CN209104269U - A kind of positive grid of the punching of high-temperature corrosion resistance - Google Patents

A kind of positive grid of the punching of high-temperature corrosion resistance Download PDF

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CN209104269U
CN209104269U CN201821533740.1U CN201821533740U CN209104269U CN 209104269 U CN209104269 U CN 209104269U CN 201821533740 U CN201821533740 U CN 201821533740U CN 209104269 U CN209104269 U CN 209104269U
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width
positive grid
frame
corrosion
grid
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王廷华
刘可畅
王静
王再红
皇甫志坤
杨博
马继军
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Fengfan Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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    • Y02E60/10Energy storage using batteries

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Abstract

一种耐高温腐蚀的冲孔正板栅,包括上边框、下边框、左边框、右边框和横筋、竖筋,上边框上部设有板耳,所述竖筋的宽度尺寸由上至下递减;横筋的宽度尺寸由上至下递减。本实用新型根据对失效电池正板栅腐蚀失效模式分析,针对正板栅最容易发生腐蚀的部位,设计了一种筋条宽度和间隔宽度渐变的冲孔正板栅。所述正板栅对易发生腐蚀的上部结构进行了加强,同时降低了板栅下部不易腐蚀部位的材料投入。上述结构一方面有效解决由于正板栅腐蚀导致的电池过早失效问题,另一方面合理控制产品成本,具有批量推广应用的可行性。

A high-temperature corrosion-resistant punched positive grid, comprising an upper frame, a lower frame, a left frame, a right frame, horizontal ribs and vertical ribs, the upper part of the upper frame is provided with plate ears, and the width of the vertical ribs decreases from top to bottom. ; The width dimension of the transverse rib decreases from top to bottom. According to the corrosion failure mode analysis of the positive grid of a failed battery, the utility model designs a punched positive grid with gradual rib width and interval width for the most prone to corrosion part of the positive grid. The positive grid strengthens the corrosion-prone upper structure, and at the same time reduces the material input at the lower part of the grid that is not easy to corrode. On the one hand, the above structure effectively solves the problem of premature failure of the battery caused by the corrosion of the positive grid, and on the other hand, it reasonably controls the product cost, which is feasible for mass promotion and application.

Description

一种耐高温腐蚀的冲孔正板栅A kind of punched positive grid with high temperature corrosion resistance

技术领域technical field

本实用新型涉及一种蓄电池零件,特别是耐高温腐蚀的正板栅,属蓄电池技术领域。The utility model relates to a battery part, in particular to a high-temperature corrosion-resistant positive grid, which belongs to the technical field of batteries.

背景技术Background technique

铅酸蓄电池主要由电池壳、正、负极板、隔板和电解液等组成。其中,极板作为发生电化学反应的载体而成为铅酸蓄电池的核心部分。极板由板栅及活性物质组成。板栅是蓄电池的重要零件,作为载体支撑活性物质,使电流在活性物质上均匀分布,提高了活性物质利用率,防止极板变形。目前正板栅的制造一般有三种方式,重力浇铸、拉网、冲孔。浇铸板栅厚度和重量大,性能较好,但生产效率低,成本高。冲孔板栅采用一定规格的冷轧铅带或铅合金带在冲床上使用模具冲孔成型。与重力浇铸板栅相比,冲孔板栅生产效率高,且比重力浇铸板栅减重15%~20%,但冲孔板栅厚度受到限制,一般不超过1.4mm。另外,冲孔板栅生产时能耗低,污染小,是铅酸蓄电池的发展方向。使用在高温环境下铅酸蓄电池的失效原因主要是是正板栅腐蚀,由于正板栅总是处于较高的电极电位作用下,其主要成份铅容易被氧化腐蚀为氧化铅,随着蓄电池使用过程中充放电次数的增加,正板栅被腐蚀而越来越薄,甚至断裂,最终导致电池失效。通常蓄电池厂家通过增加正板栅厚度的方法来延长正极板抵抗腐蚀的时间,从而延长使用寿命,但是冲孔正板栅的厚度受限,因此,设计合理的板栅结构解决冲孔正板栅耐高温腐蚀是亟待解决的问题。Lead-acid batteries are mainly composed of battery shells, positive and negative plates, separators and electrolytes. Among them, the electrode plate is the core part of the lead-acid battery as the carrier for the electrochemical reaction. The plate is composed of grid and active material. The grid is an important part of the battery. As a carrier to support the active material, the current is evenly distributed on the active material, which improves the utilization rate of the active material and prevents the deformation of the electrode plate. At present, there are generally three ways to manufacture positive grids, gravity casting, drawing net, and punching. Casting grids have large thickness and weight and good performance, but low production efficiency and high cost. The punching grid adopts a certain specification of cold-rolled lead strip or lead alloy strip to be punched and formed by a die on a punching machine. Compared with gravity cast grids, punched grids have high production efficiency and are 15% to 20% lighter than gravity cast grids, but the thickness of punched grids is limited, generally not exceeding 1.4mm. In addition, the production of perforated grids has low energy consumption and low pollution, which is the development direction of lead-acid batteries. The main reason for the failure of lead-acid batteries used in high temperature environments is the corrosion of the positive grid. Because the positive grid is always under the action of a high electrode potential, its main component lead is easily oxidized and corroded to lead oxide. As the number of times of charging and discharging increases, the positive grid is corroded and becomes thinner and thinner, or even breaks, eventually leading to battery failure. Usually, battery manufacturers increase the thickness of the positive grid to prolong the corrosion resistance time of the positive plate, thereby prolonging the service life, but the thickness of the punched positive grid is limited. Therefore, a reasonable grid structure should be designed to solve the problem of the punched positive grid. High temperature corrosion resistance is an urgent problem to be solved.

