CN208222987U - Device for preparing fluid ice crystals by using L NG cold energy - Google Patents

Device for preparing fluid ice crystals by using L NG cold energy Download PDF

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Publication number
CN208222987U
CN208222987U CN201820434374.8U CN201820434374U CN208222987U CN 208222987 U CN208222987 U CN 208222987U CN 201820434374 U CN201820434374 U CN 201820434374U CN 208222987 U CN208222987 U CN 208222987U
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bed
gas
ice crystal
fluid ice
cold energy
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CN201820434374.8U
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陶汉中
刘士琦
芮磊
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Nanjing Tech University
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Nanjing Tech University
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Abstract

The utility model discloses an utilize L NG cold energy to prepare device of fluid ice crystal, including spraying the bed, the boiling bed, nitrogen gas opens and stops the purge system, vacuum pumping system, tube coupling system and control system, L NG import pipeline and the intercommunication of spraying bed below, it is hollow circular cylinder to spray the bed, upper and lower both ends have the toper head, it is equipped with spraying system to spray the inside top of bed, spraying system top is provided with the gas-solid separator, gas through the gas-solid separator separation rises to the gas vent at spraying bed top, and discharge through the first exhaust pipeline with the gas vent intercommunication, the sub-unit connection of NG return line and boiling bed is passed through to first exhaust pipeline, the NG that lets in the boiling bed among the NG return line, be provided with nitrogen gas on the return line and open the purge system, the utility model discloses ice making is fast, weak point consuming time, output is high, easy control, very big extremely strong electric energy has been saved, the industrialization prospect that has.

