CN208226051U - A kind of fuel cell for adding metal fuel - Google Patents

A kind of fuel cell for adding metal fuel Download PDF

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Publication number
CN208226051U
CN208226051U CN201820726602.9U CN201820726602U CN208226051U CN 208226051 U CN208226051 U CN 208226051U CN 201820726602 U CN201820726602 U CN 201820726602U CN 208226051 U CN208226051 U CN 208226051U
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China
Prior art keywords
metal
battery
fuel cell
electrode
fuel
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CN201820726602.9U
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Chinese (zh)
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易祖成
许煌
吴辉
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Hunan Yuanda New Materials Co Ltd
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Hunan Yuanda New Materials Co Ltd
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Abstract

The utility model provides a kind of fuel cell that can add metal fuel, including Battery case and battery component, battery component is located in Battery case, battery component includes: electrolyte, metal electrode, air electrode and diaphragm, metal electrode, air electrode and diaphragm are immersed in electrolyte, and metal electrode includes metal mesh, and the aluminum material being contained in metal mesh, air electrode is set at least side of Battery case inner wall, and diaphragm is between metal electrode and air electrode.Fuel cell provided by the utility model, electrode material can be supplemented according to service condition, eliminate the inconvenience that multiple person cooperational is needed when the replacement of traditional aluminium-air cell electrode material, battery structure is compact, ingenious in design simultaneously, air electrode is close to cabinet wall, space is saved, battery volume is reduced.

