CN215855269U - Water purification system - Google Patents

Water purification system Download PDF

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CN215855269U
CN215855269U CN202022997919.6U CN202022997919U CN215855269U CN 215855269 U CN215855269 U CN 215855269U CN 202022997919 U CN202022997919 U CN 202022997919U CN 215855269 U CN215855269 U CN 215855269U
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water
module
water inlet
purification
electrolysis
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宾倩韵
孙天厚
刘梦薇
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Foshan Midea Qinghu Water Purification Equipment Co ltd
Midea Group Co Ltd
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Foshan Midea Qinghu Water Purification Equipment Co ltd
Midea Group Co Ltd
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Abstract

The utility model discloses a water purification system. This water purification system includes: an electrical purification module adapted to perform purification treatment of incoming water; the electrolysis module is communicated with the electric purification module, water entering the electrolysis module is electrolyzed to generate strong oxidizing ions with strong oxidizing property, and the generated strong oxidizing ions are at least used for sterilization. According to the water purification system, the electrolysis module is communicated with the electric purification module, so that the electrolysis module can sterilize water passing through the electrolysis module, and the problems of turbidity and odor of the water outlet of the water purification system are solved.

Description

Water purification system
Technical Field
The utility model relates to the technical field of water purification, in particular to a water purification system.
Background
The electric purification module consists of electrodes, a partition board and anion and cation exchange membranes, wherein the anion and cation exchange membranes are the core of the electric purification module and also the core of the whole EDR (electrode inversion electrodialysis) system. Ion exchange membranes are generally composed of an ion exchange resin backbone, fixed groups, and mobile ions on the groups. Wherein, the cation exchange membrane generally has sulfonic acid groups, and the sulfonic acid groups can be dissociated to provide negatively charged fixed groups and only allow cations to pass through; anion exchange membranes typically carry quaternary ammonium groups which dissociate to provide positively charged anchor groups, allowing only anions to pass through.
Cation exchange membrane: R-SO3H—→R-SO3 -+H+
Anion exchange membrane: R-N (CH3)3OH—→R-N+(CH3)3+OH-
In the operation of the electrical purification module, a process of membrane fouling is often accompanied. Organic fouling is a relatively common type of membrane fouling in electrodialysis processes. Since most of organic substances in tap water, such as proteins, amino acids, humic acids, surfactants, aromatic hydrocarbon derivatives, etc., have negative charges, they tend to contaminate the anion exchange membrane. Besides the electrostatic attraction effect, the organic matter with negative charges and the anion exchange membrane also have affinity effect (hydrophobic interaction), so that the organic matter is deposited on the surface of the membrane or blocks the pore channel of the membrane, and a series of problems of increased membrane resistance, reduced desalination rate and the like are caused. In addition, the organic matter deposit on the tunica vaginalis also can lead to breeding of bacterium, makes the play water of electric purification module rear end become smelly, become turbid, influences the user experience of water purifier.
SUMMERY OF THE UTILITY MODEL
The present invention is directed to solving, at least to some extent, one of the above-mentioned problems in the prior art. Therefore, the utility model provides a water purification system to relieve the phenomenon that the outlet water at the rear end of an electric purification module becomes smelly and turbid.
A water purification system according to an embodiment of the present invention includes: an electrical purification module adapted to perform purification treatment of incoming water; the electrolysis module is communicated with the electric purification module, water entering the electrolysis module is electrolyzed to generate strong oxidizing ions with strong oxidizing property, and the generated strong oxidizing ions are at least used for sterilization.
According to the water purification system disclosed by the embodiment of the utility model, the electrolysis module is communicated with the electric purification module, so that the electrolysis module can sterilize water passing through the electrolysis module, and the problems of turbidity and odor of the water outlet of the water purification system are solved.
According to some embodiments of the utility model, the strong oxidizing ion is a hypochlorite ion.
According to some embodiments of the utility model, the electrolysis module is disposed at a front end of the electrical purification module, and water entering the electrical purification module preferentially passes through the electrolysis module.
According to some embodiments of the utility model, the electrolysis module is disposed at a rear end of the electrical purification module, and water entering the electrical purification module subsequently passes through the electrolysis module.
