozzle is d, the second Laval pipeline is divided into a convergent pipe section and a divergent pipe section, the minimum diameter of the convergent pipe section and the divergent pipe section is 0.25d, the length of the divergent pipe section is longer than that of the pipe section, and the throat diameter of the second Laval pipeline is 0.1-0.5 d.
Preferably, the supersonic cyclone separation device is internally provided with at least one spiral blade, the number of the spiral blades is d, and the included angle between the spiral blade and the wall surface of the supersonic cyclone separation device is 30-60 degrees.
Preferably, the supersonic cyclone separation device is provided with a waste liquid outlet, the included angle between the waste liquid outlet and the horizontal plane is 0-60 degrees, and a waste liquid recovery device is arranged below the waste liquid outlet.
Preferably, the gas cylinder is also connected with a stop valve, and the stop valve is connected with the supersonic cyclone separation device.
Preferably, one end of the atomizing nozzle is provided with a reactant inlet.
Preferably, a pressure release valve is arranged between the gas booster pump and the air compressor.
The technical scheme provided by the utility model has at least the following technical effects:
(1) The water bath refrigeration equipment is replaced by the Laval nozzle, so that the effects of saving equipment cost, reducing energy consumption and simplifying operation are achieved.
(2) The Laval nozzle and the helical blade are utilized to realize the efficient gas-liquid separation operation without external energy consumption.
(3) The Laval nozzle can be used for quickly cooling gas, and the gas and the liquid are in contact with each other to directly transfer heat, so that a third heat transfer medium is not needed, and the generation speed of the hydrate is accelerated.
(4) The gas hydrate preparation device adopted by the utility model has low preparation investment and device operation cost.
Drawings
In order to more clearly illustrate the technical solutions of the embodiments of the present utility model, the drawings that are needed in the embodiments or the description of the prior art will be briefly described below, it being obvious that the drawings in the following description are only some embodiments of the present utility model, and that other drawings may be obtained according to these drawings without inventive effort for a person skilled in the art.
FIG. 1 is a schematic view of a device according to an embodiment of the present utility model;
FIG. 2 is a schematic view of the structure of a first Laval nozzle according to an embodiment of the present utility model;
FIG. 3 is a schematic view of a supersonic cyclone separation device according to an embodiment of the present utility model;
FIG. 4 is a cross-sectional view of a helical vane duct according to an embodiment of the utility model;
the main reference numerals illustrate: 1. a gas cylinder; 2. a stop valve; 3. a pressure gauge; 4. a gas booster pump; 5. a pressure release valve; 6. a gas compressor; 7. a supersonic cyclone separator; 7-1, helical blades; 7-2, a second Laval nozzle; 7-3, a waste liquid outlet; 8. a waste liquid recovery device; 9. a reactant inlet; 10. an atomizing nozzle; 11. a high-pressure reaction kettle; 12. a first laval nozzle; 12-1, a tapered tube section; 12-2, gradually expanding the pipe section; 12-3, throat; 12-4, inlet of the tapered pipe section; 12-5, an outlet of the diverging pipe section; 13. an observation window; 14. a temperature sensor; 15. a pressure sensor; 16. a high-fiber camera device; 17. a vacuum pump; 18. a computer; 19. and a data acquisition device.
Detailed Description
Embodiments of the present utility model are described in detail below, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to like or similar elements or elements having like or similar functions throughout. The embodiments described below by referring to the drawings are exemplary and intended to illustrate embodiments of the utility model and should not be construed as limiting the utility model.
In the description of the embodiments of the present utility model, it should be understood that the terms "length," "width," "upper," "lower," "front," "rear," "left," "right," "vertical," "horizontal," "top," "bottom," "inner," "outer," and the like indicate orientations or positional relationships based on the orientation or positional relationships shown in the drawings, merely to facilitate description of the embodiments of the present utility model and simplify description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present utility model.
Furthermore, the terms "first," "second," and the like, are used for descriptive purposes only and are not to be construed as indicating or implying a relative importance or implicitly indicating the number of technical features indicated. Thus, a feature defining "a first" or "a second" may explicitly or implicitly include one or more of the described features. In the description of the embodiments of the present utility model, the meaning of "plurality" is two or more, unless explicitly defined otherwise.
