CN212655605U - Drinking water disinfection device - Google Patents
Drinking water disinfection device Download PDFInfo
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- CN212655605U CN212655605U CN202021093040.2U CN202021093040U CN212655605U CN 212655605 U CN212655605 U CN 212655605U CN 202021093040 U CN202021093040 U CN 202021093040U CN 212655605 U CN212655605 U CN 212655605U
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- 235000020188 drinking water Nutrition 0.000 title claims abstract description 69
- 239000003651 drinking water Substances 0.000 title claims abstract description 69
- 238000004659 sterilization and disinfection Methods 0.000 title claims abstract description 57
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 139
- 238000011282 treatment Methods 0.000 claims abstract description 71
- 239000011347 resin Substances 0.000 claims abstract description 65
- 229920005989 resin Polymers 0.000 claims abstract description 65
- 238000001179 sorption measurement Methods 0.000 claims abstract description 61
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 34
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 34
- 238000011221 initial treatment Methods 0.000 claims abstract description 33
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 28
- 239000003957 anion exchange resin Substances 0.000 claims description 27
- 239000003729 cation exchange resin Substances 0.000 claims description 23
- 238000005342 ion exchange Methods 0.000 claims description 20
- 239000003463 adsorbent Substances 0.000 claims description 11
- 230000004888 barrier function Effects 0.000 claims description 10
- 239000002957 persistent organic pollutant Substances 0.000 claims description 10
- 239000000460 chlorine Substances 0.000 claims description 9
- 229910052801 chlorine Inorganic materials 0.000 claims description 8
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 abstract description 22
- 230000000694 effects Effects 0.000 abstract description 12
- 230000008569 process Effects 0.000 abstract description 11
- 238000000746 purification Methods 0.000 abstract description 11
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- 230000001954 sterilising effect Effects 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 5
- 238000007872 degassing Methods 0.000 abstract description 4
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- 230000015572 biosynthetic process Effects 0.000 abstract description 3
- ZFXVRMSLJDYJCH-UHFFFAOYSA-N calcium magnesium Chemical compound [Mg].[Ca] ZFXVRMSLJDYJCH-UHFFFAOYSA-N 0.000 abstract description 3
- 230000008878 coupling Effects 0.000 abstract description 3
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- 238000001728 nano-filtration Methods 0.000 description 4
- 238000001223 reverse osmosis Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 238000005349 anion exchange Methods 0.000 description 3
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
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- 125000001309 chloro group Chemical group Cl* 0.000 description 1
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- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 1
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- Treatment Of Water By Ion Exchange (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
Abstract
The utility model discloses a drinking water degassing unit belongs to water treatment technical field. The utility model comprises a shell, wherein a drinking water inlet and a drinking water outlet are arranged on the shell, and a primary treatment cavity, a secondary treatment cavity and an electrolysis cavity are sequentially arranged in the shell along the direction from the drinking water inlet to the drinking water outlet; wherein, the primary treatment cavity is internally provided with adsorption resin, the secondary treatment cavity is internally provided with ion exchange resin, and the electrolysis cavity is internally provided with an anode electrode and a cathode electrode; the utility model discloses an adsorption resin and ion exchange resin jointly purify the water in first, the secondary treatment chamber to coupling resin treatment chamber and electrolytic treatment chamber, the effect of getting rid of electrified property organic matter, halogen ion, calcium magnesium ion in improving the water greatly, and be favorable to the further disinfection of electrolytic process to the water, under the condition of low cost, can cut down the formation volume of disinfection accessory substance by a wide margin in high-efficient water purification, the sterilization, reduce out water toxicity.
Description
Technical Field
The utility model relates to a water treatment technical field, more specifically say, relate to a drinking water degassing unit.
