CN208762364U - Dyeing waste water advanced treatment system - Google Patents

Dyeing waste water advanced treatment system Download PDF

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Publication number
CN208762364U
CN208762364U CN201821235149.8U CN201821235149U CN208762364U CN 208762364 U CN208762364 U CN 208762364U CN 201821235149 U CN201821235149 U CN 201821235149U CN 208762364 U CN208762364 U CN 208762364U
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pipeline
pond
ultrafiltration
water
advanced treatment
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叶舟
李金页
曾淼
陈烨
董菲菲
曾丽
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Last Environmental Technology (jinhua) Co Ltd
Top Environmental Protection Technology (hangzhou) Co Ltd
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Last Environmental Technology (jinhua) Co Ltd
Top Environmental Protection Technology (hangzhou) Co Ltd
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Abstract

The utility model discloses a kind of dyeing waste water advanced treatment systems, including pretreatment unit, advanced treatment unit and the Treatment for Reuse unit being connected through pipeline;The advanced treatment unit includes the coagulation floatation being sequentially connected through pipeline, biological aerated filter, clear water reserviors and O3 contacted oxidation tower;The Treatment for Reuse unit includes the quartz filter being connected with clear water reserviors through pipeline, quartz filter is connected with ultrafiltration film module in turn through pipeline, ultrafiltration produces pond, cartridge filter and reverse osmosis unit, reverse osmosis unit is connected separately with the production pond RO through pipeline and RO concentrated water pond, RO concentrated water pond are connected with Fenton reactor, sedimentation basin and blowoff basin in turn through pipeline;The sedimentation basin and coagulation floatation are also connected with sludge-tank.The utility model has the characteristics that greatly improve wastewater treatment efficiency.

