CN214619009U - Solid-state hydrogen storage and supply system - Google Patents

Solid-state hydrogen storage and supply system Download PDF

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Publication number
CN214619009U
CN214619009U CN202122198318.3U CN202122198318U CN214619009U CN 214619009 U CN214619009 U CN 214619009U CN 202122198318 U CN202122198318 U CN 202122198318U CN 214619009 U CN214619009 U CN 214619009U
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China
Prior art keywords
hydrogen storage
valve
blowing
solid
pipeline
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CN202122198318.3U
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Chinese (zh)
Inventor
方沛军
邹建新
朱阳林
张雷
陈斌
张鹏
伍远安
曹俊
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Shanghai Hyfun Energy Technology Co Ltd
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Hydrogen Storage Shanghai Energy Technology Co ltd
Hydrogen Storage Xinxiang Energy Technology Co ltd
Shanghai Hyfun Energy Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/32Hydrogen storage
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/34Hydrogen distribution
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P90/00Enabling technologies with a potential contribution to greenhouse gas [GHG] emissions mitigation
    • Y02P90/45Hydrogen technologies in production processes

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Abstract

The utility model discloses a solid-state hydrogen storage and supply system. The system comprises a solid-state hydrogen storage device, a cooling device, a filtering device, a first one-way valve, a temperature sensor and a first valve which are sequentially communicated through a main pipeline, wherein the flowing direction of the first one-way valve is from the filtering device to the temperature sensor, an inflation branch is connected in parallel with the filtering device and the first one-way valve, a second one-way valve is arranged on the inflation branch, and the flowing direction of the second one-way valve is from the temperature sensor to the solid-state hydrogen storage device; the solid-state hydrogen storage device includes at least one hydrogen storage tank equipped with a heating assembly for heating the interior thereof. The utility model discloses when storing hydrogen, hydrogen enters into solid-state hydrogen storage tank through aerifing the branch road, and when external hydrogen supply, the exit of hydrogen storage tank is equipped with cooling device for cooling high temperature hydrogen, the temperature sensor of cooling device rear end is used for the temperature in the real-time supervision main line, and filter equipment is arranged in filtering to fall slight magnesium alloy dust in the gas, reaches and cools down and remove dust and handle it.

