CN219531759U - Heat exchange ozone generator system - Google Patents

Heat exchange ozone generator system Download PDF

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Publication number
CN219531759U
CN219531759U CN202222885412.0U CN202222885412U CN219531759U CN 219531759 U CN219531759 U CN 219531759U CN 202222885412 U CN202222885412 U CN 202222885412U CN 219531759 U CN219531759 U CN 219531759U
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ozone generator
pipe
cooling water
ozone
heat exchange
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CN202222885412.0U
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于秀梅
杨新明
刘承业
尚友才
于国磊
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Lihuayi Weiyuan Chemical Co ltd
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Lihuayi Weiyuan Chemical Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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Abstract

The utility model relates to the technical field of ozone generators, and provides a heat exchange ozone generator system which comprises a heat exchanger, an ozone generator, an ozone power supply cabinet and a circulating pipeline. The external circulation cooling water supply pipe and the external circulation cooling water return pipe are respectively connected with an external circulation pipe and an internal circulation pipe of the heat exchanger; the ozone generator is provided with an ozone generator circulating water tank and a circulating water inlet pipe and an ozone generator circulating water outlet pipe which are communicated with the circulating water tank; the internal circulation cooling water inlet and outlet pipe is respectively connected with the internal circulation pipe of the heat exchanger and the water outlet pipe of the ozone generator. The utility model adopts pure oxygen source to replace instrument wind as raw material source of ozone generator, designs heat exchanger and heat exchange circulation pipeline matched with ozone generator and ozone power cabinet, and can make cooling water temperature and water quality index meet optimum working requirements of ozone generator, and can greatly reduce produced ozone concentration, failure rate and energy consumption.

