CN209623513U - A kind of firecrackers based on the quick-fried principle of dirt - Google Patents

A kind of firecrackers based on the quick-fried principle of dirt Download PDF

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Publication number
CN209623513U
CN209623513U CN201822201615.7U CN201822201615U CN209623513U CN 209623513 U CN209623513 U CN 209623513U CN 201822201615 U CN201822201615 U CN 201822201615U CN 209623513 U CN209623513 U CN 209623513U
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capsule
firecrackers
quick
flammable
fried
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CN201822201615.7U
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Chinese (zh)
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程爱宝
陈昊彬
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Abstract

The utility model discloses a kind of firecrackers based on the quick-fried principle of dirt, including cylinder, flammable capsule, sealing end, back cover and lead, and flammable capsule is located in cylinder, internal filled with part explosion flour;Sealing end, back cover are located at cylinder both ends, and flammable capsule are sealed in inner barrel;Lead one end is located at outside cylinder through sealing end and face contact on the outside of flammable capsule, the other end.The purpose of this utility model is, a kind of firecrackers based on the quick-fried principle of dirt are provided, under the low-frequency vibration environment that the firecrackers generate in production, transport, storing process, explosive substance is difficult to form the quick-fried cloud of dirt in capsule, only when lead burns the duration vibration for generating 3Hz or more, explosive substance can just generate resonance, so that it be promoted quickly to mix with air in capsule, form the quick-fried cloud of dirt.The flammable capsule for lighting the quick-fried cloud of not formed dirt, only occurs vigorous combustion, and without exploding, therefore the firecrackers are relatively stable in production, transport, storing process, safety.

Description

A kind of firecrackers based on the quick-fried principle of dirt
Technical field
The utility model belongs to firecrackers technical field, specially a kind of firecrackers based on the quick-fried principle of dirt.
Background technique
Traditional firecrackers have more than 1,000 years developing histories, it relies on the utility model of black powder, during setting off Generated heat color, the sound bring people's joy, meet the cultural life of people.In the long river of historical development In, people impart more and more folk custom meanings to firecrackers.Nowadays, China is increasingly heavier to the succession protection of traditional firecrackers folk custom Depending on having multiple firecrackers folk custom projects and entering non-material cultural heritage country, China register.
According to ASSOCIATE STATISTICS, in first three batch of national non-material cultural heritage register of national publication, be expressly recited and its Relevant project 18, wherein traditional technology 2, conventional motion 1, apply for 26 cities and counties in ground by traditional folk 15.At 15 In traditional folk project, 4 projects are related with sacrifice, and 11 projects are related with red-letter day.Our province fireworks and firecrackers industry goes out within 2017 Factory's delivery value is about 37,000,000,000 yuan, and middle outlet is about 3,800,000,000 yuan, and factory delivery value accounts for about the 55% of the whole nation, and outlet accounts for about the whole nation 60%。
Maximum succession and influence on development to firecrackers industry development, related folk culture are safety problem, environmental pollution And human health problems, traditional firecrackers have the following deficiencies:
1, the blasting compound of traditional firecrackers includes the metals such as a large amount of nitrate, perchlorate, sulphur, carbon dust, aluminium, copper, antimony, Can be generated after burning a variety of pernicious gases such as a large amount of carbon monoxide, nitrogen oxides, chloride, sulfide, nitrate, sulfate and Suspended particulate substance is one of the reason of forming acid rain, haze weather, and effect on environment is very big.According to statistics, until in January, 2018, entirely State, which carries out there are about more than 900 cities above county level because of haze reason, prohibits combustion, limit combustion measure.
2, the harmful substance that traditional firecracker setting-off generates can affect human health, and correlative study shows breathing system The generation of system disease can draw after having direct relationship, suspended particulate substance to enter lung with the presence of environment middle strong acidity suspended particulate substance Chronic obstructive pulmonary disease is played, transition metal ions enters the generation that can promote excess oxygen radical after lung, causes under intracellular activities of antioxidant enzymes Drop, can cause human body heavy metal poisoning after causing oxidative stress that Normal cell death, heavy metal ion is caused to enter lung.
3, traditional firecrackers industry is difficult to mass mechanized production, the main reason is that the powder composition of traditional firecrackers is hit Susceptibility is high.Therefore, firecrackers industry propelling machinery metaplasia produces difficult big, is still mainly turned at present using handwork and semi-machine Industry, operating personnel face biggish security risk.