According to some embodiments of the utility model, the electrical purification module has a fresh water inlet, a concentrated water inlet, a fresh water outlet, and a concentrated water outlet, the fresh water inlet is connected to a fresh water inlet line, the concentrated water inlet is connected to a concentrated water inlet line, both the fresh water inlet line and the concentrated water inlet line are connected to a main water inlet line, the fresh water outlet is connected to a fresh water outlet line, and the concentrated water outlet is connected to a concentrated water outlet line.
According to some embodiments of the present invention, the number of the electrical purification modules is one, and the electrolysis module is disposed on at least one of the main water inlet pipeline, the fresh water inlet pipeline, the concentrated water inlet pipeline, and the fresh water outlet pipeline.
According to some embodiments of the present invention, the number of the electrical purification modules is multiple, the electrolysis modules are disposed on the water inlet main pipelines of the electrical purification modules, and/or the electrolysis modules are disposed on the fresh water outlet pipelines of the electrical purification modules.
According to some embodiments of the present invention, the number of the electrical purification modules is multiple, the main water inlet pipeline of the electrical purification modules is connected to the main water inlet pipeline, and the electrolysis module is disposed on the main water inlet pipeline.
According to some embodiments of the present invention, the number of the electrical purification modules is multiple, the fresh water outlet pipes of the electrical purification modules are all connected to a fresh water outlet main pipe, and the electrolysis module is disposed on the fresh water outlet main pipe.
According to some embodiments of the utility model, the electrolysis module comprises a fixed support, an anode electrolytic sheet and a cathode electrolytic sheet, the anode electrolytic sheet and the cathode electrolytic sheet are arranged in the fixed support, after water enters the electrolysis module, under the action of an electric field, anions migrate to the anode electrolytic sheet, and cations migrate to the cathode electrolytic sheet to generate the hypochlorite ions.
Additional aspects and advantages of the utility model will be set forth in part in the description which follows and, in part, will be obvious from the description, or may be learned by practice of the utility model.
Drawings
FIG. 1 is a schematic diagram of a water purification system having a single electrical purification module;
FIG. 2 is a schematic view of a water purification system with electrolysis modules disposed on a plurality of water inlet main pipelines;
FIG. 3 is a schematic view of a water purification system with a plurality of fresh water outlet pipelines each provided with an electrolysis module;
FIG. 4 is a schematic diagram of a water purification system with an electrolysis module disposed on a water inlet main line;
FIG. 5 is a schematic diagram of a water purification system with an electrolysis module disposed on a fresh water outlet main pipeline;
FIG. 6 is a schematic of an electrolysis module.
Reference numerals:
the device comprises an electric purification module 1, a fresh water inlet 11, a concentrated water inlet 12, a fresh water outlet 13, a concentrated water outlet 14, a fresh water inlet pipeline 41, a concentrated water inlet pipeline 42, a main water inlet pipeline 43, a main water inlet pipeline 44, a fresh water outlet pipeline 51, a concentrated water outlet pipeline 52, a main fresh water outlet pipeline 53, an electrolysis module 91, a fixed support 911, an anode electrolytic sheet 912 and a cathode electrolytic sheet 913.
Detailed Description
Reference will now be made in detail to embodiments of the present invention, examples of which are illustrated in the accompanying drawings, wherein like or similar reference numerals refer to the same or similar elements or elements having the same or similar function throughout. The embodiments described below with reference to the drawings are illustrative and intended to be illustrative of the utility model and are not to be construed as limiting the utility model.
In the description of the present invention, it is to be understood that the terms "upper", "lower", "front", "rear", "inner", "outer", and the like, indicate orientations or positional relationships based on the orientations or positional relationships shown in the drawings, are only for convenience in describing the present invention and simplifying the description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and thus, should not be construed as limiting the present invention.
Further, in the description of the present invention, "a plurality" means at least two, e.g., two, three, etc., unless specifically limited otherwise.
In the present invention, unless otherwise expressly stated or limited, the terms "mounted," "connected," "secured," and the like are to be construed broadly and can, for example, be fixedly connected, detachably connected, or integrally formed; can be mechanically connected, electrically connected or can communicate with each other; either directly or indirectly through intervening media, either internally or in any other relationship. The specific meanings of the above terms in the present invention can be understood by those skilled in the art according to specific situations.
