CN208727515U - Vacuumed insulation panel and hot box - Google Patents

Vacuumed insulation panel and hot box Download PDF

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Publication number
CN208727515U
CN208727515U CN201690000817.1U CN201690000817U CN208727515U CN 208727515 U CN208727515 U CN 208727515U CN 201690000817 U CN201690000817 U CN 201690000817U CN 208727515 U CN208727515 U CN 208727515U
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CN
China
Prior art keywords
insulation panel
vacuumed insulation
outer container
core material
enclosure
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Expired - Fee Related
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CN201690000817.1U
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Chinese (zh)
Inventor
藤村正
藤村一正
向山贵祥
安孙子尚平
高井浩明
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Mitsubishi Electric Corp
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Mitsubishi Electric Corp
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L59/00Thermal insulation in general
    • F16L59/06Arrangements using an air layer or vacuum
    • F16L59/065Arrangements using an air layer or vacuum using vacuum

Abstract

Vacuumed insulation panel involved in the utility model has core material and coats the enclosure of above-mentioned core material, the inside of above-mentioned enclosure is in decompression state, above-mentioned enclosure is the stacked film with barrier layer for gases, above-mentioned enclosure has two faces opposed on the thickness direction of the Vacuumed insulation panel in the range opposed with above-mentioned core material, in the case where the part in the composition of above-mentioned enclosure two faces is defined as core material covering portion, above-mentioned gas barrier layer exists only in above-mentioned core material covering portion.Therefore, Vacuumed insulation panel involved in the utility model can reduce the gases such as vapor and air from the situation of the external inside for invading enclosure of enclosure, the pyroconductivity of the central portion of Vacuumed insulation panel can be maintained for a long time low.

Description

Vacuumed insulation panel and hot box
Technical field
The utility model relates to realize the Vacuumed insulation panel of the maintenance of heat-proof quality and have the Vacuumed insulation panel every Hot tank.
Background technique
As the existing Vacuumed insulation panel that the thermal insulator in refrigerator etc. uses, have the core material and packet for keeping vacuum space The enclosure of the core material is covered, the inside of enclosure is in decompression state.Moreover, inside is maintained by vacuum by enclosure, from And Vacuumed insulation panel is maintained low pyroconductivity.Therefore, the enclosure of existing Vacuumed insulation panel, in order to reduce vapor And the gases such as air, from the external inside for invading enclosure of enclosure, long-term maintenance pyroconductivity is low, and throughout integrally Barrier layer for gases is set.The barrier layer for gases constitutes (example by the vapor deposition layer of metal foil, the vapor deposition layer of metal or metal oxide Such as, referring to patent document 1).
Patent document 1: Japanese Unexamined Patent Publication 2015-104704 bulletin
When manufacturing Vacuumed insulation panel, firstly, enclosure to be formed as to the bag shape of a part opening of peripheral part.In detail Say that the enclosure of Vacuumed insulation panel has hot welding layer in a face in ground.Match moreover, an enclosure is bent into hot welding layer It is placed in inside or two enclosures is overlapped into hot welding layer is opposed, and by sealing the hot welding layer welding of peripheral part etc. It forms sealing, thus enclosure is formed as to the bag shape of a part opening of peripheral part.Then, it is inserted into the enclosure Opening portion welding is formed sealing, to complete by heat-sealing etc. after the inside to enclosure is depressurized by core material Vacuumed insulation panel.
Therefore, Vacuumed insulation panel forms the sealing for not covering core material in the peripheral side of core material.The sealing of the enclosure It is heat-insulated due to not contributeing to, thus the case where use the sealing along the shape bending of core material there are Vacuumed insulation panel.
It is used simultaneously using the Vacuumed insulation panel of the hot box in refrigerator etc. with polyurathamc thermal insulator for example, existing The case where.At this point, there is the sealing by enclosure along core material in order to ensure the filling flow path of polyurathamc thermal insulator Shape bending carrys out the case where using Vacuumed insulation panel.In the end for the Vacuumed insulation panel that the sealing of enclosure is bent over, generate Because hot around entering i.e. heat bridge (heat bridge) caused by enclosure.Therefore, the thermal insulation as Vacuumed insulation panel entirety is indicated The effective thermal conductivity of energy increases.
Generally, it is contemplated that the effective thermal conductivity λ eff of the heat bridge (heat bridge) in the end of Vacuumed insulation panel It can be acquired by following formula (1).
λ eff=λ cop+ ψ (d) × d × p ÷ A ... (1)
In addition, λ cop is the central portion of Vacuumed insulation panel when along heat-insulated direction that is, thickness direction observation Vacuumed insulation panel The pyroconductivity of position.In other words, λ cop be along heat-insulated direction that is, thickness direction observation Vacuumed insulation panel when core material in The pyroconductivity of centre portion position.ψ (d) is the pyroconductivity of the part for not covering core material of the enclosures such as sealing.D be vacuum every The thickness of warmware.The perimeter of Vacuumed insulation panel when P is along heat-insulated direction that is, thickness direction observation Vacuumed insulation panel.A is The area of Vacuumed insulation panel when along heat-insulated direction that is, thickness direction observation Vacuumed insulation panel.
Here, it is being arranged in the whole region of enclosure by metal foil, the vapor deposition layer or gold of metal as patent document 1 In the case where the barrier layer for gases of vapor deposition layer composition for belonging to oxide, the gases such as vapor and air can be reduced from enclosure External intrusion enclosure inside situation, the pyroconductivity of the central portion of Vacuumed insulation panel can be maintained for a long time low.However, In the whole region setting as patent document 1 in enclosure by metal foil, the vapor deposition layer of metal or the steaming of metal oxide In the case where the barrier layer for gases that coating is constituted, the pyroconductivity of the sealing of enclosure becomes larger, thus effective thermal conductivity increases Add, there are the projects that heat-proof quality reduces.
