CN211471073U - Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater - Google Patents

Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater Download PDF

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Publication number
CN211471073U
CN211471073U CN201921513636.0U CN201921513636U CN211471073U CN 211471073 U CN211471073 U CN 211471073U CN 201921513636 U CN201921513636 U CN 201921513636U CN 211471073 U CN211471073 U CN 211471073U
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oxidation pond
filler layer
carbon contact
cover plate
industrial wastewater
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唐娜
张平
项军
张蕾
陈乃麟
杜威
程鹏高
王松博
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Tianjin University of Science and Technology
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Tianjin University of Science and Technology
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Abstract

A novel iron-carbon contact oxidation pond for treating methyl benzotriazole industrial wastewater is characterized by comprising an oxidation pond main body, a water storage tank, a filler system and an electric control dosing system; the oxidation pond comprises an overflow plate and a gas distribution device, wherein the overflow plate is arranged at the top of the equipment, and the gas distribution device is arranged at the bottom of the equipment; the filler system comprises a first-stage filler layer, a second-stage filler layer, a first-stage filler layer bracket and cover plate, and a second-stage filler layer bracket and cover plate, wherein the filler layer is arranged between the filler layer bracket and the cover plate; the electric control dosing system comprises an acid-resistant dosing pump, a pH induction meter, an FIC flow indicating control, an electromagnetic valve and a sulfuric acid dosing barrel. The utility model discloses an iron carbon contact oxidation pond that introduces adopts and compares with traditional iron carbon oxidation pond, and whole iron carbon contact oxidation treatment process reaction is fast, does not have secondary pollution, and adaptability is strong, low energy consumption, and area is little, and the treatment effeciency is high, and degree of automation is high.

Description

Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater
Technical Field
The patent of the utility model belongs to the relevant field of environmental protection equipment, especially relates to a handle novel iron carbon contact oxidation pond of methyl benzotriazole industrial waste water.
Background
The iron-carbon micro-electrolysis technology is a good process for treating wastewater by using a metal corrosion principle to form a galvanic cell, and is also called an internal electrolysis method, an iron scrap filtration method and the like. The micro-electrolysis technology is an ideal process for treating high-concentration organic wastewater at present, and is also called as an internal electrolysis method. Under the condition of no power supply, the micro-electrolysis material filled in the wastewater generates a 1.2V potential difference to carry out electrolysis treatment on the wastewater so as to achieve the purpose of degrading organic pollutants, and iron is corroded to become bivalent iron ions to enter a solution as a result of reaction. Because of the coagulation effect of iron ions, the iron ions attract particles with weak negative charges in pollutants in an opposite way, and form stable flocs (also called iron sludge) for removal. Wherein iron with low potential is used as anode, carbon with high potential is used as cathode, and electrochemical reaction is carried out under acidic oxygenation condition.
Patents CN203890172U, CN204958622U, and CN202658035U disclose the application of iron carbon pond in pharmaceutical wastewater, 2B acid-precipitation wastewater, and rice paper black liquor, respectively; the patents CN106277596A and CN106315977A disclose the effect of iron carbon technology in degrading organic matters in high concentration pharmaceutical wastewater and printing and dyeing wastewater.
Due to the particularity of the production process of the methylbenzotriazole, compared with industrial wastewater of other industries, the methylbenzotriazole industrial wastewater has the particularity of high salt content, high chroma, high COD (chemical oxygen demand) and low pH, so that the iron-carbon contact oxidation and the design of an iron-carbon contact oxidation tank for the special methylbenzotriazole industrial wastewater are of great significance.
SUMMERY OF THE UTILITY MODEL
The utility model aims to provide a handle the novel iron carbon contact oxidation pond of methyl benzotriazole industrial waste water to the characteristics of methyl benzotriazole industrial waste water high salt content, high chroma, high COD, low pH.
In order to realize the utility model discloses, adopt following technical scheme:
a novel iron-carbon contact oxidation pond for treating methyl benzotriazole industrial wastewater is characterized by comprising an oxidation pond main body, a water storage tank, a filler system and an electric control dosing system; the oxidation pond comprises an overflow plate and a gas distribution device, wherein the overflow plate is arranged at the top of the equipment, and the gas distribution device is arranged at the bottom of the equipment; the filler system comprises a first-stage filler layer, a second-stage filler layer, a first-stage filler layer bracket and cover plate, and a second-stage filler layer bracket and cover plate, wherein the filler layer is arranged between the filler layer bracket and the cover plate; the electric control dosing system comprises an acid-resistant dosing pump, a pH inductor, an FIC flow indicating control, an electromagnetic valve and a sulfuric acid dosing barrel; the top of the tower body is provided with an overflow port, and the side wall of the tower body is provided with an air inlet, a water outlet and a water inlet.
Furthermore, the water running mode adopts a mode from bottom to top.
Furthermore, the upper part of the main structure of the oxidation pond is provided with an overflow plate, so that large-particle impurities in water can be effectively filtered, and the lower part of the main structure of the oxidation pond is provided with a gas distribution device.
Furthermore, the fillers in the first-stage filler layer and the second-stage filler layer are iron-carbon fillers.
Furthermore, the heights between the first-stage filler layer bracket and the second-stage filler layer bracket and the cover plate are both 0.5-1.0m, and the distance between the first-stage filler layer cover plate and the second-stage filler layer bracket is 0.1-0.5 m.
Furthermore, the diameter of the oxidation pond is 2-4 m.
Furthermore, the electric control dosing system is fully automatically controlled, and the pH value in the oxidation pond needs to be kept between 1 and 4.
The invention has the advantages and effects that:
the arrangement of water flowing from bottom to top can ensure that the sewage is fully contacted with the iron carbon in the oxidation pond.
The upper portion of oxidation pond major structure is equipped with the overflow board, can effectual filtration aquatic large granule impurity, and the lower part is equipped with the gas distribution device.
The arrangement of the multiple layers of the fillers can increase the oxidation times of the sewage on the premise of fully contacting with the iron carbon, prolong the time of contact oxidation reaction and improve the utilization rate of the iron carbon.
The arrangement of the electric control dosing system can keep the whole process of the iron-carbon contact oxidation reaction under a stable pH condition, and the oxidation effect is improved.
The whole iron-carbon contact oxidation treatment process has the advantages of fast reaction, no secondary pollution, strong adaptability, low energy consumption, small occupied area, high treatment efficiency and high automation degree.
Drawings
Fig. 1 is a schematic structural diagram of the present invention.
Detailed Description
The present invention will be described with reference to the accompanying drawings.
As shown in fig. 1, a novel iron-carbon contact oxidation tank for treating methyl benzotriazole industrial wastewater comprises a tower body 1, a water storage tank 14, a filler system and an electric control dosing system; the packing system comprises a primary packing layer 6, a secondary packing layer 9 and a gas distribution device 2; a first filler bracket 8 is arranged in the tower body 1, a first filler layer 9 is arranged on the first filler bracket 8, a first cover plate 10 covers the first filler layer, a second filler layer 6 is arranged below the first filler layer 9, the second filler layer 6 is arranged between a second filler bracket 5 and a cover plate 7, and a gas distribution device 2 is arranged below the second filler bracket 5; an overflow plate 11 is arranged at the upper part of the tower body 1, and an overflow port 12 is arranged at the right side of the upper part of the tower body 1; the lower part of the left side of the tower body 1 is provided with a water inlet 4 and an air inlet 3, the lower part of the right side of the tower body 1 is provided with a circulating water inlet 18, and the middle upper part of the right side of the tower body 1 is provided with a circulating water outlet 22; a circulating water inlet 13 is formed in the upper part of the water storage tank 14, and a circulating water outlet 15 is formed in the left side wall of the water storage tank; the electric control dosing system comprises an acid-resistant dosing pump 16, an electromagnetic valve 17, an FIC flow indicating control 19, a sulfuric acid dosing pump 20 and a pH induction meter 21.
The water running mode adopts a mode from bottom to top.
The upper portion of oxidation pond major structure 1 be equipped with overflow plate 11, large granule impurity in can effectual filtration aquatic, the lower part is equipped with the gas distribution device.
The fillers in the first-stage filler layer 9 and the second-stage filler layer 6 are both iron carbon fillers.
The heights between the first-stage and second-stage filler layer brackets 8 and 5 and the cover plates 10 and 7 are 0.5-1.0m, and the distance between the first-stage filler layer bracket 8 and the second-stage filler layer cover plate 7 is 0.1-0.5 m.
The diameter of the oxidation pond main body 1 is 2-4 m.
The electric control dosing system is fully automatically controlled, and the pH value in the oxidation pond main body 1 needs to be kept between 1 and 4.