A water purification system according to an embodiment of the present invention will be described in detail with reference to fig. 1 to 6.
Referring to fig. 1 to 5, a water purification system according to an embodiment of the present invention may include: an electrical purification module 1 and an electrolysis module 91.
The electric purification module 1 is adapted to purify incoming water, and specifically, in some optional embodiments, the electric purification module 1 may purify incoming water by using an electrodialysis technique, the electric purification module 1 has a positive electrode and a negative electrode pair for electrodialysis water purification, the electric purification module 1 is alternately arranged between the positive electrode and the negative electrode by using cation-anion exchange membranes, and is separated by using a special partition plate to form two systems of desalination and concentration, under the action of a direct current electric field, cations in water migrate to the negative electrode and only pass through the cation exchange membranes, anions migrate to the positive electrode and only pass through the anion exchange membranes, so that raw water in a dilute chamber is desalinated, and raw water in a dense chamber is concentrated. The electric purification module 1 can also switch the polarities of the positive electrode and the negative electrode at preset intervals (for example, 15-20 min), automatically clean dirt formed on the surfaces of the ion exchange membrane and the electrodes, and ensure the long-term stability of the ion exchange membrane effect and the quality and quantity of fresh water.
Electrolysis module 91 is linked together with electric purification module 1, and the water electrolysis that gets into in electrolysis module 91 produces the strong oxide ion that has strong oxidizing property, and the strong oxide ion that produces is used for disinfecting at least, in other words, strong oxide ion is for having the ion of bactericidal action, and like this, strong oxide ion can play the effect of suppression, killing to the bacterium through electrolysis module 91 to effectively avoid bacterial growing, prevent that water purification system goes out that the water is muddy, smelly.
According to the water purification system disclosed by the embodiment of the utility model, the electrolysis module 91 is communicated with the electric purification module 1, so that the electrolysis module 91 sterilizes water passing through the electrolysis module, the problems of turbidity and odor of the outlet water of the water purification system are solved, and the requirements on sanitation and safety are met.
Optionally, the strong oxidizing ion is a hypochlorite ion.
The strong oxidizing ions with strong oxidizing property can act on bacterial pollutants and can also act on organic matters to carry out oxidative degradation on the organic matters. In the embodiment shown in fig. 1-2 and 4, the electrolysis module 91 is disposed at the front end of the electrical purification module 1, water entering the electrical purification module 1 preferentially passes through the electrolysis module 91, water entering the electrolysis module 91 is electrolyzed to generate strong oxidizing ions with strong oxidizing property, the generated strong oxidizing ions enter the electrical purification module 1, and after the strong oxidizing ions enter the electrical purification module 1, on one hand, the organic matters in the electrical purification module 1 are subjected to oxidative degradation, so as to achieve the purpose of cleaning the electrical purification module 1; on the other hand, the water purifying device plays a role in bacteriostasis and sterilization on the electric purification module 1, and reduces bacterial breeding, thereby solving the problems of turbid and smelly outlet water of the water purifying system.
Table one is the relevant experimental data of the electrolytic module 91 acting on the front end of the electrical purification module 1. Raw water for experiments is tap water, under the condition that the electrolysis module 91 is not electrified, COD (Chemical Oxygen Demand) of the effluent of the electric purification module 1 exceeds the standard of drinking water, and residual chlorine is not detected; after adding electrolysis module 91, fresh water, dense water both ends COD all have obvious reduction, reach the drinking water requirement, and can discover from the comparison of electric purification module 1 front and back end chlorine residue, fresh water, dense water chlorine residue content behind electric purification module 1 reduce, prove that chlorine residue acts on organic matter or bacterium in electric purification module 1 and is consumed. The residual chlorine in the effluent can be removed by the post-filter element of the water purification system.
