CN208270900U - A kind of electrochromic device - Google Patents

A kind of electrochromic device Download PDF

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Publication number
CN208270900U
CN208270900U CN201821039654.5U CN201821039654U CN208270900U CN 208270900 U CN208270900 U CN 208270900U CN 201821039654 U CN201821039654 U CN 201821039654U CN 208270900 U CN208270900 U CN 208270900U
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layer
electrochromic device
dielectric layer
transparent substrate
conductive layer
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CN201821039654.5U
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潘瑞
周伟杰
冯毅
段成兵
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Truly Opto Electronics Ltd
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Truly Opto Electronics Ltd
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Abstract

The utility model discloses a kind of electrochromic devices, including the first transparent substrate, the first conductive layer, electrochromic layer, the second conductive layer and the second transparent substrate set gradually;Wherein, dielectric layer is additionally provided between the first transparent substrate and the first conductive layer, dielectric layer is the changed film layer of the curve of spectrum for making the visible light through dielectric layer.Electrochromic device in the utility model can be realized each electrochromic device and different colors be presented, and user is allow to meet the visual enjoyment of user and the requirement of personalization according to the color of the hobby selection electrochromic device of oneself.

Description

A kind of electrochromic device
Technical field
The utility model relates to electrochromic device fields, more particularly to a kind of electrochromic device.
Background technique
Electrochromism refers to the optical properties of material, i.e., reflectivity, transmitance, absorptivity etc. are under the action of extra electric field Color change there is a phenomenon where stablizing, reversible shows as the reversible change of color and transparency in appearance.Electrochromism device Part is using device made of electrochromic material, and there are commonly automobile anti-dazzle back vision mirror, display, light-sensitive sunglasses, discoloration doors Window and Electronic Paper etc..
For current electrochromic device, the color presented is often determined by the color of electrochromic material, Color is single, is unsatisfactory for requirement of the user to various electrochromic device personalizations.
Utility model content
The purpose of the utility model is to provide a kind of electrochromic device, solve that electrochromic device color is single to ask Topic, meets demand of the user to electrochromic device color personalization.
In order to solve the above technical problems, the utility model provides a kind of electrochromic device, comprising:
The first transparent substrate, the first conductive layer, electrochromic layer, the second conductive layer and the second transparent base set gradually Plate;
Wherein, dielectric layer is additionally provided between first transparent substrate and second conductive layer, the dielectric layer is Make the changed film layer of the curve of spectrum of the visible light through the dielectric layer.
Wherein, the dielectric layer is antireflective coating.
Wherein, the dielectric layer is the film layer with conducting function.
Wherein, the dielectric layer includes stratified film.
Wherein, the dielectric layer includes one or more layers film layer in SiO2 layers, TiO2 layers, Nb2O5 layers, MgF2 layers.
Wherein, first transparent substrate and second transparent substrate are glass substrate.
It wherein, further include the adhesion layer being arranged between the dielectric layer and first transparent substrate.
Wherein, the adhesion layer is third conductive layer, and first conductive layer, second conductive layer and described the Three conductive layers are ito thin film layer.
Electrochromic device provided by the utility model is provided with Jie between the first transparent substrate and the first conductive layer Matter layer, and the dielectric layer can make the curve of spectrum of the visible light through dielectric layer change, and finally change through medium The color of the visible light of layer, and electrochromic layer is equally the component that can change light color, then incident electrochromism device For the light of part through in dielectric layer and electrochromic layer back reflection to the sight of human eye, color observed by human eye is by electroluminescent change The color that chromatograph and dielectric layer show the neutralization of light.So for each electrochromic device, medium Layer and electrochromic layer can make electrochromic device show a kind of color, for multiple electrochromic devices, each The dielectric layer of electrochromic device can be different to the Color influences of light, to realize that multiple electrochromic devices can Different colours are presented.And the color after light reflection is only determined by electrochromic layer in the prior art, so that color category is more It is single.
Therefore, the electrochromic device in the utility model can be realized each electrochromic device and different face be presented Color allows user to meet visual enjoyment and the personalization of user according to the color of the hobby selection electrochromic device of oneself Requirement.
Detailed description of the invention
