US20130186749A1 - Cell Bottom Structure of Reduction Cell - Google Patents

Cell Bottom Structure of Reduction Cell Download PDF

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Publication number
US20130186749A1
US20130186749A1 US13/520,894 US201113520894A US2013186749A1 US 20130186749 A1 US20130186749 A1 US 20130186749A1 US 201113520894 A US201113520894 A US 201113520894A US 2013186749 A1 US2013186749 A1 US 2013186749A1
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United States
Prior art keywords
cell
column
carbon blocks
reduction cell
reduction
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Abandoned
Application number
US13/520,894
Inventor
Chongai Bao
Pu Zheng
Canming Xi
Bin Cao
Yi Yang
Jun Huang
Tao Yang
Zhaohong Yang
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CHINA ALUMINUM INTERNATIONAL ENGINEERING Corp Ltd
China Aluminum International Engr Corp Ltd
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China Aluminum International Engr Corp Ltd
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Assigned to CHINA ALUMINUM INTERNATIONAL ENGINEERING CORPORATION LIMITED reassignment CHINA ALUMINUM INTERNATIONAL ENGINEERING CORPORATION LIMITED ASSIGNMENT OF ASSIGNORS INTEREST (SEE DOCUMENT FOR DETAILS). Assignors: BAO, CHONGAI, CAO, BIN, HUANG, JUN, XI, CANMING, YANG, TAO, YANG, YI, YANG, ZHAOHONG, ZHENG, PU
Publication of US20130186749A1 publication Critical patent/US20130186749A1/en
Abandoned legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C25ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25CPROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
    • C25C3/00Electrolytic production, recovery or refining of metals by electrolysis of melts
    • C25C3/06Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
    • C25C3/08Cell construction, e.g. bottoms, walls, cathodes

