CN209019185U - Utilize the absorbent article of close and distant waterpower control liquid directional profile - Google Patents

Utilize the absorbent article of close and distant waterpower control liquid directional profile Download PDF

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Publication number
CN209019185U
CN209019185U CN201721463116.4U CN201721463116U CN209019185U CN 209019185 U CN209019185 U CN 209019185U CN 201721463116 U CN201721463116 U CN 201721463116U CN 209019185 U CN209019185 U CN 209019185U
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water repellent
close
layer
distant
absorbent article
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甘以明
汪凌
高超
张帅
刘宝江
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Suzhou Kangfu Intelligent Science & Technology Co Ltd
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Suzhou Kangfu Intelligent Science & Technology Co Ltd
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Abstract

The utility model relates to a kind of absorbent articles using close and distant waterpower control liquid directional profile, including the liquid permeable surface layer set gradually from top to bottom;Close water repellent capacity variation functional layer, its surface selectivity is coated with water repellent auxiliary agent, close water repellent capacity variation functional layer constitutes the fluid flow guiding frame of plane, close water repellent capacity variation function layer surface is equipped with continuous circulation canal and discontinuous structure, so that liquid is flowed along plane, close water repellent capacity variation functional layer includes a variety of dimension flexible material layers, and the upper and lower surfaces of a variety of dimension flexible material layers are connected separately with high hydroscopic resin particle;Water absorption layer, including high hydroscopic resin particle;And the bottom that liquid is impermeable.