Utility model content
The utility model be it is completed to solve the above problems, first, which is designed to provide one kind, to be reduced The gases such as vapor and air maintain Vacuumed insulation panel from the situation of the external inside for invading enclosure of enclosure for a long time Central portion pyroconductivity it is low, and be able to maintain that the low vacuum that can maintain high heat-proof quality for a long time of effective thermal conductivity Thermal insulator.In addition, second is designed to provide a kind of hot box for having the Vacuumed insulation panel.
Vacuumed insulation panel involved in the utility model has core material and coats the enclosure of above-mentioned core material, above-mentioned enclosure Inside be in decompression state, above-mentioned enclosure is the stacked film with barrier layer for gases, above-mentioned enclosure with above-mentioned core material Opposed range have two faces opposed on the thickness direction of the Vacuumed insulation panel, by the composition of above-mentioned enclosure this two In the case that the part in a face is defined as core material covering portion, above-mentioned gas barrier layer exists only in above-mentioned core material covering portion, is inciting somebody to action In the case that the range in addition to above-mentioned core material covering portion in above-mentioned enclosure is defined as the non-covering portion of core material, above-mentioned core material is non- Covering portion is bent over along the shape of above-mentioned core material.
Preferably, above-mentioned enclosure has above-mentioned gas barrier layer, substrate layer, the outer surface side for being set to the substrate layer Sealer and be set to above-mentioned substrate layer inner surface side hot welding layer.
Preferably, above-mentioned gas barrier layer be set between above-mentioned sealer and above-mentioned substrate layer, above-mentioned substrate layer Between above-mentioned hot welding layer and at least one of between above-mentioned hot welding layer and above-mentioned core material.
Preferably, above-mentioned gas barrier layer is in the vapor deposition layer of metal foil layer, the vapor deposition layer of metal and metal oxide At least one.
It preferably, the use of the metal on above-mentioned gas barrier layer is aluminium.
Preferably, above-mentioned core material is fiber assembly.
Preferably, above-mentioned core material is mineral wool.
Preferably, has the adsorbent of adsorption moisture, above-mentioned core material and above-mentioned adsorbent are coated by above-mentioned enclosure.
Hot box involved in the utility model, has: outer container;Interior case is configured at the inside of above-mentioned outer container;And such as Upper above-mentioned Vacuumed insulation panel, is configured between above-mentioned outer container and above-mentioned interior case.
Vacuumed insulation panel involved in the utility model has barrier layer for gases in the core material covering portion of enclosure.Therefore, The external intrusion that Vacuumed insulation panel involved in the utility model can reduce the gases such as vapor and air from enclosure is outer The situation of the inside of parcel post can maintain for a long time the pyroconductivity of the central portion of Vacuumed insulation panel low.In addition, the utility model institute The Vacuumed insulation panel being related to does not have barrier layer for gases in the range in addition to core material covering portion.Therefore, involved by the utility model And Vacuumed insulation panel can reduce enclosure the range in addition to core material covering portion pyroconductivity, additionally it is possible to maintain effective Pyroconductivity is low.Therefore, Vacuumed insulation panel involved in the utility model can maintain high heat-proof quality for a long time.
Detailed description of the invention
Fig. 1 is the cross-sectional view for indicating the brief configuration of Vacuumed insulation panel involved in the embodiments of the present invention 1.
Fig. 2 is to indicate the non-covering portion of bending core material in the Vacuumed insulation panel involved in the embodiments of the present invention 1 State cross-sectional view.
Fig. 3 is the cross-sectional view for indicating the brief configuration of hot box involved in the embodiments of the present invention 2.
Specific embodiment
Embodiment 1.
Fig. 1 is the cross-sectional view for indicating the brief configuration of Vacuumed insulation panel involved in the embodiments of the present invention 1.It is right For the Vacuumed insulation panel 1 shown in FIG. 1, the up and down direction of paper is thickness direction, that is, heat-insulated direction.In addition, in Fig. 1, In order to be easy observation attached drawing, the hatching of the substrate layer 42 of enclosure 4 is omitted.
Hereinafter, being illustrated according to Fig. 1 to Vacuumed insulation panel 1 involved in present embodiment 1.In addition, including Fig. 1 In attached drawing below inside, there is a situation where that relationship and shape of the size of each component parts etc. are different from practical structures. Specific size of each component parts etc. should be judged on the basis of reference the following description.
As shown in Figure 1, Vacuumed insulation panel 1 is to realize the heat-insulated of low pyroconductivity by the way that inside is maintained vacuum Part.The Vacuumed insulation panel 1 has core material 2 and coats the enclosure 4 of the core material 2.As described later, the vacuum as defined in enclosure 4 Space is by inciting somebody to action in the state that the inside of the enclosure 4 of the bag shape to a part opening is depressurized by heat-sealing etc. Opening portion thermal welding and formed.That is, the inside of enclosure 4 is in decompression state.Vacuumed insulation panel 1 is along the Vacuumed insulation panel It is whole that there is generally rectangular flat shape when the observation of the arrow Z-direction of 1 thickness direction that is, Fig. 1.In addition, at this In embodiment 1, Vacuumed insulation panel 1 is also equipped with the adsorbent 3 of the moisture inside absorption enclosure 4.That is, 1 institute of present embodiment The core material 2 and adsorbent 3 for the Vacuumed insulation panel 1 being related to are outsourced the cladding of part 4.