Definitions

  • the present invention relates to a cell bottom structure of a reduction cell, pertaining to the technical field of aluminum reduction cell.
  • the horizontal electric current tends to cause the molten aluminum to form an eddy flow under the action of magnetic field to generate a relatively large wave crest, such that on one hand, it influences the stable operation of the reduction cell, and on the other hand, in order to prevent a short circuit due to a wave crest of the molten aluminum scours to a anode, a polar distance of the cathode and the anode must be increased, resulting a rise in cell voltage and an increase in electricity consumption.
  • the cathode carbon blocks are placed horizontally, this results in a complicated structure of a cell housing of the reduction cell since thermal expansion and sodium absorption expansion render complicated force conditions for the cell housing and its periphery.
  • failure of introducing electricity and aggregation of lateral output electric current towards cell edges impact the safety of cell ledges of the reduction cell, resulting a large amount of steel used for the cell ledges.
  • the technical problem to be solved by the present invention is to provide a cell bottom structure of a reduction cell, which can reduce horizontal electrical current in a layer of molten aluminum, eliminate stresses on a cell housing generated due to cathode expansion, simply the structure of the cell housing, reducing polar distance of the reduction cell and cell voltage, alleviate a construction cost of the cell housing and overcome shortages in the prior art.
  • the technical solution of the present invention is in that it comprises a reduction cell and a cathode bus, wherein the bottom of the reduction cell is provided with column-shaped cathode carbon blocks perpendicular to the bottom of the reduction cell, and that a lower end of the column-shaped cathode carbon block is connected to the cathode bus.
  • the column-shaped cathode carbon blocks are located below anode carbon blocks.
  • the column-shaped cathode carbon blocks extend a length of 5 ⁇ 200 mm into molten aluminum of the reduction cell.
  • the column-shaped cathode carbon blocks are connected with the cathode bus through bolts.
  • the column-shaped cathode carbon blocks have a shape of quadrangular prism or quadrangular prism with steps.
  • the present invention reduces horizontal electrical current in the molten aluminum, such that the cathode extending into the molten aluminum can effectively reduce fluctuations of the molten aluminum to obtain a stable surface of the molten aluminum, thereby reducing a polar distance of a cathode and an anode and lowering cell voltage so as to achieve the object of lowering electricity consumption.
  • a cathode/anode polar distance can reduce 100 ⁇ 250 mm
  • a voltage drop of the cathode can reduce 100 ⁇ 200 mv
  • a cell voltage can reduce 400 ⁇ 850 mv
  • an effect of saving 1200 ⁇ 2500 kwh/t-Al is achieved.
  • the column-shaped cathode carbon blocks have a shape of quadrangular prism or quadrangular prism with steps, and segment-splicing arrangement and cell bottom placement thereof eliminate stresses exerted on the cell housing by the thermal expansion and sodium absorption expansion, enabling a simplification of the cell housing design and the material used.
  • the steel amount used for the cell bottom can be saved 70%, the lifespan of the cell can increase 500 days, allowing the impact of electrolyte deposition on the cell bottom electric conduction to be minimized.
  • the column-shaped cathode carbon blocks are located below the anode carbon blocks, so as to facilitate the electric current to be vertically guided from the anode carbon blocks.
  • the column-shaped cathode carbon blocks are interconnected with the cathode bus through bolts, wherein the cross-sectional dimension of the bus and the number of the bolts are determined in accordance with the magnitude of current.
  • the present invention can also effectively inhibit eddy flow of molten aluminum, simplify the cell housing structure, decrease initial construction investment, improve current distribution, extend lifespan of the reduction cell, and has a very good popularizing value.
  • FIG. 1 is a schematic view of the configuration of the present invention
  • FIG. 2 is an A-A view of FIG. 1 .
  • Embodiment 1 as shown in FIGS. 1 and 2 , in a design of a reduction cell, cathodes are made as column-shaped cathode carbon blocks 3 which have a shape of quadrangular prism or quadrangular prism with steps.
  • the column-shaped cathode carbon blocks 3 are placed perpendicular to a cell bottom of the reduction cell 1 when placing the column-shaped cathode carbon blocks 3 .
  • Upper ends of the perpendicularly placed column-shaped cathode carbon blocks 3 extend a length of 5 ⁇ 200 mm into molten aluminum in the reduction cell 1 and lower ends of the column-shaped cathode carbon blocks 3 are connected with a cathode bus 2 through bolts.
  • the column-shaped cathode carbon blocks 3 are mounted below anode carbon blocks 4 .
  • the reduction cell 1 arranged according to the present invention can eliminate the cathode steel rod and steel cell housing in the cathode carbon blocks.
  • the reduction cell employs heat insulation materials and corrosion resistant materials to design a lava pool, thus it is only necessary to consider self expansion of the materials during the manufacture, enabling the structure of the reduction cell to be simplified to a great extent.
  • the design of the reduction cell is based on a low cell voltage, thereby decreasing the amount of heat dissipation. According to a test examination, the reduction cell produced in accordance with the present invention can save 10% ⁇ 20% of energy compared to conventional reduction cells.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Electrolytic Production Of Metals (AREA)
  • Secondary Cells (AREA)

Abstract

The present invention discloses a cell bottom structure of a reduction cell which comprises a reduction cell and a cathode bus, wherein the bottom of the reduction cell is provided with column-shaped cathode carbon blocks perpendicular to the bottom of the reduction cell, and a lower end of the column-shaped cathode carbon block is connected to the cathode bus. By means of inserting the column-shaped cathode carbon blocks perpendicular to the bottom of the reduction cell and connecting the lower end of the column-shaped cathode carbon block with the cathode bus, such that electrical current that guided from anode carbon blocks is guided through the molten aluminum to the column-shaped cathode carbon blocks and is downwardly guided out, the present invention reduces horizontal electrical current in the molten aluminum, such that the cathode extending into the molten aluminum can effectively reduce fluctuations of the molten aluminum to obtain a stable surface of the molten aluminum, thereby reducing a polar distance between a cathode and an anode and lowering cell voltage so as to achieve the object of lowering electricity consumption.

