CN105006600A - Magnesium alloy storage battery - Google Patents
Magnesium alloy storage battery Download PDFInfo
- Publication number
- CN105006600A CN105006600A CN201510450995.6A CN201510450995A CN105006600A CN 105006600 A CN105006600 A CN 105006600A CN 201510450995 A CN201510450995 A CN 201510450995A CN 105006600 A CN105006600 A CN 105006600A
- Authority
- CN
- China
- Prior art keywords
- battery
- magnesium alloy
- storage battery
- alloy storage
- magnesium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/24—Alkaline accumulators
- H01M10/28—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
- H01M4/46—Alloys based on magnesium or aluminium
- H01M4/466—Magnesium based
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
The invention discloses a magnesium alloy storage battery which comprises a battery shell, partition layers and an upper cover. The interior of the battery shell is divided into a plurality of reaction chambers. Each reaction chamber is covered with the corresponding partition layer which is provided with a plurality of water inlets. The upper cover is matched with the battery shell and provided with a water injecting hole. In each reaction chamber, a tinplate sheet is placed on one side of the reaction chamber to serve as a battery cathode, the surface of the tinplate sheet is wrapped by a conductive electrode film, a magnesium plate is placed on the other side of the reaction chamber to serve as a battery anode, the surface of the magnesium plate is wrapped by glass fiber partition plate paper, and the space between the cathode and the anode is filled with a cathode powder material which is then compacted. Each reaction chamber serves as an independent battery. The cathode plates and the anode plates of the reaction chambers are connected with one another in series or in parallel through conductive rods, and therefore the requirements of different output voltages and different output currents can be met. As a storage type battery, the magnesium alloy storage battery has the storage life of 20 years or more; the magnesium alloy storage battery can be used by injecting clean water or other liquid through the water injecting hole before use and activating the magnesium alloy storage battery for 1 min, and the working voltage is quite stable.
Description
Technical field
The present invention relates to storage battery, especially a kind of reserve cell.
Background technology
Commercially available storage battery generally in the market is lead acid accumulator.The advantage of lead acid accumulator is technology maturation, can uses by recharge.But lead acid accumulator uses lead and plumbous oxide to make electrode, and sulfuric acid solution makes electrolyte, severe contamination soil and water resources after battery is discarded is very large to environmental disruption; Plumbous density is very large, and the weight of intermediate size (100AH) lead acid accumulator can reach 30kg, cannot carry with use; The life-span of lead acid accumulator is generally 5 years, this makes in some application, such as the lead acid accumulator of communication base station power-off stand-by power supply, often spending 5 years must all change once, wherein most of lead acid accumulator may never be previously used, cause great waste, and the manpower and materials changed spent by a time by the storage battery of all base stations in city proper and suburb are also considerable.
Summary of the invention
The object of the invention is to overcome above-mentioned mentioned problem, provide long, the environmental protection of a kind of storage time and light storage battery.The technical solution used in the present invention is as follows:
A kind of magnesium alloy storage battery, comprising: battery container, interlayer and upper cover.Be separated into several reative cells in described battery container, in each reative cell, be placed with anode and battery cathode; All be coated with described interlayer on each reative cell, described interlayer is provided with several inlet openings; Described upper cover and described battery container match, and are covered with water injection hole on described.
Described anode is tinplate sheet, its Surface coating conductive electrode film.
Described battery cathode is magnesium plate, its Surface coating glass fibre separator paper.
Space positive mix between described anode and battery cathode is filled and compacting.
Described magnesium plate is pure magnesium plate, AZ31 magnesium alloy plate, AZ91 magnesium alloy plate etc.
Described positive mix is by MnO
2, acetylene black, crystalline flake graphite, NaCl be formulated, weight ratio is 85: 7.5: 7.5: 15.