4, traditional firecrackers do not have waterproof layer using gunpowder mode, inside is directly filled in paper tube, and hydrone can readily pass through Firecrackers paper-tube, so that firecrackers moisture-sensitive or excessively dry, so as to cause can not normal ignition or excessively inflammable.Therefore, firecrackers are transported Defeated, storage economy and safety cost are higher.
It is reported that having there are capsule firecrackers at present to substitute traditional firecrackers, but existing capsule firecrackers also have the following drawbacks:
1, existing capsule firecrackers mainly use the gaseous mixture of the fuel gas such as hydrogen, methane, coal gas and air as explosion Substance, but its explosion limit range is big, and ignition energy is low, colorless and odorless, and concentration is difficult to control and monitoring, mechanization production, fortune Defeated, storage has the problems such as larger security risk.If hydrogen explosion is limited to 4% ~ 75.6%, minimum ignition can be only 0.02 millijoule, During mechanization production, electrostatic, minor impact may ignite;As body in Zhangjiakou Area, Hebei Province in this year generation " 11.28 " is great quick-fried Combustion accident, cause of accident are the leakages of chemical plant vinyl chloride gas holder, and vinyl chloride and air form gaseous mixture, occur after chance open fire quick-fried Combustion, causes great casualties and property loss.Therefore use the gaseous mixtures such as hydrogen as firecrackers explosive substance, produce, Transport, store, set off during there is larger security risk.
2, the capsule material that existing capsule firecrackers use is plastics, and in various plastic components, it is most of for containing fluorine, Chlorine, sulphur, aromatic rings, heterocycle etc. can generate the objects such as a large amount of hydrogen chloride, sulfide, carcinogenic aromatic compound in combustion Matter endangers environment and human body larger;Moreover, the clast generated after setting off is difficult to natural degradation, have greater environmental impacts.
3, the capsule material that existing capsule firecrackers use is plastics, capsule charged pressure gas, there are discouraged problem, To influence firework display effect.
4, the fuse that existing capsule firecrackers use is located at the end of capsule firecrackers, exists during setting off and is not easy the glue that ignites Capsule is easy discouraged defect during capsule, production and transportation, if fuse is located on the outside of the capsule wall at the center of end, ignites Line and capsule catalytic combustion time are shorter, and temperature is lower, there are problems that capsule is not easy to ignite;For another example fuse is located at end center There is gas leakage and the moisture absorption in place and insertion capsule, fuse and capsule contact position, firecrackers is caused to fail.
Dust explosion principle: combustible dust encounters heat source (open fire or high temperature), flame moment within the scope of explosion limit It propagates in entire mixed dust space, chemical reaction velocity is exceedingly fast, while discharging a large amount of heat, forms very high temperature and very greatly Pressure, the energy of system is converted into the radiation of mechanical energy and light and heat, has very strong destructive power.Dust at present explosion tool There is more uncontrollable factor, is generally easy to happen dust explosion accident in metal, organic intermediate powder mull processing factory, and Correlative study and application report at home and abroad there is no controlled condition dust explosion technology in firecrackers field.It is how former using dust It manages to manufacture a kind of controllable firecrackers, has for firecrackers industry development, the succession of related folk culture and development and open Invasive meaning.
Utility model content
The purpose of this utility model is in view of the above problems, providing a kind of firecrackers based on the quick-fried principle of dirt, the firecrackers are in life Produce, transport, under the low-frequency vibration environment that generates in storing process, explosive substance is difficult to form the quick-fried cloud of dirt in capsule, only when drawing Line burning generate 3Hz or more duration vibration when, explosive substance can just generate resonance, thus promote its in capsule quickly with Gas mixing forms the quick-fried cloud of dirt.The flammable capsule for lighting the quick-fried cloud of not formed dirt, only occurs vigorous combustion, quick-fried without occurring It is fried, therefore the firecrackers are relatively stable in production, transport, storing process, safety.
In order to achieve the above object, the technical solution adopted in the utility model is: a kind of firecrackers based on the quick-fried principle of dirt, including Cylinder, flammable capsule, sealing end, back cover and lead, the flammable capsule are located in cylinder, internal filled with part explosion powdery Substance;The sealing end, back cover are located at cylinder both ends, and flammable capsule are sealed in inner barrel;Described lead one end is passed through Sealing end and face contact on the outside of flammable capsule are worn, the other end is located at outside cylinder.
