CN208885395U - Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation - Google Patents
Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation Download PDFInfo
- Publication number
- CN208885395U CN208885395U CN201821076512.6U CN201821076512U CN208885395U CN 208885395 U CN208885395 U CN 208885395U CN 201821076512 U CN201821076512 U CN 201821076512U CN 208885395 U CN208885395 U CN 208885395U
- Authority
- CN
- China
- Prior art keywords
- gas
- carbon dioxide
- turbine
- hydrogen
- energy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn - After Issue
Links
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 239000001257 hydrogen Substances 0.000 title claims abstract description 68
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 68
- 239000007789 gas Substances 0.000 title claims abstract description 65
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 33
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims abstract description 158
- 229910002092 carbon dioxide Inorganic materials 0.000 claims abstract description 78
- 239000001569 carbon dioxide Substances 0.000 claims abstract description 78
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 51
- 238000010248 power generation Methods 0.000 claims abstract description 32
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 25
- 239000000567 combustion gas Substances 0.000 claims abstract description 25
- 239000001301 oxygen Substances 0.000 claims abstract description 25
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 25
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 14
- 239000003345 natural gas Substances 0.000 claims abstract description 13
- 239000002737 fuel gas Substances 0.000 claims abstract description 9
- 230000000295 complement effect Effects 0.000 claims abstract description 6
- 239000007787 solid Substances 0.000 claims description 28
- 230000008676 import Effects 0.000 claims description 24
- 238000003860 storage Methods 0.000 claims description 21
- 238000005984 hydrogenation reaction Methods 0.000 claims description 14
- 238000002360 preparation method Methods 0.000 claims description 14
- 238000002485 combustion reaction Methods 0.000 claims description 11
- 238000012546 transfer Methods 0.000 claims description 11
- 238000005868 electrolysis reaction Methods 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 5
- 230000008901 benefit Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 2
- 239000003792 electrolyte Substances 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000005373 pervaporation Methods 0.000 claims 1
- 238000006467 substitution reaction Methods 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract description 2
- 230000001351 cycling effect Effects 0.000 abstract description 2
- 229960004424 carbon dioxide Drugs 0.000 description 60
- 238000005516 engineering process Methods 0.000 description 19
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 230000005611 electricity Effects 0.000 description 8
- KDRIEERWEFJUSB-UHFFFAOYSA-N carbon dioxide;methane Chemical compound C.O=C=O KDRIEERWEFJUSB-UHFFFAOYSA-N 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000004408 titanium dioxide Substances 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 2
- 241000790917 Dioxys <bee> Species 0.000 description 2
- 238000004458 analytical method Methods 0.000 description 2
- 238000004177 carbon cycle Methods 0.000 description 2
- 229910002090 carbon oxide Inorganic materials 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000004146 energy storage Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000003949 liquefied natural gas Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 241001347978 Major minor Species 0.000 description 1
- GCNLQHANGFOQKY-UHFFFAOYSA-N [C+4].[O-2].[O-2].[Ti+4] Chemical compound [C+4].[O-2].[O-2].[Ti+4] GCNLQHANGFOQKY-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000005243 fluidization Methods 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/40—Solar thermal energy, e.g. solar towers
- Y02E10/46—Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/70—Wind energy
- Y02E10/72—Wind turbines with rotation axis in wind direction
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/10—Biofuels, e.g. bio-diesel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E70/00—Other energy conversion or management systems reducing GHG emissions
- Y02E70/30—Systems combining energy storage with energy generation of non-fossil origin
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation, and the renewable energy such as solar wind-energy and half-closed supercritical carbon dioxide combustion gas Bretton heat generating system is made full use of to realize complementary cycle power generation；The water that the main electric power generated using solar wind-energy generates system power generation carries out electrolytic hydrogen production oxygen, effluent carbon dioxide is carried out plus hydrogen methane is standby, and oxygen is combustion-supporting to natural gas or the progress of self-produced methane gas for half-closed supercritical carbon dioxide combustion gas Bretton heat generating system, well-mixed high-temperature fuel gas and supercritical carbon dioxide power working medium drive the workmanship power generation of turbine turbine jointly；System condensing and the water of the standby discharge of methanation are applied not only to electrolytic hydrogen production through collecting, and extra water is used for cleaning solar Jing Chang or photovoltaic panel.The device realizes cycling hot power generation by renewable energy, establishes technical foundation for substitution fossil energy power generation.The invention category solar energy thermal-power-generating and high temperature heat chemistry interdiscipline technical field.