Description

Utilize the absorbent article of close and distant waterpower control liquid directional profile
Technical field
The utility model relates to disposable sanitary articles preparation fields more particularly to a kind of close and distant waterpower of utilization to control liquid The absorbent article of directional profile.
Background technique
Existing absorbent article is mainly by personal pervious bed, the waterproof ventilated membrane group of intermediate water-absorbent material and bottom At, intermediate water-absorbent material is divided into multilayer, and some addition fluid conducting material layers also have using pure high hydroscopic resin (SAP), or The absorbing material that SAP is mixed with Time of Fluff Slurry.Using pure SAP as intermediate absorption material core after imbibition at planar, i.e., Make to suppress decorative pattern on core, or other channel for helping water conservancy diversion can also be blocked after imbibition, make product surface layer and Skin contact area is big, and skin surface air is unable to fully convection current of circulating and formed, the pernicious gas for evaporating out, easily right Liquid outlet skin damages, and liquid outlet includes urethral orifice, introitus, the human bodies liquid outlet such as wound.The slightly feelings of external force Under condition, be close to liquid outlet imbibition part local accumulation it is agglomerating, not only influence secondary imbibition effect, have an effect on continue to use relax Adaptive.Absorptive core comprising the SAP absorbing material mixed with Time of Fluff Slurry, such core body generally largely use Time of Fluff Slurry, inhale Most of liquid is instantaneously captured by Time of Fluff Slurry after liquid, it is difficult to and it is spread to both ends, be easy to cause core, it is locally swollen in liquid outlet position Cripling rises into bag-like.In addition to easily causing tomography, water lock loosely, be easy to cause liquid reverse osmosis, and it is volatile come out damage skin or Influence skin feel.Part manufacturer does subtle adjustment to absorptive core, changes the type of upper and lower layer covering material, with wet strong Perhaps hydrophily spinning building enhances the fluid ability of liquid or adjusts the proportion etc. of SAP in absorptive core paper.There are also manufacturers to exist Grid or striped are suppressed on absorptive core, so that absorber is seemed closer thinner, are kept surface diversion effect more preferable.
But during actually using the above absorbent article, common general core imbibition diffusion effect is weak, and upper layer is high Molecule absorbs rapidly expansion, causes gel blockage, in liquid outlet collected liquid, seriously affects double absorption speed, leads to surface layer Dry-ness decline causes core utilization rate not high.
Utility model content
In order to solve the above technical problems, being oriented the purpose of the utility model is to provide a kind of using close and distant waterpower control liquid The absorbent article of distribution, the absorbent article guarantee that liquid is not assembled in liquid outlet, facilitate the absorption of secondary liquid, can keep out liquid Dry is refreshing, is effectively improved snugness of fit
The utility model provides a kind of absorbent article using close and distant waterpower control liquid directional profile, including from upper and Under set gradually
Liquid permeable surface layer;
The surface of close water repellent capacity variation functional layer, the close water repellent capacity variation functional layer in part is coated with water repellent auxiliary agent, parent Water repellent capacity variation functional layer constitutes the fluid flow guiding frame of plane, and close water repellent capacity variation function layer surface is equipped with asperities Road, so that liquid substantially flows in the plane, close water repellent capacity variation functional layer is made of flexible material, flexible material Upper and lower surfaces are connected separately with high hydroscopic resin particle;The thickness of the water repellent auxiliary agent of coating is less than close water repellent capacity variation function The thickness of layer;
Water absorption layer, including high hydroscopic resin particle, water absorption layer constitute the accumulation layer of fluid;
The impermeable bottom of liquid.
Further, between surface layer and close water repellent capacity variation functional layer further include:
Porous layer, the surface irregularity of porous layer offer several through-holes in porous layer, and porous layer constitutes fluid and leads Circulation road, the inner wall of at least part through-hole are coated with water repellent auxiliary agent, and the surface of partially porous layer is coated with water repellent auxiliary agent, so that The position aggregation that liquid is not coated with water repellent auxiliary agent in porous layer is obtained, pressure difference is formed with lower layer, drives liquid along vertical plane Flowing.The surface of partially porous layer coats water repellent auxiliary agent, so that in the horizontal plane, the close and distant outlet capacity of porous layer is variant, until The inner wall of few a part of through-hole is coated with water repellent auxiliary agent (i.e. the inner wall of partial through holes or whole through-holes coats water repellent auxiliary agent), due to There is also the positions for not offering through-hole for porous layer, so that the close and distant outlet capacity of porous layer is variant, to make on vertical plane It obtains liquid and is not coated in porous layer in a part of porous layer of water repellent auxiliary agent and assembled.
Further, porous layer by sponge kind flexible cellular material, have the fiber of absorbent function and have waterproofing function One or more of fiber constitute.