Beneficial effect of the present invention:
A kind of magnesium alloy storage battery of the present invention is as a kind of reserve cell; In battery container can according to capacitance need be separated into several reative cells, each reative cell is an independently battery, and reative cell is more, and battery capacity is larger, and the requirement of different output voltage, electric current is met by the series and parallel of reacting chamber space, be equivalent to form battery pack; By the water injection hole injected clear water of upper cover before using, clear water flows through interlayer inlet opening and flows in each reative cell, makes positive mix and battery cathode generation redox reaction, produces electric charge; Positive/negative plate in each reative cell needs to carry out series and parallel with conducting rod depending on use and connects, and be provided with binding post in one end of conducting rod, binding post stretches out outside upper cover, forms positive pole and negative pole, for being connected with the both positive and negative polarity of electrical appliance.Storage life of the present invention can reach more than 20 years, and operating voltage is very steady.
The present invention is long, the environmental protection of a kind of storage time and light storage battery.The present invention uses magnesium plate to make battery cathode, and tinplate sheet makes anode, and magnesium, iron all do not belong to heavy metal element, and other raw materials used are not also containing poisonous and harmful substance, and using front injected clear water to make cell activation produce electricity, is environmental protection battery; The density of magnesium is 1.74g/cm
3, the density of iron is 7.86g/cm
3, be all significantly less than plumbous density 11.34g/cm
3, significantly reduce battery weight; The present invention can deposit and still can use for more than 20 years under the condition of good seal; this is due to the present invention's only water filling activation before needs use; during daily preservation, inside is in drying regime; positive/negative plate from corrosion reaction speed slowly; therefore the shelf-life is very long; if for communication base station power-off stand-by power supply, greatly the replacement cycle can be extended, save extensive fund.
Accompanying drawing explanation
Fig. 1 is the structural representation of a kind of magnesium alloy storage battery of the present invention;
Fig. 2 is the spacer structure schematic diagram of a kind of magnesium alloy storage battery of the present invention.
Embodiment
Consult Fig. 1 and Fig. 2, a kind of magnesium alloy storage battery of the present invention, comprise battery container 7, interlayer 11 and upper cover 9, upper cover 9 and battery container 7 match, and upper cover 9 is provided with water injection hole 14; Be separated into several reative cells in battery container 7, the anode in each reative cell is tinplate sheet 3, Surface coating conductive electrode film 5; Battery cathode is magnesium plate 4, Surface coating glass fibre separator paper 6, and the positive mix of the space 12 between battery plus-negative plate is filled and compacting, and positive mix is by MnO
2, acetylene black, crystalline flake graphite, NaCl be formulated, weight ratio is 85: 7.5: 7.5: 15; All be coated with interlayer 11 on each reative cell, interlayer 11 is provided with inlet opening 13; Be connected by the anode conducting rod 2 of each reative cell, the battery cathode conducting rod 10 of each reative cell is connected; Be provided with positive terminal 1 in one end of conducting rod 2, one end of conducting rod 10 is provided with negative terminal 8, and positive terminal and negative terminal stretch out outside upper cover 9, for being connected with the both positive and negative polarity of electrical appliance.During use, by water injection hole 14 injected clear water or other liquid of upper cover 9, clear water flows through interlayer 11 inlet opening 13 and flows in each reative cell, makes cell activation produce electricity.
Claims (6)
1. a magnesium alloy storage battery, is characterized in that comprising: battery container, interlayer and upper cover.Be separated into several reative cells in described battery container, in each reative cell, be placed with anode and battery cathode; All be coated with described interlayer on each reative cell, described interlayer is provided with several inlet openings; Described upper cover and described battery container match, and are covered with water injection hole on described.
2. a kind of magnesium alloy storage battery according to claim 1, is characterized in that described anode is tinplate sheet, its Surface coating conductive electrode film.
3. a kind of magnesium alloy storage battery according to claim 1, is characterized in that described battery cathode is magnesium plate, its Surface coating glass fibre separator paper.
4. a kind of magnesium alloy storage battery according to claim 1, is characterized in that the space positive mix between described anode and battery cathode is filled and compacting.
5. a kind of magnesium alloy storage battery according to claim 3, is characterized in that the magnesium plate of described battery cathode is pure magnesium plate, AZ31 magnesium alloy plate, AZ91 magnesium alloy plate etc.