Referring to fig. 1-4, the present utility model provides a throttling type gas hydrate generating device, which is characterized by comprising a gas-liquid conveying device, a cooling device, a reaction device and a monitoring device, wherein the reaction device comprises a high-pressure reaction kettle and an atomization nozzle arranged in the high-pressure reaction kettle; the gas-liquid conveying device comprises a gas storage bottle, a supersonic rotational flow separation device arranged between the high-pressure reaction kettle and the gas storage bottle and a gas booster pump connected with the gas storage bottle, wherein one end of the gas booster pump is further connected with an air compressor, the cooling device comprises a first Laval nozzle connected with the gas storage bottle, an observation window is formed in the high-pressure reaction kettle, the high-pressure reaction kettle is further connected with a vacuum pump, the monitoring device comprises a sensor connected with the high-pressure reaction kettle, a high-fiber camera device connected with the high-pressure reaction kettle and a data collector connected with the sensor, the data collector is connected with a computer, the sensor is used for measuring the pressure and the temperature in the high-pressure reaction kettle, the pipeline diameter of the first Laval nozzle in the cooling device is d, the first Laval nozzle is divided into a tapered pipe section and a gradually-expanded pipe section, the minimum diameter of the tapered pipe section and the gradually-expanded pipe section is 0.35d, the length of the gradually-expanded pipe section is longer than the length of the first Laval pipe is 0.4d throat. The ultrasonic cyclone separation device is characterized in that a second Laval nozzle is arranged in the ultrasonic cyclone separation device, the inner diameter of a pipeline of the second Laval nozzle is d, the second Laval pipeline is divided into a convergent pipe section and a divergent pipe section, the minimum diameter of the convergent pipe section and the divergent pipe section is 0.25d, the length of the divergent pipe section is longer than that of the pipe section, the throat diameter of the second Laval pipeline is 0.5d, helical blades are further arranged in the ultrasonic cyclone separation device, the number of the helical blades is 2, the width is d, the included angle between the helical blades and the wall surface of the ultrasonic cyclone separation device is 60 degrees, a waste liquid outlet is formed in the ultrasonic cyclone separation device, the included angle between the waste liquid outlet and the horizontal plane is 30 degrees, a waste liquid recovery device is arranged below the waste liquid outlet, a stop valve is further connected with the ultrasonic cyclone separation device, a reaction reagent inlet is formed in one end of the atomizing nozzle, and a pressure release valve is further arranged between the booster pump and the air compressor.
Before the experiment starts, the high-pressure reaction kettle is required to be cleaned for 2-3 times by using distilled water, and then a vacuum pump is started to enable the inside of the kettle to be in a vacuum state. The experimental gas is provided by a gas cylinder, when the experiment is started, the gas cylinder is opened, the gas enters the first Laval nozzle with the inlet diameter of the convergent pipe section of 0.8d, the throat diameter of 0.4d and the outlet diameter of the divergent pipe section of 0.8d along with the pipeline, the speed of the gas is increased to supersonic speed after the gas passes through the first Laval nozzle, the temperature is rapidly reduced along with the gas, and the gas is rapidly cooled. The cooled gas then rapidly enters the autoclave and comes into sufficient contact with the reaction solution which has entered via the reaction solution inlet and has been atomized by the atomizer head to form hydrates. The macroscopic generation process of the hydrate can be observed through an observation window arranged on the high-pressure reaction kettle. In addition, the macro generation process of the hydrate in each time can be shot through a high-fiber shooting device. The temperature and pressure changes in the high-pressure reaction kettle are measured by a temperature sensor and a pressure sensor respectively and transmitted to a data acquisition device and a computer for data processing and recording. If the pressure of the gas entering the high-pressure reaction kettle does not reach the value set by the experiment, the gas can be pressurized by a gas booster pump and a gas compressor. In addition, the gas pressure in the high-pressure reaction kettle can be regulated through a gas circulation pipeline, in order to obtain circulating gas without impurities, the gas and the liquid are separated through a supersonic cyclone separation device, the supersonic cyclone separation device consists of a second Laval nozzle and a helical blade, and the second Laval nozzle plays a role in continuously cooling the gas on one hand and accelerating the gas on the other hand. In this embodiment, the diameter of the inlet of the tapered tube section of the second laval nozzle is d, the diameter of the throat is 0.5d, the diameter of the outlet of the tapered tube section is d, the number of spiral blades is 2, the width is d, the twist rate is 2, and the angle between the blades and the wall surface is 60 °. The waste liquid is discharged from the system through an outlet arranged on the supersonic cyclone separation device and is received by the waste liquid recovery device, and the included angle between the waste liquid outlet of the device and the wall surface is 30 degrees. The rest clean gas enters the system again through the circulating pipeline to participate in the reaction, thereby achieving the effect of recycling and saving resources.
The utility model has the following advantages:
(1) The water bath refrigeration equipment is replaced by the Laval nozzle, so that the effects of saving equipment cost, reducing energy consumption and simplifying operation are achieved.
(2) The Laval nozzle and the helical blade are utilized to realize the efficient gas-liquid separation operation without external energy consumption.
(3) The Laval nozzle can be used for quickly cooling gas, and the gas and the liquid are in contact with each other to directly transfer heat, so that a third heat transfer medium is not needed, and the generation speed of the hydrate is accelerated.
(4) The gas hydrate preparation device adopted by the utility model has low preparation investment and device operation cost.
The foregoing description of the preferred embodiment of the utility model is not intended to be limiting, but rather is intended to cover all modifications, equivalents, and alternatives falling within the spirit and principles of the utility model.