Description

    FIELD OF THE INVENTION
  • The present invention relates to a cell bottom structure of a reduction cell, pertaining to the technical field of aluminum reduction cell.
  • BACKGROUND OF THE INVENTION
  • In the production of a prebaked reduction cell, most of the aluminum reduction cells select a planar cell bottom with cathode carbon blocks placed horizontally, into which an electric current enters from an upper anode and is guided out of a lateral portion of the cell to form a turn of 90°, thereby forming a relatively large horizontal electric current at a layer of molten aluminum. The horizontal electric current tends to cause the molten aluminum to form an eddy flow under the action of magnetic field to generate a relatively large wave crest, such that on one hand, it influences the stable operation of the reduction cell, and on the other hand, in order to prevent a short circuit due to a wave crest of the molten aluminum scours to a anode, a polar distance of the cathode and the anode must be increased, resulting a rise in cell voltage and an increase in electricity consumption. At the same time, the cathode carbon blocks are placed horizontally, this results in a complicated structure of a cell housing of the reduction cell since thermal expansion and sodium absorption expansion render complicated force conditions for the cell housing and its periphery. In addition, failure of introducing electricity and aggregation of lateral output electric current towards cell edges impact the safety of cell ledges of the reduction cell, resulting a large amount of steel used for the cell ledges.
  • SUMMARY OF THE INVENTION
  • The technical problem to be solved by the present invention is to provide a cell bottom structure of a reduction cell, which can reduce horizontal electrical current in a layer of molten aluminum, eliminate stresses on a cell housing generated due to cathode expansion, simply the structure of the cell housing, reducing polar distance of the reduction cell and cell voltage, alleviate a construction cost of the cell housing and overcome shortages in the prior art.
  • The technical solution of the present invention is in that it comprises a reduction cell and a cathode bus, wherein the bottom of the reduction cell is provided with column-shaped cathode carbon blocks perpendicular to the bottom of the reduction cell, and that a lower end of the column-shaped cathode carbon block is connected to the cathode bus.
  • The column-shaped cathode carbon blocks are located below anode carbon blocks.
  • There is/are 1˜4 column-shaped cathode carbon blocks provided below each anode carbon block.
  • The column-shaped cathode carbon blocks extend a length of 5˜200 mm into molten aluminum of the reduction cell.
  • The column-shaped cathode carbon blocks are connected with the cathode bus through bolts.
  • The column-shaped cathode carbon blocks have a shape of quadrangular prism or quadrangular prism with steps.
  • By comparison with the prior art, by means of inserting the column-shaped cathode carbon blocks perpendicular to the bottom of the reduction cell and connecting the lower end of the column-shaped cathode carbon block with the cathode bus, such that electrical current that guided from anode carbon blocks is guided through the molten aluminum to the column-shaped cathode carbon blocks and is downwardly guided out, the present invention reduces horizontal electrical current in the molten aluminum, such that the cathode extending into the molten aluminum can effectively reduce fluctuations of the molten aluminum to obtain a stable surface of the molten aluminum, thereby reducing a polar distance of a cathode and an anode and lowering cell voltage so as to achieve the object of lowering electricity consumption. According to a number of tests by the applicant, a cathode/anode polar distance can reduce 100˜250 mm, a voltage drop of the cathode can reduce 100˜200 mv, a cell voltage can reduce 400˜850 mv, and an effect of saving 1200˜2500 kwh/t-Al is achieved. The column-shaped cathode carbon blocks have a shape of quadrangular prism or quadrangular prism with steps, and segment-splicing arrangement and cell bottom placement thereof eliminate stresses exerted on the cell housing by the thermal expansion and sodium absorption expansion, enabling a simplification of the cell housing design and the material used. According to the statistics of the test examination, the steel amount used for the cell bottom can be saved 70%, the lifespan of the cell can increase 500 days, allowing the impact of electrolyte deposition on the cell bottom electric conduction to be minimized. The column-shaped cathode carbon blocks are located below the anode carbon blocks, so as to facilitate the electric current to be vertically guided from the anode carbon blocks. There is/are 1˜4 column-shaped cathode carbon blocks provided below each of the anode carbon blocks, and the column-shaped cathode carbon blocks extend a length of 5˜200 mm into the molten aluminum of the reduction cell, wherein the specific number and positions thereof are determined in accordance with the reduction cell capacity and the anode dimension. The column-shaped cathode carbon blocks are interconnected with the cathode bus through bolts, wherein the cross-sectional dimension of the bus and the number of the bolts are determined in accordance with the magnitude of current. The present invention can also effectively inhibit eddy flow of molten aluminum, simplify the cell housing structure, decrease initial construction investment, improve current distribution, extend lifespan of the reduction cell, and has a very good popularizing value.
  • BRIEF DESCRIPTION OF THE DRAWINGS
  • FIG. 1 is a schematic view of the configuration of the present invention;
  • FIG. 2 is an A-A view of FIG. 1.
  • DETAILED DESCRIPTION OF THE INVENTION
  • Embodiment 1: as shown in FIGS. 1 and 2, in a design of a reduction cell, cathodes are made as column-shaped cathode carbon blocks 3 which have a shape of quadrangular prism or quadrangular prism with steps. The column-shaped cathode carbon blocks 3 are placed perpendicular to a cell bottom of the reduction cell 1 when placing the column-shaped cathode carbon blocks 3. Upper ends of the perpendicularly placed column-shaped cathode carbon blocks 3 extend a length of 5˜200 mm into molten aluminum in the reduction cell 1 and lower ends of the column-shaped cathode carbon blocks 3 are connected with a cathode bus 2 through bolts. When placing and mounting the column-shaped cathode carbon blocks 3 perpendicular to the cell bottom of the reduction cell, the column-shaped cathode carbon blocks 3 are mounted below anode carbon blocks 4. There is/are 1˜4 column-shaped cathode carbon blocks 3 provided below each anode carbon block 4, wherein the specific number and positions thereof are determined in accordance with the reduction cell capacity and the anode dimension. Besides, the reduction cell 1 arranged according to the present invention can eliminate the cathode steel rod and steel cell housing in the cathode carbon blocks. The reduction cell employs heat insulation materials and corrosion resistant materials to design a lava pool, thus it is only necessary to consider self expansion of the materials during the manufacture, enabling the structure of the reduction cell to be simplified to a great extent. The design of the reduction cell is based on a low cell voltage, thereby decreasing the amount of heat dissipation. According to a test examination, the reduction cell produced in accordance with the present invention can save 10%˜20% of energy compared to conventional reduction cells.