For the clearer technical solution for illustrating the utility model embodiment or the prior art, below will to embodiment or Attached drawing needed to be used in the description of the prior art is briefly described, it should be apparent that, the accompanying drawings in the following description is only Some embodiments of the utility model, for those of ordinary skill in the art, without creative efforts, It is also possible to obtain other drawings based on these drawings.
Fig. 1 is the schematic diagram of the section structure of electrochromic device provided by the utility model embodiment;
Fig. 2 provides the schematic diagram of the section structure of electrochromic device by another embodiment of the utility model.
Specific embodiment
In order to make those skilled in the art better understand the scheme of the utility model, with reference to the accompanying drawing and specific implementation The utility model is described in further detail for mode.Obviously, described embodiment is only the utility model a part Embodiment, instead of all the embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not doing Every other embodiment obtained under the premise of creative work out, fall within the protection scope of the utility model.
As shown in Figure 1, for the schematic diagram of the section structure of electrochromic device provided by the utility model embodiment, the electricity Mutagens color device includes:
The first transparent substrate 1, the first conductive layer 2, electrochromic layer 3, the second conductive layer 4 and second set gradually is saturating Bright substrate 5.
Specifically, electroluminescent for automobile anti-dazzle back vision mirror, display, light-sensitive sunglasses, discoloration door and window and Electronic Paper etc. Electrochromic device, the first transparent substrate 1 and the second transparent substrate 5 may each be glass substrate, but in the utility model also not Exclude the substrate using transparent resin material.
The electrochromic layer 3 specifically, can be the EC liquid being packaged between the first conductive layer 2 and the second conductive layer 4, should First conductive layer 2 and the second conductive layer 4 specifically can be ITO conductive layer.Certainly, the electrochromic layer 3 in the utility model It is also possible to other similar electrochromic material to be formed by;Similarly, the first conductive layer 2 and the second conductive layer 4 also not only limit In ITO conductive layer, this is not being enumerated.
Wherein, it is additionally provided with dielectric layer 6 between the first transparent substrate 1 and electrochromic layer 3, which is that can make The changed film layer of the curve of spectrum of visible light.It is to be understood that when light is by a kind of medium incident to another medium, Its reflectivity and transmissivity be it is corresponding, the light of a certain wavelength, transmissivity is higher, then reflectivity is also lower, Conversely, its reflectivity is higher, transmissivity is also lower.The main function of the utility model dielectric layer 6 is exactly to improve to need electricity The transmissivity for the light color that mutagens color device is presented, and reduce the transmissivity of other light.
It should be noted that can be luminous ray for electrochromic device transmitted through electrochromic device and enter people Eye and the color, such as electrochromism door and window, light-sensitive sunglasses etc. observed, it is seen that the light of light is from the incidence of the first glass substrate Across electrochromic layer, second glass substrate etc., finally it is incident in human eye realization;It is also possible to this device of Antiglaring rear mirror Part, also needs to be arranged between the second conductive layer 4 and the second transparent substrate 5 reflecting layer, and eye-observation to light be from One transparent substrate 1 is incident to pass through the transmission such as dielectric layer 6, electrochromic layer 3, reaches reflecting layer back reflection, again passes through electroluminescent change Human eye is incident to after the transmission such as chromatograph 3, dielectric layer 6, first transparent substrate 1.Therefore the light that user finally observes may be The light of transmission is also likely to be the light of reflection.
For user observe be transmitted ray electrochromic device, when dielectric layer 6 is to the transmissivity of a certain light It is higher, such as red light, and it is relatively high to the reflectivity of other colors of visible light.So eventually pass through electrochromic device Biggish light intensity is exactly red light, in the adjustment effect for passing through electrochromism liquid, is by the received light liquid of human eye institute Red light partially.
For user observe be reflection light electrochromic device, when dielectric layer 6 is to the transmissivity of red light When higher, and it is higher to the reflectivity of other colors of visible light, then the transmissivity of only red light is higher, and to visible The reflectivity of other colors of light is relatively high, and only red light all has biggish transmission when passing through dielectric layer 6 twice Rate, then final eye-observation to light be also red light light intensity it is maximum, final light color seen by person It also can be partially red.
Optionally, the dielectric layer 6 in the utility model can be using with made by coloured transparent material, such as Similar to materials such as blue crystal, amethysts, not only with color but also being capable of light transmission.