实用新型内容Utility model content

本实用新型的目的在于提供一种耐高温腐蚀的冲孔正板栅,本实用新型基于对腐蚀失效模式的研究分析,合理设计冲孔板栅结构,提高其耐高温腐蚀性能,延长使用寿命。The purpose of the utility model is to provide a perforated positive grid with high temperature corrosion resistance. Based on the research and analysis of the corrosion failure mode, the utility model rationally designs the punched grid structure, improves its high temperature corrosion resistance and prolongs the service life.

本实用新型所述问题是以下述技术方案解决的:The problems described in the present utility model are solved by the following technical solutions:

一种耐高温腐蚀的冲孔正板栅,包括上边框、下边框、左边框、右边框和横筋、竖筋,上边框上部设有板耳,所述竖筋的宽度尺寸由上至下递减;横筋的宽度尺寸由上至下递减。A high-temperature corrosion-resistant punched positive grid, comprising an upper frame, a lower frame, a left frame, a right frame, a horizontal rib, and a vertical rib, the upper part of the upper frame is provided with a plate lug, and the width of the vertical rib decreases from top to bottom. ; The width dimension of the transverse rib decreases from top to bottom.

上述耐高温腐蚀的冲孔正板栅,相邻横筋之间的间隔距离由上至下递增。In the above-mentioned high-temperature corrosion-resistant punched positive grid, the spacing between adjacent transverse ribs increases from top to bottom.

上述耐高温腐蚀的冲孔正板栅,所述竖筋的上端宽度尺寸为下端宽度尺寸的2-3倍。In the above-mentioned high-temperature corrosion-resistant punched positive grid, the upper end width dimension of the vertical ribs is 2-3 times the lower end width dimension.

上述耐高温腐蚀的冲孔正板栅,下部横筋最大间隔距离是上部横筋最小间隔距离的1.2-1.5倍For the above-mentioned high-temperature corrosion-resistant punched positive grid, the maximum spacing distance of the lower transverse ribs is 1.2-1.5 times the minimum spacing distance of the upper transverse ribs

上述耐高温腐蚀的冲孔正板栅,上部横筋的宽度尺寸为下部横筋宽度尺寸的1.6-1.8倍。In the above-mentioned high-temperature corrosion-resistant punched positive grid, the width dimension of the upper transverse rib is 1.6-1.8 times that of the lower transverse rib.

上述耐高温腐蚀的冲孔正板栅,上边框的宽度为下边框宽度的2-3倍。In the above-mentioned high-temperature corrosion-resistant punched positive grid, the width of the upper frame is 2-3 times the width of the lower frame.