Further, the flammable inside capsule wall is coated with explosive substance layer.
Further, described lead one end through sealing end and extends at the 1/4 of flammable capsule total length or at 1/2 Or it is contacted at 3/4 or with back cover.
Further, one end of the lead and face contact on the outside of flammable capsule is arranged to zig-zag type or knotting or lead applies Glue enables it to generate duration vibration in burning.
Further, the flammable capsule is made of gas impermeable material.
Further, the flammable capsule is made of organic material.The organic material is polyethylene, polypropylene, gathers One of materials such as propenyl, polycarbonate, polyether polyol, cellulose, polysaccharide, gelatin a variety of mix.
Further, the explosion flour uses carbon dust, single original washing powder, starch, pyrotechnic composition, black powder, polyethylene, gathers Propylene, POLYPROPYLENE GLYCOL, phenolic resin, phenol formamide, ethyl cellulose, polypropylene amine, polyacrylonitrile, paraformaldehyde, propionic acid are fine One of dimension materials such as element a variety of mix.
A kind of production method of the firecrackers based on the quick-fried principle of dirt, comprising the following steps:
S1, explosion flour processing: explosion flour is uniformly mixed, and is dried;
S2, capsule production: in the explosion flour to flammable capsule in filling step S1, then closing forms flammable glue Capsule;
S3, firecrackers encapsulation: the flammable capsule in step S2 is encased in cylinder, and back cover is installed in one end of cylinder, another Lead is first inserted at end, is finally packed into sealing end, forms firecrackers.
Further, the ambient humidity when flour that explodes in the step S1 mixes is lower than 80%.
Further, the moisture content after the flour that explodes in the step S1 is dry is lower than 50%.
Further, it takes part explosion flour to be dissolved in organic solvent in the step S1, and applies as flammable capsule Explosive substance layer is formed on inner wall, after its drying, is refilled in the explosion flour to flammable capsule in step S1, finally Closing forms flammable capsule.
Further, closing is sealed again to being filled with after oxygen or air inside it when forming flammable capsule in the step S2 It closes.
The utility model has the beneficial effects that the low-frequency vibration environment that the firecrackers generate in production, transport, storing process Under, explosive substance is difficult to form the quick-fried cloud of dirt in capsule, quick-fried only when lead burns the duration frequency vibration for generating 3Hz or more Fried substance can just generate resonance, so that it be promoted quickly to mix with air in capsule, form the quick-fried cloud of dirt;It is quick-fried to light not formed dirt The flammable capsule of cloud, only occurs vigorous combustion, and without exploding, therefore the firecrackers are in production, transport, storing process Relatively stable, safety.
1, the utility model mainly solves Environmental security existing for traditional firecrackers and capsule firecrackers, and mechanization production is safe, Transport, storage safety, set off safety, the defect of human health etc..Mentioned component can also be used and carry out any mixing
2, explosive substance uses carbon dust, single original washing powder, starch, pyrotechnic composition, black powder, polyethylene, poly- third in the utility model Alkene, POLYPROPYLENE GLYCOL, phenolic resin, phenol formamide, ethyl cellulose, polypropylene amine, polyacrylonitrile, paraformaldehyde, cellulose propionate One of materials such as element or it is a variety of mix, only contain organic element, but be free of the high molecular polymer of heterocycle, the explosion The advantage of substance is the pressure that the minimum ignition that explosive substance is adjusted using different formulations can be generated with explosion time, this is quick-fried Fried substance contains tetra- kinds of elements of C, H, O, N, and containing substances such as trace meter, halogens, and N element content is lower, therefore explodes When can only generate carbon dioxide, water, a small amount of nitrogen oxides and carbon monoxide, but not aromatics carcinogen is generated, with reality Existing environment and human body safety.
3, flammable capsule material is more using polyethylene, polypropylene, POLYPROPYLENE GLYCOL, polycarbonate, polyethers in the utility model One of materials such as first alcohol, cellulose, polysaccharide, gelatin or it is a variety of mix, only contain organic element, but without heterocycle Or mixtures thereof high molecular polymer, which is the organic matter containing elements such as C, H, O, but does not contain metal, halogen Equal substances, explosion time can only generate carbon dioxide, water, a small amount of carbon monoxide, imperfect combustion clast can natural degradation, with reality Existing Environmental security.