Claims (6)

1. A novel iron-carbon contact oxidation pond for treating methyl benzotriazole industrial wastewater is characterized by comprising an oxidation pond main body, a water storage tank, a filler system and an electric control dosing system; the oxidation pond comprises an overflow plate and a gas distribution device, wherein the overflow plate is arranged at the top of the equipment, and the gas distribution device is arranged at the bottom of the equipment; the filler system comprises a first-stage filler layer, a second-stage filler layer, a first-stage filler layer bracket and cover plate, and a second-stage filler layer bracket and cover plate, wherein the filler layer is arranged between the filler layer bracket and the cover plate; the electric control dosing system comprises an acid-resistant dosing pump, a pH inductor, an FIC flow indicating control, an electromagnetic valve and a sulfuric acid dosing barrel; the top of the oxidation pond is provided with an overflow port, and the side wall of the oxidation pond is provided with an air inlet, a water outlet and a water inlet.
2. The novel iron-carbon contact oxidation pond for treating the industrial wastewater of the methylbenzotriazole according to claim 1, which is characterized in that a water flowing mode is a bottom-up mode.
3. The novel iron-carbon contact oxidation pond for treating methyl benzotriazole industrial wastewater as claimed in claim 1, wherein an overflow plate is arranged at the upper part of the main structure of the oxidation pond, so that large-particle impurities in water can be effectively filtered, and a gas distribution device is arranged at the lower part of the main structure of the oxidation pond.
4. The novel iron-carbon contact oxidation pond for treating methyl benzotriazole industrial wastewater as claimed in claim 1, wherein the fillers in the primary and secondary filler layers are both iron-carbon fillers.
5. The novel iron-carbon contact oxidation pond for treating methylbenzotriazole industrial wastewater according to claim 1, wherein the heights between the brackets of the primary and secondary packing layers and the cover plate are both 0.5-1.0m, and the distance between the brackets of the primary packing layer and the cover plate of the secondary packing layer is 0.1-0.5 m.
6. The novel iron-carbon contact oxidation pond for treating the industrial wastewater of the methylbenzotriazole according to claim 1, wherein the diameter of the oxidation pond main body is 2-4 m.
CN201921513636.0U 2019-09-11 2019-09-11 Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater Active CN211471073U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201921513636.0U CN211471073U (en) 2019-09-11 2019-09-11 Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201921513636.0U CN211471073U (en) 2019-09-11 2019-09-11 Novel iron-carbon contact oxidation tank for treating methylbenzotriazole industrial wastewater

Publications (1)

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CN211471073U true CN211471073U (en) 2020-09-11

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