本实用新型根据对失效电池正板栅腐蚀失效模式分析,针对正板栅最容易发生腐蚀的部位,设计了一种筋条宽度和间隔宽度渐变的冲孔正板栅。所述正板栅对易发生腐蚀的上部结构进行了加强,同时降低了板栅下部不易腐蚀部位的材料投入。上述结构一方面有效解决由于正板栅腐蚀导致的电池过早失效问题,另一方面合理控制产品成本,具有批量推广应用的可行性。本实用新型在不增加生产成本的前提下,解决了多年来一直困扰着蓄电池厂家由于正板栅高温腐蚀导致的电池过早失效问题,提高了蓄电池使用寿命。According to the corrosion failure mode analysis of the positive grid of a failed battery, the utility model designs a punched positive grid with the width of the rib and the interval width gradually changing for the part where the positive grid is most likely to be corroded. The positive grid strengthens the corrosion-prone upper structure, and at the same time reduces the material input at the lower part of the grid that is not easy to corrode. On the one hand, the above structure effectively solves the problem of premature failure of the battery caused by the corrosion of the positive grid, and on the other hand, it reasonably controls the product cost, which is feasible for mass promotion and application. On the premise of not increasing the production cost, the utility model solves the problem of premature battery failure caused by the high temperature corrosion of the positive grid that has plagued battery manufacturers for many years, and improves the service life of the battery.

附图说明Description of drawings

下面结合附图对本实用新型作进一步说明。The utility model will be further described below in conjunction with the accompanying drawings.

图1是本实用新型的结构示意图。Figure 1 is a schematic structural diagram of the present invention.

图中各标号清单为:1、板耳,2、上边框,3、左边框,4、下边框,5、右边框,6、竖筋,7、横筋。The list of labels in the figure is: 1, plate lug, 2, upper frame, 3, left frame, 4, lower frame, 5, right frame, 6, vertical bars, 7, horizontal bars.

具体实施方式Detailed ways

参看图1,本实用新型包括上边框2、下边框4、左边框3、右边框5,在上、下、左、右边框围成的矩形框内设有横筋7和竖筋6,在上边框的上部设有板耳1。本实用新型通过解剖大量的寿命试验和退返蓄电池发现,由于正板栅腐蚀导致电池失效的电池,腐蚀部位主要集中在正板栅的中上部,越靠近板耳,板栅腐蚀越严重。因此,基于控制生产成本、延长产品寿命对本实用新型提出了以下结构设计:Referring to FIG. 1, the present utility model includes an upper frame 2, a lower frame 4, a left frame 3, and a right frame 5, and horizontal ribs 7 and vertical ribs 6 are arranged in the rectangular frame surrounded by the upper, lower, left and right frames. The upper part of the frame is provided with a plate lug 1 . The utility model finds by dissecting a large number of life tests and returning batteries that the battery fails due to the corrosion of the positive grid, and the corrosion part is mainly concentrated in the middle and upper part of the positive grid. Therefore, based on controlling production cost and prolonging product life, the following structural design is proposed to the present utility model:

1、竖筋的宽度尺寸由上至下递减,竖筋的上端宽度尺寸为下端宽度尺寸的2-3倍。1. The width of the vertical bars decreases from top to bottom, and the width of the upper end of the vertical bars is 2-3 times the width of the lower end.

2、横筋的宽度尺寸由上至下递减,上部横筋的宽度尺寸为下部横筋宽度尺寸的1.6-1.8倍。2. The width of the transverse bars decreases from top to bottom, and the width of the upper transverse bars is 1.6-1.8 times the width of the lower transverse bars.

3、相邻横筋之间的间隔距离由上至下递增,下部相邻横筋最大间隔距离是上部相邻横筋最小间隔距离的1.2-1.5倍。3. The spacing between adjacent transverse bars increases from top to bottom, and the maximum spacing distance between the lower adjacent transverse ribs is 1.2-1.5 times the minimum spacing distance between the upper adjacent transverse ribs.

4、上边框的宽度为下边框宽度的2-3倍。4. The width of the upper border is 2-3 times the width of the lower border.