Effect of the Meter-Electrolysis Module 91 on the Electrical purification Module 1
Figure BDA0002828846240000041
In fig. 3, the embodiment shown in fig. 5, electrolysis module 91 sets up the rear end at electric purification module 1, the water that gets into electric purification module 1 passes through electrolysis module 91 afterwards, water gets into behind electrolysis module 91, the electrolysis produces strong oxidizing ion in electrolysis module 91, strong oxidizing ion plays the suppression to the bacterium through electrolysis module 91, the effect of killing, reduce bacterial growing, thereby kill the bacterium that electric purification module 1 goes out the aquatic, it is muddy to solve water purification system play water, smelly problem, satisfy the sanitary safety requirement, improve user experience. The electrolysis module 91 is arranged at the rear end of the electric purification module 1, and the ion exchange membrane in the electric purification module 1 can be prevented from being influenced by the excessive hypochlorite concentration generated due to the fault of the electrolysis module 91.
The electric purification module 1 is connected with a water inlet pipeline and a water outlet pipeline, and the electrolysis module 91 can be arranged on the water inlet pipeline and also can be arranged on the water outlet pipeline. The water inlet pipeline at least comprises a main water inlet pipeline 43, a fresh water inlet pipeline 41 and a concentrated water inlet pipeline 42, and the water outlet pipeline at least comprises a fresh water outlet pipeline 51 and a concentrated water outlet pipeline 52.
The main water inlet pipeline 43 may be a section of pipeline connected to the raw water port, or may be the raw water port itself.
In the embodiment shown in fig. 1-5, the electrical purification module 1 has a fresh water inlet 11, a concentrated water inlet 12, a fresh water outlet 13, and a concentrated water outlet 14, the fresh water inlet 11 is connected to a fresh water inlet pipe 41, the concentrated water inlet 12 is connected to a concentrated water inlet pipe 42, both the fresh water inlet pipe 41 and the concentrated water inlet pipe 42 are connected to a main water inlet pipe 43, the fresh water outlet 13 is connected to a fresh water outlet pipe 51, and the concentrated water outlet 14 is connected to a concentrated water outlet pipe 52.
In some optional embodiments, the number of the electrical purification modules 1 is one, and the electrolysis module 91 is disposed on at least one of the main water inlet pipeline 43, the fresh water inlet pipeline 41, the concentrated water inlet pipeline 42, and the fresh water outlet pipeline 51.
For example, in the embodiment shown in fig. 1, the electrolysis module 91 is disposed on the water inlet main pipeline 43, such that raw water enters the electrolysis module 91 through the water inlet main pipeline 43, strong oxidizing ions with strong oxidizing property are generated by electrolysis in the electrolysis module 91, and the generated strong oxidizing ions enter the electrical purification module 1 through the fresh water inlet pipeline 41 and the concentrated water inlet pipeline 42 to clean the electrical purification module 1 and sterilize.
In some embodiments, not shown, the electrolysis module 91 is disposed on the fresh water inlet pipeline 41 and the concentrated water inlet pipeline 42, such that the raw water enters the electrolysis module 91 on the fresh water inlet pipeline 41 and the concentrated water inlet pipeline 42 through the main water inlet pipeline 43, strong oxidizing ions with strong oxidizing property are generated by electrolysis in the electrolysis module 91, and the generated strong oxidizing ions enter the electrical purification module 1 through the fresh water inlet 11 and the concentrated water inlet 12 to clean the electrical purification module 1 and sterilize.
In other embodiments, not shown, the electrolysis module 91 is disposed on the fresh water inlet conduit 41 or the concentrated water inlet conduit 42, i.e. the electrolysis module 91 is disposed on one of the fresh water inlet conduit 41 and the concentrated water inlet conduit 42 to generate strong oxidizing ions on the conduit, and the strong oxidizing ions enter the purification module 1 through the corresponding water inlet to clean the electrical purification module 1 and sterilize the same.
In other embodiments, not shown, the electrolysis module 91 is disposed on the fresh water outlet conduit 51 of a single electrical purification module 1, so that the strong oxidizing ions generated by the electrolysis module 91 can sterilize the fresh water in the fresh water outlet conduit 51.
In some optional embodiments, the number of the electrical purification modules 1 is multiple, the water inlet main pipelines 43 of multiple electrical purification modules 1 are all provided with the electrolysis modules 91, and/or the fresh water outlet pipelines 51 of multiple electrical purification modules 1 are all provided with the electrolysis modules 91.