Core material 2 is to keep the purpose of vacuum space to be used.As core material 2, generally using fiber assemblies such as mineral wools. In addition, the fiber assembly for constituting core material 2 can be the structure for carrying out heating press molding, it is also possible to carry out using interior parcel post The structure of sealing can also be the structure being bonded with adhesive.
Adsorbent 3 is inhibited in pyroconductivity with keeping vacuum degree by the vapor inside absorption Vacuumed insulation panel 1 The purpose risen is used.As adsorbent 3, generally calcium oxide (CaO) is used.In addition, adsorbent 3 is also possible to silica gel or boiling Stone.In addition, adsorbent 3 can also combine at least two in calcium oxide, silica gel and zeolite.
In addition, adsorbent 3 can also be packed by the packaging material with aeration.Packaging material with aeration is by selecting It is constituted from the material with aeration in paper, non-woven fabrics, plastic foil and cancellous cloth.It is packed and is adsorbed using packaging material Agent 3, thus, it is possible to expect the raising of the workability when the inside of enclosure 4 configures adsorbent 3.Packaging material can be stacking Two or more components in the above-mentioned component with aeration.
Enclosure 4 is the stacked film to form the multi-ply construction for being laminated with multilayer.Enclosure 4 involved in present embodiment 1 It stacks gradually sealer 41, substrate layer 42, barrier layer for gases 44 and hot welding layer 43 and constitutes.With hot welding layer 43 that This opposed mode is covered core material 2 and adsorbent 3 by 2 enclosures 4 in the way of clamping, and core material 2 with And the peripheral side of adsorbent 3 by heat-sealing etc. by the thermal welding each other of hot welding layer 43, and form sealing 43a, thus enclosure 4 Coat core material 2 and adsorbent 3.At this point, the space between the inside of enclosure 4 i.e. 2 enclosure 4 is in and is depressurized as 1Pa The state of the vacuum degree of (Pascal)~3Pa or so.
Here, in the Vacuumed insulation panel 1 involved in present embodiment 1, as shown in Figure 1, enclosure 4 is right with core material 2 The range set has two faces opposed on the thickness direction of heat-insulated direction that is, Vacuumed insulation panel 1.Two faces are in Fig. 1 Refer to the face of upper surface and lower surface.Above-mentioned two face actual disposition is parallel.In present embodiment 1, by the structure of enclosure 4 Core material covering portion 5 is defined as at the part in above-mentioned two face.A side (such as upper surface of Fig. 1) in above-mentioned two face is and height The opposed face of the heat source of warm side or space.In addition, another party (such as lower surface of Fig. 1) in above-mentioned two face is and low temperature side The opposed face of heat source or space.In other words, the composition in the part opposed with core material 2 in enclosure 4 and heat-insulated direction That is, the range in the orthogonal face of thickness direction of Vacuumed insulation panel 1 becomes core material covering portion 5.In addition, by removing in enclosure 4 Range other than core material covering portion 5 is defined as the non-covering portion 6 of core material.That is, in the part opposed with core material 2 in enclosure 4 The range for constituting the face (side of Fig. 1) for connecting two faces for becoming core material covering portion 5 is the non-covering portion 6 of core material.Separately Outside, the sealing 43a of enclosure 4 is the non-covering portion 6 of core material.In the case where being defined in this way, involved by present embodiment 1 And Vacuumed insulation panel 1 only in core material covering portion 5, there are barrier layer for gases 44.Here, described above for as core material covering portion 5 Two faces be configured in parallel, but it is mentioned here in parallel do not imply that it is parallel under stricti jurise.Even because of vacuum heat-insulation The fabrication error of part 1 and lead to above-mentioned two face slightly askew opposed situation, it is also referred to as parallel in present embodiment 1.
In addition, barrier layer for gases 44 is set between substrate layer 42 and hot welding layer 43 in present embodiment 1.However, The allocation position of barrier layer for gases 44 is not limited to the position.For example, it is also possible to sealer 41 and substrate layer 42 it Between or hot welding layer 43 and core material 2 between be arranged barrier layer for gases 44.Alternatively, it is also possible to which multi-layer gas barrier layer 44 is arranged.? In this case, between sealer 41 and substrate layer 42, between substrate layer 42 and hot welding layer 43 and hot welding layer In between 43 and core material 2 at least two between be arranged barrier layer for gases 44.That is, vacuum involved in present embodiment 1 Thermal insulator 1 is between sealer 41 and substrate layer 42, between substrate layer 42 and hot welding layer 43 and hot welding layer 43 Barrier layer for gases 44 is set between at least one of between core material 2.
Sealer 41 protects the surface of Vacuumed insulation panel 1, is set to the outer surface side of substrate layer 42.Sealer 41 film thickness is 25 μm etc..In addition, the material of sealer 41 is the thermoplastic that fusing point is 150 DEG C or more and traumatic resistance is excellent Property resin etc..For example, the material as sealer 41, is able to use the drawing polyamides such as tensile nylon, is poly- to benzene Naphthalate and oriented polypropylene etc..Sometimes tensile nylon is referred to as ONY, polyethylene terephthalate letter Referred to as PET, oriented polypropylene are referred to as OPP.
The excellent thermoplastic resin of the materials'use paracentesis resistance of substrate layer 42.Substrate layer 42 is by such thermoplastic Property resin single layer formed or formed by thermoplastic resin as laminated multi-layer.For example, substrate layer 42 is, for example, by film thickness 24 μm of single layer is formed.In addition, such as substrate layer 42 is formed by the way that the layer that two layers of film thickness is, for example, 12 μm is laminated.Substrate layer 42 Materials'use polyethylene terephthalate, ethylene-vinyl alcohol or their combination etc..Sometimes ethylene-vinyl alcohol letter Referred to as EVOH.