4, flammable inside capsule wall is coated with explosive substance in the utility model, and the effect that inner wall is coated with explosive substance is to work as to ignite When line burns capsule wall, the explosive substance for the inside capsule wall that can ignite rapidly forms high temperature and pressure, and then ignites the quick-fried cloud of dirt, reaches The effect quickly ignited.
5, in the utility model flammable capsule material be gas impermeable material, can effectively avoid capsule lose heart and moisture in air Son enters capsule and firecrackers is caused to fail.
6, the content of explosive substance is 0.02g/dm in flammable capsule in the utility model3To 60g/dm3, explode on an equal basis Under effect, which is only 50% of explosive substance content in traditional firecrackers hereinafter, the explosive substance used is few, can The total amount of pollutant that production cost is effectively reduced and is generated when setting off, to realize product high added value and Environmental security.
7, flammable capsule diameter is 5mm ~ 10mm in the utility model, and length is 5mm ~ 20mm, with a thickness of 0.1mm ~ 2mm, Conducive to industrialized production.
8, auxiliary filling gas is air or oxygen in flammable capsule in the utility model, and air pressure is 0.8 ~ 1.2 in capsule Times standard atmospheric pressure, i.e., manufacture close under atmospheric pressure environment, and production requirement is low, simple process, is not necessarily to dedicated high cost Equipment investment, production cost is low, in addition mixes in a low pressure environment, fills explosive substance, can effectively reduce the machine of explosive substance Tool is hit, electrostatic ignites susceptibility, it can be achieved that mechanization is kept the safety in production.
9, lead is located across sealing end in the utility model, is close to capsule side wall, and cylinder lead is extended to positioned at flammable It is contacted at the 1/4 of capsule total length or at 1/2 or at 3/4 or with back cover, the advantage that lead is located at capsule side wall is that lead exists Burning time is longer in cylinder, and the duration time of vibration of 3Hz or more is longer, can produce higher temperature and pressure, it is ensured that glue Capsule side wall can be burnt, and lead is located at capsule side-wall outer side, it can be ensured that capsule it is complete, it is ensured that gas and explosive substance in capsule It is not influenced by outside air humidity, effectively avoids the problems such as capsule is discouraged, and explosive substance agglomerates.
10, when generating the duration vibration of 3Hz or more in the utility model in lead combustion process, explosive substance can just be produced Raw resonance, so that it be promoted quickly and gas mixing, quickly to form the quick-fried cloud of dirt in capsule.
11, a variety of explosive substances can be used to realize dust explosion process for the explosive substance of the utility model firecrackers, and minimum Ignition can be higher, and generally more than tens millijoules, and explosive substance is low to mechanical impact, electrostatic discharge susceptivity.
Detailed description of the invention
Fig. 1 is the utility model schematic view of the front view.
Fig. 2 is the utility model side structure schematic view.
Fig. 3 is the utility model lead schematic view of the front view.
Label character described in figure indicates are as follows: 1, cylinder;2, flammable capsule;21, explode flour;22, explosive substance Layer;3, it blocks;4, back cover;5, lead.
Specific embodiment
In order to enable those skilled in the art to better understand the technical solutions of the present invention, with reference to the accompanying drawing to this reality Be described in detail with novel, the description of this part be only it is exemplary and explanatory, should not be to the protection scope of the utility model There is any restriction effect.
As shown in Figure 1-3, the specific structure of the utility model are as follows: a kind of firecrackers based on the quick-fried principle of dirt, including cylinder 1 (preferably paper material is made, and materials are convenient, save the cost), flammable capsule 2, sealing end 3, back cover 4 and lead 5, the flammable glue Capsule 2 is located in cylinder 1, internal filled with part explosion flour 21;The sealing end 3, back cover 4 are located at 1 liang of cylinder End, and flammable capsule 2 is sealed in inside cylinder 1;Sealing end 3 and flammable 2 outside face contact of capsule are run through in described 5 one end of lead, The other end is located at outside cylinder 1.
Preferably, 2 inner wall of flammable capsule is coated with explosive substance layer 22.It is when fuse burns capsule wall that it, which is acted on, When, the explosive substance for the inside capsule wall that can ignite rapidly forms high temperature and pressure, and then ignites the quick-fried cloud of dirt.