以下给出本实用新型的两个具体实施例:Two specific embodiments of the present utility model are provided below:

实施例1:板栅高度为98毫米,竖筋的上端宽度尺寸为3毫米,下端宽度尺寸为1.3毫米;上部横筋的宽度尺寸为2.5毫米,下部横筋的宽度尺寸为1.5毫米;下部横筋的间隔距离是12毫米,上部横筋的间隔距离的9.9毫米。上边框宽度为5毫米,下边框宽度为2毫米。Example 1: The height of the grid is 98 mm, the width of the upper end of the vertical bars is 3 mm, and the width of the lower end is 1.3 mm; the width of the upper horizontal bars is 2.5 mm, and the width of the lower bars is 1.5 mm; the interval between the lower bars is 1.5 mm. The distance is 12 mm and the spacing distance of the upper cross bars is 9.9 mm. The width of the upper border is 5 mm and the width of the lower border is 2 mm.

实施例2:板栅高度为114毫米,竖筋的上端宽度尺寸为3毫米,下端宽度尺寸为1.0毫米;上部横筋的宽度尺寸为2.5毫米,下部横筋的宽度尺寸为1.5毫米;下部相邻横筋的间隔距离是14毫米,上部相邻横筋的间隔距离的9.9毫米。上边框宽度为5毫米,下边框宽度为2毫米。Example 2: The height of the grid is 114 mm, the width of the upper end of the vertical bar is 3 mm, and the width of the lower end is 1.0 mm; the width of the upper horizontal bar is 2.5 mm, and the width of the lower horizontal bar is 1.5 mm; The spacing distance is 14 mm, and the spacing distance between the upper adjacent cross bars is 9.9 mm. The width of the upper border is 5 mm and the width of the lower border is 2 mm.

Claims (4)

1.一种耐高温腐蚀的冲孔正板栅,包括上边框(2)、下边框(4)、左边框(3)、右边框(5)和横筋(7)、竖筋(6),上边框上部设有板耳(1),其特征在于:所述竖筋的宽度尺寸由上至下递减;横筋的宽度尺寸由上至下递减;1. A high-temperature corrosion-resistant punched positive grid, comprising an upper frame (2), a lower frame (4), a left frame (3), a right frame (5), horizontal ribs (7), and vertical ribs (6), The upper part of the upper frame is provided with a plate lug (1), which is characterized in that: the width dimension of the vertical rib decreases from top to bottom; the width dimension of the horizontal rib decreases from top to bottom; 相邻横筋之间的间隔距离由上至下递增;The spacing distance between adjacent transverse bars increases from top to bottom; 上边框的宽度为下边框宽度的2-3倍。The width of the upper border is 2-3 times the width of the lower border. 2.根据权利要求1所述的耐高温腐蚀的冲孔正板栅,其特征在于:所述竖筋的上端宽度尺寸为下端宽度尺寸的2-3倍。2 . The high temperature corrosion resistant punched positive grid according to claim 1 , wherein the width of the upper end of the vertical rib is 2-3 times the width of the lower end. 3 . 3.根据权利要求2所述的耐高温腐蚀的冲孔正板栅,其特征在于:下部横筋最大间隔距离是上部横筋最小间隔距离的1.2-1.5倍。3. The high-temperature corrosion-resistant punched positive grid according to claim 2, wherein the maximum spacing distance of the lower transverse ribs is 1.2-1.5 times the minimum spacing distance of the upper transverse ribs. 4.根据权利要求3所述的耐高温腐蚀的冲孔正板栅,其特征在于:上部横筋的宽度尺寸为下部横筋宽度尺寸的1.6-1.8倍。4 . The high-temperature corrosion-resistant punched positive grid according to claim 3 , wherein the width dimension of the upper transverse rib is 1.6-1.8 times the width of the lower transverse rib. 5 .
CN201821533740.1U 2018-09-19 2018-09-19 A kind of positive grid of the punching of high-temperature corrosion resistance Active CN209104269U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113285074A (en) * 2021-06-18 2021-08-20 浙江天能电池(江苏)有限公司 Lead grid plate for power storage battery
CN115207364A (en) * 2022-07-06 2022-10-18 双登集团股份有限公司 Novel corrosion-resistant positive grid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113285074A (en) * 2021-06-18 2021-08-20 浙江天能电池(江苏)有限公司 Lead grid plate for power storage battery
CN115207364A (en) * 2022-07-06 2022-10-18 双登集团股份有限公司 Novel corrosion-resistant positive grid

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