Hot welding layer 43 is set to the inner surface side of substrate layer 42.The film thickness of hot welding layer 43 is 30 μm etc., hot welding layer 43 film thickness of sealing 43a for being fused to each other and being formed are 60 μm etc..As hot welding layer 43, such as use low density polyethylene Alkene, straight-chain low density polyethylene (LDPE) etc..If elasticity modulus height, the excellent high density polyethylene (HDPE) of blocking property of vapor or without drawing Stretched polypropylene is more preferably.Sometimes low density polyethylene (LDPE) is referred to as LDPE, and straight-chain low density polyethylene (LDPE) is referred to as LLDPE, highly dense Degree polyethylene is referred to as HDPE, and tensionless winkler foundation polypropylene is referred to as CPP.In addition, in the following description, above-mentioned abbreviation, which is recorded in, to be included In arc.
Barrier layer for gases 44 reduces the external inside that invades enclosure 4 of the gases such as vapor and air from enclosure 4 (i.e. space between 2 enclosures 4).The material of barrier layer for gases 44 metal excellent for the blocking property of vapor and air Vapor deposition at least one of the layer and the vapor deposition layer of metal oxide of layers of foil, metal.Use the gold in the barrier layer for gases 44 Belong to for example, aluminium etc..For example, if aluminium foil layer, then film thickness is 6 μm etc., and if aluminium-vapour deposition layer, then film thickness is 40nm etc..Layer is deposited Aluminium oxide or silica etc. can be used.
Next, being illustrated to the manufacturing process of Vacuumed insulation panel 1 involved in present embodiment 1.
In the manufacturing process of Vacuumed insulation panel 1 involved in present embodiment 1, firstly, 2 enclosures 4 are overlapped into Hot welding layer 43 is opposed.Moreover, be fused to each other the hot welding layer 43 of the peripheral part in addition to a part by heat-sealing etc., and Sealing 43a is formed in the position.Enclosure 4 becomes the bag shape of a part opening of peripheral part as a result,.
Then, it is inserted into core material 2 in the inside for the enclosure 4 for being formed as bag shape, it is 2 small heats them at 100 DEG C When.Moisture is removed from core material 2 and enclosure 4 as a result,.Next, by adsorbent 3 be configured at core material 2 and enclosure 4 it Between.Moreover, the vacuum degree of the inner pressure relief of enclosure 4 to 1Pa~3Pa or so is passed through heat-sealing etc. under this reduced pressure condition By opening portion welding, sealing 43a is formed, reduced pressure sealing is carried out to the inside of enclosure 4.
Furthermore, it is possible to which an enclosure 4, which is bent into hot welding layer 43, is configured inside, and enclosure 4 is formed as into bag Shape.As long as reduced pressure sealing can be carried out to core material 2 and adsorbent 3, the number of enclosure 4 is not limited.
Fig. 2 is to indicate the non-covering portion of bending core material in the Vacuumed insulation panel involved in the embodiments of the present invention 1 State cross-sectional view.The Fig. 2 is same as Fig. 1, and the up and down direction of paper is thickness direction, that is, heat-insulated side of Vacuumed insulation panel 1 To.In addition, in order to be easy observation attached drawing, omitting the hatching of the substrate layer 42 of enclosure 4 in Fig. 2.
By heat-sealing etc. by opening portion welding, sealing 43a is formed, and reduced pressure sealing is carried out to the inside of enclosure 4 Later, by the non-covering portion 6 of the core material of enclosure 4 along the shape bending of core material 2.Even Vacuumed insulation panel 1 and foaming is poly- as a result, The case where urethane thermal insulator uses simultaneously can also prevent the non-covering portion 6 of core material from blocking the filling stream of polyurathamc thermal insulator Road, it can be ensured that the filling flow path of polyurathamc thermal insulator.
The Vacuumed insulation panel 1 obtained via the above process enclosure 4 core material covering portion 5 there are barrier layer for gases 44, Thus, it is possible to reduce the external inside that invades enclosure 4 of the gases such as vapor and air from enclosure 4, can tie up for a long time The pyroconductivity for holding the central portion of Vacuumed insulation panel 1 is low.In addition, Vacuumed insulation panel 1 is hindered in the non-covering portion 6 of core material without gas Barrier 44.In more detail, in the non-covering portion 6 of core material, there is only the resins that pyroconductivity is less than barrier layer for gases 44.Therefore, very Empty thermal insulator 1 can reduce the pyroconductivity of the non-covering portion 6 of core material, and effective thermal conductivity also can maintain low.Therefore, vacuum every Warmware 1 can maintain high heat-proof quality for a long time.
Next, the Vacuumed insulation panel 1 of present embodiment 1 is made as 1~embodiment of embodiment 3, and carried out with than Compared with the comparison of 1~comparative example of example 3.Its comparison result is illustrated below.