Claims (6)

1. A cell bottom structure of a reduction cell comprising a reduction cell (1) and a cathode bus (2), characterized in that the bottom of the reduction cell (1) is provided with column-shaped cathode carbon blocks (3) perpendicular to the bottom of the reduction cell (1), and that a lower end of the column-shaped cathode carbon block (3) is connected to the cathode bus (2).
2. The cell bottom structure of a reduction cell according to claim 1, characterized in that: the column-shaped cathode carbon blocks (3) are located below anode carbon blocks (4).
3. The cell bottom structure of a reduction cell according to claim 2, characterized in that: there is/are 1˜4 column-shaped cathode carbon blocks (3) provided below each anode carbon block (4).
4. The cell bottom structure of a reduction cell according to claim 1, characterized in that: the column-shaped cathode carbon blocks (3) extend a length of 5˜200 mm into molten aluminum of the reduction cell (1).
5. The cell bottom structure of a reduction cell according to claim 1, characterized in that: the column-shaped cathode carbon blocks (3) are connected with the cathode bus (2) through bolts.
6. The cell bottom structure of a reduction cell according to claim 1, characterized in that: the column-shaped cathode carbon blocks (3) have a shape of quadrangular prism or quadrangular prism with steps.
US13/520,894 2010-01-07 2011-01-06 Cell Bottom Structure of Reduction Cell Abandoned US20130186749A1 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
CN2010103000912A CN102121118A (en) 2010-01-07 2010-01-07 Cell bottom structure of electrolytic cell
CN201010300091.2 2010-01-07
PCT/CN2011/000027 WO2011082657A1 (en) 2010-01-07 2011-01-06 Bottom structure of electrolytic cell