Further, the material of porous layer be biomass porous material, vulcanized rubber, cellulose fibre, protein fibre, One or more of polyester fiber, polyethers, polyvinyl alcohol.Preferably, porous layer is made of cellular rubber.
Further, water repellent auxiliary agent is water-proof aagent, including fluorine-containing water-proof aagent or floride-free water-proof aagent.
Specifically, water repellent auxiliary agent is organo-silicon compound, aliphatic hydrocarbon melamine derivative class compound, fatty acid metal Species compound, quaternized pyridinium salt compound, aluminium soap or paraffin/metallic salt finishing agent is complexed.Preferably, water repellent auxiliary agent is Organo-silicon compound.More specifically, water repellent auxiliary agent is octyl trimethoxy silane class water repellent auxiliary agent.
Further, concave convex texture is continuous channel and/or discontinuous structure, and discontinuous structure is linear structure, square Battle array structure, fork type structure open up and foretell one or more of structure and the structure dissipated around by center.
Further, the structure dissipated around by center is by multiple round, multiple rectangles and/or multiple non-regular shapes Composition.
Further, flexible material is in one-dimensional linear direction material, two-dimensional sheet flexible material and three-dimensional material It is one or more of.Wherein, three-dimensional material is the three-dimensional flow-guiding channel material of three dimensional designs.
Further, one-dimensional linear direction material includes but is not limited to textile yarn, long filament aggregate, continuous tubulose, column Shape material;Two-dimensional sheet flexible material include but is not limited to paper products, textile fabrics, non-woven cloth, film article and they Multilayer composite product;Three-dimensional material includes that the three-dimensional flexible material with hole includes but is not limited to fiber assembly, sponge system Product, Batt material and their complex.
Further, one-dimensional linear direction material the preparation method is as follows:
It selects terylene and/or viscose filament yarn is core, in core outer cladding water suction yarn, twisting forms composite yarn;
Along yarn axial direction, water repellent finishing agent is sprayed in its surface compartment, forms coating;
Using the composite yarn for being coated with coating as heart yarn, the soybean protein by hydrophilic treated is coated again in heart yarn outer layer Fiber filament forms one-dimensional linear direction material.
Further, high hydroscopic resin particle can absorb the liquid of 0.01-5000 times of own wt, preferably 300- 500 times.
Further, the partial size of high hydroscopic resin particle is 0.001 centimetre -10 centimetres, preferably 0.1-0.5 centimetres.
Further, the shape of high hydroscopic resin particle is spherical shape, cylindrical body, square, radial sphere and hollow type One or more of sphere.Preferably, using spherical shape.
Further, the partial size of the high hydroscopic resin particle of flexible material upper surface connection is greater than the height of its lower surface connection The partial size of water absorbing resin particle.
Further, water absorption layer further includes Time of Fluff Slurry or cellulose fibre, and cellulose fibre is wood pulp, cotton, flax and One or more of moss.
Further, pass through adhesive between surface layer, porous layer, close water repellent capacity variation functional layer, water absorption layer and bottom Bonding, hot adhesion or ultrasonic bonds mode are bonded.Preferably, adhesive is hot melt adhesive.
Further, water repellent auxiliary agent is water-proof aagent, including fluorine-containing water-proof aagent or floride-free water-proof aagent.
Specifically, water repellent auxiliary agent is organo-silicon compound, aliphatic hydrocarbon melamine derivative class compound, fatty acid metal Species compound, quaternized pyridinium salt compound, aluminium soap or paraffin/metallic salt finishing agent is complexed.Preferably, water repellent auxiliary agent is Organo-silicon compound.More specifically, water repellent auxiliary agent is octyl trimethoxy silane class water repellent auxiliary agent.
Further, (the surface coating water repellent of the close water repellent capacity variation functional layer in part helps after local water repellent finish Agent), for the water absorbing capacity of the high hydroscopic resin particle on surface in the inconsistent of topical manifestations, the part for being modified with water repellent auxiliary agent is straight When connecing contact liq, has water repellent ability, water repellent contact angle is greater than 140 degree;After the unmodified part water suction for having water repellent auxiliary agent, It is destroyed by the surface water repellent ability that modification absorbs resin, hydrophilic ability is enhanced.Due to the change of shape, or and its The particular chemicals of his part obtain release etc. and contact angle are caused to become smaller, less than 90 degree.
Porous layer is set between close water repellent capacity variation functional layer and surface layer, fluid flow guiding channel is constituted, so that liquid Body is flowed along vertical plane, plays the role of pre- conducting fluid in the vertical direction, helps liquid to be distributed rapidly, due to porous layer table Face is uneven and the close water repellent ability of porous layer surface is variant, causes porous layer part (hydrophobic part) storage liquid, office Portion absorbs liquid (hydrophilic segment), and the liquid of storage forms driving force in close water repellent capacity variation layer, drives liquid in close water repellent Directed flow on the vertical plane of capacity variation layer.