Description

Dyeing waste water advanced treatment system
Technical field
The utility model relates to a kind of printing and dyeing wastewater treatment system, especially a kind of dyeing waste water advanced treatment system.
Background technique
Dyeing waste water mainly includes dyeing waste-water and poaching wastewater, and the processing mode of dyeing waste-water mainly passes through grid mistake The processing such as filter tank, conditioning tank, sedimentation basin, hydrolysis acidification pool, contact-oxidation pool and secondary settling tank, poaching wastewater is by conditioning tank, rotation Turn the processing such as grid pond, flotation tank and sedimentation basin, still, dyeing waste-water and poaching wastewater are handled through existing sewage disposal device The discharge that water outlet afterwards can only achieve " textile dyeing and finishing industrial water pollution object discharge standard " (GB4287-2012) newly-built enterprise is dense Degree, the direct emission mark being unable in meet the requirement of environmental protection " textile dyeing and finishing industrial water pollution object discharge standard " (GB4287-2012) It is quasi-.Therefore, existing technology has that wastewater treatment efficiency is bad.
Utility model content
The purpose of the utility model is to provide a kind of dyeing waste water advanced treatment systems.The utility model has can The characteristics of greatly improving wastewater treatment efficiency.
The technical solution of the utility model includes: a kind of dyeing waste water advanced treatment system, including the pre-treatment being connected through pipeline Unit, advanced treatment unit and Treatment for Reuse unit;The advanced treatment unit includes the coagulation air-float being sequentially connected through pipeline Pond, biological aerated filter, clear water reserviors and O3 contacted oxidation tower;The Treatment for Reuse unit includes being connected with clear water reserviors through pipeline Quartz filter, quartz filter through pipeline be connected in turn ultrafiltration film module, ultrafiltration produce pond, cartridge filter and Reverse osmosis unit, reverse osmosis unit is connected separately with the production pond RO through pipeline and RO concentrated water pond, RO concentrated water pond successively connect through pipeline It is connected to Fenton reactor, sedimentation basin and blowoff basin;The sedimentation basin and coagulation floatation are also connected with sludge-tank.
In dyeing waste water advanced treatment system above-mentioned, the ultrafiltration film module includes ultrafiltration apparatus, ultrafiltration apparatus into The mouth of a river is connected with quartz filter through pipeline, and the production mouth of a river of ultrafiltration apparatus produces pond with ultrafiltration and is connected through pipeline, ultrafiltration apparatus Dope exit equipped with flush cycle pump, flush cycle pump is connected through pipeline with the water inlet of ultrafiltration apparatus;The ultrafiltration dress The production mouth of a river set is also connected with backwashing pump through pipeline, and backwashing pump produces pond with ultrafiltration through pipeline and is connected;The water inlet of ultrafiltration apparatus It is also connected with air compressor machine through pipeline, air compressor machine is connected through pipeline with compressed air reservoir.
In dyeing waste water advanced treatment system above-mentioned, the pretreatment unit includes through the sequentially connected grid mistake of pipeline Filter tank, conditioning tank, rotary grate filtering ponds, primary sedimentation tank, hydrolysis acidification pool and secondary settling tank, secondary settling tank is through pipeline and coagulation floatation It is connected;Primary sedimentation tank and secondary settling tank are also connected with sludge-tank.
Compared with prior art, the utility model passes through pretreatment unit, advanced treatment unit and Treatment for Reuse unit Mutual cooperation successively pre-processes dyeing waste-water and poaching wastewater, advanced treating and reuse water process, so that treated Water outlet can reach the direct emission standard of defined, to effectively raise the treatment effect of dyeing waste water, and pass through Mutual cooperation between three processing units can also effectively improve waste water under the premise of guaranteeing disposal effect of dyeing wastewater Treatment effeciency.Advanced treatment unit is handled dyeing waste water using coagulation floatation and biological aerated filter, so as to The suspension colloid COD and solubility COD contained in enough effective removal waste water;By direct to a part of aqueous in clear water reserviors Then the coloration and COD for carrying out O3 contacted oxidation reaction to be effectively reduced in water reach discharge standard, double so as to mitigate Treating capacity when film process improves treatment effeciency;Recycling processing system passes through double membrane treatment process (ultrafiltration film module and reverse osmosis Device) and Fenton reactor mutual cooperation, double films are carried out to another part aqueous in clear water reserviors by double membrane treatment process Processing, it is ensured that water outlet reaches quality of reused water standard, and concentrated water will require to receive pipe discharge to environmental protection and mark through Fenton's reaction heel row is unconventional and unrestrained Standard is effectively improved the treatment effect of waste water by above-mentioned improvement.In conclusion the utility model have can be very big The characteristics of improving wastewater treatment efficiency.
In addition, the utility model is pumped by the way that flush cycle is arranged in the dope exit of ultrafiltration apparatus, concentrate from out Mouth is back to film import, increases film by improving the cross-flow rate of film surface under the premise of keeping the higher system rate of recovery Contamination resistance;By the way that backwashing pump is arranged at the production mouth of a river of ultrafiltration apparatus, air compressor machine is arranged in the water inlet of ultrafiltration apparatus, convenient for pair Ultrafiltration apparatus, which carries out backwash and gas flushing, backwash operation, is in the pollution of film surface in the state of a kind of loosening, gas punching Ultrafiltration membrane filaments outer surface is washed, causes the strong shake of film wire, the particulate matter for being adhered to film wire surface is made further to loosen It falls, so as to the good cleaning effect taken.