Description

Solid-state hydrogen storage and supply system
Technical Field
The utility model relates to a hydrogenation technical field especially relates to a solid-state hydrogen storage hydrogen supply system.
Background
The high-pressure hydrogen storage steel cylinder is a common hydrogen supply mode, but the steel cylinder is heavy, the hydrogen storage amount is small, and the use and the scheduling are very inconvenient. Compared with the prior art, the magnesium alloy hydrogen storage technology has the advantages of high hydrogen storage capacity, low working pressure, good safety and the like. However, the temperature of hydrogen charging and discharging of the magnesium alloy hydrogen storage material is high, particularly the temperature is usually over 300 ℃ for rapid hydrogen discharging, fine magnesium alloy dust is usually carried in high-temperature hydrogen released by the magnesium alloy, the high-temperature hydrogen cannot be directly supplied to hydrogen equipment at the rear end, and the temperature reduction and dust removal treatment are required.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a solid-state hydrogen storage and supply system to the above-mentioned not enough of prior art.
The utility model discloses a solid-state hydrogen storage and supply system, including solid-state hydrogen storage device, cooling device, filter equipment, first check valve, temperature sensor and the first valve that communicate with each other in proper order through the main line, the flow direction of first check valve is from filter equipment to temperature sensor, aerifys the branch road and connect in parallel on filter equipment and first check valve, be equipped with the second check valve on aerifing the branch road, the flow direction of second check valve is from temperature sensor to solid-state hydrogen storage device; the solid hydrogen storage device comprises at least one hydrogen storage tank, wherein magnesium alloy hydrogen storage materials are filled in the hydrogen storage tank, and a heating component for heating the inside of the hydrogen storage tank is arranged in the hydrogen storage tank.
Furthermore, still be equipped with first pressure sensor, flow sensor and second pressure sensor on the main pipeline, first pressure sensor is located the pipeline section between cooling device and the filter equipment, flow sensor and second pressure sensor are located the pipeline section between temperature sensor and the first valve.
Further, the first pressure sensor is arranged on the main pipeline through a first pipeline, a first root valve is arranged on the first pipeline, the second pressure sensor is arranged on the main pipeline through a second pipeline, and a second root valve is arranged on the second pipeline.
Furthermore, a second valve is arranged on a pipeline section between the first pressure sensor and the filtering device, a diffusing pipe is arranged on a pipeline section between the first pressure sensor and the second valve, and a diffusing valve is arranged on the diffusing pipe.
Furthermore, a flame arrester is arranged at one end, far away from the main pipeline, of the diffusing pipe.
Furthermore, a safety pipe is arranged on the pipeline section between the second valve and the filtering device, a third partial valve and a safety valve are arranged on the safety pipe, one end of the safety pipe is connected with the main pipeline, and the other end of the safety pipe is communicated with the diffusing pipe.
Furthermore, the system also comprises a blowing device, wherein the blowing device is communicated with the main pipeline through a blowing pipeline, one end of the blowing pipeline is communicated with the blowing device, and the other end of the blowing pipeline is connected to a pipeline section between the first pressure sensor and the second valve.
Further, the air blowing device comprises an air blowing tank, nitrogen is filled in the air blowing tank, and the air blowing tank is communicated with the main pipeline through an air blowing pipeline.
Furthermore, an air blowing valve and a pressure reducing valve are arranged on the air blowing pipeline.
Furthermore, the heating assembly comprises at least one explosion-proof electric heating rod, and the explosion-proof electric heating rod is arranged in the hydrogen storage tank.
The utility model discloses a solid-state hydrogen storage hydrogen supply system, when storing hydrogen, hydrogen enters into solid-state hydrogen storage tank through aerifing the branch road, need not open cooling device and cool off hydrogen this moment, when external hydrogen supply, the exit of hydrogen storage tank is equipped with cooling device for the high temperature hydrogen of cooling magnesium alloy hydrogen storage material release, the temperature sensor of cooling device rear end is used for the temperature in the real-time supervision main line, filter equipment is arranged in filtering to fall slight magnesium alloy dust in the gas, reach and cool down and remove dust to it and handle.
Drawings
Fig. 1 is a schematic structural diagram of a solid-state hydrogen storage and supply system of the present invention.