Description

Heat exchange ozone generator system
Technical Field
The utility model relates to the technical field of ozone generators, in particular to a heat exchange ozone generator system.
Background
The preparation of industrial ozone generally uses instrument wind or power wind as raw materials, firstly uses a gas storage tank to stabilize pressure, then uses a cold drier to dehydrate and deoil and filter dust, then uses an oxygen-enriched machine to support nitrogen to obtain an oxygen-enriched source, and the oxygen is subjected to electrochemical reaction in a high-voltage discharge type ozone generator, so that the ozone is manufactured. When the ozone generator works, a large amount of heat energy is generated, cooling is needed, otherwise, ozone can be decomposed while being generated due to high temperature. The water-cooled ozone generator has good cooling effect, stable operation, no ozone attenuation and long-time continuous operation. The ozone generator has the advantages of mature technology, stable operation, long service life, large ozone yield (the single machine can reach 1 Kg/h) and the like, so the ozone generator is the most widely used ozone generator in relevant industries at home and abroad. However, the process has the advantages of complex ozone preparation structure, high cost, high investment and high operation and use cost, and not only does auxiliary equipment occupy more space, but also needs to further improve the benefit and reduce the investment and operation cost.
To improve the benefit, the investment on equipment is reduced, the process flow is optimized, the failure rate of the equipment is reduced, and the energy consumption is reduced. Using instrument wind as raw material, only the unit price of the instrument wind is 0.37 yuan/m 3 If other surplus pure oxygen is utilized, the investment cost of the equipment for preparing the instrument wind and the oxygen is saved.
The method comprises the steps of using instrument wind (clean and dry compressed air) as a raw material, separating nitrogen from oxygen by an oxygen enriching machine (PSA air separation system), and collecting oxygen as a raw material gas (the raw material gas contains inert gas, carbon dioxide and a small amount of nitrogen, and is not pure oxygen, so called a rich oxygen source), wherein the ozone is generated by oxygen, the content of oxygen in the air is only 21%, so that the ozone concentration generated by an air type generator is relatively low, and the oxygen purity of the oxygen type oxygen generator is above 90%, so that the ozone concentration of the oxygen type generator is high. The pure oxygen is higher than the oxygen-enriched source, so that the concentration of ozone generated is higher, the electric power loss of inert gas, carbon dioxide and a small amount of nitrogen in the oxygen-enriched source when electrochemical reaction occurs in the high-voltage discharge type ozone generator is reduced, and the operation cost is reduced.
Substantially all generator ozone production is sensitive to changes in coolant temperature due to the greater effect of heat dissipation on ozone production. With the increase of the cooling water temperature, the relative ozone yield is obviously reduced, the cooling water temperature used by a common ozone generator is controlled to be 15-25 ℃, and 2500-4000L of cooling water at 15-25 ℃ is needed for producing 1kg of ozone by the common water-cooled ozone generator. Increasing the coolant flow helps to compensate for both the reduced capacity due to the high power density (gas temperature) and the loss of dielectric damage due to the increased dielectric temperature. However, in reality, cooling water of most enterprises has poor water temperature and water quality indexes, so that the capacity of the ozone generator is too low and the failure rate is too high.
Disclosure of Invention
In order to solve the problems existing in the background technology, the utility model provides a heat exchange ozone generator system, which comprises a heat exchanger, an ozone generator, an ozone power cabinet and a circulation pipeline, wherein the circulation pipeline comprises an outer circulation cooling water supply pipe, an outer circulation cooling water return pipe, an inner circulation cooling water inlet and outlet pipe and a power cabinet cooling water supply pipe; wherein the heat exchanger is provided with a heat exchange plate, an outer circulation pipe and an inner circulation pipe which are connected with the heat exchange plate; the external circulation cooling water supply pipe and the external circulation cooling water return pipe are respectively connected with an external circulation pipe and an internal circulation pipe of the heat exchanger; the ozone generator is provided with an ozone generator circulating water tank and a circulating water inlet pipe and an ozone generator circulating water outlet pipe which are communicated with the circulating water tank; the inner circulating cooling water inlet and outlet pipe is respectively connected with an inner circulating pipe of the heat exchanger and an outlet pipe of the ozone generator; an electrode tube electrically connected with the ozone power supply cabinet is arranged in the circulating water tank, and a pure oxygen inlet and an ozone outlet are arranged at two ends of the electrode tube.
In the preferred scheme, the internal circulation cooling water inlet and outlet pipe is internally provided with double pipelines, namely a hot water pipeline and a cold water pipeline.
In the preferred scheme, a heat exchange circulation loop is arranged in the ozone power cabinet, and a power cabinet cooling water outlet pipe and a power cabinet cooling water supply pipe are arranged in the heat exchange circulation loop; the cooling water supply pipe of the power cabinet is connected with the cold water pipeline of the internal circulating cooling water inlet and outlet pipe, and the cooling water outlet pipe of the power cabinet is connected with the circulating water inlet pipe of the ozone generator.
In the preferred scheme, a pipeline pump and a damper for absorbing impact force and reducing vibration generated by impact are arranged in a connecting pipeline of the inner circulating cooling water inlet and outlet pipe and the inner circulating pipe of the heat exchanger.
In a preferred scheme, the heat exchange plate is formed by stacking metal sheets, cold and hot channels are formed between various sheets, and heat exchange is carried out through the sheets.
In a preferred embodiment, the heat exchanger is provided with a base, and the heat exchanger plate is mounted on the base.
The beneficial effects achieved by the utility model are as follows:
firstly, the utility model adopts pure oxygen source to replace instrument wind as raw material source of ozone generator, and designs heat exchanger and heat exchange circulation pipeline matched with ozone generator and ozone power supply cabinet, and the cooling water temperature and water quality index can meet the optimum working requirements of ozone generator, and the produced ozone concentration can be increased, and the failure rate can be greatly reduced, and compared with instrument wind system, the ozone power consumption produced by ozone generator can be reduced by above 50%.
And secondly, the system is simple to operate and maintain, is simple and convenient to mount and dismount, and is suitable for the transformation of old equipment and the installation of a new ozone generator.
Drawings
Fig. 1 is an overall construction diagram of the present utility model.
Fig. 2 is a diagram of a heat exchanger and circulation line of the present utility model.
FIG. 3 is a diagram of an ozone generator and a circulation line of the present utility model.
The reference numbers shown in the drawings:
1. an external circulation cooling water supply pipe; 2. an external circulation cooling return pipe; 3. a heat exchanger; 301. a pipeline pump; 302. a damper; 303. a heat exchange plate; 304. a base; 4. internal circulation cooling water inlet and outlet pipes; 5. an ozone generator; 501. circulating water inlet pipe of ozone generator; 502. circulating water outlet pipe of ozone generator; 6. the power cabinet cools the water outlet pipe; 7. the power supply cabinet cools the water supply pipe; 8. an ozone power supply cabinet; 9. a pure oxygen inlet; 10. an ozone outlet.