[embodiment 1]
In embodiment 1, the incrementss of the pyroconductivity of Vacuumed insulation panel 1 and the relationship of barrier layer for gases 44 are carried out Investigation.Vacuumed insulation panel 1 involved in embodiment 1 is with flowering structure.Core material 2 is made of mineral wool.Adsorbent 3 is aoxidized by 50g Calcium (CaO) is constituted.The sealer 41 of enclosure 4 is made of 25 μm of film thickness of tensile nylon (ONY).The substrate of enclosure 4 Layer 42 is made of 12 μm of film thickness of polyethylene terephthalate (PET) and 12 μm of film thickness of ethylene-vinyl alcohol (EVOH).Outside The hot welding layer 43 of parcel post 4 is made of 30 μm of film thickness of straight-chain low density polyethylene (LDPE) (LLDPE).Exist only in core material covering portion The barrier layer for gases 44 of 5 enclosure 4 is configured to 6 μm of film thickness of aluminium foil layer.Moreover, using enclosure 4 coat core material 2 and Adsorbent 3 has made Vacuumed insulation panel 1 involved in embodiment 1.
The size of Vacuumed insulation panel 1 is thickness 20mm, width 500mm, length 1500mm.In addition, the thickness of Vacuumed insulation panel 1 Degree 20mm refers to include core material non-cladding in the state of the core material of the shape bending enclosure 4 along core material 2 non-covering portion 6 The thickness of Vacuumed insulation panel 1 including portion 6 is the size indicated in Fig. 2 with T.In addition, the width 500mm of Vacuumed insulation panel 1 Refer in the state of covering portion 6 non-along the core material of the shape bending enclosure 4 of core material 2 including the non-covering portion 6 of core material Vacuumed insulation panel 1 width, be the size indicated in Fig. 2 with W.In addition, the length 1500mm of Vacuumed insulation panel 1 refers on edge Vacuum in the state of the non-covering portion 6 of core material of the shape bending enclosure 4 of core material 2 including the non-covering portion 6 of core material every The length of warmware 1 is the size of the Vacuumed insulation panel 1 including the non-covering portion 6 of core material on the paper orthogonal direction of Fig. 2.
Moreover, to production 1 day after embodiment 1 involved in Vacuumed insulation panel 1 central portion pyroconductivity in gas The center of Vacuumed insulation panel 1 involved in embodiment 1 after being taken care of 30 days under 25 DEG C of temperature, the environment of relative humidity 60% The pyroconductivity in portion is measured, their difference is calculated as to the incrementss of pyroconductivity.
Wherein, the pyroconductivity of the central portion of Vacuumed insulation panel 1 refer to along heat-insulated direction that is, thickness direction observation it is true Pyroconductivity when empty thermal insulator 1 as the central portion position of Vacuumed insulation panel 1.In the following description, referred to as vacuum every In the case where the pyroconductivity of the central portion of warmware, become when indicating along heat-insulated direction that is, thickness direction observation Vacuumed insulation panel The pyroconductivity of the position of the central portion of Vacuumed insulation panel.
The gas of Vacuumed insulation panel 1 involved in embodiment 1 is set to using not having in the Vacuumed insulation panel in comparative example 1 Body barrier layer 44.The other structures of Vacuumed insulation panel involved in comparative example 1 and 1 phase of Vacuumed insulation panel involved in embodiment 1 Together.It is same as Vacuumed insulation panel 1 involved in embodiment 1, even if in the Vacuumed insulation panel involved in comparative example 1, also to system The pyroconductivity of the central portion of Vacuumed insulation panel after making 1 day is protected under the environment of 25 DEG C of temperature, relative humidity 60% The pyroconductivity of the central portion of Vacuumed insulation panel after pipe 30 days is measured, their difference is calculated as to the increasing of pyroconductivity Dosage.
Table 1 is involved by pyroconductivity and comparative example 1 to the central portion in Vacuumed insulation panel 1 involved in embodiment 1 Vacuumed insulation panel in central portion the result that compares of pyroconductivity.
[table 1]
As shown in table 1, involved in the embodiment 1 for Vacuumed insulation panel 1, the heat of the central portion after production 1 day is passed Conductance is 1.8mW/ (mK), and the incrementss of the pyroconductivity of the central portion after production 30 days are 0.3mW/ (mK).
In contrast, involved in the comparative example 1 for Vacuumed insulation panel, the heat transfer of the central portion after production 1 day Rate is 2.0mW/ (mK), and the incrementss of the pyroconductivity of the central portion after production 30 days are 2.4mW/ (mK).
That is, being made 1 day compared with the Vacuumed insulation panel involved in the comparative example 1 of Vacuumed insulation panel 1 involved in embodiment 1 The pyroconductivity of central portion afterwards is low 0.2mW/ (mK), and the incrementss of the pyroconductivity of the central portion after production 30 days are low 2.1mW/ (mK).
In this way, there is barrier layer for gases 44 by the core material covering portion 5 in enclosure 4, so as to remain true for a long time The pyroconductivity of the central portion of empty thermal insulator 1 is low.
[embodiment 2]
In example 2, the pyroconductivity to the non-covering portion of core material 6 and the relationship of effective thermal conductivity are investigated. The barrier layer for gases 44 that Vacuumed insulation panel 1 involved in embodiment 2 is configured to exist only in the enclosure 4 of core material covering portion 5 is The aluminium-vapour deposition layer of film thickness 40nm.Vacuum involved in the other structures Yu embodiment 1 of Vacuumed insulation panel 1 involved in embodiment 2 Thermal insulator 1 is identical.
Moreover, in the Vacuumed insulation panel 1 involved in embodiment 2, the core material of pyroconductivity and enclosure 4 to central portion The pyroconductivity of non-covering portion 6 is measured, and calculates effective thermal conductivity.Wherein, the pyroconductivity of the non-covering portion 6 of core material It is to be measured in the sealing 43a of enclosure 4.