1. A main pipeline; 2. a solid-state hydrogen storage device; 3. a cooling device; 4. a filtration device; 5. a first check valve; 6. a temperature sensor; 7. a first valve; 8. an inflation branch; 9. a second one-way valve; 10. a hydrogen storage tank; 11. a heating assembly; 12. a first pressure sensor; 13. a flow sensor; 14. a second pressure sensor; 15. a first root valve; 16. a second root valve; 17. a second valve; 18. a diffusing pipe; 19. a bleed valve; 20. a flame arrestor; 21. a safety tube; 22. a third partial valve; 23. a safety valve; 24. a blowing device; 25. a gas blowing line; 26. a gas blowing tank; 27. a blowing valve; 28. a pressure reducing valve; 29. explosion-proof electrical heating rod.
Detailed Description
The following are specific embodiments of the present invention and the accompanying drawings are used to further describe the technical solution of the present invention, but the present invention is not limited to these embodiments.
As shown in fig. 1, the utility model discloses a solid-state hydrogen storage and supply system, including solid-state hydrogen storage device 2, cooling device 3, filter equipment 4, first check valve 5, temperature sensor 6 and the first valve 7 that communicate in proper order through main line 1, the flow direction of first check valve 5 is from filter equipment 4 to temperature sensor 6, aerify branch road 8 and connect in parallel on filter equipment 4 and first check valve 5, aerify the branch road 8 and be equipped with second check valve 9, the flow direction of second check valve 9 is from temperature sensor 6 to solid-state hydrogen storage device 2; the solid-state hydrogen storage device 2 includes at least one hydrogen storage tank 10, and the hydrogen storage tank 10 is filled with a magnesium alloy hydrogen storage material and is provided with a heating assembly 11 for heating the inside thereof.
The utility model discloses a solid-state hydrogen storage and supply system, when storing hydrogen, hydrogen enters into solid-state hydrogen storage tank through aerifing branch road 8, need not open cooling device 3 this moment and cools off hydrogen, when external hydrogen supply, the exit of hydrogen storage tank 10 is equipped with cooling device 3, a high temperature hydrogen for cooling magnesium alloy hydrogen storage material release, the temperature sensor 6 of 3 rear ends of cooling device is used for the temperature in real-time supervision main line 1, filter equipment 4 is arranged in filtering fine magnesium alloy dust in the gas, reach and cool down and dust removal processing to it.
The main pipeline 1 can be further provided with a first pressure sensor 12, a flow sensor 13 and a second pressure sensor 14, the first pressure sensor 12 is located on a pipeline section between the cooling device 3 and the filtering device 4, the flow sensor 13 and the second pressure sensor 14 are located on a pipeline section between the temperature sensor 6 and the first valve 7, the first pressure sensor 12 and the second pressure sensor 14 monitor the pressure of different positions of the main pipeline 1 in real time, when the pressure exceeds a preset value, the system can start an early warning function, the early warning function can be realized by setting an alarm, the flow sensor 13 can observe instantaneous flow and accumulated flow in the process of hydrogen discharge in real time, and therefore the progress of the hydrogen discharge is judged.
The first pressure sensor 12 can be arranged on the main pipeline 1 through the first root valve 15, the second pressure sensor 14 can be arranged on the main pipeline 1 through the second root valve 16, and the first root valve 15 and the second root valve 16 are in a normally open state, so that the maintenance is convenient to arrange.
Still be equipped with second valve 17 on the pipeline section that is located between first pressure sensor 12 and the filter equipment 4, can also be equipped with on the pipeline section between first pressure sensor 12 and the second valve 17 and diffuse pipe 18, be equipped with on the pipe 18 and diffuse valve 19, the one end that main pipeline 1 was kept away from to diffuse pipe 18 is equipped with spark arrester 20, when the gaseous in the needs discharge system, can open and diffuse valve 19, and gaseous in the system can be passed through spark arrester 20 and is discharged to the atmosphere.
A safety pipe 21 can be arranged on the pipe section between the second valve 17 and the filtering device 4, a third root valve 22 and a safety valve 23 are arranged on the safety pipe 21, one end of the safety pipe 21 is connected with the main pipeline 1, the other end of the safety pipe is communicated with the diffusing pipe 18, the third root valve 22 is in a normally open state, and when the pressure in the main pipeline 1 exceeds the set pressure of the safety valve 23 due to an accident condition, the safety valve 23 jumps to enable the pressure in the system to be emergently discharged to the atmosphere, so that the safety of the system is ensured.
The system may further include an air blowing device 24, the air blowing device 24 is communicated with the main pipeline 1 through an air blowing pipeline 25, one end of the air blowing pipeline 25 is communicated with the air blowing device 24, the other end of the air blowing pipeline 25 is connected to a pipeline section between the first pressure sensor 12 and the second valve 17, and air in the system is discharged to the outside through the air blowing device 24.