Detailed Description
The embodiments of the present utility model will be described more fully hereinafter with reference to the accompanying drawings, in which the embodiments of the present utility model are shown by way of illustration only, and the utility model is not limited to the embodiments of the present utility model, but other embodiments of the present utility model will be apparent to those skilled in the art without making any inventive effort.
Referring to fig. 1-3, the heat exchange ozone generator system comprises a heat exchanger 3, an ozone generator 5, an ozone power cabinet 8 and a circulation pipeline, wherein the circulation pipeline comprises an outer circulation cooling water supply pipe 1, an outer circulation cooling water return pipe 2, an inner circulation cooling water inlet and outlet pipe 4 and a power cabinet cooling water supply pipe 7.
The heat exchanger 3 is provided with a heat exchange plate 303, and an outer circulation pipe and an inner circulation pipe connected with the heat exchange plate 303; the external circulation cooling water supply pipe 1 and the external circulation cooling water return pipe 2 are respectively connected with an external circulation pipe and an internal circulation pipe of the heat exchanger 3; a pipeline pump 301 and a damper 302 for absorbing impact force and reducing vibration generated by impact are arranged in a connecting pipeline of the inner circulation cooling water inlet and outlet pipe 4 and the inner circulation pipe of the heat exchanger 3. The heat exchanger is a plate heat exchanger, the heat exchange plate 303 is formed by stacking metal plates, cold and hot channels are formed between the plates, and heat exchange is carried out through the plates. The heat exchanger 3 is provided with a base 304, and the heat exchange plate 303 is mounted on the base 304.
The ozone generator 5 is provided with a circulating water tank of the ozone generator 5 and a circulating water inlet pipe and a circulating water outlet pipe 502 of the ozone generator, which are communicated with the circulating water tank; the internal circulation cooling water inlet and outlet pipe 4 is internally provided with double pipelines, namely a hot water pipeline and a cold water pipeline.
The internal circulation cooling water inlet and outlet pipe 4 is respectively connected with an internal circulation pipe of the heat exchanger 3 and a water outlet pipe of the ozone generator 5; an electrode tube electrically connected with the ozone power cabinet 8 is arranged in the circulating water tank, and a pure oxygen inlet 9 and an ozone outlet 10 are arranged at two ends of the electrode tube.
A heat exchange circulation loop is arranged in the ozone power cabinet 8, and a power cabinet cooling water outlet pipe 6 and a power cabinet cooling water supply pipe 7 are arranged in the heat exchange circulation loop; the power cabinet cooling water supply pipe 7 is connected with a cold water pipeline of the internal circulation cooling water inlet and outlet pipe 4, and the power cabinet cooling water outlet pipe 6 is connected with the ozone generator circulation water inlet pipe 501.
When the heat exchange ozone generator system works, the external circulation cooling water supply pipe 1 and the external circulation cooling water return pipe 2 are connected with a cooling water tower; cooling water enters an outer circulating pipe of the heat exchanger 3 from an outer circulating cooling water supply pipe 1 and flows back to the cooling tower from an outer circulating cooling water return pipe 2; pure oxygen directly enters an electrode tube of the ozone generator 5 from a pure oxygen inlet 9 to produce ozone through electrochemical reaction, an ozone power cabinet 8 provides electric energy for the electrochemical reaction of the electrode tube of the ozone generator 5, and the produced ozone is discharged from an ozone outlet 10 tube for downstream use.
Pure water is filled in the ozone generator 5, and enters the water tank through the internal circulation cooling water inlet and outlet pipe 4 and the internal circulation pipe of the heat exchanger 3 to exchange heat with the electrode pipe; in the process, a large amount of heat energy generated by the electrode tube of the ozone generator 5 enters the heat exchanger 3 through the circulating water outlet tube 502 of the ozone generator to dissipate heat and exchange heat energy.
Inside the ozone power cabinet 8, cold water enters a heat exchange circulation loop through a cold water pipeline of the internal circulation cooling water inlet and outlet pipe 4 and a power cabinet cooling water supply pipe 7, and then enters the ozone generator 5 through a power cabinet cooling water outlet pipe 6 and an ozone generator circulation water inlet pipe 501 to participate in heat exchange in the ozone generator 5.
Example 1:
the present embodiment illustrates the present utility model through specific application cases, and specific application backgrounds are as follows:
before the heat exchange ozone generator system of the utility model is not applied:
design scale of sewage treatment capacity of sewage plant in water purification workshop is 450m 3 And (h) deeply treating and constructing an ozone catalytic pond and an ozone stabilizing pond, constructing a machine room 1 seat of an ozone generator 5 in a matched manner, and preparing ozone by taking instrument wind as a raw material. The machine room is matched with 4 air storage tanks, 4 sets of cold dryer, 8 sets of filter, 4 sets of oxygen enriching machine and 54 sets of ozone generator, and 2 sets of air storage tanks are used for 2 sets of air storage tanks in normal operation. The cooling water is directly supplied from the cooling tower by using a DN125 pipeline, and 7.5 kilowatt pipeline pumps 3011 are arranged for improving the circulation effect of the cooling water. Because the temperature and the water quality index of the cooling water are not up to standard, the ozone generator 5 can not normally operate all the time, the faults frequently occur, the maintenance cost is increased, and the concentration of ozone generated by the ozone generator 5 is only 15-25mg/L. In order to meet the sewage reaching the standard, the original 2-to-3-to-1-to-2-to-1-to-greatly increase the instrument wind and power consumption and increase the extra burden.
The utility model is applied and embodied:
newly paving DN40 and 0.6MPa pure oxygen pipelines in a workshop, and dismantling four sets of an original gas storage tank, a cold dryer and an oxygen enriching machine, 8 sets of filters and matched process pipelines; removing one cooling water pipeline and one cooling water forced circulation pipeline pump 301 of the original part; two sets of plate heat exchangers 3 and matched pipelines are added, each two sets of ozone generators 5 share a platen heat exchanger 3, and the single power is 4kw. According to the technical scheme of the utility model, a circulating pipeline is arranged among the heat exchanger 3, the ozone generator 5 and the ozone power cabinet 8.
After the installation, the pure oxygen pipeline and the plate heat exchanger 3 are put into operation immediately, and the original oxygenerator is stopped, and the total power of the motors of the two circulating pipeline pumps 301 of the two platen heat exchangers 3 is 8kw, but the power of the two circulating pipeline pumps 301 is 3.5kw lower than that of the original circulating pipeline pumps 301, and meanwhile, the electricity cost and the instrument wind preparation cost of the oxygenerator are saved. Through a one-year continuous operation test, the requirement of the sewage treatment for the standard emission of ozone can be met by only opening 1 set of ozone generator 5, and no equipment fault exists in operation. The power consumption of the ozone generator 5 is saved by more than 50% compared with the original power consumption.
The foregoing description of the preferred embodiments of the utility model is not intended to limit the utility model to the precise form disclosed, and any such modifications, equivalents, and alternatives falling within the spirit and principles of the utility model are intended to be included within the scope of the utility model.