Background
Water is a source of life, and the quality of the drinking water is closely related to the health of people. In order to ensure the safety of drinking water, the drinking water needs to be disinfected before being conveyed to an urban pipe network. At present, chlorination disinfection is the most widely applied in China, but the chlorination disinfection can generate teratogenic, carcinogenic and mutagenic disinfection byproducts. In addition, after leaving the factory, tap water still needs to pass through facilities such as a long water delivery pipe network, a high-rise water tower, a water tank and the like, and rust, dirt and the like cause serious secondary pollution to water quality in the conveying process and can also cause breeding of pathogenic bacteria. Thus, when drinking water is transported to a user terminal, deep purification is important. Natural Organic Matter (NOM) and halogen ion (Br) widely existing in drinking water source water–、Cl–) Under the action of the disinfectant, a series of halogenated disinfection byproducts are generated and are main precursors of the disinfection byproducts. In addition, after the tap water leaves the factory, the tap water passes through facilities such as a water conveying pipe network, a high-rise water tower and a water tank in the conveying process, so that rust, dirt and the like cause secondary pollution to the water quality, and meanwhile, pathogenic bacteria (such as escherichia coli) can be bred.
At present, the water purifiers on the market mainly adopt a membrane technology, a ceramic filter element technology, an active carbon technology and the like to carry out deep purification of drinking water. The water purifiers of the membrane technology are divided into four categories of microfiltration, ultrafiltration, nanofiltration and reverse osmosis. Wherein, the technology of micro-filtration, ultra-filtration and ceramic filter element is difficult to effectively filter fine pollutants and reduce disinfection by-products; the nano-filtration and the reverse osmosis can produce pure water, but on one hand, the nano-filtration and the reverse osmosis consume serious water and electricity, have high cost, on the other hand, the nano-filtration and the reverse osmosis are not resistant to pollution, and are easily decomposed by microorganisms such as bacteria, so the service life is reduced; the activated carbon adsorption technology cannot remove pathogenic microorganisms in water, and needs to be matched with other disinfection technologies, so that the practical application of the activated carbon adsorption technology is limited. In summary, some water purifiers on the market at present are difficult to have conditions for advanced treatment of drinking water due to the limitation of end user conditions, and the water quality safety and health cannot be guaranteed.
By way of retrieval, application No.: 201710925957.0, filing date: 10 and 05 in 2017, the name of the invention is: a novel water purifier for sterilizing and disinfecting drinking water comprises a base, a first purifying tank and a second purifying tank, wherein a metal tank is fixedly arranged at the bottom of an inner cavity of the first purifying tank, an ultraviolet lamp tube is fixedly arranged between a top plate and a bottom plate of the metal tank, a water inlet pipe is arranged at the top end of the metal tank, and one end, away from the metal tank, of the water inlet pipe penetrates through the first purifying tank and extends to the outside of the first purifying tank; the inside of second purifying tank is provided with the baffle, and the baffle is located the lower part of connecting the water pipe, is provided with gas shower nozzle on the baffle, and the top fixed mounting of second purifying tank has ozone generator, and ozone generator's gas outlet passes through the air inlet intercommunication of first connecting pipe with gas shower nozzle, and the dorsal part fixed mounting of second purifying tank has the ozone recoverer, and ozone recoverer air inlet intercommunication has the second connecting pipe, and the one end that the ozone recoverer was kept away from to the second connecting pipe runs through the roof of second purifying tank and extends to the inside of second purifying tank. The device can realize that the drinking water carries out the disinfection for the first time to the drinking water when the metal can through first purifying tank, the ultraviolet tube in the metal can, and the disinfection for the second time is carried out through letting in ozone gas in to the drinking water in the second purifying tank, makes the disinfection of drinking water more thorough, has increased the security of drinking water. However, the device is not provided with a purification module, so that fine particles and partial organic matters in the drinking water cannot be effectively removed, and a disinfection by-product can be further generated in the subsequent ozone disinfection process. In addition, the adoption of ozone can affect the taste of water, damage gastric mucosa, increase free radicals and be harmful to human bodies; the ultraviolet sterilizer is adopted, the quartz sleeve needs to be cleaned every week, otherwise, the sterilization effect of ultraviolet rays can be greatly reduced and even eliminated by a mucous membrane layer formed on the quartz tube by bacterial secretion and bacterial corpses, so that the treatment effect and the treatment efficiency are very limited in practical application, and the use cost is high.