Description

A kind of fuel cell for adding metal fuel
Technical field
The utility model belongs to field of batteries, and in particular to one kind can add the fuel cell of metal fuel.
Background technique
Battery is one of most common article in life, and currently used is lead-acid accumulator and lithium battery, and lithium battery holds Amount is big, and energy density is high, memory-less effect, but higher cost, battery management are complex;Lead-acid battery is low in cost, but energy Metric density is lower, and weight is big, there is memory effect, needs certain maintenance and the service life is shorter, while being also easy to pollute. The theoretical specific energy of aluminium-air-fuel battery has at low cost, specific energy density and specific power density high up to 8100Wh/kg The advantages that, as a kind of special fuel cell, aluminium-air cell is in military, civilian and water-bed dynamical system, telecommunications system The application aspects such as backup power source and portable power of uniting have huge business potential.
It is not big enough using alkaline solution and existing power to solve the electrolyte in existing metal-air battery, make With, maintenance is more troublesome the problems such as, CN101090168 discloses a kind of salt battery, includes shell in the salt battery of the invention Body, electrolyte, metal electrode and air electrode, offer one or more windows on shell, and air electrode is mounted on The container for accommodating electrolyte is constituted at window and together with shell, metal electrode is magnesium alloy or electron pole, electricity Solution liquid is neutral electrolyte, such as sodium chloride solution and seawater, air electrode by electroplate conductive copper silk screen, be attached to copper The oxyphie material layer of silk screen two sides and the waterproof ventilated membrane being attached in the oxyphie material layer of inside composition, the salt water The duration of power supply of battery is long, high-efficient, and the neutral electrolytes such as common salt water, seawater can be used, so working service is convenient, Pollution will not be generated, however the water battery aluminum substrate is easy failure, and conductive copper silk screen is at high cost, cell output is paid no attention to Think, affects practicability.CN2377685 discloses a kind of salt battery between primary battery and battery, this battery Do not need charging equipment, generated electrolyte is free from environmental pollution, can in a dry environment long-term preservation it is spare, with battery It compares, the salt battery is small in size, light-weight, non-corrosive, long service life, anode plate is only needed to change, with dry cell It compares, expense reduces 70%, in non-transformer, 6W compact electric apparatus below can be driven, however the salt battery Cathode plate is made of electrically conductive graphite, and aluminium anodes plate is with high costs using magnesium metal, and the electrical power of battery is lower.
Existing aluminium-air cell is substantially a kind of chemical reaction equipment for discharging electric energy, cannot charge, need repeatedly Replacement aluminium electrode can just work on, and in real work, replacement aluminium electrode, which usually requires multiple person cooperational, to be completed, time-consuming to take Power.Therefore, it is necessary to develop a kind of new battery, keep the replacement of aluminium electrode more convenient, or even can be as automobile fuel filler Realize the replacement of aluminium electrode.
Utility model content
To solve problems of the prior art, the purpose of the utility model is to provide one kind can add metal fuel Fuel cell.
To achieve the above object, the utility model uses following technical scheme:
A kind of fuel cell for adding metal fuel, including
Battery case,
Battery component, the battery component are located in Battery case;
The battery component includes:
Electrolyte, metal electrode, air electrode and diaphragm, the metal electrode, air electrode and diaphragm are immersed in electrolysis In liquid;
The metal electrode includes metal mesh, and the aluminum material being contained in metal mesh;
The air electrode is set at least side of Battery case inner wall;
The diaphragm is between metal electrode and air electrode.
Preferably, the fuel cell further includes battery box cover, and the battery box cover and Battery case removable seal connect It connects.
Preferably, the aluminum material is at least one of sheet, bulk and strip fine aluminium.
Preferably, the aluminum material is at least one of sheet, bulk and strip aluminium alloy.
Preferably, the aluminum material is the pure aluminum or aluminum alloy of graininess, and the partial size of the pure aluminum or aluminum alloy of graininess is big Small is 0.5~5mm.
Preferably, the air electrode includes Catalytic Layer, conductive mesh and waterproof layer.
It is further preferred that the Catalytic Layer includes the component of following parts by weight:
20~30 parts of active carbon,
10~20 parts of conductive black,
20~30 parts of catalyst,
20~30 parts of binder.
It is further preferred that the conductive mesh is one of nickel screen, copper mesh, nickel plating copper mesh and nickel foam.
It is further preferred that the waterproof layer includes the component of following parts by weight:
30~60 parts of conductive black,
40~70 parts of binder.
It is further preferred that the binder is PTFE or PE.
Preferably, the metal mesh be copper mesh, tin plating copper mesh, tin plating stainless (steel) wire, lead plating stainless (steel) wire and cadmium plating not Become rusty one of steel mesh.
Preferably, the diaphragm is PP film or PE film.
Preferably, the electrolyte is one of neutral electrolyte, alkaline electrolyte or organic electrolyte.
It is further preferred that the alkaline electrolyte is the hydroxide solution of alkali metal, the organic electrolyte is six Lithium fluophosphate solution, hexafluorophosphoric acid sodium solution or hexafluorophosphoric acid potassium solution.
The beneficial effects of the utility model
1, fuel cell provided by the utility model can supplement electrode material according to service condition, eliminate conventional aluminum- Air cell electrode material needs the inconvenience of multiple person cooperational when replacing;
2, fuel cell provided by the utility model, compact-sized, ingenious in design, air electrode is close to cabinet wall, section Space has been saved, battery volume is reduced.
Detailed description of the invention
Fig. 1 is the battery structure cross-sectional view that aluminum alloy anode material is graininess aluminium alloy;
Fig. 2 is the battery structure cross-sectional view that aluminum alloy anode material is blocky aluminium alloy.
Specific embodiment
Specific embodiment of the utility model below, and be described with reference to the drawings to the technical solution of the utility model make into The description of one step, but the utility model is not limited to these examples.
Embodiment 1
As shown in Figure 1, a kind of fuel cell that can add metal fuel, including Battery case 1, battery component, battery pack Part is located in Battery case 1, and battery component includes electrolyte, be immersed in metal electrode 2 in electrolyte, air electrode 3 and every Film 4, metal electrode 2 include metal mesh 5 and the aluminum material 6 being contained in metal mesh, and aluminum material 6 is graininess aluminium alloy, empty Pneumoelectric pole 3 is set at least side of 1 inner wall of Battery case, and diaphragm 4 is between metal electrode 2 and air electrode 3.
Fuel cell can be connect with external battery case lid, battery box cover with Battery case removable seal.
Air electrode 3 includes Catalytic Layer and conductive mesh waterproof layer.
Metal mesh 5 is copper mesh.
Diaphragm 4 is PP film.
Electrolyte is neutral electrolyte.
After a period of use, electrode material can be consumed existing fuel cell, need to dismantle spiral shell when replacing battery Silk, electrode plate is taken out, heavy workload, and do not embody " fuel cell " well to add the concept of fuel, especially It is the battery on bus, and when disassembly needs more than the ten people cooperation that cooperates that could complete.In the utility model, aluminum material is Granular pure aluminum or aluminum alloy, particle size is 0.5~5mm, instead of the plate structure in existing fuel cell, with material It uses and consumes, particle can become smaller, and top particle can sink, and directly add from top when requiring supplementation with, and realize true Fuel is added in positive meaning, the pure aluminum or aluminum alloy service efficiency of graininess is also higher.
Embodiment 2
The fuel cell structure of the present embodiment is same as Example 1, the difference is that metal mesh 5 is tin plating copper mesh.Every Film 4 is PE film.Electrolyte is alkaline electrolyte, specially the hydroxide solution of alkali metal.
Embodiment 3
The fuel cell structure of the present embodiment is same as Example 1, the difference is that metal mesh 5 is cadmium plating stainless steel Net.Diaphragm 4 is PP film.Electrolyte is organic electrolyte, specially hexafluorophosphoric acid sodium solution.
Embodiment 4
As shown in Fig. 2, a kind of fuel cell that can add metal fuel, including Battery case 1, battery component, battery pack Part is located in Battery case 1, and battery component includes electrolyte, be immersed in metal electrode 2 in electrolyte, air electrode 3 and every Film 4, metal electrode 2 include metal mesh 5 and the aluminum material 6 being contained in metal mesh, and aluminum material 6 is blocky aluminium alloy, air Electrode 3 is set at least side of 1 inner wall of Battery case, and diaphragm 4 is between metal electrode 2 and air electrode 3.
Fuel cell can be connect with external battery case lid, battery box cover with Battery case removable seal.
Air electrode 3 includes Catalytic Layer and conductive mesh waterproof layer.
Metal mesh 5 is copper mesh.
Diaphragm 4 is PP film.
Electrolyte is organic electrolyte, specially lithium hexafluorophosphate solution.