Detailed description of the invention
Fig. 1 is the process flow chart of the utility model;
Fig. 2 is the flow diagram of ultrafiltration film module.
The label in accompanying drawing is: 1- coagulation floatation, 2- biological aerated filter, 3- clear water reserviors, 4- O3 contacted oxidation tower, 5- quartz filter, 6- ultrafiltration film module, 7- ultrafiltration produce pond, 8- cartridge filter, 9- reverse osmosis unit, 10-RO production water Pond, 11-RO concentrated water pond, 12- Fenton reactor, 13- sedimentation basin, 14- blowoff basin, 15- ultrafiltration apparatus, 16- flush cycle pump, 17- backwashing pump, 18- air compressor machine, 19- compressed air reservoir, 20- primary sedimentation tank, 21- hydrolysis acidification pool, 22- secondary settling tank, 23- grid Filtering ponds, 24- conditioning tank, 25- rotary grate filtering ponds.
Specific embodiment
The utility model is further described with reference to the accompanying drawings and examples, but is not intended as to the utility model The foundation of limitation.
Embodiment.Dyeing waste water advanced treatment system is constituted as shown in Figure 1 to Figure 2, including the pre-treatment being connected through pipeline Unit, advanced treatment unit and Treatment for Reuse unit;The advanced treatment unit includes the coagulation air-float being sequentially connected through pipeline Pond 1, biological aerated filter 2, clear water reserviors 3 and O3 contacted oxidation tower 4;The Treatment for Reuse unit includes with clear water reserviors 3 through pipe The connected quartz filter 5 in road, quartz filter 5 is connected with ultrafiltration film module 6 in turn through pipeline, ultrafiltration produces pond 7, protects Pacify filter 8 and reverse osmosis unit 9, reverse osmosis unit 9 is connected separately with RO through pipeline and produces pond 10 and RO concentrated water pond 11, and RO is dense Pond 11 is connected with Fenton reactor 12, sedimentation basin 13 and blowoff basin 14 in turn through pipeline;The sedimentation basin 13 and coagulation air-float Pond 1 is also connected with sludge-tank.
The ultrafiltration film module 6 includes ultrafiltration apparatus 15, and the water inlet and quartz filter 5 of ultrafiltration apparatus 15 are through pipeline It is connected, the production mouth of a river of ultrafiltration apparatus 15 produces pond 7 with ultrafiltration and is connected through pipeline, and the dope exit of ultrafiltration apparatus 15, which is equipped with, to be rinsed Circulating pump 16, flush cycle pump 16 are connected through pipeline with the water inlet of ultrafiltration apparatus 15;The production mouth of a river of the ultrafiltration apparatus 15 passes through Pipeline is also connected with backwashing pump 17, and backwashing pump 17 produces pond 7 with ultrafiltration through pipeline and is connected;The water inlet of ultrafiltration apparatus 15 is through pipeline It is also connected with air compressor machine 18, air compressor machine 18 is connected through pipeline with compressed air reservoir 19.
It further include the chemical cleaning module being connected respectively with ultrafiltration apparatus 15 and reverse osmosis unit 9;The chemical cleaning mould Block includes cleaning solution case, cleaning pump and the accurate filter being sequentially connected through pipeline, accurate filter through pipeline respectively with it is super Filter device 15 is connected with the cleaning interface of reverse osmosis unit 9.
The pretreatment unit includes through the sequentially connected grid filtration pond 23 of pipeline, conditioning tank 24, rotary grate filtering Pond 25, primary sedimentation tank 20, hydrolysis acidification pool 21 and secondary settling tank 22, secondary settling tank 22 are connected through pipeline with coagulation floatation 1;Primary sedimentation tank 20 Also it is connected with sludge-tank with secondary settling tank 22.
Coagulant or flocculation aid are added in the coagulation floatation 1.
Dilute sulfuric acid, ferrous sulfate and hydrogen peroxide are added in Fenton reactor 12.
The order of addition of each component in the Fenton reactor are as follows: first adjusted the pH value in Fenton reactor with dilute sulfuric acid To 3, n (Fe is then pressed2+)/n(H2O2After the proportion of)=1:3 carries out Fenton's reaction, then plus alkali is by pH value adjustment to 7-8.
A kind of processing method of dyeing waste water advanced treatment system, comprising the following steps: dyeing waste-water and poaching wastewater warp Pretreated waste water is obtained after pretreatment unit processing, pretreated waste water successively passes through coagulation floatation and biological aerated filter processing After obtain B liquid, B liquid, which enters in clear water reserviors, to be stored;Then, 1/5th B liquid flow into O3 contacted oxidation tower in into It is discharged after row O3 contacted oxidation reaction, remaining 4/5ths B liquid, which flows into quartz filter, obtains C liquid after filtering Body;C liquid successively obtains recycle-water D and concentrated water E, reuse after the filtering of ultrafiltration film module, cartridge filter and reverse osmosis unit Water enters RO and produces pond then discharge, and concentrated water E flows into RO concentrated water pond, and then concentrated water E obtains F after the processing of Fenton reactor Liquid, F liquid stream, which enters, carries out precipitation process in sedimentation basin, G liquid is obtained after separation of solid and liquid, G liquid stream, which enters in blowoff basin, discharges.
Water pump is equipped between each reaction tank or device being connected by pipeline.
Liquid addition PH regulator and/or fungicide during flowing into clear water reserviors from biological aerated filter;Liquid from Ultrafiltration produces during pond flows into cartridge filter and adds antisludging agent, reducing agent and non-oxidizable bacterium.
