CN219462997U - Carbon dioxide absorption tower - Google Patents

Carbon dioxide absorption tower Download PDF

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Publication number
CN219462997U
CN219462997U CN202320390422.9U CN202320390422U CN219462997U CN 219462997 U CN219462997 U CN 219462997U CN 202320390422 U CN202320390422 U CN 202320390422U CN 219462997 U CN219462997 U CN 219462997U
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China
Prior art keywords
spraying
tower body
carbon dioxide
pipe
spray
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Application number
CN202320390422.9U
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Chinese (zh)
Inventor
王淼
董仕宏
吴倩倩
何文
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Anhui Yanoda New Materials Technology Co ltd
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Suzhou Shijing Technology Co ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02CCAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00Capture or disposal of greenhouse gases
    • Y02C20/40Capture or disposal of greenhouse gases of CO2

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  • Gas Separation By Absorption (AREA)

Abstract

The utility model relates to a carbon dioxide absorption tower, which comprises a tower body, a packing layer and a spraying assembly, wherein the tower body is provided with an air inlet, an air outlet, a liquid inlet and a liquid outlet, the packing layer is arranged in the tower body and is positioned between the air inlet and the liquid inlet, the spraying assembly is arranged in the tower body and is communicated with the liquid inlet, an anti-corrosion layer is arranged on the inner wall of the tower body, the spraying assembly comprises a plurality of spraying pieces, the spraying pieces are in a circular shape, the spraying pieces are arranged in concentric circles and are mutually communicated, each spraying piece comprises a circular connecting pipe and a plurality of spraying units, the spraying units are arranged on the connecting pipe and are radially distributed around the connecting pipe, the spraying units are respectively provided with a plurality of spraying ports, and the spraying ports are in a circular shape. The spraying component can uniformly spray the absorption liquid in the packing layer, prevent the phenomenon of liquid bias flow, improve the absorption efficiency, ensure that the inner wall of the tower body cannot be corroded by arranging the anti-corrosion layer, improve the durability and prolong the service life.