SUMMERY OF THE UTILITY MODEL
1. Technical problem to be solved by the utility model
An object of the utility model is to provide a drinking water degassing unit to current drinking water is difficult to carry out disinfection's technical problem through low-cost, efficient mode, makes the multistage series connection of adsorption resin, ion exchange resin and water electrolysis through the device, realizes carrying out effectual disinfection to the water.
2. Technical scheme
In order to achieve the above purpose, the utility model provides a technical scheme does:
the utility model discloses a drinking water disinfection device, which comprises a shell, wherein a drinking water inlet and a drinking water outlet are arranged on the shell, and a primary treatment cavity, a secondary treatment cavity and an electrolysis cavity are sequentially arranged in the shell along the direction from the drinking water inlet to the drinking water outlet; wherein, the primary treatment cavity is internally provided with adsorption resin which firstly adsorbs the chromaticity and organic pollutants in the water body; ion exchange resin is arranged in the secondary treatment cavity, and the water body adsorbed by the adsorption resin is subjected to ion exchange; an anode electrode and a cathode electrode are arranged in the electrolytic cavity, and the water body after ion exchange by the ion exchange resin is electrolyzed.
Preferably, the primary treatment chamber and the secondary treatment chamber are separated by a first barrier layer, and the secondary treatment chamber and the electrolysis chamber are separated by a second barrier layer.
Preferably, the primary treatment cavity is provided with a back flush water inlet, and the adsorption resin is arranged in the primary treatment cavity between the drinking water inlet and the back flush water inlet.
Preferably, the adsorption resin is an adsorption resin layer, a first clamping groove is formed in the side wall of the primary treatment cavity, the adsorption resin layer is fixed in the primary treatment cavity through the first clamping groove, and/or the ion exchange resin is an ion exchange resin layer, a second clamping groove is formed in the side wall of the secondary treatment cavity, and the ion exchange resin layer is fixed in the secondary treatment cavity through the second clamping groove.
Preferably, the adsorbent resin is an ultra-high cross-linked adsorbent resin.
Preferably, an electrode clamping groove is formed in the electrolytic cavity, and the anode electrode and the cathode electrode are fixed in the electrolytic cavity through the electrode clamping groove.
Preferably, the ion exchange resin comprises a cation exchange resin layer and an anion exchange resin layer, and the water body passes through the cation exchange resin layer and then passes through the anion exchange resin layer.
Preferably, the anion exchange resin layer is a chlorine type anion exchange resin.
The drinking water disinfection method of the utility model firstly carries out adsorption treatment on the water body through the adsorption resin, and adsorbs the chromaticity and organic pollutants in the water body; then carrying out ion exchange on the water body after adsorption treatment by using ion exchange resin; and finally, electrolyzing the water body subjected to ion exchange.
Preferably, the specific steps are as follows:
introducing a water body into a primary treatment cavity, and adsorbing chromaticity and organic pollutants in the water body by using ultra-high cross-linked adsorbent resin;
step two, introducing the water body after adsorption treatment into a secondary treatment cavity, exchanging cations in the water body through cation exchange resin, and then performing ion exchange on the water body through chlorine type anion exchange resin;
and step three, introducing the water body subjected to ion exchange into an electrolytic chamber for electrolytic treatment.