Ultrafiltration apparatus uses cross-flow filtration.Device designs water yield 75m3/h, operating condition are as follows: operation 30-60 minutes, Auto-flushing is primary.Since any chemical agent need not be added in backwash, and it is very short (usually 30~60 seconds) to carry out the time Therefore the expense of backwash reinforces backwash well below chemistry.Suspended particulate cannot be contained in backwash water, it is desirable that produce using ultrafiltration Water outlet.Step: first carrying out backwash operation, and ultrafiltration is produced water by hyperfiltration reverse-rinsing pump and is thrown into membrane module by producing water side, film is made The pollution on surface is in the state of a kind of loosening, is cleaned ultrafiltration membrane filaments outer surface carrying out gas, is caused the strong shake of film wire, It loosens the particulate matter for being adhered to film wire surface further to be fallen, just rinsed finally by the intake pump of ultrafiltration apparatus Membrane module, the good cleaning effect that can be taken is discharged in the pollutant of film surface.
According to operating condition, air purge is divided into single air purge and double air purges, such as single air purge can be thus capable of sufficiently recovering when time membrane pressure, then into Row list air purge, single air purge step sequence are as follows: filter 23 0 minute;Air purge, backwash, 30 seconds;It just washes, 30 seconds.
It is positive to rinse, it uses intake pump as positive flush power, opens membrane module concentrated water spout valve, close membrane module and produce mouth of a river valve, It is rinsed with low-pressure, big flow.
Gas flushing is gas impulsion power by air compressor machine, enters from membrane module bottom and from bottom to top rinse, flushing pressure controls Within 1Bar, the air purge flow of every film is 3-5m3, opens membrane module concentrated water spout valve, closes membrane module and produces mouth of a river valve.
Flushing water is produced the mouth of a river from membrane module and entered, gone out from concentrated water by backwash method with backwashing pump as backwash power Mouth and water inlet outflow control lower operating pressure (general≤0.1Mpa), to prevent having received high internal pressure, lead to membrane module inner membrance Silk explosion.
When backwash, flushing water cannot be recycled, direct emission or original materializing strategy system is gone to be further processed.
High-pressure pump is equipped between cartridge filter and reverse osmosis unit.
High-pressure pump is according to reverse osmosis 70.0m3/h RO system Calculation of Water producing capacity, and at 25 DEG C, RO device inflow is 70m3/ H, operating pressure are 1.0~1.5MPa, and reverse osmosis unit selects multistage high-pressure pump 1, and separate unit flow is 70m3/h, lift 135m, power 37kw, circulating pump 1, separate unit flow is 12m3/h, lift 50m, power 3.0kw.High-pressure pump matches frequency converter, It needs to adjust operating pressure according to water yield.
Reverse-osmosis membrane element uses pollution-resistant membrane.Ro components quantity totally 84.Every element duration is 1 meter.
A kind of processing method of dyeing waste water advanced treatment system, dyeing waste-water and the premenstrual processing unit processes of poaching wastewater After obtain pretreated waste water, pretreated waste water successively obtains B liquid after coagulation floatation and biological aerated filter (BAF) processing Body, B liquid, which enters in clear water reserviors, to be stored;Then, 1/5th B liquid, which flows into, carries out ozone contact in O3 contacted oxidation tower It is discharged after oxidation reaction, remaining 4/5ths B liquid, which flows into quartz filter, obtains C liquid after filtering;C liquid according to Recycle-water D and concentrated water E are obtained after the filtering of secondary ultrafiltration film module, cartridge filter and reverse osmosis unit, recycle-water enters RO production Then pond is discharged, concentrated water E flows into RO concentrated water pond, and then concentrated water E obtains F liquid after the processing of Fenton reactor, and F liquid stream enters Precipitation process is carried out in sedimentation basin, G liquid is obtained after separation of solid and liquid, and G liquid stream, which enters in blowoff basin, discharges.
Dyeing waste-water and poaching wastewater are passing through grid filtration pond, conditioning tank, rotary grate filtering ponds, primary sedimentation tank, hydrolysis It is discharged after acidification pool and secondary settling tank, mixing of removing contamination after secondary clarifier effluent, water 2000m3/ d, water outlet flow to coagulation floatation certainly, Air-floating apparatus in coagulation floatation is soluble in water by large quantity of air under pressure condition, forms dissolved air water, is situated between as work Matter generates a large amount of micro air bubbles by the release sudden pressure reduction quick release in coagulation floatation.Micro air bubble is anti-with coagulation It answers the condensation product in waste water to be adhered to each other, wadding body specific gravity is made to bubble through the water column less than 1, so that pollutant be made to be separated from the water out It goes, achievees the purpose that water purification.The water outlet of coagulation floatation flow to biological aerated filter certainly, attached on the filler in biological aerated filter Microbial degradation organic matter, to achieve the purpose that water purification.The water outlet of biological aerated filter is divided into two gangs of 400m3/ d and 1600m3/ d, wherein 400m3/ d enters O3 contacted oxidation tower and carries out O3 contacted oxidation reaction, further decolourizes and removes A small amount of COD, then qualified discharge;1600m3/ d is handled by dual membrane system, reverse osmosis unit output reuse water 1000m3/ d and 600m3/ d concentrated water (COD concentration 250mg/L), concentrated water enter Fenton reactor and carry out Fenton's reaction, and dilute sulfuric acid is first added and adjusts pH 3 or so, while ferrous sulfate and hydrogen peroxide is added, further removes pollutant, then water outlet is flowed into sedimentation basin and is precipitated, Gu After liquid separation, liquid adjusts back pH with sodium hydroxide, then discharges water to blowoff basin outlet.
Table 1 is expected treatment effect