Description
Technical field
The utility model solar wind-energy is combined hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation and is made full use of too
The renewable energy power generations such as positive energy wind energy are simultaneously complementary with half-closed supercritical carbon dioxide combustion gas Bretton heat generating system realization；
The water that the electric power generated in particular with solar wind-energy generates system power generation carries out electrolytic hydrogen production oxygen, to effluent dioxy
Change carbon to carry out adding hydrogen methane standby, and oxygen is used for half-closed supercritical carbon dioxide combustion gas Bretton heat generating system to natural
Gas or the progress of self-produced methane gas are combustion-supporting, and well-mixed high-temperature fuel gas and supercritical carbon dioxide power working medium drive turbine jointly
Turbine workmanship power generation；System condensing and the water of the standby discharge of methanation are applied not only to electrolytic hydrogen production through collecting, and extra water is used for
Cleaning solar Jing Chang or photovoltaic panel.The device realizes cycling hot power generation by renewable energy, for substitution fossil energy power generation
Establish technical foundation.The utility model category solar energy thermal-power-generating and high temperature heat chemistry interdiscipline technical field.
Background technique
The power generation of supercritical carbon dioxide Bretton heat is contemporary energy field cutting edge technology to be broken through, and the technology is once big
Sizable application will change the mankind to the Land use systems of the energy, especially half-closed supercritical carbon dioxide Bretton combustion gas heat power generation
Technology can all recycle effluent carbon dioxide, and make full use of as resource, and then realize French scientist Paul
The imagination that Sabatier was proposed in 1902, it is exactly to mix titanium dioxide in proportion under certain temperature and pressure that this, which is imagined,
Carbon and hydrogen catalytic reaction generate water and methane, and methane oxygenation is then mixed and burned regeneration carbon dioxide and water, is borrowed simultaneously
Solar energy electrolyzing water hydrogen manufacturing is helped, the realization of hydrogenation of carbon dioxide methane is recycled to recycle.People are to realize this over 100 years
Dream of unremitting effort, especially into the 1960s since the technologies such as hydrogenation of carbon dioxide methane and methanol processed gradually
Realize industrialization.Perfect, skill has been carried out to Paul Sabatier imagination based on this " Analysis of Global Carbon Cycle policy system "
Art route includes three steps, and then electrolysis water generates hydrogen and oxygen for first step solar energy or wind power generation；Second step titanium dioxide
Carbon hydrogenation reaction generates methane；Third step, the methane and oxygen mix of generation consume regeneration carbon dioxide as power fuel
It being looped back and forth like this with water, core is exactly to utilize solar power generation hydrogen manufacturing and catalytic hydrogenation of carbon dioxide methanation reaction, when
So prior there are also the acquisitions of carbon dioxide, although after current carbon capture technique can burn or refine from fossil energy
It is obtained in product, but cost is still very high, therefore finds reproducible carbon source and inexpensive carbon capture and just asked at very real
Topic.The technologies such as similar hydrogenation of carbon dioxide methane and methanol processed such as US5128003, CN102549121,
The patent documents such as CN104025356 have very much, although these patented technologies are in hydrogenation of carbon dioxide methanation and utilize renewable
There is novel viewpoint in electricity power hydrogen manufacturing, has innovation on " whole plus hydrogen methanation combined cycle " (IHCC), but select carbon source
It is very traditional, and the more options conventional boiler combusts fossil energy or use open type fuel gas generation technology recycle carbon dioxide, these
Technology obviously can not avoid discharge and recycle the cost problem of carbon dioxide.For another example publication 201710515869.3 is also such as
This, the acquisition of carbon dioxide is still recycled from power plant using the combustion gas of fossil fuel.But with half-closed overcritical titanium dioxide