Claims (8)

1. the fuel cell that one kind can add metal fuel, which is characterized in that including
Battery case,
Battery component, the battery component are located in Battery case;
The battery component includes:
Electrolyte, metal electrode, air electrode and diaphragm, the metal electrode, air electrode and diaphragm are immersed in electrolyte;
The metal electrode includes metal mesh, and the aluminum material being contained in metal mesh;
The air electrode is set at least side of Battery case inner wall;
The diaphragm is between metal electrode and air electrode.
2. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the fuel cell also wraps Battery box cover is included, the battery box cover is connect with Battery case removable seal.
3. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the aluminum material is piece At least one of shape, bulk and strip fine aluminium.
4. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the aluminum material is piece At least one of shape, bulk and strip aluminium alloy.
5. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the aluminum material is particle The pure aluminum or aluminum alloy of shape, the particle size of the pure aluminum or aluminum alloy of graininess are 0.5~5mm.
6. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the air electrode includes Catalytic Layer and conductive mesh waterproof layer.
7. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the metal mesh is copper wire One of net, tin plating copper mesh, tin plating stainless (steel) wire, lead plating stainless (steel) wire and cadmium plating stainless (steel) wire.
8. the fuel cell according to claim 1 for adding metal fuel, which is characterized in that the diaphragm be PP film or PE film.
CN201820726602.9U 2018-05-16 2018-05-16 A kind of fuel cell for adding metal fuel Active CN208226051U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201820726602.9U CN208226051U (en) 2018-05-16 2018-05-16 A kind of fuel cell for adding metal fuel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201820726602.9U CN208226051U (en) 2018-05-16 2018-05-16 A kind of fuel cell for adding metal fuel

Publications (1)

Publication Number Publication Date
CN208226051U true CN208226051U (en) 2018-12-11

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108666716A (en) * 2018-05-16 2018-10-16 湖南源达新材料有限公司 A kind of fuel cell for adding metal fuel

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108666716A (en) * 2018-05-16 2018-10-16 湖南源达新材料有限公司 A kind of fuel cell for adding metal fuel

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