Electrochromic device provided by the utility model can be directed to the different demand of user, in electrochromic device The middle a variety of different dielectric layers of setting, dielectric layer and electrochromic layer collective effect, so that each with different dielectric layers Different colors is presented in electrochromic device.Blue or blackish green single is only presented in middle electrochromic layer compared with the existing technology The color of color, the electrochromic device in the utility model is more rich and varied, meets user to the individual character of electrochromic layer The demand of change.
Based on the above embodiment, in the utility model another specific embodiment, dielectric layer 6 can be antireflective coating.
For example, the thickness of the anti-reflection film is equal to red light in a quarter of anti-reflection film medium wavelength, then in this layer The red light that the two sides of film reflect back will interfere, to cancel out each other, according to the conservation of energy, this Shu Hongguang is Completely extend across the antireflective coating, that is to say, that the transmissivity of red light nearly reaches absolutely, and other light is saturating Penetrating rate opposite can then weaken.
Optionally, the dielectric layer 6 in the utility model can be a tunic layer and be also possible to what stratified film was composed Film layer.When using multiple film layers composition dielectric layer 6, the thickness and type of film layer can be selected according to actual needs.It is different Influence of the film layer of type to the reflectivity of visible light is different, and the film layer of one species different-thickness is to each of visible light The reflectivity and transmissivity of the pipeline of a wave band are also different.
Certainly, it if necessary to which multiple color is presented on electrochromic device surface, can also be spliced into using multiple film layers The dielectric layer 6 of one entirety, to not specifically described in this utility model.
Optionally, the utility model dielectric layer 6 specifically can be the film that the Coating Materials of nonmetallic compound is formed Layer, such as SiO2Layer, TiO2Layer, Nb2O5Layer, MgF2One of layer or a variety of film layers.
Optionally, in the another specific embodiment of the utility model, it is contemplated that when electrochromic layer 3 works normally, It needs to be powered to the first conductive layer 2 and the second conductive layer 4, it, can in order to enable electrochromic layer 3 that there is better working effect Dielectric layer 6 to be used to the film layer with conducting function.
It, can also be in dielectric layer 6 and in the another specific embodiment of the utility model based on above-mentioned any embodiment Adhesion layer is set between one transparent substrate 1, with the tightness degree connected between amplified medium layer 6 and the first transparent substrate 1.
Optionally, which can be conductive layer, and the conductive layer can be ITO conductive layer, can be effectively reduced whole The manufacturing cost of a electrochromic device.
Based on above-mentioned any embodiment, in the another specific embodiment of the utility model, which be can refer to Fig. 2 is specifically included:
The first transparent substrate 1, third conductive layer 7, dielectric layer 6, the first conductive layer 2, the electrochromic layer, set gradually Two conductive layers 4, buffer layer 8, reflecting layer 9, prime coat 10, the second transparent substrate 5.
Wherein, the first transparent substrate 1 and the second transparent substrate 5 are glass substrate;First conductive layer 2, the second conductive layer 4 It is ITO conductive layer with third conductive layer;Electrochromic layer includes annular glue frame 31 and the EC liquid 32 for being packaged in glue frame inner ring;It is slow Rushing layer 8 is in order to avoid the contact of the EC liquid 32 of reflecting layer 9 and electrochromic layer, and EC liquid 32 pollutes reflecting layer 9.Dielectric layer 6 be the film layer that can change the reflectance spectrum curve of the incident visible light of the first transparent substrate 1.
Electrochromic device provided in the present embodiment, be user observe be reflection light electrochromic device A kind of specific embodiment, specifically can be applied to the equipment such as Antiglaring rear mirror, display screen.It can select according to actual needs Dielectric layer 6 and electrochromic layer collective effect is adjusted to the color of electrochromic device in different dielectric layers 6, can Meets the needs of user is to different electrochromic device personalization colors.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with it is other The difference of embodiment, same or similar part may refer to each other between each embodiment.For being filled disclosed in embodiment For setting.
Electrochromic device provided by the utility model is described in detail above.It is used herein specifically a Example is expounded the principles of the present invention and embodiment, this reality that the above embodiments are only used to help understand With novel method and its core concept.It should be pointed out that for those skilled in the art, not departing from this Under the premise of utility model principle, several improvements and modifications can be made to this utility model, these improvement and modification are also fallen Enter in the protection scope of the utility model claims.