The appearance and Success in Experiment of carbon Bretton hot generation technology, objectively to realize that above-mentioned strategy brings dawn, because half-closed super
The power generation of critical carbon dioxide combustion gas Bretton heat is pure using alkanes gas such as natural gas, methanol gas, biogas, synthesis gas mixing
Whole recycling and reusings can be carried out to effluent water and carbon dioxide in oxygen combustion process, therefore author attempts in patent
It is in 201310180460.2 and 201610856317.4 that the technology is complementary with solar energy thermal-power-generating realization, to make up solar heat
Generate electricity unstable and discontinuous defect, while overcoming the problems, such as pollutant emission existing for fuel gas generation.United States Patent (USP) US3736745
Relatively early to disclose the technical principle of half-closed supercritical carbon dioxide combustion gas Bretton heat power generation, which once advocates to use
Oxygen is mixed with natural gas to reduce ignition temperature, and is used to recycle using effluent carbon dioxide as dynamic medium, the U.S.
Patent US5724805 and US6622470 then advocate to use in semiclosed supercritical carbon dioxide combustion gas Brayton cycle respectively
Pure oxygen or air-breathing are to reduce cost of electricity-generating using the advantages of air, the disadvantage is that effluent nitrogen-containing oxide.Currently accumulate
What pole promoted the technical industry be 2016 the city Texas ,Usa La Bode establish 25 megawatts using natural gas as fuel
Half-closed supercritical carbon dioxide combustion gas Bretton thermal power station, test objective be realize fossil energy non-carbon-emitting hair
Electricity, using air separation plant obtain oxygen, the direction of research obviously with above-mentioned " Analysis of Global Carbon Cycle policy system " carry on the back road and
It speeds.The project is retrieved at present in the granted patent such as 201180016993.6 in China and thereafter several patents for applying also exist
In continuously improving.The technology is classified as one of annual ten big inventive techniques by Massachusetts Institute Technology at the beginning of 2018, it is believed that the skill
Art is possible to change world energy sources general layout.Open type fuel gas generation is compared in half-closed supercritical carbon dioxide combustion gas Bretton heat power generation
Advantage be effluent be water and carbon dioxide and complete recycling and reusing, use half-closed overcritical titanium dioxide earliest in China
The patent CN02107780.0 of carbon combustion gas Bretton hot generation technology is proposed by Engineering Thermophysics research institute, the Chinese Academy of Sciences, mesh
The Liquefied Natural Gas Import growing mainly for China is marked, advocates to use air-breathing, while utilizing liquefied natural gas
Cold energy further increases fuel gas generation efficiency.
Objective theory, there are more idealism for China's photo-thermal power generation industry, prefer to solar energy thermal-power-generating and do not have to or lack
It is complementary with fossil fuel, therefore day is reduced or not used by half-closed supercritical carbon dioxide combustion gas Bretton hot generation technology
Right gas, abandoning the power generation of photoelectromotive force hydrogen manufacturing methane cycle heat even with abandonment just becomes an important technology project.
Summary of the invention
It is to be solved that the utility model solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation
The half-closed supercritical carbon dioxide that technical problem is used aiming at patent 201310180460.2 and 201610856317.4
The power generation complemented technology of solar gas Bretton heat improves, using renewable energy power generations such as solar energy and wind energies to semi-closure
The water of formula supercritical carbon dioxide combustion gas Bretton heat generating system output carries out electrolytic hydrogen production, using discharge carbon dioxide with
Hydrogen mixing progress methane is standby, is electrolysed the oxygen of generation for gas-fired combustion-supporting driving turbine turbine acting power generation.The technology is real
Border is to be stored the renewable energy such as solar wind-energy by electrolytic hydrogen production and methane preparation method, is realizing that zero-emission is high
Strive substituting fossil energy power generation while effect power generation.The utility model is also the improvement to patent 201810585123.4.