Description

A kind of device for producing fluid ice crystal using LNG cold energy
Technical field
The utility model relates to a kind of device for producing fluid ice crystal, more particularly relate to a kind of produce using LNG cold energy The device of fluid ice crystal belongs to comprehensive utilization of energy technical field.
Background technique
Fluid ice crystal is a kind of ice of novel concept different from conventional solid ice, it is a kind of ice of subcircular particle Crystalline substance, both with the characteristic of fluid, available pipe is conveyed, and the characteristic with ice, and cooling fast, latent heat is big.
Fluidic ice crystal phase for traditional snowflake ice because have huge table (contact) area, superpower heat transfer property, The performances such as constant temperature, the very fast cooling of energy and cooling can be kept, in fishery fishing, marine products processing, processing of poultry, fresh-keeping of vegetables, are surpassed The fields such as city is fresh-keeping, (fermentation) industrial technology, ice-storage air-conditioning, artificial snow, downhole cooling have extensive Utilization prospects.
Currently, the manufacturing technology of fluid ice crystal is also a kind of completely new ice making skill different from conventional solid ice manufacturing technology Art.Its principle is that cooling salting liquid reaches certain temperature, and moisture crystallization in solution is made to be precipitated as tiny spherical ice crystal and swim From in solution, to form the ice slurry with mobility, under certain condition, the separation of ice crystal and liquid is realized, thus Form pure solia particle ice crystal.
However the method for using cooling salting liquid manufacture fluidic ice needs to consume a large amount of electric energy, and this method is time-consuming It is long, it is very slow to make fluid speed of icing, it is not easy to control, limits throughput is unfavorable for industrializing.
On the other hand, liquefied natural gas (LNG) is used as a kind of deep cooling (- 162 DEG C) liquid, belongs to high-grade cold source, as clear Clean fuel by gasification and need to be heated to 15 DEG C or more just convenient for utilizing, discharge a large amount of cold energy in the process.
China's ten million ton of natural gas of annual umber of feed inlet, most imports in a manner of liquid shipping, this part number are huge Cold energy be not utilized effectively, except small part is freezed for Air separation industry and icebox, a large amount of cold energy pass through heating of seawater gas Change, not only wastes the energy, and polluted marine environment.
In Chinese national economy, refrigeration industry energy consumption accounts for about social terminal energy ground 10%, and energy consumption and energy-saving potential are huge Greatly, therefore in society it is huge mobile cold source demand to can be convenient to safety, economy.In recent years, it is stored in building energy saving field ice Cold in the ascendant, in summer, ice storage rationally utilizes the electric energy of night power grid electricity consumption trough to make ice, and puts that will save cold energy in the daytime Out.But this method drawback low there is also refrigeration efficiency.
Utility model content
To solve the deficiencies in the prior art, it is released in the process the purpose of this utility model is to provide a kind of using LNG gasification The cold energy put produces the device of fluid ice crystal, and the structure design of the utility model is reasonable, and process is simple, low in cost, produces stream Body ice crystal it is high-efficient.
In order to achieve the above objectives, the utility model adopts the following technical solutions:
A kind of device for producing fluid ice crystal using LNG cold energy produces fluidic ice using the cold energy that LNG gasification process discharges Crystalline substance, device include trickle bed, ebullated bed, nitrogen start and stop purge system, pumped vacuum systems, pipe connection system and control system, Be connected to below LNG inlet ductwork and trickle bed, trickle bed is in hollow cylindrical, and upper and lower ends are with conical head, in trickle bed Spray system is equipped with above portion, such setting may make water directly to contact with LNG, and spray head used in spray system has There is low temperature resistant performance;It is provided with gas-solid separator above spray system, rises to spray by the gas that gas-solid separator separates The exhaust outlet at the top of bed is drenched, and the first exhaust pipeline by being connected to exhaust outlet is discharged, first exhaust pipeline is flowed back by NG The lower part of pipeline and ebullated bed connects, and the NG of ebullated bed is passed through in NG return line, and temperature is controlled at -35 DEG C ~ -50 DEG C.Boiling One end that down-comer is connected at the top of bed is risen, the other end of down-comer is connected to the bottom of trickle bed, sets on NG return line It is equipped with nitrogen start and stop purge system.
Further, first exhaust pipeline is also connected with one end of gas-gas heat exchanger, the other end connection of gas-gas heat exchanger There is second exhaust pipeline, the hot fluid used in gas-gas heat exchanger is normal temperature air or low boiling working fluid, the cold flow used Body is the cold natural gas of first exhaust pipeline discharge, and cold natural gas temperature after exchanging heat reaches room temperature.
Further, second exhaust pipe road is provided with pumped vacuum systems.
Further, the bottom of ebullated bed is connected with fluid ice crystal discharge line, is connected with shunt valve in the middle part of ebullated bed One end, the other end of shunt valve is connected to the middle part of trickle bed, and shunt valve connects ebullated bed and trickle bed, is passed through trickle bed Internal cold NG can help to form one layer of cold NG gas-bearing formation on trickle bed inner wall, and fluid ice crystal is prevented to be pasted onto the wall surface of trickle bed On.
Further, spray system steam-out (SO) inlet ductwork.
Further, control system includes the first control valve being set on fluid ice crystal discharge line, is set to decline The second control valve on pipe, the third control valve being set on NG return line, the 4th control being set in pumped vacuum systems Valve, the 5th control valve for being set to second exhaust pipe road and the 6th control valve being set in LNG inlet ductwork, the first control Valve processed also has tracing system, prevents the control valve in equipment running process from freezing.
On the one hand the utility model has the beneficial effect that the utility model gasifies and returns using liquefied natural gas (LNG) High-grade cold energy is used to produce fluid ice crystal by the cold energy discharged in thermal process, also achieves more low-grade cold energy step benefit With;And the temperature for the fluid ice crystal produced belongs to high-quality cold source between -40 DEG C to -50 DEG C.And due to fluid ice crystal Design feature makes it possible to flowing, greatly facilitates transport and conveying.On the other hand, water by trickle bed directly and gas Change natural gas (NG) contact, water directly mixes from the gaseous natural gas (NG) in spray system ejection and trickle bed and carries out hot friendship It changes, moment can be frozen into ice crystal, icemaking rate is fast, and time-consuming short, yield is high, is easy to control, is greatly saved electric energy, has pole Strong industrial prospect.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of the utility model one embodiment.