3. Advantageous effects
Adopt the technical scheme provided by the utility model, compare with existing well-known technique, have following apparent effect:
(1) the utility model discloses a drinking water disinfection device, which comprises a shell, wherein a drinking water inlet and a drinking water outlet are arranged on the shell, and a primary treatment cavity, a secondary treatment cavity and an electrolysis cavity are sequentially arranged in the shell along the direction from the drinking water inlet to the drinking water outlet; wherein the primary treatment intracavity is provided with adsorption resin, the secondary treatment intracavity is provided with ion exchange resin, be provided with anode electrode and cathode electrode in the electrolysis intracavity, through one, adsorption resin and ion exchange resin carry out joint purification to the water in the secondary treatment chamber, and carry out the coupling with resin treatment chamber and electrolysis treatment chamber, improve the effect of getting rid of electrified organic matter, halogen ion, calcium magnesium ion in the water greatly, and be favorable to the further disinfection of electrolysis process to the water, under the condition of low cost, can reduce the formation volume of disinfection accessory substance by a wide margin when high-efficient water purification, disinfect, reduce out water toxicity.
(2) The drinking water disinfection method of the utility model firstly carries out adsorption treatment on the water body through the adsorption resin, and adsorbs the chromaticity and organic pollutants in the water body; then carrying out ion exchange on the water body after adsorption treatment by using ion exchange resin; finally, electrolyzing the water body subjected to ion exchange; the drinking water is subjected to primary pretreatment by virtue of the characteristic advantages of large surface area, strong adsorption performance and easy elution and regeneration of the adsorption resin through secondary series connection of the adsorption resin and the ion exchange resin, and the secondary resin further removes charged organic matters, inorganic halogen ions and calcium and magnesium ions in the water body through the ion exchange effect, so that the effects of purifying and softening the water quality are enhanced through the secondary resin reactor through the series connection, wherein the primary pretreatment also effectively reduces the problem of pollution saturation of the secondary resin reactor, and provides convenience for resin regeneration.
Drawings
FIG. 1 is a sectional view of a drinking water sterilizer according to the present invention;
fig. 2 is a schematic view of a sectional three-dimensional structure of a drinking water disinfection device of the present invention.
The reference numerals in the schematic drawings illustrate:
100. a housing; 101. a first blocking layer; 102. a second blocking layer;
110. a primary treatment chamber; 111. a drinking water inlet; 112. a first card slot; 113. an adsorption resin layer; 114. backwashing the water inlet;
120. a secondary treatment chamber; 121. a cation exchange resin layer; 122. an anion exchange resin layer; 123. a second card slot;
130. an electrolysis chamber; 131. an electrode card slot; 132. an anode electrode; 133. a cathode electrode; 134. a water outlet; 135. and (4) a flow hole.
Detailed Description
For a further understanding of the present invention, reference will be made to the following detailed description taken in conjunction with the accompanying drawings and examples.
The structure, ratio, size and the like shown in the drawings of the present specification are only used for matching with the content disclosed in the specification, so as to be known and read by people familiar with the art, and are not used for limiting the limit conditions which can be implemented by the present invention, so that the present invention does not have the substantial significance in the technology, and any structure modification, ratio relationship change or size adjustment should still fall within the scope which can be covered by the technical content disclosed by the present invention without affecting the efficacy which can be produced by the present invention and the achievable purpose. Meanwhile, the terms such as "upper", "lower", "left", "right", "middle", and the like, referred to in the present specification, are used for clarity of description only, and are not used to limit the implementable scope, and changes or adjustments of the relative relationship thereof are also regarded as the implementable scope of the present invention without substantial changes in the technical content; in addition, the embodiments of the present invention are not independent of each other, but can be combined.
Example 1
The drinking water disinfection device of the embodiment, as shown in fig. 1-2, includes a housing 100, the housing 100 is provided with a drinking water inlet 111 and a drinking water outlet 134, and a primary treatment chamber 110, a secondary treatment chamber 120 and an electrolysis chamber 130 are sequentially arranged in the housing 100 along a direction from the drinking water inlet 111 to the drinking water outlet 134; wherein, the first-stage treatment cavity 110 is internally provided with adsorption resin which firstly adsorbs the chromaticity and organic pollutants in the water body; ion exchange resin is arranged in the secondary treatment cavity 120, and the water body adsorbed by the adsorption resin is subjected to ion exchange; an anode electrode 132 and a cathode electrode 133 are arranged in the electrolysis chamber 130, and the water body after ion exchange by the ion exchange resin is electrolyzed.