The utility model is achieved through the following technical solutions:
It includes that tower type solar is solid that the solar wind-energy, which combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation,
Body particle condenser system, wind power system, photovoltaic generating system, half-closed supercritical carbon dioxide combustion gas Bretton heat power generation system
System；Device for preparing hydrogen, oxygen storage tank, hydrogenation of carbon dioxide methanation preparation facilities；Triple valve, carbon dioxide gas heat transfer
Pipeline；Condenser, water separator, gas storage holder, water tank, carbon dioxide gas bag, pressure pump；Heat exchanger, evaporator, power supply
Rectifier, it is characterised in that: the fluid-bed heat exchanger outlet of tower type solar solids condenser system is main through triple valve connection,
Secondary turbine turbine import, main turbine turbine Driven by Coaxial generator, main turbine turbine outlet connection evaporator one end import, evaporation
Device outlet connection regenerator one end import, regenerator outlet connection condenser, condensate outlet connect water separator, carbonated drink point
It is separately connected water tank and carbon dioxide drum from device outlet, carbon dioxide drum connects major and minor compressor inlet, and master calms the anger
Machine outlet connection other end regenerator import, regenerator outlet connect tower type solar solids condenser system stream through triple valve
Solar energy and half-closed supercritical carbon dioxide combustion gas Bretton complementary thermal power generation cycle are realized in heat exchanger of fluidized bed import；Secondary whirlpool
Wheel turbine coaxially drives major and minor compressor to operate, secondary turbine turbine outlet connection regenerator import；Secondary blower outlet connection two
Carbonoxide adds hydrogen methanation preparation facilities import；Water tank one end connects pressure pump, and pressure pump discharge connects water electrolysis hydrogen production dress
It sets, or carries out high temperature steam electrolytic hydrogen manufacturing by evaporator other end inlet and outlet connection device for preparing hydrogen；The oxygen produced
It connects oxygen storage tank to combustion chamber and methane blended by gas pipeline to burn, the hydrogen produced connects dioxy by gas pipeline
Change carbon and add another import of hydrogen methanation preparation facilities, is mixed with methane with the carbon dioxide gas from secondary compressor, outlet connects
Connect gas storage holder；Another import of gas storage holder connects natural-gas transfer pipeline；Gas storage holder outlet connection combustion chamber, conveys natural gas or two
The mixed gas of person；Combustor exit connects major and minor turbine turbine import；Device for preparing hydrogen connects power rectifier, electricity
Source rectifier, which receives, comes from solar energy, wind energy or other renewable energy powers or network load excess power；Carbon dioxide adds
Hydrogen methanation preparation facilities high-temperature steam outlet connects heat exchanger, and outlet connection water tank, the heat exchanger other end or access are organic
Rankine thermal electric generator, or connect other heat utilization devices；Or high-temperature steam is directly transported after evaporator heats up and is used to be electrolysed
Hydrogen manufacturing；Or enclosed supercritical carbon dioxide Bretton generating set is added, the calorific value for more making full use of fuel gas generation to discharge；
1) the tower type solar solids condenser system includes that the ceramic receiver for receiving tower top end is arranged in, solid
Particle heat transfer medium, solids conveying device, high temperature solid particles storeroom, solids fluid-bed heat exchanger, solid grain
Sub- storeroom, heliostat light-condensing array；
2) the half-closed supercritical carbon dioxide combustion gas Bretton heat generating system includes that main turbine turbine, secondary turbine are saturating
Flat, combustion chamber, regenerator, main compressor, secondary compressor, condenser, water separator, carbon dioxide gas bag, water tank；Hair
Motor group；Control system, gas three-way control valve, carbon dioxide gas line；Gas storage holder, pressure pump；
3) the half-closed supercritical carbon dioxide combustion gas Bretton heat generating system and wind power system configure power rectifier
Device carries out hydrogen and oxygen production so that direct current is conveyed to device for preparing hydrogen；
4) device for preparing hydrogen is solid oxide electrolyte device for producing hydrogen (SOEC)；Or polymer (SPE) hydrogen manufacturing
Equipment；Or high-temperature electrolysis water device for producing hydrogen；Or electrolyzed alkaline water device for producing hydrogen.