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US20130186749A1 true US20130186749A1 (en) 2013-07-25

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US (1) US20130186749A1 (en)
CN (1) CN102121118A (en)
AU (1) AU2011204683B2 (en)
CA (1) CA2785868C (en)
MY (1) MY159932A (en)
WO (1) WO2011082657A1 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111153395A (en) * 2020-01-16 2020-05-15 眉山顺应循环再生资源有限公司 Method for comprehensively recovering fluorine and carbon powder in electrolytic aluminum cathode carbon block

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102400175A (en) * 2011-10-08 2012-04-04 高伟 Conducting structure of cathode of aluminum electrolytic cell
RU2553132C1 (en) * 2012-12-21 2015-06-10 Общество с ограниченной ответственностью "Объединенная Компания РУСАЛ Инженерно-технологический центр" Design of current taps of cathode of aluminium electrolyser
CN105648474B (en) * 2016-03-10 2017-09-01 河南中孚实业股份有限公司 Large-scale pre-baked cell current stabilization saving construction method
CN113445079B (en) * 2021-06-17 2023-09-22 合肥工业大学 Cathode steel bar structure capable of reducing horizontal current of aluminum liquid for aluminum electrolysis cell

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4071420A (en) * 1975-12-31 1978-01-31 Aluminum Company Of America Electrolytic production of metal
US4405433A (en) * 1981-04-06 1983-09-20 Kaiser Aluminum & Chemical Corporation Aluminum reduction cell electrode
US8206560B2 (en) * 2007-03-02 2012-06-26 Northeastern University Engineering & Research Institute Co, Ltd. Aluminum electrolytic cells having heterotypic structured cathode carbon blocks

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996007773A1 (en) * 1994-09-08 1996-03-14 Moltech Invent S.A. Aluminium electrowinning cell with improved carbon cathode blocks
CN200964442Y (en) * 2006-06-30 2007-10-24 东北大学设计研究院(有限公司) Aluminum cell bus collocation structure
CN201367471Y (en) * 2009-03-05 2009-12-23 沈阳铝镁设计研究院 Cathode carbon block structure
CN201367472Y (en) * 2009-03-05 2009-12-23 沈阳铝镁设计研究院 Cathode structure of aluminium electrolysis bath of bath bottom tapping

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4071420A (en) * 1975-12-31 1978-01-31 Aluminum Company Of America Electrolytic production of metal
US4405433A (en) * 1981-04-06 1983-09-20 Kaiser Aluminum & Chemical Corporation Aluminum reduction cell electrode
US8206560B2 (en) * 2007-03-02 2012-06-26 Northeastern University Engineering & Research Institute Co, Ltd. Aluminum electrolytic cells having heterotypic structured cathode carbon blocks

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111153395A (en) * 2020-01-16 2020-05-15 眉山顺应循环再生资源有限公司 Method for comprehensively recovering fluorine and carbon powder in electrolytic aluminum cathode carbon block

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CA2785868A1 (en) 2011-07-14
CN102121118A (en) 2011-07-13
AU2011204683A1 (en) 2012-07-26
WO2011082657A1 (en) 2011-07-14
MY159932A (en) 2017-02-15
CA2785868C (en) 2015-04-14
AU2011204683B2 (en) 2014-03-20

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Owner name: CHINA ALUMINUM INTERNATIONAL ENGINEERING CORPORATI

Free format text: ASSIGNMENT OF ASSIGNORS INTEREST;ASSIGNORS:BAO, CHONGAI;ZHENG, PU;XI, CANMING;AND OTHERS;REEL/FRAME:030152/0434

Effective date: 20120703

STCB Information on status: application discontinuation

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