Claims (6)

1. The heat exchange ozone generator system is characterized by comprising a heat exchanger, an ozone generator, an ozone power cabinet and a circulating pipeline, wherein the circulating pipeline comprises an outer circulating cooling water supply pipe, an outer circulating cooling water return pipe, an inner circulating cooling water inlet and outlet pipe and a power cabinet cooling water supply pipe; wherein:
the heat exchanger is provided with a heat exchange plate, an outer circulating pipe and an inner circulating pipe which are connected with the heat exchange plate;
the external circulation cooling water supply pipe and the external circulation cooling water return pipe are respectively connected with an external circulation pipe and an internal circulation pipe of the heat exchanger;
the ozone generator is provided with an ozone generator circulating water tank and a circulating water inlet pipe and an ozone generator circulating water outlet pipe which are communicated with the circulating water tank;
the inner circulating cooling water inlet and outlet pipe is respectively connected with an inner circulating pipe of the heat exchanger and an outlet pipe of the ozone generator;
an electrode tube electrically connected with the ozone power supply cabinet is arranged in the circulating water tank, and a pure oxygen inlet and an ozone outlet are arranged at two ends of the electrode tube.
2. The heat exchange ozone generator system of claim 1, wherein: the internal circulation cooling water inlet and outlet pipe is internally provided with a double pipeline, namely a hot water pipeline and a cold water pipeline.
3. The heat exchange ozone generator system of claim 2, wherein: a heat exchange circulation loop is arranged in the ozone power cabinet, and a power cabinet cooling water outlet pipe and a power cabinet cooling water supply pipe are arranged in the heat exchange circulation loop; the cooling water supply pipe of the power cabinet is connected with the cold water pipeline of the internal circulating cooling water inlet and outlet pipe, and the cooling water outlet pipe of the power cabinet is connected with the circulating water inlet pipe of the ozone generator.
4. The heat exchange ozone generator system of claim 1, wherein: and a pipeline pump and a damper for absorbing impact force and reducing vibration generated by impact are arranged in a connecting pipeline of the internal circulation cooling water inlet and outlet pipe and the internal circulation pipe of the heat exchanger.
5. The heat exchange ozone generator system of claim 1, wherein: the heat exchange plate is formed by stacking metal sheets, cold and hot channels are formed between various sheet plates, and heat exchange is carried out through the sheet plates.
6. The heat exchange ozone generator system of claim 1, wherein: the heat exchanger is provided with a base, and the heat exchange plate is arranged on the base.
CN202222885412.0U 2022-10-31 2022-10-31 Heat exchange ozone generator system Active CN219531759U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202222885412.0U CN219531759U (en) 2022-10-31 2022-10-31 Heat exchange ozone generator system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202222885412.0U CN219531759U (en) 2022-10-31 2022-10-31 Heat exchange ozone generator system

Publications (1)

Publication Number Publication Date
CN219531759U true CN219531759U (en) 2023-08-15

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Application Number Title Priority Date Filing Date
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115744831A (en) * 2022-10-31 2023-03-07 利华益维远化学股份有限公司 Heat exchange ozone generator system and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115744831A (en) * 2022-10-31 2023-03-07 利华益维远化学股份有限公司 Heat exchange ozone generator system and method

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