Claims (8)

1. a kind of electrochromic device, which is characterized in that including the first transparent substrate, the first conductive layer, electroluminescent set gradually Photochromic layer, the second conductive layer and the second transparent substrate;
Wherein, dielectric layer is additionally provided between first transparent substrate and first conductive layer, the dielectric layer is to make Cross the changed film layer of the curve of spectrum of the visible light of the dielectric layer.
2. electrochromic device according to claim 1, which is characterized in that the dielectric layer is antireflective coating.
3. electrochromic device according to claim 1, which is characterized in that the dielectric layer is the film with conducting function Layer.
4. electrochromic device according to claim 1, which is characterized in that the dielectric layer includes stratified film.
5. electrochromic device according to claim 1, which is characterized in that the dielectric layer includes SiO2Layer, TiO2Layer, Nb2O5Layer, MgF2One or more layers film layer in layer.
6. electrochromic device according to claim 1, which is characterized in that first transparent substrate and described second is thoroughly Bright substrate is glass substrate.
7. electrochromic device according to any one of claims 1 to 6, which is characterized in that further include that setting is being given an account of Adhesion layer between matter layer and first transparent substrate.
8. electrochromic device according to claim 7, which is characterized in that the adhesion layer is third conductive layer, and institute Stating the first conductive layer, second conductive layer and the third conductive layer is ito thin film layer.
CN201821039654.5U 2018-06-29 2018-06-29 A kind of electrochromic device Active CN208270900U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109782506A (en) * 2019-01-10 2019-05-21 上海理工大学 A kind of optically-variable glass and optically-variable suspension display device
CN110196524A (en) * 2019-05-30 2019-09-03 Oppo广东移动通信有限公司 Electrochromic device and preparation method thereof, electronic equipment
CN110471231A (en) * 2019-08-21 2019-11-19 Oppo广东移动通信有限公司 Housing unit and electronic equipment
CN111609381A (en) * 2019-02-25 2020-09-01 南昌光谷光电工业研究院有限公司 Application method of electrochromic material in lighting lamp
TWI737010B (en) * 2019-10-21 2021-08-21 欣興電子股份有限公司 Electrochromic mirror module

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109782506A (en) * 2019-01-10 2019-05-21 上海理工大学 A kind of optically-variable glass and optically-variable suspension display device
CN109782506B (en) * 2019-01-10 2021-08-03 上海理工大学 Optically variable glass and optically variable suspension display device
CN111609381A (en) * 2019-02-25 2020-09-01 南昌光谷光电工业研究院有限公司 Application method of electrochromic material in lighting lamp
CN110196524A (en) * 2019-05-30 2019-09-03 Oppo广东移动通信有限公司 Electrochromic device and preparation method thereof, electronic equipment
CN110471231A (en) * 2019-08-21 2019-11-19 Oppo广东移动通信有限公司 Housing unit and electronic equipment
TWI737010B (en) * 2019-10-21 2021-08-21 欣興電子股份有限公司 Electrochromic mirror module
US11472344B2 (en) 2019-10-21 2022-10-18 Unimicron Technology Corp. Electrochromic mirror module

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