The utility model maximum technical characterstic is that half-closed supercritical carbon dioxide combustion gas Bretton heat is made full use of to generate electricity
System burning pure oxygen and methane are simultaneously excellent with power working medium supercritical carbon dioxide combination drive turbine turbine acting efficiency power generation
Gesture, by renewable energy electrolytic hydrogen production oxygen, effluent carbon dioxide removes to be continued to do the effluent water that system operation is generated
The outer extra carbon dioxide of power working medium operation then adds hydrogen methanation is standby to realize that circulating generation, the technology path are entirely possible to
The century-old dream of French scientist is come true, ultimate aim is with renewable energy substitution fossil energy power generation.
Detailed description of the invention
Fig. 1 is that the utility model solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator operation mould with gas burning mutual compensation
One schematic diagram of formula
Fig. 2 is that the utility model solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator operation mould with gas burning mutual compensation
Two schematic diagram of formula
Wherein: 1 tower type solar solids condenser system, 2 solids heat transfer mediums, 3 heat storage cans, 4 solids
Fluid-bed heat exchanger, 5 triple valves, 6 carbon dioxide gas heat transfer pipes, 7 wind-power electricity generations or photovoltaic generating system, 8 encloseds surpass and face
It is boundary's carbon dioxide Bretton thermal electric generator group, 9 device for preparing hydrogen, 10 hydrogenation of carbon dioxide methanation preparation facilities, 11 cold
Condenser, 12 water separators, 13 gas storage holders, 14 water tanks, 15 carbon dioxide gas bags, 16 main compressors, 17 main turbine turbines,
18 regenerators, 19 combustion chambers, 20 natural-gas transfer pipelines, 21 pressure pumps, 22 evaporators, 23 heat exchangers, 24 secondary turbine turbines, 25
Secondary compressor, 26 oxygen storage tanks
Specific embodiment
Carbon dioxide pressurized gas from carbon dioxide gas bag 15 enters tower type solar solid grain by heat transfer pipe
The solids fluid-bed heat exchanger 4 of sub- condenser system 1 carries out high temperature heat exchange, and the supercritical carbon dioxide gas through high temperature heat exchange passes through
The high-temperature gas of triple valve 5 and natural gas and oxygen mix burning from combustion chamber 19 enters main turbine turbine 17 jointly and does work
Major-minor compressor 16,25 is driven to operate with secondary turbine turbine 24；Mixed gas through the acting discharge of main turbine turbine 17 is through backheat
Device 18 enters condenser 11, and the mixture for condensing generation enters water separator 12, and the water isolated enters water tank 14, point
The carbon dioxide gas separated out respectively enters main compressor 16 and secondary compressor 25, the titanium dioxide after main 16 adherence pressure of compressor
Carbon gas is again introduced into the fluidisation being arranged in tower type solar solids condenser system 1 through triple valve 5 after the heat exchange of regenerator 18
Bed 4 import of heat exchanger, realizes the half-closed hot power generation cycle of supercritical carbon dioxide Bretton combustion gas；14 one end of water tank connection electricity
It solves water hydrogen producer 9 and carries out water electrolysis, the oxygen produced conveys combustion chamber 19, the hydrogen produced by gas pipeline oxygen storage tank 26
Gas by gas pipeline connect hydrogenation of carbon dioxide methanation preparation facilities 10, with the carbon dioxide gas from secondary compressor 25 into
Row methanation is standby, and the methane gas of preparation enters gas storage holder 13；Another import of gas storage holder 13 connects natural-gas transfer pipeline 20；Storage
The outlet of gas holder 13 connection combustion chamber 19, conveys natural gas or methane gas, or both mixed gas；Water-electrolytic hydrogen making equipment 9 connects
It receives from wind-powered electricity generation and 7 electric power of photovoltaic or network load excess power or self-produced electric power；14 one end of water tank connects pressure pump 21