In this embodiment, a first clamping groove 112 is formed in a side wall of the primary processing chamber 110, the adsorption resin layer 113 is fixed in the primary processing chamber 110 through the first clamping groove 112, and the adsorption resin arranged in the primary processing chamber 110 is ultrahigh cross-linked adsorption resin.
The primary treatment cavity 110 and the secondary treatment cavity 120 are separated by a first barrier layer 101, the first barrier layer 101 is a screen layer, and the screen layer is formed by overlapping 2 layers of 100-mesh annular screens in a staggered manner. The ion exchange resin arranged in the secondary treatment cavity 120 is an ion exchange resin layer, a second clamping groove 123 is arranged on the side wall of the secondary treatment cavity 120, and the ion exchange resin layer is fixed in the secondary treatment cavity 120 through the second clamping groove 123. The ion exchange resin layer comprises a cation exchange resin layer 121 and an anion exchange resin layer 122, and the water body needs to be treated by passing through the cation exchange resin layer 121 and then through the anion exchange resin layer 122, wherein the anion exchange resin layer 122 is chlorine type anion exchange resin.
In the embodiment, the disinfection device is cylindrical, the water inlet 111 to the water outlet 134 are respectively arranged at two ends of the cylindrical disinfection device, the water to be treated firstly enters the primary treatment cavity 110 from the water inlet 111 at one end, and in the primary treatment cavity 110, the water to be treated passes through the adsorption resin layer 113, and primary pretreatment is performed on drinking water by utilizing the characteristic advantages of large surface area, strong adsorption performance and easy elution and regeneration of the ultrahigh cross-linked adsorption resin in the adsorption resin layer 113, so that the disinfection device is mainly used for adsorbing and removing chromaticity and organic pollutants in the water, and improving the water quality and the taste; wherein the adsorption resin layer 113 may be provided in plural, 3 in the present embodiment.
In addition, the primary treatment cavity 110 is provided with a back flush water inlet 114, and the adsorption resin is arranged in the primary treatment cavity 110 between the drinking water inlet 111 and the back flush water inlet 114; when the adsorption resin layer 113 in the primary treatment chamber 110 needs to be cleaned after being treated for a period of time, the used water enters the primary treatment chamber 110 from the back-flushing water inlet 114 and then flows out from the water inlet 111, and the process realizes back-flushing of the adsorption resin layer 113, so that the adsorption resin layer 113 is subsequently adsorbed more efficiently.
After the water body is adsorbed by the adsorption resin layer 113 in the primary treatment cavity 110, the water body enters the secondary treatment cavity 120 through the first barrier layer 101, the water body firstly passes through the cation exchange resin layer 121 in the secondary treatment cavity 120, and the water body is softened by ion exchange of cations such as calcium, magnesium and the like in the water body through the cation exchange resin layer 121; the water then passes through anion exchange resin layer 122 for the anion exchange process.
After the adsorption treatment is carried out on the adsorption resin layer 113 in the primary treatment cavity 110, the synergistic treatment of the cation exchange resin layer 121 and the anion exchange resin layer 122 in the secondary treatment cavity 120 is combined, so that the charged organic matters, calcium and magnesium ions and inorganic halogen ions in the water body are effectively removed, the multi-stage purification treatment is carried out on the drinking water, and the chlorine ions necessary for the subsequent electrolytic disinfection are exchanged.
Inside the electrolysis chamber 130, there are disposed an anode electrode 132 and a cathode electrode 133, which electrolyze the water body ion-exchanged by the ion exchange resin. Specifically, an electrode clamping groove 131 is arranged in the electrolysis cavity 130, and the anode electrode 132 and the cathode electrode 133 are fixed in the electrolysis cavity 130 through the electrode clamping groove 131; the anode electrode 132 and the cathode electrode 133 are connected to an external power supply; as shown in fig. 2, a flow hole 135 is provided between the electrode card slot 131 and each electrode.