Claims (3)

1. dyeing waste water advanced treatment system, it is characterised in that: including pretreatment unit, the advanced treatment unit being connected through pipeline With Treatment for Reuse unit;The advanced treatment unit includes the coagulation floatation (1) being sequentially connected through pipeline, biological aerated filter (2), clear water reserviors (3) and O3 contacted oxidation tower (4);The Treatment for Reuse unit includes being connected with clear water reserviors (3) through pipeline Quartz filter (5), quartz filter (5) is connected with ultrafiltration film module (6) in turn through pipeline, ultrafiltration produces pond (7), protects Pacify filter (8) and reverse osmosis unit (9), reverse osmosis unit (9) is connected separately with RO through pipeline and produces pond (10) and RO concentrated water Pond (11), RO concentrated water pond (11) are connected with Fenton reactor (12), sedimentation basin (13) and blowoff basin (14) in turn through pipeline;It is described Sedimentation basin (13) and coagulation floatation (1) are also connected with sludge-tank.
2. dyeing waste water advanced treatment system according to claim 1, it is characterised in that: ultrafiltration film module (6) packet It includes ultrafiltration apparatus (15), the water inlet of ultrafiltration apparatus (15) is connected with quartz filter (5) through pipeline, ultrafiltration apparatus (15) It produces the mouth of a river and is connected with ultrafiltration production pond (7) through pipeline, the dope exit of ultrafiltration apparatus (15) is equipped with flush cycle pump (16), punching It washes circulating pump (16) and is connected through pipeline with the water inlet of ultrafiltration apparatus (15);The production mouth of a river of the ultrafiltration apparatus (15) through pipeline also It is connected with backwashing pump (17), backwashing pump (17) produces pond (7) with ultrafiltration through pipeline and is connected;The water inlet of ultrafiltration apparatus (15) is through pipe Road is also connected with air compressor machine (18), and air compressor machine (18) is connected through pipeline with compressed air reservoir (19).
3. dyeing waste water advanced treatment system according to claim 1, it is characterised in that: the pretreatment unit includes warp The sequentially connected grid filtration pond (23) of pipeline, conditioning tank (24), rotary grate filtering ponds (25), primary sedimentation tank (20), hydrolysis acid Change pond (21) and secondary settling tank (22), secondary settling tank (22) are connected through pipeline with coagulation floatation (1);Primary sedimentation tank (20) and secondary settling tank (22) also it is connected with sludge-tank.
CN201821235149.8U 2018-08-02 2018-08-02 Dyeing waste water advanced treatment system Active CN208762364U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793642A (en) * 2018-08-02 2018-11-13 上环保科技(杭州)有限公司 A kind of dyeing waste water advanced treatment system and processing method
CN112919734A (en) * 2021-01-26 2021-06-08 北京今大禹环境技术股份有限公司 Coking wastewater deep treatment and evaporative crystallization zero-discharge process

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108793642A (en) * 2018-08-02 2018-11-13 上环保科技(杭州)有限公司 A kind of dyeing waste water advanced treatment system and processing method
CN112919734A (en) * 2021-01-26 2021-06-08 北京今大禹环境技术股份有限公司 Coking wastewater deep treatment and evaporative crystallization zero-discharge process

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