Vacuumed insulation panel involved in comparative example 2 is also provided with barrier layer for gases in the non-covering portion of core material.That is, 2 institute of comparative example The Vacuumed insulation panel being related to is integrally provided with barrier layer for gases throughout enclosure.Vacuumed insulation panel involved in comparative example 2 Other structures are identical as Vacuumed insulation panel 1 involved in embodiment 2.In addition, Vacuumed insulation panel involved in comparative example 2 prepares Two kinds.Vacuumed insulation panel involved in the first comparative example 2 is configured to The aluminium foil layer that 6 μm of film thickness.Vacuumed insulation panel involved in second of comparative example 2 is configured to the gas of the whole installation throughout enclosure Body barrier layer is the aluminium-vapour deposition layer of film thickness 40nm.
Moreover, in each Vacuumed insulation panel involved in comparative example 2, the core material of pyroconductivity and enclosure to central portion The pyroconductivity of non-covering portion is measured, and calculates effective thermal conductivity.Wherein, the pyroconductivity of the non-covering portion of core material is It is measured in the sealing of enclosure.
Table 2 is to each true involved in the effective thermal conductivity of Vacuumed insulation panel 1 involved in embodiment 2 and comparative example 2 The result that the effective thermal conductivity of empty thermal insulator compares.
Wherein, the perimeter of Vacuumed insulation panel shown in table 2 is acquired by following formula (2).
The perimeter of Vacuumed insulation panel=(width+Vacuumed insulation panel length of Vacuumed insulation panel) × 2 ... (2)
In addition, the area of Vacuumed insulation panel shown in table 2 is acquired by following formula (3).
Area=Vacuumed insulation panel width × Vacuumed insulation panel length ... (3) of Vacuumed insulation panel
In addition, the effective thermal conductivity of Vacuumed insulation panel shown in table 2 is acquired by above-mentioned formula (1).
[table 2]
As shown in table 2, for each vacuum heat-insulation involved in Vacuumed insulation panel 1 involved in embodiment 2 and comparative example 2 For part, the pyroconductivity of the central portion after production 1 day is 1.8mW/ (mK), is identical value.
In addition, the heat of the non-covering portion 6 of the core material of enclosure 4 passes for the Vacuumed insulation panel 1 involved in the embodiment 2 Conductance is 1.0mW/ (mK), and effective thermal conductivity is 1.9mW/ (mK).
In contrast, involved in the comparative example 2 of the barrier layer for gases with aluminium foil layer for Vacuumed insulation panel, outside The pyroconductivity of the non-covering portion of the core material of parcel post is 17.0mW/ (mK), and effective thermal conductivity is 3.6mW/ (mK).In addition, For the Vacuumed insulation panel involved in the comparative example 2 of the barrier layer for gases with aluminium-vapour deposition layer, the core material non-packet of enclosure The pyroconductivity for covering portion is 7.0mW/ (mK), and effective thermal conductivity is 2.5mW/ (mK).
That is, only Vacuumed insulation panel 1 involved in the embodiment 2 in core material covering portion 5 there are barrier layer for gases 44 with spread Vacuumed insulation panel involved in the comparative example 2 for being integrally provided with barrier layer for gases of enclosure is compared, and effective thermal conductivity can Low 0.6mW/ (mK)~1.7mW/ (mK).
[embodiment 3]
Vacuumed insulation panel 1 involved in embodiment 3 be by Vacuumed insulation panel 1 involved in embodiment 2 25 DEG C of temperature, 30 days Vacuumed insulation panels have been taken care of under the environment of relative humidity 60%.The Vacuumed insulation panel 1 involved in embodiment 3 In, the pyroconductivity of the pyroconductivity of central portion and the non-covering portion 6 of the core material of enclosure 4 is measured, and calculates effectively Pyroconductivity.
In addition, Vacuumed insulation panel involved in comparative example 3 is by each Vacuumed insulation panel involved in comparative example 2 in temperature 25 DEG C, 30 days Vacuumed insulation panels have been taken care of under the environment of relative humidity 60%.Each vacuum heat-insulation involved in comparative example 3 In part, the pyroconductivity of the non-covering portion of core material of pyroconductivity and enclosure to central portion is measured, and is calculated effectively Pyroconductivity.
Table 3 is to each true involved in the effective thermal conductivity of Vacuumed insulation panel 1 involved in embodiment 3 and comparative example 3 The result that the effective thermal conductivity of empty thermal insulator compares.In other words, table 3 is to involved by the embodiment 2 after production 30 days And Vacuumed insulation panel 1 effective thermal conductivity with production 30 days after comparative example 2 involved in each Vacuumed insulation panel it is effective The result that pyroconductivity compares.
[table 3]
As shown in table 3, compared with the Vacuumed insulation panel involved in the comparative example 3 of Vacuumed insulation panel 1 involved in embodiment 3, High 0.2mW/ (the mK)~0.3mW/ (mK) of the pyroconductivity of central portion after production 30 days.However, involved by embodiment 3 And the Vacuumed insulation panel involved in the comparative example 3 of Vacuumed insulation panel 1 compared with, the effective thermal conductivity after production 30 days can Low 0.4mW/ (mK)~1.4mW/ (mK).