The secondary treatment cavity 120 and the electrolysis cavity 130 are separated by a second barrier layer 102, the second barrier layer 102 is a sieve layer formed by overlapping 3 layers of 200-mesh annular sieves in a staggered mode, and the sieve layer is used for intercepting resin fragments in a water body and guaranteeing the water inlet quality of the electrolysis cavity 130. The water body treated by the ion exchange in the secondary treatment cavity 120 enters the electrolysis cavity 130 through the second barrier layer 102, the water body treated by the anion exchange resin layer 122 in the secondary treatment cavity 120 contains chloride ions, the water body is electrolyzed after the anode electrode 132 and the cathode electrode 133 in the electrolysis cavity 130 are electrified, the chloride ions are electrolyzed to separate out chlorine gas, the water body in the secondary treatment cavity 120 flows through the electrode clamping grooves 131 and the circulation holes 135 between the electrodes, and the separated chlorine gas generates hypochlorous acid in the water body to disinfect the water body in the flowing process.
The disinfection method using the implementation device comprises the steps of firstly adsorbing the water body by the adsorption resin to adsorb the chromaticity and organic pollutants in the water body; then carrying out ion exchange on the water body after adsorption treatment by using ion exchange resin; and finally, electrolyzing the water body after ion exchange.
The method comprises the following specific steps:
introducing a water body into a primary treatment cavity (110), and adsorbing chromaticity and organic pollutants in the water body by using ultrahigh cross-linked adsorbent resin;
step two, introducing the water body after adsorption treatment into a secondary treatment cavity (120), exchanging cations in the water body through cation exchange resin, and then performing ion exchange on the water body through chlorine type anion exchange resin;
and step three, introducing the water body subjected to ion exchange into an electrolysis cavity (130) for electrolysis treatment.
In the embodiment, the water body is sampled after being treated by the ion exchange resin, and the content of Natural Organic Matters (NOM) and Br in the water body are detected-Content, Total hardness (as CaCO)3In mg/L), and Cl-Content (c); and (3) electrolyzing the water body in the electrolytic cavity (130) for 19s, sampling and detecting after the water body is discharged from the water outlet (134), and detecting the content of escherichia coli and the content of total organic halogen (TOX). The results are shown in Table 1.
Comparative example 1
Comparative example 1 is basically the same as example 1, except that in the comparative example, no adsorption resin is arranged in the primary treatment cavity (110), and water directly enters the secondary treatment cavity (1) after entering from the drinking water inlet (111)20) Wherein the cation exchange treatment and the anion exchange treatment are carried out by ion exchange resin. In the disinfection step, the ultrahigh cross-linked adsorbent resin used in the first step is adsorbed, and the chromaticity and organic pollutants in the water body are removed. In the embodiment, the water body is sampled after being treated by the ion exchange resin, and the content of Natural Organic Matters (NOM) and Br in the water body are detected-Content, Total hardness (as CaCO)3In mg/L), and Cl-Content (c); and (3) electrolyzing the water body in the electrolytic cavity (130) for 19s, sampling and detecting after the water body is discharged from the water outlet (134), and detecting the content of escherichia coli and the content of total organic halogen (TOX). The results are shown in Table 1.
Comparative example 2
The comparative example 2 is basically the same as the example 1, except that no cation exchange resin layer (121) is arranged in the secondary treatment cavity (120) in the comparative example, and after water enters from the drinking water inlet (111) and is treated by the adsorption resin in the primary treatment cavity (110), the water enters the secondary treatment cavity (120) and is not treated by the cation exchange resin layer (121) but is treated only by the anion exchange resin layer (122). And in the disinfection step, the step of exchanging the cations in the water body through the cation exchange resin in the step two is also removed. In the embodiment, the water body is sampled after being treated by the ion exchange resin, and the content of Natural Organic Matters (NOM) and Br in the water body are detected-Content, Total hardness (as CaCO)3In mg/L), and Cl-Content (c); and (3) electrolyzing the water body in the electrolytic cavity (130) for 19s, sampling and detecting after the water body is discharged from the water outlet (134), and detecting the content of escherichia coli and the content of total organic halogen (TOX). The results are shown in Table 1.