For example, in the embodiment shown in fig. 2, the electrolysis modules 91 are disposed on the water inlet main pipelines 43 of the plurality of electrical purification modules 1, so that water on the water inlet main pipeline 43 becomes water containing strong oxidizing ions after passing through the electrolysis modules 91, and when the water enters the electrical purification modules 1, organic matters in the electrical purification modules 1 can be subjected to oxidative degradation, and bacteria in the water can be inhibited and killed.
For another example, in the embodiment shown in fig. 3, the electrolysis modules 91 are disposed on the fresh water outlet pipes 51 of the plurality of electrical purification modules 1, and the strong oxide ions generated by the electrolysis modules 91 can sterilize the water in the fresh water outlet pipes 51, thereby preventing the water flowing out of the fresh water outlet pipes 51 from being turbid and smelly.
In some embodiments, not shown, the electrolysis modules 91 are disposed on the main water inlet pipeline 43 and the fresh water outlet pipeline 51 of the plurality of electrical purification modules 1, so that organic matters in the electrical purification modules 1 can be oxidized and degraded, and bacteria in the water purification system can be inhibited and killed.
In the embodiment shown in fig. 4, the number of the electrical purification modules 1 is multiple, the water inlet main pipelines 43 of the multiple electrical purification modules 1 are all connected with the water inlet main pipeline 44, and the electrolysis module 91 is arranged on the water inlet main pipeline 44. Thus, after the electrolysis module 91 generates strong oxidizing ions through electrolysis, the strong oxidizing ions can enter each water inlet main pipeline 43 and then each electric purification module 1 so as to clean and sterilize each electric purification module 1.
In the embodiment shown in fig. 5, there are a plurality of electrical purification modules 1, the fresh water outlet pipes 51 of the electrical purification modules 1 are all connected to the fresh water outlet main pipe 53, and the electrolysis module 91 is disposed on the fresh water outlet main pipe 53. All the water in the fresh water outlet pipeline 51 is collected in the fresh water outlet main pipeline 53, and the electrolysis module 91 sterilizes the water in the fresh water outlet main pipeline 53, so that the water flowing out of the fresh water outlet main pipeline 53 is prevented from being turbid and smelly.
In the present invention, "fresh water" refers to purified pure water, and "concentrated water" refers to concentrated waste water, and does not mean the taste of water.
Referring to fig. 6, electrolysis module 91 includes a fixing bracket 911, an anode electrolyte sheet 912 and a cathode electrolyte sheet 913, and anode electrolyte sheet 912 and cathode electrolyte sheet 913 are disposed in fixing bracket 911. After the water enters the electrolysis module 91, under the action of the electric field, anions migrate to the anode electrolyte sheet 912 and cations migrate to the cathode electrolyte sheet 913.
In the vicinity of the anolyte sheet 912, chloride ions lose electrons more readily than other anions and are oxidized to chlorine gas:
2Cl--2e-—→Cl2
in the vicinity of the catholyte sheet 913, hydrogen ions are reduced to hydrogen gas, more readily available electrons than other cations:
2H++2e-—→H2
the hydrogen ions continuously get electrons on the cathode electrolyte sheet 913 to generate hydrogen gas to be discharged, which destroys the ionization balance of water near the cathode electrolyte sheet 913 and generates more hydroxyl OH-And an alkaline environment is formed. Chlorine gas generates hypochlorite ions in an alkaline environment:
Cl2+4OH-—→2ClO-+2H2O
hypochlorite ions have strong oxidizing property, and can act on organic matters and bacterial pollutants to play a role in cleaning the electric purification module 1.
The concentration of hypochlorite ions generated by the electrolysis module 91 can be changed by changing at least one of the flow rate of the inflow water to the electrolysis module 91, the voltage applied to the electrolysis module 91, and the pitch between the anode electrolyte sheet 912 and the cathode electrolyte sheet 913. In other words, the concentration of hypochlorite ions generated by the electrolysis module 91 depends on the flow rate of the feed water, the applied voltage, and the distance between the anode electrolyte sheet 912 and the cathode electrolyte sheet 913. The concentration of the generated residual chlorine is controlled within the range of 0.01-1.0mg/L, the effects of preventing the deposition of organic matters in the electric purification module 1 and the breeding of bacteria in a water purification system are achieved, meanwhile, the ion exchange membrane cannot become brittle under the action of the electric purification module 1, and the performance of the ion exchange membrane is favorably maintained.