Import, outlet connection evaporator 22, evaporator 22, which is changed thermogenetic high-temperature steam and enters electrolytic hydrogen production equipment 9, carries out electrolysis system
Hydrogen oxygen；The condensation that the high-temperature gas that hydrogenation of carbon dioxide methanation preparation facilities 10 generates in synthesis is generated through heat exchanger 23
Water enters water tank 14, and extra water is cleaned for Jing Chang；23 other end of heat exchanger or access organic Rankine thermal electric generator, or
Connect other heat utilization devices；Or the high-temperature steam for generating hydrogenation of carbon dioxide methanation preparation facilities 10 in synthesis is direct
It conveys after evaporator 22 heats up for electrolytic hydrogen production to substitute condensed water.
The renewable energy powers such as wind energy or photovoltaic are fully utilized and carry out electrolytic hydrogen production oxygen, close tower using triple valve 5
Formula solar energy solid particle condenser system 1, or it is not provided with tower type solar solids condenser system 1；Half-closed overcritical two
The operational process and hydrogenation of carbon dioxide methane of carbonoxide Bretton combustion gas thermal electric generator are as previously described.Or it adds enclosed and surpasses
Critical carbon dioxide Bretton generating set, the calorific value for more making full use of fuel gas generation to discharge；In view of China's wind power hydrogen production energy storage
It is at the early-stage, it achieves that methanation energy storage as can suitably extending investment in conjunction with this technology and substitutes fossil energy power generation, future
It is inestimable.
The utility model is not limited to above-mentioned illustrative ranges, answers without departing from the utility model Writing principle or equivalents
With range, within scope of protection of the utility model.
Claims (1)
1. solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator, including tower type solar solids with gas burning mutual compensation
Condenser system, wind power system, photovoltaic generating system, half-closed supercritical carbon dioxide combustion gas Bretton heat generating system；Electrolysis
Water device for producing hydrogen, oxygen storage tank, hydrogenation of carbon dioxide methanation preparation facilities；Triple valve, carbon dioxide gas heat transfer pipe；It is cold
Condenser, water separator, gas storage holder, water tank, carbon dioxide gas bag, pressure pump；Heat exchanger, evaporator, power rectifier,
It is characterized by: the fluid-bed heat exchanger of tower type solar solids condenser system, which is exported, connects major and minor turbine through triple valve
Turbine import, main turbine turbine Driven by Coaxial generator, main turbine turbine outlet connection evaporator one end import, evaporator outlet
The import of regenerator one end, regenerator outlet connection condenser are connected, condensate outlet connects water separator, water separator
Outlet is separately connected water tank and carbon dioxide drum, and carbon dioxide drum connects major and minor compressor inlet, main blower outlet
The import of other end regenerator is connected, regenerator outlet is changed through triple valve connection tower type solar solids condenser system fluidized bed
Solar energy and half-closed supercritical carbon dioxide combustion gas Bretton complementary thermal power generation cycle are realized in hot device import；Secondary turbine turbine
Major and minor compressor is coaxially driven to operate, secondary turbine turbine outlet connection regenerator import；Secondary blower outlet connects carbon dioxide
Add hydrogen methanation preparation facilities import；Water tank one end connects pressure pump, and pressure pump discharge connects device for preparing hydrogen, or warp
Pervaporation device other end inlet and outlet connection device for preparing hydrogen carries out high temperature steam electrolytic hydrogen manufacturing；The oxygen produced passes through gas