Description

Carbon dioxide absorption tower
Technical Field
The utility model belongs to the technical field of environmental protection equipment, and particularly relates to a carbon dioxide absorption tower.
Background
At present, the technology of capturing, adsorbing and recycling carbon dioxide is a research hot spot in the field of environmental protection. A carbon dioxide absorber is generally required for the adsorption of carbon dioxide. Carbon dioxide absorption towers can be classified into three types according to gas-liquid phase contact forms: the first type is a plate column, a bubbling absorption column, a stirring bubbling absorption column and the like in which gas is dispersed in a liquid phase in the form of bubbles; the second type is an ejector, venturi, spray tower, etc. in which a liquid is dispersed in a gas phase in the form of droplets; the third type is a packed absorber, a falling film absorber, or the like in which a liquid contacts a gas phase in a film-like motion. The flow modes of the gas phase and the liquid phase in the carbon dioxide absorption tower comprise a countercurrent flow mode and a parallel flow mode, the common carbon dioxide absorption tower adopts the countercurrent flow mode, namely, the absorption liquid flows from top to bottom in the carbon dioxide absorption tower and is contacted with the gas flowing from bottom to top to perform absorption reaction, the absorption liquid after reaction is discharged from the bottom of the carbon dioxide absorption tower, and the gas after absorption is discharged from the top of the carbon dioxide absorption tower.
The absorption liquid is a chemical agent which can react with carbon dioxide in the gas to be absorbed to realize efficient absorption. Activating MDEA solution is one of the absorption solutions, and CO is removed by activating MDEA solution 2 Is a low-energy decarburization technology which is rapidly developed in recent years, and is increasingly applied to the purification process of natural gas and synthesis gas. The activated MDEA solution has low desorption temperature, stable chemical property and CO resistance 2 The gas absorption capacity is strong, and the reaction heat is small. Since the carbon dioxide absorption tower is generally made of a metal material, feCO is produced by using an activated MDEA solution as an absorption liquid for carbon dioxide absorption 3 Will dissolve in solution, but HCO 3- The presence of (C) inhibits FeCO 3 Promote the formation of passivation film on the metal surface and reduce the corrosion speed, so that the activation MDEA solution does not corrode the inner wall of the carbon dioxide absorption towerEven the activated MDEA solution is covered on the metal surface to isolate CO 2 The contact of the gas with the metal surface also prevents corrosion from occurring. The existing carbon dioxide absorption tower is poor in uniformity when spraying absorption liquid, the absorption reaction efficiency is reduced, the phenomenon of liquid bias flow possibly occurs, and part of the area of the inner wall of the carbon dioxide absorption tower is not covered by the activated MDEA solution, so that corrosion phenomenon possibly occurs, and the service life is reduced.
Disclosure of Invention
The utility model aims to provide a carbon dioxide absorption tower which is uniform in absorption and good in corrosion resistance.
In order to achieve the above purpose, the utility model adopts the following technical scheme:
the carbon dioxide absorption tower comprises a tower body, a packing layer and a spraying assembly, wherein the tower body is provided with an air inlet, an air outlet, a liquid inlet and a liquid outlet, the air inlet and the liquid inlet are formed in the side part of the tower body, the air outlet is formed in the top of the tower body, the liquid outlet is formed in the bottom of the tower body, the packing layer is arranged in the tower body and between the air inlet and the liquid inlet, the spraying assembly is arranged in the tower body, the spraying assembly is communicated with the liquid inlet, and an anti-corrosion layer is arranged on the inner wall of the tower body; the spraying assembly comprises a plurality of spraying pieces, the spraying pieces are in a circular shape, the spraying pieces are arranged in a concentric circle shape and are mutually communicated, each spraying piece comprises a circular connecting pipe and a plurality of spraying units, the spraying units are arranged on the connecting pipe and are radially distributed around the connecting pipe, each spraying unit is provided with a plurality of spraying ports, and the spraying ports are distributed in a circular shape.
Preferably, the spraying unit comprises a spraying pipe, the spraying pipe is in a circular ring shape, the spraying pipe and the connecting pipe are arranged on the same plane, and the connecting pipe penetrates through the center of the spraying pipe and is communicated with the center of the spraying pipe.