6. a kind of magnesium alloy storage battery according to claim 4, is characterized in that described positive mix is by MnO
2, acetylene black, crystalline flake graphite, NaCl be formulated, weight ratio is 85: 7.5: 7.5: 15.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510450995.6A CN105006600A (en) | 2015-07-15 | 2015-07-15 | Magnesium alloy storage battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510450995.6A CN105006600A (en) | 2015-07-15 | 2015-07-15 | Magnesium alloy storage battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105006600A true CN105006600A (en) | 2015-10-28 |
Family
ID=54379185
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510450995.6A Pending CN105006600A (en) | 2015-07-15 | 2015-07-15 | Magnesium alloy storage battery |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105006600A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106898764A (en) * | 2017-03-28 | 2017-06-27 | 青岛华高墨烯科技股份有限公司 | A kind of Graphene Magnesium sea water battery device |
| KR101876665B1 (en) * | 2017-02-02 | 2018-07-09 | 한국산업기술대학교산학협력단 | Magnesium electrode and magnesium secondary battery and hybrid battery including the same |
| CN108649212A (en) * | 2018-04-13 | 2018-10-12 | 清华大学 | Magnesium-alloy anode material preparation method and device |
| CN110350183A (en) * | 2019-07-22 | 2019-10-18 | 太原科技大学 | A kind of novel magnesium alloy battery |
| CN112002945A (en) * | 2020-10-28 | 2020-11-27 | 深圳市寒暑科技新能源有限公司 | Solid-state flexible battery, preparation method and use method |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1710736A (en) * | 2005-06-28 | 2005-12-21 | 李宏斌 | Primary magnesium-manganese dioxide battery |
| CN201402832Y (en) * | 2009-01-14 | 2010-02-10 | 胡安顺 | Magnesium alloy battery |
| CN101894968A (en) * | 2010-06-30 | 2010-11-24 | 中国电力科学研究院 | Novel battery module |
| CN202178343U (en) * | 2011-08-04 | 2012-03-28 | 深圳市雄韬电源科技股份有限公司 | Unpaired weldment plumbic acid battery pack |
| CN103000855A (en) * | 2012-11-29 | 2013-03-27 | 广州神力能源科技有限公司 | Assembly method of carbon fiber composite storage battery |
| CN103022524A (en) * | 2012-11-28 | 2013-04-03 | 嘉兴中科亚美合金技术有限责任公司 | Water-activated magnesium battery |
| CN103022525A (en) * | 2012-11-28 | 2013-04-03 | 嘉兴中科亚美合金技术有限责任公司 | Magnesium air battery |
| JP2014143191A (en) * | 2012-12-27 | 2014-08-07 | Toyo Eng Works Ltd | Magnesium battery |
| CN104064719A (en) * | 2014-07-01 | 2014-09-24 | 同济汽车设计研究院有限公司 | Car battery module |
-
2015
- 2015-07-15 CN CN201510450995.6A patent/CN105006600A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1710736A (en) * | 2005-06-28 | 2005-12-21 | 李宏斌 | Primary magnesium-manganese dioxide battery |
| CN201402832Y (en) * | 2009-01-14 | 2010-02-10 | 胡安顺 | Magnesium alloy battery |
| CN101894968A (en) * | 2010-06-30 | 2010-11-24 | 中国电力科学研究院 | Novel battery module |
| CN202178343U (en) * | 2011-08-04 | 2012-03-28 | 深圳市雄韬电源科技股份有限公司 | Unpaired weldment plumbic acid battery pack |
| CN103022524A (en) * | 2012-11-28 | 2013-04-03 | 嘉兴中科亚美合金技术有限责任公司 | Water-activated magnesium battery |
| CN103022525A (en) * | 2012-11-28 | 2013-04-03 | 嘉兴中科亚美合金技术有限责任公司 | Magnesium air battery |
| CN103000855A (en) * | 2012-11-29 | 2013-03-27 | 广州神力能源科技有限公司 | Assembly method of carbon fiber composite storage battery |
| JP2014143191A (en) * | 2012-12-27 | 2014-08-07 | Toyo Eng Works Ltd | Magnesium battery |