In figure: 1- ebullated bed;2- down-comer;3-LNG inlet ductwork;4- steam inlet pipeline;5- spray system;6- gas-solid Separator;7- first exhaust pipeline;8- pumped vacuum systems;9- second exhaust pipeline;10- gas-gas heat exchanger;11- nitrogen start and stop are blown Sweep system;12-NG return line;13- shunt valve;The first return pipe of 14-;15- fluid ice crystal discharge line;16- trickle bed; The first control valve of 17-;The second control valve of 18-;19- third control valve;The 4th control valve of 20-, the 5th control valve of 21-, 22- the 6th Control valve.
Specific embodiment
Specific introduce is made to the utility model below in conjunction with the drawings and specific embodiments.
Embodiment 1
The utility model provides a kind of device that fluid ice crystal is produced using LNG cold energy, utilizes the release of LNG gasification process Cold energy produces fluid ice crystal, and device includes trickle bed 16, ebullated bed 1, nitrogen start and stop purge system 11, pumped vacuum systems 8, pipeline It is connected to below connection system and control system, LNG inlet ductwork 3 and trickle bed 16, trickle bed is in hollow cylindrical, upper and lower ends With conical head, 16 inner upper of trickle bed is equipped with spray system 5, and such setting may make water directly to contact with LNG, and Spray head used in spray system has low temperature resistant performance;Gas-solid separator 6 is provided with above spray system 5, by gas The isolated gas of solid separator 6 rises to the exhaust outlet at the top of trickle bed, and the first exhaust pipeline 7 by being connected to exhaust outlet Discharge, first exhaust pipeline 7 are connect by NG return line 12 with the lower part of ebullated bed 1, are passed through ebullated bed in NG return line NG, temperature control at -35 DEG C ~ -50 DEG C.One end of down-comer 2, the other end of down-comer 2 are connected at the top of ebullated bed It is connected to the bottom of trickle bed 16, nitrogen start and stop purge system 11 is provided on NG return line 12.First exhaust pipeline 7 also connects It is connected to one end of gas-gas heat exchanger 10, the other end of gas-gas heat exchanger 10 is connected with second exhaust pipeline 9, in gas-gas heat exchanger The hot fluid used is normal temperature air or low boiling working fluid, and the cold fluid used is that the cold day of first exhaust pipeline discharge is right Gas, cold natural gas temperature after exchanging heat reach room temperature.Pumped vacuum systems 8 is provided on second exhaust pipeline 9.The bottom of ebullated bed 1 Portion is connected with fluid ice crystal discharge line 15, and the middle part of ebullated bed 1 is connected with one end of shunt valve 13, the other end of shunt valve 13 It is connected to the middle part of trickle bed 16, shunt valve connects ebullated bed and trickle bed, and being passed through the cold NG inside trickle bed can help One layer of cold NG gas-bearing formation is formed on trickle bed inner wall, and fluid ice crystal is prevented to be pasted on the wall surface of trickle bed.The external steaming of spray system Vapor inlet pipeline 4.Control system includes the first control valve 17 being set on fluid ice crystal discharge line 15, is set to down-comer The second control valve 18 on 2, the third control valve 19 being set on NG return line, the 4th control being set in pumped vacuum systems Valve 20, the 5th control valve 21 being set on second exhaust pipeline 9 and the 6th control being set in LNG inlet ductwork 3 processed Valve 22, the first control valve 17 also have tracing system, prevent the control valve in equipment running process from freezing.
The application method of the utility model, including work step and stopping step, work step include the following:
1) open pumped vacuum systems, by trickle bed 16, ebullated bed 1, nitrogen start and stop purge system 11, pipe connection system and Each valve in control system is evacuated to the explosion limit of methane, generally makes volume fraction of the methane in gaseous mixture low In 4.9%;
2) nitrogen start and stop purge system 11 is opened, each pipeline and valve are purged, control purge flow rate is small flow, time root It is determined according to engineering experience;It is then turned off the 5th control valve 21, opens the 6th control valve 22, makes circulation in nitrogen, until bypass After one end temperature that pipe 13 is connected to trickle bed 16 reaches -100 DEG C, nitrogen start and stop purge system 11 is closed;
3) the 6th control valve 22 is opened, so that LNG enters trickle bed 16 from LNG inlet ductwork 3, then turns on spray system 5, with dampening after spraying in spray system, the LNG in trickle bed is contacted with water and the moment that exchanges heat is frozen into fluid ice crystal, fluid Ice crystal is precipitated to trickle bed bottom under the effect of gravity;
4) when being accumulate to fluid ice crystal away from the one third of trickle bed bottom, the second control on down-comer 2 is opened Valve 18, so that fluid ice crystal drains into inside ebullated bed 1 from trickle bed 16 through down-comer 2;
5) temperature that ebullated bed 1 is discharged into the fluid ice crystal of ebullated bed 1, by NG return line 12 is -35 DEG C ~ -55 DEG C NG and LNG exchange heat, LNG carries out gasification boiling, and in addition the NG in ebullated bed 1 is sent through shunt valve to trickle bed, then Gas-gas heat exchanger 10 and NG return line 12 are drained into through first exhaust pipeline 7.
6) NG be discharged into after exchanging heat in gas-gas heat exchanger 10 to room temperature behind second exhaust pipe road 9 opened through the 4th control valve it is defeated It send to user terminal.
7) fluid ice crystal is periodically discharged from the fluid ice crystal discharge line 15 of ebullated bed bottom, is packed into storage facilities.
Stop step include the following:
1) LNG inlet ductwork is closed;
2) when the LNG liquidus of trickle bed bottom reaches the fluid ice crystal ice line of trickle bed, spray system is closed, and open Control valve on steam inlet pipeline 4, until after the residual water in spray system drains, the control in steam off inlet ductwork 4 Valve processed;
3) while opening the control valve on steam inlet pipeline 4, nitrogen start and stop purge system 11 is opened, is this moment small stream Amount is opened, until increasing blowing for nitrogen start and stop purge system after the LNG and fluid ice crystal in trickle bed are fully entered in ebullated bed Sweep flow;
4) after it is water that the fluid ice crystal in fluid ice crystal discharge line 15, which all melts, residual water is drained, and close stream The first control valve 17 on body ice crystal discharge line, during fluid ice crystal discharge stream body ice crystal discharge line 15, heat tracing system It unites always on, prevents the control valve in equipment running process from freezing.
5) nitrogen start and stop purge system is always on, until all control valves are closed after reaching room temperature.
The basic principles and main features and advantage of the utility model have been shown and described above.The technical staff of the industry It should be appreciated that above-described embodiment does not limit the utility model in any form, it is all by the way of equivalent substitution or equivalent transformation Technical solution obtained, all falls in the protection scope of the utility model.