The rear end of the water purification system can be provided with a post-arranged filter element, and the generated redundant residual chlorine can be adsorbed and removed by the post-arranged filter element.
In the description herein, references to the description of the term "one embodiment," "some embodiments," "an example," "a specific example" or "some examples" or the like are intended to mean that a particular feature, structure, material, or characteristic described in connection with the embodiment or example is included in at least one embodiment or example of the utility model. In this specification, the schematic representations of the terms used above are not necessarily intended to refer to the same embodiment or example. Furthermore, the particular features, structures, materials, or characteristics described may be combined in any suitable manner in any one or more embodiments or examples. Furthermore, various embodiments or examples described in this specification can be combined and combined by those skilled in the art.
Although embodiments of the present invention have been shown and described above, it is understood that the above embodiments are exemplary and should not be construed as limiting the present invention, and that variations, modifications, substitutions and alterations can be made to the above embodiments by those of ordinary skill in the art within the scope of the present invention.

Claims (10)

1. A water purification system, comprising:
an electrical purification module adapted to perform purification treatment of incoming water;
the electrolysis module is communicated with the electric purification module, water entering the electrolysis module is electrolyzed to generate strong oxidizing ions with strong oxidizing property, and the generated strong oxidizing ions are at least used for sterilization.
2. The water purification system of claim 1, wherein the strong oxidizing ions are hypochlorite ions.
3. The water purification system of claim 1, wherein the electrolysis module is disposed at a front end of the electrical purification module, and water entering the electrical purification module preferentially passes through the electrolysis module.
4. The water purification system of claim 1, wherein the electrolysis module is disposed at a rear end of the electrical purification module, and water entering the electrical purification module subsequently passes through the electrolysis module.
5. The water purification system according to claim 3 or 4, wherein the electrical purification module has a fresh water inlet, a concentrated water inlet, a fresh water outlet, and a concentrated water outlet, the fresh water inlet is connected to a fresh water inlet line, the concentrated water inlet is connected to a concentrated water inlet line, the fresh water inlet line and the concentrated water inlet line are both connected to a main water inlet line, the fresh water outlet is connected to a fresh water outlet line, and the concentrated water outlet is connected to a concentrated water outlet line.
6. The water purification system of claim 5, wherein the number of the electrical purification modules is one, and the electrolysis module is disposed on at least one of the main water inlet pipeline, the fresh water inlet pipeline, the concentrated water inlet pipeline, and the fresh water outlet pipeline.
7. The water purification system of claim 5, wherein the number of the electrical purification modules is multiple, the electrolysis modules are arranged on the water inlet main pipelines of the electrical purification modules, and/or the electrolysis modules are arranged on the fresh water outlet pipelines of the electrical purification modules.
8. The water purification system of claim 5, wherein the number of the electric purification modules is multiple, the main water inlet pipelines of the electric purification modules are all connected with a main water inlet pipeline, and the electrolysis module is arranged on the main water inlet pipeline.
9. The water purification system of claim 5, wherein the number of the electrical purification modules is multiple, the fresh water outlet pipes of the electrical purification modules are all connected with a fresh water outlet main pipe, and the electrolysis module is arranged on the fresh water outlet main pipe.
10. The water purification system of claim 2, wherein the electrolysis module comprises a fixing bracket, an anode electrolytic sheet and a cathode electrolytic sheet, the anode electrolytic sheet and the cathode electrolytic sheet are arranged in the fixing bracket, after water enters the electrolysis module, under the action of an electric field, anions migrate to the anode electrolytic sheet, and cations migrate to the cathode electrolytic sheet to generate the hypochlorite ions.
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114162920A (en) * 2020-12-10 2022-03-11 佛山市美的清湖净水设备有限公司 Water purification system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114162920A (en) * 2020-12-10 2022-03-11 佛山市美的清湖净水设备有限公司 Water purification system

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