Preferably, described 5 one end of lead through sealing end 3 and extends at the 1/4 of flammable 2 total length of capsule or 1/2 It is contacted at place or 3/4 or with back cover 4.Increase lead burning length, to prevent not burning through flammable capsule wall.
Preferably, one end of the lead 5 and flammable 2 outside face contact of capsule is arranged to zig-zag type or knots (respectively such as In attached drawing 3 shown in a, b) or lead gluing, so that it is generated duration vibration in burning.Lead is arranged to zig-zag type or knotting Or lead gluing, it may make lead to generate the duration vibration of 3Hz or more in burning.
Preferably, the flammable capsule 2 is made of gas impermeable material.It can effectively avoid capsule to lose heart and moisture in air Into capsule.
Preferably, the flammable capsule 2 is made of organic material.The organic material is polyethylene, polypropylene, poly- third One of materials such as enol, polycarbonate, polyether polyol, cellulose, polysaccharide, gelatin a variety of mix.Polyethylene, Polypropylene, POLYPROPYLENE GLYCOL, polycarbonate, polyether polyol, cellulose, polysaccharide, gelatin are the high molecular polymer without heterocycle Or mixtures thereof, the organic matter containing elements such as C, H, O, but dioxy can not only be generated containing substances, explosion times such as metal, halogens Change carbon, water, a small amount of carbon monoxide, imperfect combustion clast can natural degradation, to realize Environmental security.
Preferably, the explosion flour 21 uses carbon dust, single original washing powder, starch, pyrotechnic composition, black powder, polyethylene, gathers Propylene, POLYPROPYLENE GLYCOL, phenolic resin, phenol formamide, ethyl cellulose, polypropylene amine, polyacrylonitrile, paraformaldehyde, propionic acid are fine One of dimension materials such as element a variety of mix.Or mixtures thereof high molecular polymer without heterocycle, the explosive substance Advantage be to be adjusted using different formulations explosive substance minimum ignition can and the pressure that generates of explosion time, the explosive Matter contains tetra- kinds of elements of C, H, O, N, and containing substances such as trace meter, halogens, and N element content is lower, thus explosion time only Carbon dioxide, water, a small amount of nitrogen oxides and carbon monoxide can be generated, but not generates aromatics carcinogen, to realize ring Border and human-body safety.
Embodiment one
A kind of production method of the firecrackers based on the quick-fried principle of dirt, comprising the following steps:
S1, explosion flour processing: under 0.8 times of atmospheric pressure, in environment of the humidity lower than 80%, by the powder that explodes The carbon dust 15g of single the original washing powder 30g and D50=48 μm of matter 21(130 mesh) it is uniformly mixed, and be dried, the moisture after drying Content is lower than 50%;
S2, capsule production: it takes part explosion flour 21 to be dissolved in organic solvent, and applies as on flammable 2 inner wall of capsule Explosive substance layer 22 is formed, after its drying, refills in the explosion flour 21 to flammable capsule 2 in step S1, is full of Air, then closing forms flammable capsule 2;The diameter of flammable capsule 2 is 5mm ~ 10mm, and length is 5mm ~ 20mm, and wall thickness is 0.1mm~2mm;
S3, firecrackers encapsulation: the flammable capsule 2 in step S2 is encased in cylinder 1, and back cover 4 is installed in one end of cylinder 1, The other end is first inserted into lead 5, and 5 one end of lead extends at the 1/4 of flammable 2 total length of capsule, is finally packed into sealing end 3, shape At firecrackers.
Embodiment two
A kind of production method of the firecrackers based on the quick-fried principle of dirt, comprising the following steps:
S1, explosion flour processing: under normal pressure, in environment of the humidity lower than 80%, explosion flour 21(is ground It is milled to the carbon dust 2g of D50 < 48 μm) it is uniformly mixed, and be dried, the moisture content after drying is lower than 30%;
S2, capsule production: the part explosion mono- original washing powder of flour 21(is taken) it is dissolved in organic solvent, and apply as flammable capsule Explosive substance layer 22 is formed on 2 inner walls, after its drying, refills explosion flour 21 in step S1 to flammable capsule 2 It is interior, and it is filled with oxygen, then closing forms flammable capsule 2;The diameter of flammable capsule 2 is 5mm ~ 10mm, and length is 5mm ~ 20mm, Wall thickness is 0.1mm ~ 2mm;
S3, firecrackers encapsulation: the flammable capsule 2 in step S2 is encased in cylinder 1, and back cover 4 is installed in one end of cylinder 1, The other end is first inserted into lead 5, and 5 one end of lead, which is extended to, blocks 3 with 4 contact position of back cover, finally loading, formation firecrackers.