Pipeline connects oxygen storage tank to combustion chamber and methane blended and burns, and the hydrogen produced connects hydrogenation of carbon dioxide by gas pipeline
Another import of methanation preparation facilities is mixed with methane, outlet connection gas storage holder with the carbon dioxide gas from secondary compressor；
Another import of gas storage holder connects natural-gas transfer pipeline；Gas storage holder outlet connection combustion chamber, the mixing of conveying natural gas or both
Gas；Combustor exit connects major and minor turbine turbine import；Device for preparing hydrogen connects power rectifier, power rectifier
It receives and comes from solar energy, wind energy electric power or network load excess power；Hydrogenation of carbon dioxide methanation preparation facilities high-temperature steam
Outlet connection heat exchanger, outlet connection water tank, the heat exchanger other end or access organic Rankine thermal electric generator, or connection heat benefit
Use device；Or high-temperature steam is directly transported after evaporator heats up and is used for electrolytic hydrogen production；Or add enclosed supercritical carbon dioxide
Bretton generating set, the calorific value for more making full use of fuel gas generation to discharge；
1) the tower type solar solids condenser system includes that the ceramic receiver for receiving tower top end is arranged in, solids
Heat transfer medium, solids conveying device, high temperature solid particles storeroom, solids fluid-bed heat exchanger, solids storage
Hide room, heliostat light-condensing array；
2) the half-closed supercritical carbon dioxide combustion gas Bretton heat generating system include main turbine turbine, secondary turbine turbine,
Combustion chamber, regenerator, main compressor, secondary compressor, condenser, water separator, carbon dioxide gas bag, water tank；Power generation
Unit；Control system, gas three-way control valve, carbon dioxide gas line；Gas storage holder, pressure pump；
3) the half-closed supercritical carbon dioxide combustion gas Bretton heat generating system and wind power system configuration power rectifier with
Just direct current is conveyed to device for preparing hydrogen and carries out hydrogen and oxygen production；
4) device for preparing hydrogen selection solid oxide electrolyte device for producing hydrogen (SOEC)；Or polymer (SPE) hydrogen manufacturing is set
It is standby；Or high-temperature electrolysis water device for producing hydrogen；Or electrolyzed alkaline water device for producing hydrogen.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821076512.6U CN208885395U (en) | 2018-07-09 | 2018-07-09 | Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201821076512.6U CN208885395U (en) | 2018-07-09 | 2018-07-09 | Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN208885395U true CN208885395U (en) | 2019-05-21 |
Family
ID=66506401
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201821076512.6U Withdrawn - After Issue CN208885395U (en) | 2018-07-09 | 2018-07-09 | Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN208885395U (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112003309A (en) * | 2020-07-13 | 2020-11-27 | 上海发电设备成套设计研究院有限责任公司 | Electric power peak shaving system |
| CN112811440A (en) * | 2021-03-03 | 2021-05-18 | 西安热工研究院有限公司 | System and method for preparing ammonium sulfate by using boiler sulfur-containing flue gas |
| CN113666372A (en) * | 2021-09-18 | 2021-11-19 | 江苏亿万物联科技有限公司 | Method for preparing carbon dioxide by introducing photovoltaic electric energy into chemical industry |
| WO2022160060A1 (en) * | 2021-01-29 | 2022-08-04 | Industriasys Corp. | Zero emission power generation systems and methods |
| CN115710710A (en) * | 2022-10-17 | 2023-02-24 | 中国矿业大学 | Coastal coal-fired electricity-gas comprehensive energy production method for digesting offshore wind power |
-
2018
- 2018-07-09 CN CN201821076512.6U patent/CN208885395U/en not_active Withdrawn - After Issue
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112003309A (en) * | 2020-07-13 | 2020-11-27 | 上海发电设备成套设计研究院有限责任公司 | Electric power peak shaving system |
| CN112003309B (en) * | 2020-07-13 | 2021-12-10 | 上海发电设备成套设计研究院有限责任公司 | Electric power peak shaving system |