| CN104064719A (en) * | 2014-07-01 | 2014-09-24 | 同济汽车设计研究院有限公司 | Car battery module |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101876665B1 (en) * | 2017-02-02 | 2018-07-09 | 한국산업기술대학교산학협력단 | Magnesium electrode and magnesium secondary battery and hybrid battery including the same |
| CN106898764A (en) * | 2017-03-28 | 2017-06-27 | 青岛华高墨烯科技股份有限公司 | A kind of Graphene Magnesium sea water battery device |
| CN106898764B (en) * | 2017-03-28 | 2019-06-21 | 青岛华高墨烯科技股份有限公司 | A kind of graphene-Magnesium sea water battery device |
| CN108649212A (en) * | 2018-04-13 | 2018-10-12 | 清华大学 | Magnesium-alloy anode material preparation method and device |
| CN108649212B (en) * | 2018-04-13 | 2020-08-04 | 清华大学 | Preparation method and device of magnesium alloy anode material |
| CN110350183A (en) * | 2019-07-22 | 2019-10-18 | 太原科技大学 | A kind of novel magnesium alloy battery |
| CN112002945A (en) * | 2020-10-28 | 2020-11-27 | 深圳市寒暑科技新能源有限公司 | Solid-state flexible battery, preparation method and use method |
| CN112002945B (en) * | 2020-10-28 | 2021-03-12 | 深圳市寒暑科技新能源有限公司 | Solid-state flexible battery, preparation method and use method |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104885287B (en) | Secondary zinc-manganese dioxide battery for high power applications | |
| CN105742727B (en) | A kind of preparation method of secondary cell, purposes and its cathode | |
| CN105006600A (en) | Magnesium alloy storage battery | |
| JP5956175B2 (en) | Magnesium secondary battery, method of using electrolyte in magnesium secondary battery, and electrolyte for magnesium secondary battery | |
| JP2016535408A (en) | New flow battery and its use | |
| CN105977526A (en) | Rechargeable aluminum carbon battery and preparation method thereof | |
| CN104037458A (en) | Manufacturing method of lithium ion energy storage device | |
| CN101299476A (en) | Zinc-nickel static single fluid flow battery | |
| US20140075745A1 (en) | High Capacity Alkali/Oxidant Battery | |
| CN106972192A (en) | For the method and electrolytic cell device, lithium-ion energy storage device of the prefabricated lithium of lithium-ion energy storage device negative pole | |
| US3625764A (en) | Electrode for electric storage batteries containing zinc halide in aqueous solution, of the type having a soluble cathode and a dissolved anode | |
| US20140038000A1 (en) | Flow-Through Metal Battery with Ion Exchange Membrane | |
| CN107768679A (en) | A kind of composite carbon alloy accumulator production technology and preparation method thereof | |
| KR101599711B1 (en) | Electric double layer device | |
| CN205264826U (en) | Magnesium alloy battery | |
| CN205159472U (en) | Metal -air battery | |
| CN205016632U (en) | Energy storage cell | |
| Nohara et al. | Self-discharge characteristics of an electric double-layer capacitor with polymer hydrogel electrolyte | |
| CN203300769U (en) | Zinc air-powered battery and battery pack | |
| CN109686588B (en) | Super capacitor battery based on seawater electrolyte | |
| CN206040835U (en) | It is two according to applying different level with pressing battery | |
| CN203800138U (en) | Tubular zinc-nickel storage battery | |
| CN204424325U (en) | A kind of battery cover board and the lithium ion battery containing this cover plate | |
| CN104393264B (en) | high-capacity battery and preparation method thereof | |
| CN203521561U (en) | Zinc air-powered battery and zinc air-powered battery pack |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20151028 |
|
| RJ01 | Rejection of invention patent application after publication |