According to the above aspect of the present invention, the utility model at least has the following advantages:
The close water repellent capacity variation functional layer and water absorption layer (and porous layer) of the utility model, which are constituted, to be absorbed in liquid Interbed, ordering structure is reasonable between the utility model different layers, the close water repellent capacity variation functional layer table on the close surface layer of setting The close and distant outlet capacity in face is variant, and surface has relatively thin local water repellent surface and relatively thick water suction deformation material Expect (high hydroscopic resin particle), by the part of the non-water repellent in part, the i.e. surface of local hydrophilic ability, facilitates absorption deformable material It contacts and absorbs liquid.
A variety of dimension flexible material layer upper and lower surfaces respectively connect the high hydroscopic resin particle of different water absorbing capacities, in liquid out The SAP particle of mouth position is relatively large, and water absorbing capacity is relatively poor, can form gap structure after absorbing liquid, can facilitate subsequent Liquid fast strikethrough, the SAP particle used apart from the position of liquid outlet relatively far away from is relatively small, and water absorbing capacity is relatively By force.Absorption liquid ability between the different layers constantly enhances, and while to ensure that liquid is spread to the periphery from liquid outlet, also exists Paste the diffusion of skin surface outer layers.
The absorbent article of the utility model can be got by simple preparation method, easy to industrialized production, and this is practical Novel absorbent article ensures that liquid in liquid outlet localized clusters, does not facilitate multiple liquid absorption, keeps liquid outlet dry and comfortable, effectively Improve the comfort in its use process.
The above description is merely an outline of the technical solution of the present invention, in order to better understand the skill of the utility model Art means, and can be implemented in accordance with the contents of the specification, below on the preferred embodiment of the present invention and the accompanying drawings in detail It describes in detail bright as after.
Detailed description of the invention
Fig. 1 used covering template when being the utility model spraying water repellent auxiliary agent;
Fig. 2 is the partial profile structure of 3 absorbent article of the utility model embodiment;
Description of symbols:
The surface layer 1-;2- cellular rubber layer;3- parent's water repellent capacity variation functional layer;4- water absorption layer;5- bottom.
Specific embodiment
With reference to the accompanying drawings and examples, specific embodiment of the present utility model is described in further detail.Below Embodiment is not intended to limit the scope of the present invention for illustrating the utility model.
Embodiment 1
The close water repellent capacity variation functional layer of the utility model is made of flexible material, and flexible material is selected from one-dimensional linear side To one or more of material, two-dimensional sheet flexible material and three-dimensional material.Wherein, one-dimensional linear direction material can choose Textile yarn, preparation method are as follows:
The viscose filament yarn of the terylene bulk filament and 50D of selecting 50D/144F is core, and 80 water suction yarns are used outside core Line (SAF) cladding, twists to form composite yarn using 200 twists/m of the twist;Along yarn axial direction, on its surface every 0.2 centimetre Water repellent finishing agent spraying is carried out, coating layer thickness is 10 microns, and the contact angle of coating is 150 degree, and the length of coating is 2 centimetres.It will The composite yarn of coating is coated with as heart yarn, coats the soybean fiber long filament by hydrophilic treated again in heart yarn outer layer, Soybean fiber filament contact angle is less than 90 degree, fineness 20D.Ultimately forming one, liquid flow direction is controllable and multilayer is equal The even yarn for absorbing liquid.When in use, for liquid when touching the yarn of close and distant waterpower control liquid directional profile, liquid is logical The outside for crossing hydrophilic treated enters yarn interior, is first absorbed by water suction yarn (SAF) in interior radical, the yarn is swollen after absorbing water It is swollen, then with the position that is sprayed by water repellent, groove is formed, with the increase of liquid, liquid can gather groove, in groove and core Pressure difference is formed in interior long filament, driving liquid is flowed along heart yarn.
Using yarn made above can weave as two-dimensional sheet flexible material or be complex as three-dimensional material.
Embodiment 2
The polypropylene fibre hot-wind nonwoven cloth for selecting 20 grams/m, in a face spraying hot-melt adhesive, uniform broadcasting diameter is 1mm's Spherical, absorptance is 280 times of SAP particles;In another side also spraying hot-melt adhesive, spherical, absorption that uniform broadcasting diameter is 0.6mm Than the SAP particle for 360 times, intermediate absorption sandwich layer is formed.Pattern mold as shown in Figure 1 is covered on intermediate absorption sandwich layer table Face, the water repellent finishing agent that then coating thickness is 15 microns, contact angle are 140 degree, form close water repellent capacity variation functional layer. In Fig. 1, white blank space is the hollow part that can pass through water repellent finishing agent, is the blocking of impermeable water repellent finishing agent at black Place.