More than, Vacuumed insulation panel 1 involved in present embodiment 1 has core material 2 and coats the enclosure 4 of core material 2, outside The inside of parcel post 4 is in decompression state.Moreover, enclosure 4 is the stacked film with barrier layer for gases 44, barrier layer for gases 44 is only It is present in core material covering portion 5.Vacuumed insulation panel 1 involved in present embodiment 1 is due to having gas barrier in core material covering portion 5 Layer 44, it is thus possible to reduce feelings of the gases such as vapor and air from the external inside for invading enclosure 4 of enclosure 4 Condition can maintain for a long time the pyroconductivity of the central portion of Vacuumed insulation panel 1 low.In addition, vacuum involved in present embodiment 1 every Range of the warmware 1 other than core material covering portion 5 does not have barrier layer for gases 44.Therefore, vacuum involved in present embodiment 1 every Warmware 1 can reduce the pyroconductivity of the non-covering portion 6 of core material, and effective thermal conductivity also can maintain low.Therefore, present embodiment Vacuumed insulation panel 1 involved in 1 can maintain high heat-proof quality for a long time.
In addition, Vacuumed insulation panel 1 involved in the utility model is not limited to structure shown in present embodiment 1, Various modifications are able to carry out, structure shown in present embodiment 1 and variation can be combined with each other to implement.
For example, instantiating the drying of the core material 2 in manufacturing process and enclosure 4 at 100 DEG C in present embodiment 1 The case where being carried out by heat treatment in 2 hours down, but the temperature heated and time, as long as core material 2 can be removed And temperature and the time of the moisture of enclosure 4, it's not limited to that.In addition, the drying of core material 2 and enclosure 4 is in benefit Carried out in the state of having coated core material 2 with enclosure 4, but can also the drying for having carried out core material 2 and enclosure 4 respectively it Afterwards, core material 2 is coated using enclosure 4.In addition, in the manufacturing process of Vacuumed insulation panel 1 involved in present embodiment 1, Adsorbent 3 is configured between core material 2 and enclosure 4 after core material 2 and enclosure 4 are dry, but can also in core material 2 and Adsorbent 3 is configured before enclosure 4 is dry.
Embodiment 2.
In present embodiment 2, to an example for having the hot box of Vacuumed insulation panel 1 involved in embodiment 1 It is illustrated.In addition, in present embodiment 2, it is identical as embodiment 1 in the project not described especially, for identical function Energy, structure, are described using identical appended drawing reference.
Fig. 3 is the cross-sectional view for indicating the brief configuration of hot box involved in the embodiments of the present invention 2.Hot box 100 such as using in the refrigerator for requiring high heat-proof quality.
As shown in figure 3, hot box 100 has the interior case 110 of outer container 120 with the inside for being configured at the outer container 120.Moreover, Configured with the Vacuumed insulation panel 1 illustrated in the embodiment 1 between interior case 110 and outer container 120, in interior case 110 and outer container 120 Between be thermally shielded.
For the position that Vacuumed insulation panel 1 configures, as long as the position that can be thermally shielded between interior case 110 and outer container 120 It sets, is just not particularly limited.For example, it is also possible to which Vacuumed insulation panel 1 is configured to and the face opposed with outer container 120 in interior case 110 Contact.In addition, for example, it is also possible to Vacuumed insulation panel 1 is configured to and the face contact opposed with interior case 110 in outer container 120.Separately Outside, for example, it is also possible to which spacer etc. is arranged between interior case 110 or outer container 120 and Vacuumed insulation panel 1, and make interior case 110 and Outer container 120 and the discontiguous mode of Vacuumed insulation panel 1, the space configuration Vacuumed insulation panel between interior case 110 and outer container 120.
Here, Vacuumed insulation panel 1 has the heat-proof quality more contour than polyurathamc thermal insulator 130.Therefore, has vacuum The hot box 100 of thermal insulator 1 obtains the heat-proof quality higher than the hot box that polyurathamc thermal insulator is used only.However, can also To be partially filled with polyurathamc thermal insulator in addition to Vacuumed insulation panel 1 in the space between interior case 110 and outer container 120 130。
In addition, in the above description, with use the part illustration omitted that is equal in the hot box of general refrigerator etc. with And explanation.
More than, hot box 100 involved in present embodiment 2 is provided with the low Vacuumed insulation panel 1 of effective thermal conductivity.By This, the pyroconductivity between interior case 110 and outer container 120 maintains low state, it is thus possible to maintain the thermal insulation of hot box 100 It can be high.For example, consumption electric power can be reduced in refrigerator for having hot box 100 etc..
In addition, having enumerated used in the hot box 100 for the refrigerator for having cold source as an example in present embodiment 2 The structure of Vacuumed insulation panel 1, but the utility model is not limited thereto.For example, Vacuumed insulation panel 1, which can also use, is having heat The hot box of the incubator in source.In addition, for example, Vacuumed insulation panel 1, which can also use, is not having the heat-insulated of cold source and heat source Case such as refrigerator etc..In addition, Vacuumed insulation panel 1 acts not only as hot box use, it is empty to can also be used as air conditioner, vehicle The cool equipments such as tune machine and water heater or the heat insulating member of hot equipment use.Alternatively, it is also possible to use vacuum in heat-insulated container etc. Thermal insulator 1.In addition, the shape of Vacuumed insulation panel 1 is also not limited to above-mentioned writing board shape.For example, it is also possible to by Vacuumed insulation panel 1 The upside or downside be formed as into Fig. 1 becomes convex curve form.In addition, can also for example have the outer bag that can be deformed And the insulated bag of inner bag uses Vacuumed insulation panel 1.
Description of symbols:
1... Vacuumed insulation panel;2... core material;3... adsorbent;4... enclosure;41... sealer; 42... Substrate layer;43... hot welding layer;43a... sealing;44... barrier layer for gases;5... core material covering portion;6... core material non-packet Cover portion;100... hot box;110... interior case;120... outer container;130... polyurathamc thermal insulator.