| WO2022160060A1 (en) * | 2021-01-29 | 2022-08-04 | Industriasys Corp. | Zero emission power generation systems and methods |
| CN112811440A (en) * | 2021-03-03 | 2021-05-18 | 西安热工研究院有限公司 | System and method for preparing ammonium sulfate by using boiler sulfur-containing flue gas |
| CN113666372A (en) * | 2021-09-18 | 2021-11-19 | 江苏亿万物联科技有限公司 | Method for preparing carbon dioxide by introducing photovoltaic electric energy into chemical industry |
| CN115710710A (en) * | 2022-10-17 | 2023-02-24 | 中国矿业大学 | Coastal coal-fired electricity-gas comprehensive energy production method for digesting offshore wind power |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN208885395U (en) | Solar wind-energy combines hydrogen manufacturing methane cycle thermal electric generator with gas burning mutual compensation | |
| CN110700944B (en) | Solar energy wind energy and fuel gas complementary combined hydrogen production methane production circulating thermal power generation device | |
| Kasaeian et al. | Solar-driven polygeneration systems: Recent progress and outlook | |
| CN107630726B (en) | Multi-energy hybrid power generation system and method based on supercritical carbon dioxide circulation | |
| CN108005742B (en) | Solid oxide fuel cell driven combined cooling, heating and power system capable of being partially recycled | |
| CN205356219U (en) | Scene gas stores up complemental combined heat and power generation system | |
| Lykas et al. | A comprehensive review of solar-driven multigeneration systems with hydrogen production | |
| CN103899371B (en) | Utilize living beings and solar energy to produce the polygenerations systeme of methyl alcohol and generating | |
| CN203783662U (en) | Poly-generation device using biomass and solar energy for preparing methanol and generating electricity | |
| CN105756782A (en) | Solar chemically recuperated gas turbine system and method implemented by same | |
| CN205779064U (en) | Supercritical water gasification and supercritical carbon dioxide Brayton cycle Joint Production system | |
| CN102345576A (en) | High-efficiency solar photo-thermal tower-type electricity generation and seawater desalinization integral system | |
| CN211258905U (en) | Solar energy and wind energy and fuel gas complementary combined hydrogen production methane production circulating thermal power generation device | |
| CN101968042B (en) | Multistage full-effect solar heat power generation method | |
| CN113005475B (en) | System and process for solar high-temperature water electrolysis coupling hydrogen production based on amino thermochemical energy storage | |
| CN104676911A (en) | Photovoltaic and photo-thermal chemical combination solar energy comprehensive utilization device and system | |
| CN110056489A (en) | Photovoltaic power generation and solar thermal energy-combined combustion and steam turbine power complementary power generation system | |
| CN108798898B (en) | System and method for supplying steam and hot water by combining proton exchange membrane fuel cell and gas turbine | |
| CN103982383A (en) | Solar energy-ocean thermal energy combined power generation system | |
| CN112290656A (en) | Supercritical CO combining hydrogen production energy storage and fuel cell technology2Solar power generation system and method | |
| CN114922733A (en) | Renewable energy source hydrogen-combustion steam combined cycle power generation system | |
| CN112832963A (en) | Solar energy and wind energy and fuel gas complementary combined hydrogen production methane production circulating thermal power generation device | |
| CN106288512A (en) | A kind of solar heat chemistry cooling heating and power generation system | |
| CN111927723B (en) | Electric power peak regulation system based on microalgae respiration coupling solar energy and supercritical hydrothermal reaction | |
| CN201827034U (en) | Plate-trough combined solar and thermal power station complementary power generating system |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| AV01 | Patent right actively abandoned |
Granted publication date: 20190521 Effective date of abandoning: 20241015 |
|
| AV01 | Patent right actively abandoned |
Granted publication date: 20190521 Effective date of abandoning: 20241015 |
|
| AV01 | Patent right actively abandoned | ||
| AV01 | Patent right actively abandoned |