Further preferably, the plurality of spraying pipes are uniformly distributed around the radial direction of the connecting pipe, each spraying pipe is provided with a plurality of spraying ports, and the plurality of spraying ports are uniformly distributed around the radial direction of the spraying pipe.
Preferably, the spraying assembly further comprises a conveying pipe, a plurality of spraying pieces are communicated with each other through the conveying pipe, and the conveying pipe is communicated with the liquid inlet.
Further preferably, the conveying pipes and the connecting pipes are arranged on the same plane, the conveying pipes are provided with a plurality of conveying pipes, one ends of the conveying pipes are mutually communicated, the other end of each conveying pipe sequentially penetrates through the center of one spraying unit on the spraying piece and is communicated with the center of the spraying unit, and the other end of one conveying pipe is communicated with the liquid inlet.
Preferably, the material of the anti-corrosion layer is metallic tantalum. The metal tantalum is an acid-resistant rare metal, and the corrosion resistance of the carbon dioxide absorption tower can be greatly improved by coating the metal tantalum on the inner wall of the tower body.
Further preferably, the thickness of the anticorrosive layer is 0.01 to 0.1mm.
Preferably, the absorption tower further comprises a mist capturing piece, wherein the mist capturing piece is arranged in the tower body and is positioned above the spraying assembly, and the dryness of the gas discharged from the gas outlet is guaranteed to meet the requirement.
Preferably, a plurality of packing layers are arranged, and the packing layers are uniformly distributed along the axial direction of the tower body.
Preferably, a first control valve is arranged at the air inlet and used for controlling the opening and closing of the air inlet; the liquid inlet is provided with a second control valve which is used for controlling the opening and closing of the liquid inlet; the liquid outlet is provided with a third control valve, and the third control valve is used for controlling the opening and closing of the liquid outlet.
Due to the application of the technical scheme, compared with the prior art, the utility model has the following advantages:
according to the utility model, the spraying assembly is arranged in a concentric circle shape, and the plurality of spraying ports distributed in a circular ring shape are arranged, so that the absorption liquid can be uniformly sprayed in the packing layer below, the phenomenon of liquid bias flow is prevented, the absorption liquid can fully contact and react with carbon dioxide, the absorption efficiency is greatly improved, the corrosion of the inner wall of the tower body due to chemical reaction can be avoided by arranging the corrosion-proof layer, the durability is greatly improved, the service life is prolonged, and the novel tower is simple in structure, convenient to use, low in cost and good in practicability.
Drawings
FIG. 1 is a schematic diagram showing the structure of a carbon dioxide absorption tower according to the present embodiment;
FIG. 2 is a schematic view of the spray assembly of the present embodiment;
FIG. 3 is an enlarged schematic view of a portion of FIG. 2 at A;
fig. 4 is a schematic structural diagram of the shower member according to the present embodiment.
In the above figures:
1. a tower body; 10. an anti-corrosion layer; 11. an air inlet; 12. an air outlet; 13. a liquid inlet; 14. a liquid outlet; 2. a filler layer; 3. a spray assembly; 30. a spray member; 301. a connecting pipe; 302. a spraying unit; 3021. a shower pipe; 3022. a spray port; 31. a delivery tube; 4. a mist capturing piece; 51. a first control valve; 52. a second control valve; 53. and a third control valve.
Detailed Description
The following description of the embodiments of the present utility model will be made apparent and fully in view of the accompanying drawings, in which some, but not all embodiments of the utility model are shown. All other embodiments, which can be made by those skilled in the art based on the embodiments of the utility model without making any inventive effort, are intended to be within the scope of the utility model.
In the description of the present utility model, it should be noted that the directions or positional relationships indicated by the terms "center", "upper", "lower", "left", "right", "vertical", "horizontal", "inner", "outer", etc. are based on the directions or positional relationships shown in the drawings, are merely for convenience of describing the present utility model and simplifying the description, and do not indicate or imply that the devices or elements referred to must have a specific orientation, be configured and operated in a specific orientation, and thus should not be construed as limiting the present utility model. Furthermore, the terms "first," "second," and "third" are used for descriptive purposes only and are not to be construed as indicating or implying relative importance.