Claims (38)

1. a kind of Vacuumed insulation panel has core material and coats the enclosure of the core material, the inside of the enclosure, which is in, to be subtracted Pressure condition,
The Vacuumed insulation panel is characterized in that,
The enclosure is the stacked film with barrier layer for gases,
The enclosure has two opposed on the thickness direction of the Vacuumed insulation panel in the range opposed with the core material Face,
In the case where the part in the composition of the enclosure two faces is defined as core material covering portion,
The barrier layer for gases exists only in the core material covering portion,
In the case where the range in addition to the core material covering portion in the enclosure is defined as the non-covering portion of core material,
The non-covering portion of core material is bent over along the shape of the core material.
2. Vacuumed insulation panel according to claim 1, which is characterized in that
The enclosure have the barrier layer for gases, substrate layer, be set to the substrate layer outer surface side sealer, And it is set to the hot welding layer of the inner surface side of the substrate layer.
3. Vacuumed insulation panel according to claim 2, which is characterized in that
The barrier layer for gases is set between the sealer and the substrate layer, the substrate layer and the thermal welding Between layer and at least one of between the hot welding layer and the core material.
4. Vacuumed insulation panel described in any one of claim 1 to 3, which is characterized in that
The barrier layer for gases is vapor deposition at least one of the layer and the vapor deposition layer of metal oxide of metal foil layer, metal.
5. Vacuumed insulation panel according to claim 4, which is characterized in that
It the use of the metal in the barrier layer for gases is aluminium.
6. Vacuumed insulation panel described in any one of claim 1 to 3, which is characterized in that
The core material is fiber assembly.
7. Vacuumed insulation panel according to claim 4, which is characterized in that
The core material is fiber assembly.
8. Vacuumed insulation panel according to claim 5, which is characterized in that
The core material is fiber assembly.
9. Vacuumed insulation panel according to claim 6, which is characterized in that
The core material is mineral wool.
10. Vacuumed insulation panel according to claim 7, which is characterized in that
The core material is mineral wool.
11. Vacuumed insulation panel according to claim 8, which is characterized in that
The core material is mineral wool.
12. Vacuumed insulation panel described in any one of claim 1 to 3, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
13. Vacuumed insulation panel according to claim 4, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
14. Vacuumed insulation panel according to claim 5, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
15. Vacuumed insulation panel according to claim 6, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
16. Vacuumed insulation panel according to claim 7, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
17. Vacuumed insulation panel according to claim 8, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
18. Vacuumed insulation panel according to claim 9, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
19. Vacuumed insulation panel according to claim 10, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
20. Vacuumed insulation panel according to claim 11, which is characterized in that
Have the adsorbent of adsorption moisture,
The core material and the adsorbent are coated by the enclosure.
21. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel according to any one of claims 1 to 3 is configured between the outer container and the interior case.
22. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel as claimed in claim 4 is configured between the outer container and the interior case.
23. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 5 is configured between the outer container and the interior case.
24. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel as claimed in claim 6 is configured between the outer container and the interior case.
25. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel as claimed in claim 7 is configured between the outer container and the interior case.
26. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel according to any one of claims 8 is configured between the outer container and the interior case.
27. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel as claimed in claim 9 is configured between the outer container and the interior case.
28. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in any one of claim 10 is configured between the outer container and the interior case.
29. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 11 is configured between the outer container and the interior case.
30. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 12 is configured between the outer container and the interior case.
31. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 13 is configured between the outer container and the interior case.
32. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 14 is configured between the outer container and the interior case.
33. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 15 is configured between the outer container and the interior case.
34. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 16 is configured between the outer container and the interior case.
35. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 17 is configured between the outer container and the interior case.
36. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 18 is configured between the outer container and the interior case.
37. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 19 is configured between the outer container and the interior case.
38. a kind of hot box, which is characterized in that have:
Outer container;
Interior case is configured at the inside of the outer container;And
Vacuumed insulation panel described in claim 20 is configured between the outer container and the interior case.
CN201690000817.1U 2016-09-02 2016-09-02 Vacuumed insulation panel and hot box Expired - Fee Related CN208727515U (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/JP2016/075755 WO2018042612A1 (en) 2016-09-02 2016-09-02 Vacuum heat insulating material and heat insulating box

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Publication Number Publication Date
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CN (1) CN208727515U (en)
WO (1) WO2018042612A1 (en)

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JPS60142928U (en) * 1984-03-06 1985-09-21 藤森工業株式会社 Packaging material for insulation materials
JPH0462379A (en) * 1990-06-29 1992-02-27 Hitachi Ltd Heat-insulated box
JPH05272864A (en) * 1992-03-27 1993-10-22 Sharp Corp Vacuum heat-insulating panel
JP2010031958A (en) * 2008-07-29 2010-02-12 Panasonic Corp Vacuum heat insulation material
JP5517150B2 (en) * 2009-11-20 2014-06-11 東洋アルミニウム株式会社 Vacuum insulation panel packaging material and vacuum insulation panel
JP2015104704A (en) * 2013-11-29 2015-06-08 三星電子株式会社Samsung Electronics Co.,Ltd. Particulate adsorbent
KR101808897B1 (en) * 2014-01-27 2017-12-13 (주)엘지하우시스 Vacuum insulation panel and the method of manufacturing the same
KR20150106306A (en) * 2014-03-11 2015-09-21 삼성전자주식회사 Vacuum heat insulating material and refrigerator including the same
JP6333085B2 (en) * 2014-06-26 2018-05-30 三菱電機株式会社 Method for forming fiber assembly, and method for manufacturing fiber assembly, vacuum heat insulating material, and heat insulation box
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Granted publication date: 20190412