The firecrackers explosion principle of the utility model: fire source is formed using the burning of lead 5, is generated in its combustion process When the duration vibration of 3Hz or more, the explosion flour 21 in capsule 2 generates resonance, to promote the flour 21 that explodes It is quickly mixed with the gas mixing in capsule 2, forms the quick-fried cloud of dirt, when the high temperature that the burning of lead 5 generates burns the side wall of broken capsule 2 Afterwards, and then the explosion flour 21 in capsule 2 is ignited.
It should be noted that, in this document, the terms "include", "comprise" or its any other variant are intended to non-row His property includes, so that the process, method, article or equipment for including a series of elements not only includes those elements, and And further include other elements that are not explicitly listed, or further include for this process, method, article or equipment institute it is intrinsic Element.
Specific case used herein is expounded the principles of the present invention and embodiment, above example Illustrate the method and its core concept for being merely used to help understand the utility model.The above is only the preferred of the utility model Embodiment, it is noted that due to the finiteness of literal expression, and objectively there is unlimited specific structure, for this technology For the those of ordinary skill in field, without departing from the principle of this utility model, several improvement, retouching can also be made Or variation, above-mentioned technical characteristic can also be combined in the right way;These improve retouching, variation or combination, or not It is improved that the conception and technical scheme of utility model are directly applied into other occasions, it is regarded as the protection of the utility model Range.

Claims (5)

1. a kind of firecrackers based on the quick-fried principle of dirt, which is characterized in that including cylinder (1), flammable capsule (2), sealing end (3), back cover (4) it is located in cylinder (1) with lead (5), the flammable capsule (2), it is internal filled with part explosion flour (21);Institute State sealing end (3), back cover (4) is located at cylinder (1) both ends, and it is internal that flammable capsule (2) is sealed in cylinder (1);It is described to draw Line (5) one end face contact on the outside of sealing end (3) and flammable capsule (2), it is external that the other end is located at cylinder (1);
One end of face contact is arranged to zig-zag type or knotting or lead gluing on the outside of the lead (5) and flammable capsule (2), makes it Duration vibration can be generated in burning.
2. a kind of firecrackers based on the quick-fried principle of dirt according to claim 1, which is characterized in that in the flammable capsule (2) Wall is coated with explosive substance layer (22).
3. a kind of firecrackers based on the quick-fried principle of dirt according to claim 1, which is characterized in that described lead (5) one end is passed through It wears sealing end (3) and extends to and back cover (4) contact position.
4. a kind of firecrackers based on the quick-fried principle of dirt according to claim 1, which is characterized in that the flammable capsule (2) by Gas impermeable material is made.
5. a kind of firecrackers based on the quick-fried principle of dirt according to claim 1, which is characterized in that the flammable capsule (2) is adopted It is made of organic material.
CN201822201615.7U 2018-12-26 2018-12-26 A kind of firecrackers based on the quick-fried principle of dirt Withdrawn - After Issue CN209623513U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109373824A (en) * 2018-12-26 2019-02-22 程爱宝 A kind of firecrackers and production method based on the quick-fried principle of dirt
CN113135812A (en) * 2021-05-20 2021-07-20 江西省李渡烟花集团有限公司 Low-temperature safe and environment-friendly firework with carmine and yellow green light
CN114838627A (en) * 2022-04-08 2022-08-02 中国科学技术大学 Explosion cylinder based on laughing gas self-decomposition reaction

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109373824A (en) * 2018-12-26 2019-02-22 程爱宝 A kind of firecrackers and production method based on the quick-fried principle of dirt
CN109373824B (en) * 2018-12-26 2024-02-06 程爱宝 Firecracker based on dust explosion principle and production method thereof
CN113135812A (en) * 2021-05-20 2021-07-20 江西省李渡烟花集团有限公司 Low-temperature safe and environment-friendly firework with carmine and yellow green light
CN114838627A (en) * 2022-04-08 2022-08-02 中国科学技术大学 Explosion cylinder based on laughing gas self-decomposition reaction

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