The structure of the blowing device 24 is various, and is not limited herein, in this embodiment, the blowing device 24 may include a blowing tank 26, the blowing tank 26 is filled with nitrogen, the blowing tank 26 is communicated with the main pipeline 1 through a blowing pipeline 25, the blowing pipeline 25 may further be provided with a blowing valve 27 and a pressure reducing valve 28, when the hydrogen supply system is used for the first time or is not used for a long time, the system needs to be blown for removing air in the system, the blowing gas may be selected from gases with inactive chemical properties, such as nitrogen, argon, etc., the pressure reducing valve 28 is used for adjusting the pressure of the blowing gas, and after the air is blown, the blowing gas is discharged through the diffusing pipe 18 by using hydrogen.
The heating assembly 11 comprises at least one explosion-proof electric heating rod 29, the explosion-proof electric heating rod 29 is arranged in the hydrogen storage tank 10, and the explosion-proof electric heating rod 29 needs to be continuously heated in the hydrogen discharging process to maintain the temperature of the system because the hydrogen discharging reaction of the magnesium alloy hydrogen storage material is endothermic.
The hydrogen storage process of the system is as follows: during hydrogen filling, the hydrogen inlet and the hydrogen outlet are connected with a hydrogen source, the first valve 7, the second valve 17 and the inlet of the hydrogen storage tank are opened, and the relief valve 19 and the blow valve 27 are closed (the first root valve 15, the second root valve 16 and the third root valve 22 are all kept in a normally open state). The hydrogen gas passes through the first valve 7, the flow sensor 13, the second one-way valve 9, the first valve 7 and the cooling device 3 and enters the hydrogen storage tank 10. The explosion-proof electric heating rod 29 is started to heat the magnesium alloy hydrogen storage material in the hydrogen storage tank 10, so that after the magnesium alloy material is heated to the working temperature of 120-320 ℃, the hydrogen and the magnesium alloy material rapidly react to generate metal hydride and release heat, and the system temperature of the hydrogen absorption reaction can be completely maintained due to the heat released by the reaction, and at the moment, the explosion-proof electric heating rod 29 can be closed. The charging pressure is less than or equal to 3MPa, preferably less than or equal to 1.5MPa, and the lower charging pressure has higher safety, can reduce the use of a compressor and reduce the electric energy consumption. The flow sensor 13 can observe the instantaneous flow and the accumulated flow during the hydrogen charging in real time, thereby judging the progress of the hydrogen charging. After the hydrogen charging is finished, the first valve 7 is closed.
The hydrogen evolution of the system is as follows: when hydrogen is discharged, the hydrogen inlet and outlet are connected to the hydrogen-using device, and the first valve 7 and the second valve 17 are opened (the first root valve 15, the second root valve 16, and the third root valve 22 are all kept in a normally open state). Starting the explosion-proof electric heating rod 29, heating the magnesium alloy material in the hydrogen storage tank 10 to the hydrogen discharge temperature of 340-. The filtering device 4 is used for removing magnesium alloy dust possibly existing in hydrogen, the temperature sensor 6 is used for detecting the temperature of the hydrogen at the outlet, and the flow sensor 13 can observe the instantaneous flow and the accumulated flow in the hydrogen discharging process in real time so as to judge the hydrogen discharging progress. The hydrogen discharge process can be realized and used immediately. When hydrogen is not needed by hydrogen equipment temporarily, the first valve 7 is closed, the magnesium alloy material in the hydrogen storage tank 10 releases hydrogen to increase the pressure, the pressure increase can inhibit the hydrogen release reaction, finally, dynamic balance can be achieved at any temperature, the pressure can not be increased any more, when hydrogen supply is needed to be continued, the first valve 7 is opened, the pressure in the hydrogen storage tank 10 is reduced, the dynamic balance is broken, the magnesium alloy material continues to release hydrogen, and therefore continuous or discontinuous hydrogen supply of a hydrogen supply system is achieved.
The above is not relevant and is applicable to the prior art.
Although certain specific embodiments of the present invention have been described in detail by way of illustration, it will be understood by those skilled in the art that the foregoing examples are for purposes of illustration only and are not intended to limit the scope of the invention, which is to be construed as broadly as the present invention will suggest themselves to those skilled in the art to which the invention pertains and which is susceptible to various modifications or additions and similar arrangements to the specific embodiments described herein without departing from the scope of the invention as defined in the appended claims. It should be understood by those skilled in the art that any modifications, equivalent substitutions, improvements and the like made to the above embodiments according to the technical spirit of the present invention should be included in the scope of the present invention.