Table 1 table of pollutant contents in water treatment of examples or comparative examples
In a normal case, the main processing object of the adsorption resin layer 113 is NOM, and the main processing object of the cation exchange resin layer 121 is cations (Ca) of calcium, magnesium, etc2+、Mg2+) The anion exchange resin layer 122 functions to remove charged organic substances and halogen ions (Br)–). As can be seen from the comparison of the data in table 1, for NOM, the NOM content is significantly reduced after the adsorption resin layer 113, the cation exchange resin and the anion exchange resin are used in cooperation in example 1; for Br-The content of Br was determined by using the adsorption resin layer 113, the cation exchange resin and the anion exchange resin in combination in example 1-The content is obviously reduced; for Cl-Content of Cl after the adsorption resin layer 113, the cation exchange resin and the anion exchange resin were used in combination in example 1-The content is obviously increased, which is beneficial to the subsequent electrolysis process; for total hardness (as CaCO)3In mg/L), CaCO was added after the adsorption resin layer 113, the cation exchange resin and the anion exchange resin were used in combination in example 13The content is obviously reduced; for the content of escherichia coli, after the adsorption resin layer 113, the cation exchange resin and the anion exchange resin are used cooperatively in example 1, the content of escherichia coli is obviously reduced; with respect to TOX, the content of TOX is significantly reduced after the adsorption resin layer 113, the cation exchange resin and the anion exchange resin are used in cooperation in example 1.
Therefore, in the drinking water disinfection device of embodiment 1, the adsorption resin and the ion exchange resin in the primary treatment cavity and the secondary treatment cavity are used for jointly purifying the water body to remove the precursors NOM and Br of the disinfection byproducts–The cutting rate is over 90 percent, and the total hardness removal rate can reach 70 percent so as to achieve the purpose of properly softening water quality. At the same time, about 106mg/L of chloride ions are exchanged for electrolytic disinfection. Under the same simulated drinking water sample condition, 5mg/L chlorine is added through a chemical chlorine adding method to generate about 500 mu g/L TOX, while the disinfection method only generates about 37 mu g/L TOX, so that the generation of halogenated disinfection byproducts can be effectively reduced; in addition, the sterilization method can achieve high-efficiency sterilization effect while controlling the generation of sterilization by-products, only electrolyzes for 19s, and treats large intestineThe killing rate of bacillus is over 99.9975%, and the sterilizing effect is obviously improved.
Comparative example 1 is substantially the same as example 1 except that there is no adsorption treatment and only ion exchange. The more decreased removal rate of NOM indicates that the anion exchange resin layer has a certain effect of removing NOM, but the effect of removing NOM is also affected by the adsorption resin layer. Based on the reduction of the precursor reduction, the amount of generated disinfection by-products was slightly increased compared to example 1, and this disinfection method generated TOX of about 85 μ g/L. Which shows that the adsorption treatment has important influence on the purification and disinfection of drinking water.
Comparative example 2 is substantially the same as example 1 except that there is no cation exchange treatment and only adsorption and anion exchange are performed. Compared with the inlet water, the total hardness content of the treated outlet water is basically unchanged, and the water quality is not softened. Ca in water although other index parameters also fluctuate less2+、Mg2+The content is high, the electrode plates are easy to scale after long-term treatment, the electrolysis efficiency is influenced, and the service cycle of the electrode plates is shortened. The method shows that the cation exchange resin treatment has important influence on the purification and disinfection of drinking water.
Therefore use the utility model discloses a drinking water degassing unit, through one, adsorption resin and ion exchange resin carry out the joint purification to the water in the secondary treatment chamber to carry out the coupling with resin treatment chamber and electrolytic treatment chamber, improve the effect of getting rid of electrified organic matter, halogen ion, calcium magnesium ion in the water greatly, and be favorable to the further disinfection of electrolytic process to the water, under the condition of low cost, at high-efficient water purification, can reduce the formation volume of disinfection accessory substance by a wide margin in the time of disinfecting, reduce out water toxicity.