A carbon dioxide absorption tower is mainly used for treating carbon dioxide in flue gas generated in industries such as natural gas, power plants and the like, and as shown in fig. 1, the carbon dioxide absorption tower comprises a tower body 1, a packing layer 2, a spray assembly 3 and a mist capturing piece 4, wherein an air inlet 11, an air outlet 12, a liquid inlet 13 and a liquid outlet 14 are formed in the tower body 1, the packing layer 2, the spray assembly 3 and the mist capturing piece 4 are all arranged in the tower body 1, the spray assembly 3 is located above the packing layer 2, and the mist capturing piece 4 is located above the spray assembly 3.
The following details of each component and its connection relation are described in detail:
as shown in fig. 1, an air inlet 11 is formed at the side part of the tower body 1, an air outlet 12 is formed at the top of the tower body 1, the air inlet 11 is used for introducing flue gas to be absorbed into the tower body 1, and the air outlet 12 is used for discharging the absorbed flue gas; the liquid inlet 13 is formed in the side part of the tower body 1, the liquid inlet 13 is used for introducing absorption liquid into the tower body 1, and the liquid inlet 13 is positioned above the air inlet 11; the liquid outlet 14 is formed in the bottom of the tower body 1, specifically, the liquid outlet 14 is formed in the side wall of the bottom of the tower body 1, and the liquid outlet 14 is used for discharging the reacted absorption liquid.
As shown in fig. 1, a first control valve 51 is arranged at the air inlet 11, and the first control valve 51 is used for controlling the opening and closing of the air inlet 11 and regulating the flow of the flue gas to be absorbed entering the tower body 1; the liquid inlet 13 is provided with a second control valve 52, and the second control valve 52 is used for controlling the opening and closing of the liquid inlet 13 and regulating the flow of the absorption liquid entering the tower body 1; the third control valve 53 is disposed at the liquid outlet 14, and the third control valve 53 is used for controlling the opening and closing of the liquid outlet 14 and adjusting the flow rate of the reacted absorption liquid discharged from the tower body 1.
As shown in fig. 1, an anti-corrosion layer 10 is arranged on the inner wall of a tower body 1, the anti-corrosion layer 10 is made of metal tantalum, tantalum (Ta) is 73 # element, is an acid-resistant rare metal, has the content of about 0.0002% in the crust, can also be used as an electrode, a rectifier, electrolysis, a capacitor and the like of an electronic tube, can not react with hydrochloric acid, concentrated nitric acid and aqua regia under cold and hot conditions, the metal tantalum is placed in the concentrated sulfuric acid at 175 ℃ for 1 year, the corroded thickness is only 0.0004 millimeter, the metal tantalum is placed in the sulfuric acid at 200 ℃ for one year, the surface layer is only damaged by 0.006 millimeter, and the corrosion resistance of the carbon dioxide absorption tower can be greatly improved by coating the metal tantalum on the inner wall of the tower body 1; the thickness of the anticorrosive layer 10 is preferably 0.01 to 0.1mm.
As shown in fig. 1, the packing layer 2 is arranged inside the tower body 1, and the packing layer 2 is positioned between the air inlet 11 and the liquid inlet 13 of the tower body 1; the packing layers 2 are provided with a plurality of packing layers 2 which are uniformly distributed along the axial direction of the tower body 1. In this embodiment: the packing layers 2 are provided with three packing layers 2, and gaps among the three packing layers 2 are consistent. The material of the packing layer 2 adopts the packing material in the existing carbon dioxide absorption tower, which is the prior art and will not be described here again.
As shown in fig. 2, the spray assembly 3 is disposed in the tower body 1, the spray assembly 3 is communicated with the liquid inlet 13, the absorption liquid can enter the spray assembly 3 from the liquid inlet 13, the spray assembly 3 sprays the absorption liquid uniformly, the spray assembly 3 comprises a plurality of spray pieces 30, the spray pieces 30 are in a ring shape, and the spray pieces 30 are disposed in concentric circles and are communicated with each other through the conveying pipe 31. Specifically:
as shown in fig. 3 and 4, each spray member 30 includes a connection pipe 301 and a spray unit 302, the connection pipe 301 is in a ring shape, the spray units 302 are connected to the connection pipe 301 and are communicated with the connection pipe 301, the spray units 302 are provided in plurality, and the plurality of spray units 302 are uniformly distributed around the radial direction of the connection pipe 301; each spray unit 302 is provided with a plurality of spray ports 3022, the spray ports 3022 are arranged and distributed in a circular ring shape, specifically, each spray unit 302 comprises a spray pipe 3021, the spray pipes 3021 are arranged in a circular ring shape, the spray pipes 3021 and the connecting pipes 301 are arranged on the same plane, the connecting pipes 301 penetrate through the centers of the spray pipes 3021 and are communicated with the same, namely, the intersections of the connecting pipes 301 and the spray pipes 3021 are mutually communicated, the spray pipes 3021 are provided with a plurality of spray ports 3022, the spray ports 3022 are uniformly distributed in the radial direction of the spray pipes 3021, and the spray pipes 3021 of the spray units 302 are uniformly distributed in the radial direction of the connecting pipes 301.
As shown in fig. 2 and 3, the plurality of spray pieces 30 are communicated with each other through a delivery pipe 31, and the delivery pipe 31 is communicated with the liquid inlet 13, specifically: the conveying pipe 31 and the connecting pipe 301 are arranged on the same plane, the conveying pipe 31 extends linearly, one end of the conveying pipe 31 is positioned at the center of a plurality of spraying pieces 30 which are concentric circles, the other end of the conveying pipe 31 sequentially passes through the center of one spraying unit 302 on each spraying piece 30 and is communicated with the spraying unit 302, that is, the other end of the conveying pipe 31 passes through the spraying pipe 3021 and the connecting pipe 301, the intersection of the conveying pipe 31 and the spraying pipe 3021 is communicated with each other, and the intersection of the conveying pipe 31 and the connecting pipe 301 is communicated with each other; the number of the conveying pipes 31 is the same as the number of the spraying units 302 on each spraying piece 30, and one ends of the conveying pipes 31 are mutually communicated at the centers of the plurality of concentric spraying pieces 30, so that each spraying unit 302 on each spraying piece 30 is communicated with one conveying pipe 31; the other end of one of the plurality of delivery pipes 31 communicates with the liquid inlet 13.
In this embodiment: three spraying pieces 30 are arranged, and the three spraying pieces 30 are uniformly distributed in a concentric circle shape; twelve spraying units 302 are uniformly distributed on the connecting pipe 301 of each spraying piece 30, and 6 spraying ports 3022 are uniformly distributed on the spraying pipe 3021 of each spraying unit 302; the twelve conveying pipes 31 are arranged, one ends of the twelve conveying pipes 31 are mutually communicated at the centers of the three spraying pieces 30, the other ends of the twelve conveying pipes 31 respectively pass through twelve spraying units 302 on the spraying piece 30 positioned at the innermost side, respectively pass through twelve spraying units 302 on the spraying piece 30 positioned at the outermost side, and the other end of one of the twelve conveying pipes 31 passes through the spraying unit 302 on the spraying piece 30 positioned at the outermost side and is communicated with the liquid inlet 13.
The mist capturing piece 4 is arranged in the tower body 1, the mist capturing piece 4 is positioned above the spraying assembly 3, and the mist capturing piece 4 is used for absorbing water mist carried in the flue gas after completion and water vapor formed by condensation, so that the drying of the gas from the gas outlet 12 is ensured. The material of the mist catcher 4 may be, for example, a PP polyhedral ball mist-removing layer, of which only an example is given here, but is not limited to this material.
The working procedure of the carbon dioxide absorption tower of this embodiment is specifically described below:
the flue gas containing carbon dioxide is introduced into the tower body 1 from the air inlet 11, the absorption liquid (activated MDEA solution) is introduced into the concentric spraying assembly 3 from the liquid inlet 13, the absorption liquid is uniformly sprayed downwards from the spraying openings of the spraying units 302 uniformly distributed on the spraying assembly 3, the absorption liquid falls into the packing layer 2, the flue gas to be absorbed enters the tower body 1 from the air inlet 11, the flue gas flows from bottom to top to chemically react with the absorption liquid through the packing layer 2, the liquid generated after the reaction flows to the bottom of the tower body 1 and is discharged from the liquid outlet 14, and the flue gas after the absorption reaction is discharged from the tower body 1 after being dried by the mist capturing piece 4.
The above embodiments are provided to illustrate the technical concept and features of the present utility model and are intended to enable those skilled in the art to understand the content of the present utility model and implement the same, and are not intended to limit the scope of the present utility model. All equivalent changes or modifications made in accordance with the spirit of the present utility model should be construed to be included in the scope of the present utility model.