Claims (10)

1. The throttling type gas hydrate generation device is characterized by comprising a gas-liquid conveying device, a cooling device, a reaction device and a monitoring device, wherein the reaction device comprises a high-pressure reaction kettle and an atomization nozzle arranged in the high-pressure reaction kettle; the gas-liquid conveying device comprises a gas storage bottle, a supersonic cyclone separation device arranged between the high-pressure reaction kettle and the gas storage bottle and a gas booster pump connected with the gas storage bottle, wherein one end of the gas booster pump is also connected with an air compressor, and the cooling device comprises a first Laval nozzle connected with the gas storage bottle.
2. The throttling gas hydrate generation device according to claim 1, wherein an observation window is formed on the high-pressure reaction kettle, and the high-pressure reaction kettle is further connected with a vacuum pump.
3. The throttling gas hydrate generation device according to claim 1, wherein the monitoring device comprises a sensor connected with the high-pressure reaction kettle, a high-fiber camera device connected with the high-pressure reaction kettle and a data collector connected with the sensor, wherein the data collector is connected with a computer, and the sensor is used for measuring the pressure and the temperature in the high-pressure reaction kettle.
4. The throttling gas hydrate formation apparatus according to claim 1, wherein a pipe diameter of a first laval nozzle in said cooling apparatus is d, said first laval nozzle is divided into a tapered pipe section and a diverging pipe section, a minimum diameter of said tapered pipe section and said diverging pipe section is 0.35d, a length of said diverging pipe section is longer than a pipe section length, and a throat diameter of said pipe of said first laval nozzle is 0.2d to 0.6d.
5. The throttling gas hydrate generation device according to claim 1, wherein a second laval nozzle is arranged in the supersonic cyclone separation device, the inner diameter of the second laval nozzle is d, the second laval nozzle is divided into a tapered pipe section and a divergent pipe section, the minimum diameter of the tapered pipe section and the divergent pipe section is 0.25d, the length of the divergent pipe section is longer than the length of the pipe section, and the throat diameter of the second laval nozzle is 0.1-0.5 d.
6. The throttling gas hydrate generation device according to claim 5, wherein a spiral blade is further arranged in the supersonic cyclone separation device, the number of the spiral blades is at least one, the width is d, and the included angle between the spiral blade and the wall surface of the supersonic cyclone separation device is 30-60 degrees.
7. The throttling gas hydrate generation device according to claim 5, wherein the supersonic cyclone separation device is provided with a waste liquid outlet, an included angle between the waste liquid outlet and a horizontal plane is 0-60 degrees, and a waste liquid recovery device is arranged below the waste liquid outlet.
8. A throttled gas hydrate formation apparatus according to claim 1, wherein the gas cylinder is further connected with a shut-off valve, the shut-off valve being connected with a supersonic cyclonic separating apparatus.
9. The throttling gas hydrate formation device according to claim 1, wherein one end of the atomizer is provided with a reactant inlet.
10. The throttling gas hydrate generation apparatus according to claim 1, wherein a pressure release valve is provided between the gas booster pump and the air compressor.
CN202321677182.7U 2023-06-29 2023-06-29 Throttling type gas hydrate generation device Active CN220759162U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202321677182.7U CN220759162U (en) 2023-06-29 2023-06-29 Throttling type gas hydrate generation device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202321677182.7U CN220759162U (en) 2023-06-29 2023-06-29 Throttling type gas hydrate generation device

Publications (1)

Publication Number Publication Date
CN220759162U true CN220759162U (en) 2024-04-12

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