The surface layer of soft pro-skin is coated in the upper surface of close water repellent capacity variation functional layer, lower surface is embedded in absorption liquid again The composite layer of Time of Fluff Slurry and SAP that ratio is 400 times coats the egative film of waterproof ventilative material material in the lower surface of composite layer, Absorbent article can be formed.When its first time absorbing liquid, only adsorbed at the position for not spraying water repellent, herein The water repellent ability at water repellent position is destroyed in the process.It then absorbs liquid second, is mainly gradually destroyed along water repellent ability Site absorption, formed hydrophobe capacity variation control liquid directed flow absorbent article.
Embodiment 3
As shown in Fig. 2, a kind of absorbent article with hydrophobe capacity variation control liquid directional profile, including from upper and Under pass sequentially through hot melt adhesive bonding pro-skin softness surface layer 1, the cellular rubber layer 2 of pre-boot liquid directional profile, close water repellent Capacity variation functional layer 3, water absorption layer 4, bottom 5.
The material on surface layer 1 is pro-skin pure cotton non-woven fabrics.
Wherein, cellular rubber layer 2 the preparation method is as follows:
It selects with a thickness of 2 millimeters of cellular rubber, surface irregularity, is evenly equipped with several through-holes in cellular rubber, it is more The surface selectivity of aperture layer is coated with octyl trimethoxy silane class water repellent auxiliary agent, and concrete operations are: by figure as shown in Figure 1 Case mold is covered on the cellular rubber surface with through-hole, then carries out the spraying of water repellent auxiliary agent, and contact angle is 120 degree.On Operation is stated so that in the horizontal plane, the surface of partial rubber sponge is coated with water repellent auxiliary agent, and on vertical plane, partial through holes are applied It is covered with water repellent auxiliary agent, porous layer constitutes fluid flow guiding channel, so that liquid is in the moiety aggregation for being not coated with water repellent auxiliary agent, under Layer forms pressure difference, and driving liquid is flowed along vertical plane.
Close water repellent capacity variation functional layer 3 the preparation method is as follows:
18 grams/m of cellulose fibre non-woven fabrics is selected, in a face spraying hot-melt adhesive, uniform broadcasting diameter is The spherical of 0.5mm, absorptance are 450 times of SAP particles;In another side also spraying hot-melt adhesive, uniform broadcasting diameter be 0.3mm not Regular shape, the SAP particle that absorptance is 600 times, form intermediate absorption sandwich layer.Pattern mold as shown in Figure 1 is covered on Intermediate absorption core layer surface, the water repellent finishing agent that then coating thickness is 10 microns, after 140 DEG C of temperature drying, Contact angle is 155 degree, forms close water repellent capacity variation functional layer.Close water repellent capacity variation function layer surface is additionally provided with asperities Road, so that liquid substantially flows in the plane, these concave convex textures are continuous channel (such as circular passage) and discontinuous knot Structure, discontinuous structure are fork type structure or the structure dissipated around by center being made of multiple circles.
Water absorption layer 4 is the mixture for the SAP that cellulose fiber peacekeeping is disposed therein.The cellulose fibre that can be used in this layer It is including wood pulp, cotton, flax and moss well known in the art.Preferably, cellulose fibre is wood pulp.The suction of water absorption layer 4 Water ratio is 300 times, and with a thickness of 3 millimeters, SAP is in spherical, a diameter of 1 millimeter.
The material of bottom 5 is made of thin polymer film, but it can have and is made of the impermeable gas permeable material of liquid, such as The nowoven membrane or microporous barrier or foam of water-proofing treatment.
Above layers can be bonded by hot melt adhesive, adhesive bonding, hot adhesion, ultrasonic bonds, radio frequency seal, it is mechanical Curling etc. and other methods combination be made the utility model with hydrophobe capacity variation control liquid directional profile Absorbent article.When in use, for liquid when entering absorbent article, the orderly direction flow distribution according to design first passes through table Layer 1 enters cellular rubber layer 2, assembles in the through-hole that cellular rubber layer 2 is not coated with water repellent auxiliary agent, forms pressure with lower layer Difference, driving liquid are flowed along vertical plane, and subsequently into close water repellent capacity variation functional layer 3, surface has relatively thin office Portion water repellent surface and relatively thick water suction deformable material (high hydroscopic resin particle), flow along the horizontal plane wherein, when not repairing After being decorated with the part water suction of water repellent auxiliary agent, it is destroyed by the surface water repellent ability that modification absorbs resin, hydrophilic ability is increased By force, liquid is absorbed again as absorbing material, reach liquid and be first distributed to designated position in absorbent article, separate liquid outlet, And stronger imbibition ability and capacity are maintained in the follow-up process.
The above is only the preferred embodiment of the utility model, is not intended to limit the utility model, it is noted that For those skilled in the art, without deviating from the technical principle of the utility model, it can also do Several improvements and modifications out, these improvements and modifications also should be regarded as the protection scope of the utility model.