Claims (10)

1. The utility model provides a carbon dioxide absorption tower, includes tower body, packing layer and spray assembly, the tower body have air inlet, gas outlet, inlet and liquid outlet, air inlet, liquid inlet set up the lateral part of tower body, the gas outlet set up the top of tower body, the liquid outlet set up the bottom of tower body, the packing layer set up in the tower body and be located between air inlet, the inlet, spray assembly set up in the tower body, spray assembly with the inlet be linked together, its characterized in that: an anti-corrosion layer is arranged on the inner wall of the tower body; the spraying assembly comprises a plurality of spraying pieces, the spraying pieces are in a circular shape, the spraying pieces are arranged in a concentric circle shape and are mutually communicated, each spraying piece comprises a circular connecting pipe and a plurality of spraying units, the spraying units are arranged on the connecting pipe and are radially distributed around the connecting pipe, each spraying unit is provided with a plurality of spraying ports, and the spraying ports are distributed in a circular shape.
2. The carbon dioxide absorption tower according to claim 1, wherein: the spraying unit comprises a spraying pipe, the spraying pipe is in a circular ring shape, the spraying pipe and the connecting pipe are arranged on the same plane, and the connecting pipe penetrates through the center of the spraying pipe and is communicated with the center of the spraying pipe.
3. The carbon dioxide absorption tower according to claim 2, wherein: the spray pipes are uniformly distributed around the radial direction of the connecting pipe, a plurality of spray openings are formed in each spray pipe, and the spray openings are uniformly distributed around the radial direction of the spray pipe.
4. The carbon dioxide absorption tower according to claim 1, wherein: the spray assembly also comprises a conveying pipe, a plurality of spray pieces are communicated through the conveying pipe, and the conveying pipe is communicated with the liquid inlet.
5. The carbon dioxide absorption tower according to claim 4, wherein: the conveying pipes are arranged on the same plane with the connecting pipes, one ends of the conveying pipes are mutually communicated, the other end of each conveying pipe sequentially penetrates through the center of one spraying unit on the spraying piece and is communicated with the center of the spraying unit, and the other end of one conveying pipe is communicated with the liquid inlet.
6. The carbon dioxide absorption tower according to claim 1, wherein: the material of the anti-corrosion layer is metallic tantalum.
7. The carbon dioxide absorption tower according to claim 6, wherein: the thickness of the anti-corrosion layer is 0.01-0.1 mm.
8. The carbon dioxide absorption tower according to claim 1, wherein: the absorption tower also comprises a mist capturing piece, wherein the mist capturing piece is arranged in the tower body and is positioned above the spraying assembly.
9. The carbon dioxide absorption tower according to claim 1, wherein: the packing layers are arranged in a plurality, and the packing layers are uniformly distributed along the axial direction of the tower body.
10. The carbon dioxide absorption tower according to claim 1, wherein: the air inlet is provided with a first control valve which is used for controlling the opening and closing of the air inlet; the liquid inlet is provided with a second control valve which is used for controlling the opening and closing of the liquid inlet; the liquid outlet is provided with a third control valve, and the third control valve is used for controlling the opening and closing of the liquid outlet.
CN202320390422.9U 2023-03-06 2023-03-06 Carbon dioxide absorption tower Active CN219462997U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202320390422.9U CN219462997U (en) 2023-03-06 2023-03-06 Carbon dioxide absorption tower

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202320390422.9U CN219462997U (en) 2023-03-06 2023-03-06 Carbon dioxide absorption tower

Publications (1)

Publication Number Publication Date
CN219462997U true CN219462997U (en) 2023-08-04

Family

ID=87462401

Family Applications (1)

Application Number Title Priority Date Filing Date
CN202320390422.9U Active CN219462997U (en) 2023-03-06 2023-03-06 Carbon dioxide absorption tower

Country Status (1)

Country Link
CN (1) CN219462997U (en)

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Effective date of registration: 20240603

Address after: 242000 Xingsheng Road, Heli Park, Ningguo Economic and Technological Development Zone, Xuancheng City, Anhui Province (within Huaren Road Bridge Company)

Patentee after: Anhui Yanoda New Materials Technology Co.,Ltd.

Country or region after: China

Address before: 215137 4th floor, 82 Jincheng Road, Taiping Street, Xiangcheng District, Suzhou City, Jiangsu Province

Patentee before: Suzhou Shijing Technology Co.,Ltd.

Country or region before: China