Claims (10)

1. A solid-state hydrogen storage and supply system is characterized in that: the device comprises a solid-state hydrogen storage device (2), a cooling device (3), a filtering device (4), a first one-way valve (5), a temperature sensor (6) and a first valve (7) which are sequentially communicated through a main pipeline (1), wherein a flowing direction of the first one-way valve (5) is from the filtering device (4) to the temperature sensor (6), an inflation branch (8) is connected in parallel to the filtering device (4) and the first one-way valve (5), a second one-way valve (9) is arranged on the inflation branch (8), and a flowing direction of the second one-way valve (9) is from the temperature sensor (6) to the solid-state hydrogen storage device (2); the solid hydrogen storage device (2) comprises at least one hydrogen storage tank (10), wherein magnesium alloy hydrogen storage materials are filled in the hydrogen storage tank (10), and a heating assembly (11) for heating the interior of the hydrogen storage tank is installed.
2. A solid state hydrogen storage and supply system according to claim 1, wherein: the main pipeline (1) is further provided with a first pressure sensor (12), a flow sensor (13) and a second pressure sensor (14), the first pressure sensor (12) is located on a pipeline section between the cooling device (3) and the filtering device (4), and the flow sensor (13) and the second pressure sensor (14) are located on a pipeline section between the temperature sensor (6) and the first valve (7).
3. A solid state hydrogen storage and supply system according to claim 2, wherein: the first pressure sensor (12) is arranged on the main pipeline (1) through a first foot valve (15), and the second pressure sensor (14) is arranged on the main pipeline (1) through a second foot valve (16).
4. A solid state hydrogen storage and supply system according to claim 2, wherein: and a second valve (17) is further arranged on the pipeline section between the first pressure sensor (12) and the filtering device (4), a diffusing pipe (18) is further arranged on the pipeline section between the first pressure sensor (12) and the second valve (17), and a diffusing valve (19) is arranged on the diffusing pipe (18).
5. A solid state hydrogen storage and supply system according to claim 4, wherein: a flame arrester (20) is arranged at one end of the diffusing pipe (18) far away from the main pipeline (1).
6. A solid state hydrogen storage and supply system according to claim 4, wherein: a safety pipe (21) is arranged on the pipeline section between the second valve (17) and the filtering device (4), a third root valve (22) and a safety valve (23) are arranged on the safety pipe (21), one end of the safety pipe (21) is connected with the main pipeline (1), and the other end of the safety pipe is communicated with the diffusing pipe (18).
7. A solid state hydrogen storage and supply system according to claim 4, wherein: the system further comprises a blowing device (24), the blowing device (24) is communicated with the main pipeline (1) through a blowing pipeline (25), one end of the blowing pipeline (25) is communicated with the blowing device (24), and the other end of the blowing pipeline (25) is connected to a pipeline section between the first pressure sensor (12) and the second valve (17).
8. A solid state hydrogen storage and supply system according to claim 7, wherein: the blowing device (24) comprises a blowing tank (26), nitrogen is filled in the blowing tank (26), and the blowing tank (26) is communicated with the main pipeline (1) through a blowing pipeline (25).
9. A solid state hydrogen storage and supply system according to claim 8, wherein: and a blowing valve (27) and a pressure reducing valve (28) are arranged on the blowing pipeline (25).
10. A solid state hydrogen storage and supply system according to any one of claims 1 to 9, wherein: the heating assembly (11) comprises at least one explosion-proof electric heating rod (29), and the explosion-proof electric heating rod (29) is arranged in the hydrogen storage tank (10).
CN202122198318.3U 2021-09-13 2021-09-13 Solid-state hydrogen storage and supply system Active CN214619009U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202122198318.3U CN214619009U (en) 2021-09-13 2021-09-13 Solid-state hydrogen storage and supply system

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Application Number Priority Date Filing Date Title
CN202122198318.3U CN214619009U (en) 2021-09-13 2021-09-13 Solid-state hydrogen storage and supply system

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114715843A (en) * 2022-05-09 2022-07-08 氢储(上海)能源科技有限公司 Self-repairing solid hydrogen storage material and preparation method thereof
CN115654372A (en) * 2022-10-19 2023-01-31 广东工业大学 Solid-state hydrogen storage and delivery pipeline system and control method thereof
CN116558864A (en) * 2023-07-05 2023-08-08 合肥通用机械研究院有限公司 Solid-state hydrogen storage test system and test method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114715843A (en) * 2022-05-09 2022-07-08 氢储(上海)能源科技有限公司 Self-repairing solid hydrogen storage material and preparation method thereof
CN115654372A (en) * 2022-10-19 2023-01-31 广东工业大学 Solid-state hydrogen storage and delivery pipeline system and control method thereof
CN115654372B (en) * 2022-10-19 2024-04-12 广东工业大学 Solid-state hydrogen storage and transportation pipeline system and control method thereof
CN116558864A (en) * 2023-07-05 2023-08-08 合肥通用机械研究院有限公司 Solid-state hydrogen storage test system and test method thereof

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Effective date of registration: 20240326

Address after: Room 901, 9th Floor, No. 1555 Lianhua Road, Minhang District, Shanghai, 202233

Patentee after: SHANGHAI HYFUN ENERGY TECHNOLOGY CO.,LTD.

Country or region after: China

Address before: 1 / F and 2 / F, No.11 plant, Xinxiang hydrogen energy industrial park, northeast corner of the intersection of East Ring Road and South Second Ring Road, Xinxiang City, Henan Province, 453000

Patentee before: Hydrogen storage (Xinxiang) Energy Technology Co.,Ltd.

Country or region before: China

Patentee before: SHANGHAI HYFUN ENERGY TECHNOLOGY CO.,LTD.

Patentee before: Hydrogen storage (Shanghai) Energy Technology Co.,Ltd.

TR01 Transfer of patent right