Claims (10)

1. a kind of absorbent article using close and distant waterpower control liquid directional profile, it is characterised in that: including from top to bottom successively It is arranged
Liquid permeable surface layer;
The surface of close water repellent capacity variation functional layer, the part close water repellent capacity variation functional layer is coated with water repellent auxiliary agent, institute The fluid flow guiding frame that close water repellent capacity variation functional layer constitutes plane is stated, parent's water repellent capacity variation function layer surface is equipped with Concave convex texture, parent's water repellent capacity variation functional layer are made of flexible material, and the upper and lower surfaces of the flexible material connect respectively It is connected to high hydroscopic resin particle;
Water absorption layer, including high hydroscopic resin particle, the water absorption layer constitute the accumulation layer of fluid;
The impermeable bottom of liquid.
2. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, which is characterized in that institute It states between surface layer and close water repellent capacity variation functional layer further include:
Porous layer, the surface irregularity of the porous layer offer several through-holes, the porous layer structure in the porous layer At fluid flow guiding channel, the inner wall of at least part through-hole is coated with water repellent auxiliary agent, and the surface of the part porous layer applies It is covered with water repellent auxiliary agent.
3. the absorbent article according to claim 2 using close and distant waterpower control liquid directional profile, it is characterised in that: institute State porous layer by sponge kind flexible cellular material, one of the fiber that has the fiber of absorbent function and have waterproofing function or Several compositions.
4. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute Stating concave convex texture is continuous channel and/or discontinuous structure, and the discontinuous structure is linear structure, matrix structure, crotch Type structure opens up and foretells one or more of structure and the structure dissipated around by center.
5. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute It states flexible material and is selected from one or more of one-dimensional linear direction material, two-dimensional sheet flexible material and three-dimensional material.
6. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute State the liquid that high hydroscopic resin particle can absorb 0.01-5000 times of own wt.
7. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute The shape for stating high hydroscopic resin particle is one of spherical shape, cylindrical body, square, radial sphere and hollow type sphere or several Kind.
8. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute The partial size of the high hydroscopic resin particle of flexible material upper surface connection is stated greater than the high hydroscopic resin particle that its lower surface connects Partial size.
9. the absorbent article according to claim 1 using close and distant waterpower control liquid directional profile, it is characterised in that: institute Stating water absorption layer further includes Time of Fluff Slurry or cellulose fibre, and the cellulose fibre is wood pulp, cotton, one of flax and moss Or it is several.
10. the absorbent article according to claim 2 using close and distant waterpower control liquid directional profile, it is characterised in that: Between the surface layer, porous layer, close water repellent capacity variation functional layer, water absorption layer and bottom by adhesive bonding, hot adhesion or Ultrasonic bonds mode is bonded.
CN201721463116.4U 2017-11-06 2017-11-06 Utilize the absorbent article of close and distant waterpower control liquid directional profile Active CN209019185U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112426272A (en) * 2021-01-04 2021-03-02 川田卫生用品(浙江)有限公司 Anti-overflow dry breast pad
CN112870427A (en) * 2021-03-12 2021-06-01 上海创始医疗科技(集团)有限公司 Hydrogel elastic patch and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112426272A (en) * 2021-01-04 2021-03-02 川田卫生用品(浙江)有限公司 Anti-overflow dry breast pad
CN112870427A (en) * 2021-03-12 2021-06-01 上海创始医疗科技(集团)有限公司 Hydrogel elastic patch and preparation method thereof

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Assignee: Foshan Ruiyuan Technology Co.,Ltd.

Assignor: SUZHOU KANGFU INTELLIGENT TECHNOLOGY Co.,Ltd.

Contract record no.: X2023990000113

Denomination of utility model: Absorbent products with hydrophilic and hydrophobic hydraulic power to control the directional distribution of liquid

Granted publication date: 20190625

License type: Common License

Record date: 20230113

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Assignee: Foshan Ruiyuan Technology Co.,Ltd.

Assignor: SUZHOU KANGFU INTELLIGENT TECHNOLOGY Co.,Ltd.

Contract record no.: X2023990000113

Date of cancellation: 20240312

EC01 Cancellation of recordation of patent licensing contract