The invention has been described above in detail with reference to specific exemplary embodiments. It will, however, be understood that various modifications and changes may be made without departing from the scope of the invention as defined by the appended claims. The detailed description and drawings are to be regarded as illustrative rather than restrictive, and any such modifications and variations are intended to be included within the scope of the present invention as described herein. Furthermore, the background is intended to illustrate the present state of the art and the meaning of the present development and is not intended to limit the present invention or the present application and the field of application of the present invention.
More specifically, although exemplary embodiments of the invention have been described herein, the invention is not limited to these embodiments, but includes any and all embodiments modified, omitted, such as combinations between various embodiments, adapted changes and/or substitutions as would be recognized by those skilled in the art from the foregoing detailed description. The limitations in the claims are to be interpreted broadly based the language employed in the claims and not limited to examples described in the foregoing detailed description or during the prosecution of the application, which examples are to be construed as non-exclusive. Any steps recited in any method or process claims may be executed in any order and are not limited to the order presented in the claims. The scope of the invention should, therefore, be determined only by the appended claims and their legal equivalents, rather than by the descriptions and examples given above.
Claims (8)
1. A drinking water disinfection device is characterized by comprising a shell (100), wherein a drinking water inlet (111) and a drinking water outlet (134) are formed in the shell (100), and a primary treatment cavity (110), a secondary treatment cavity (120) and an electrolysis cavity (130) are sequentially arranged in the shell (100) along the direction from the drinking water inlet (111) to the drinking water outlet (134);
the first-stage treatment cavity (110) is internally provided with adsorption resin which firstly adsorbs the chromaticity and organic pollutants in the water body;
ion exchange resin is arranged in the secondary treatment cavity (120) and is used for carrying out ion exchange on the water body adsorbed by the adsorption resin;
an anode electrode (132) and a cathode electrode (133) are arranged in the electrolysis cavity (130) to electrolyze the water body after ion exchange by the ion exchange resin.
2. A drinking water disinfection apparatus as claimed in claim 1, wherein the primary treatment chamber (110) and the secondary treatment chamber (120) are separated by a first barrier (101), and the secondary treatment chamber (120) and the electrolysis chamber (130) are separated by a second barrier (102).
3. A drinking water disinfection apparatus as claimed in claim 1, wherein said primary treatment chamber (110) is provided with a back flush water inlet (114), and wherein an adsorbent resin is provided in the primary treatment chamber (110) between the drinking water inlet (111) and the back flush water inlet (114).
4. A drinking water disinfection apparatus as claimed in claim 1, wherein said adsorbent resin is a layer of adsorbent resin (113), a first slot (112) is provided on the sidewall of the primary treatment chamber (110), the layer of adsorbent resin (113) is fixed in the primary treatment chamber (110) through the first slot (112), and/or said ion exchange resin is a layer of ion exchange resin, a second slot (123) is provided on the sidewall of the secondary treatment chamber (120), and the layer of ion exchange resin is fixed in the secondary treatment chamber (120) through the second slot (123).
5. A drinking water disinfection apparatus as claimed in claim 1, wherein said adsorbent resin is a super high cross-linked adsorbent resin.
6. A drinking water disinfection apparatus as claimed in claim 1, wherein an electrode slot (131) is provided in the electrolysis chamber (130), and the anode electrode (132) and the cathode electrode (133) are fixed in the electrolysis chamber (130) through the electrode slot (131).
7. A drinking water disinfection apparatus as claimed in claim 1, wherein said ion exchange resin comprises a cation exchange resin layer (121) and an anion exchange resin layer (122), and the water body passes through the cation exchange resin layer (121) and then the anion exchange resin layer (122).
8. A drinking water disinfection apparatus as claimed in claim 7, wherein said anion exchange resin layer (122) is a chlorine type anion exchange resin.
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