Claims (6)

1. a kind of device for producing fluid ice crystal using LNG cold energy, including trickle bed (16), ebullated bed (1), nitrogen start and stop purging System (11), pumped vacuum systems (8), pipe connection system and control system, it is characterised in that: LNG inlet ductwork (3) and spray Connection below bed (16), trickle bed (16) inner upper are equipped with spray system (5), setting above the spray system (5) There are gas-solid separator (6), rises to the exhaust outlet at the top of trickle bed by the gas that the gas-solid separator (6) separate, and lead to First exhaust pipeline (7) discharge being connected to exhaust outlet is crossed, the first exhaust pipeline (7) passes through NG return line (12) and boiling The lower part connection of bed (1) is risen, one end of down-comer (2), the other end of the down-comer (2) are connected at the top of the ebullated bed It is connected to the bottom of trickle bed (16), is provided with nitrogen start and stop purge system (11) on the NG return line (12).
2. a kind of device for producing fluid ice crystal using LNG cold energy according to claim 1, it is characterised in that: described One gas exhaust piping (7) is also connected with one end of gas-gas heat exchanger (10), and the other end of the gas-gas heat exchanger (10) is connected with Two gas exhaust pipings (9).
3. a kind of device for producing fluid ice crystal using LNG cold energy according to claim 2, it is characterised in that: described Pumped vacuum systems (8) are provided on two gas exhaust pipings (9).
4. a kind of device for producing fluid ice crystal using LNG cold energy according to claim 1, it is characterised in that: the boiling The bottom for rising bed (1) is connected with fluid ice crystal discharge line (15), is connected with shunt valve (13) in the middle part of the ebullated bed (1) The other end of one end, the shunt valve (13) is connected to the middle part of trickle bed (16).
5. a kind of device for producing fluid ice crystal using LNG cold energy according to claim 1, it is characterised in that: the spray Leaching system steam-out (SO) inlet ductwork (4).
6. a kind of device for producing fluid ice crystal using LNG cold energy according to claim 1, it is characterised in that: the control System processed includes the first control valve (17) being set on fluid ice crystal discharge line (15), be set on down-comer (2) the Two control valves (18), the third control valve (19) being set on NG return line, the 4th control being set in pumped vacuum systems Valve (20), the 5th control valve (21) being set on second exhaust pipeline (9) and be set on LNG inlet ductwork (3) Six control valves (22), first control valve (17) also have tracing system.
CN201820434374.8U 2018-03-28 2018-03-28 Device for preparing fluid ice crystals by using L NG cold energy Active CN208222987U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108332507A (en) * 2018-03-28 2018-07-27 南京工业大学 Device and method for preparing fluid ice crystals by using L NG cold energy

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108332507A (en) * 2018-03-28 2018-07-27 南京工业大学 Device and method for preparing fluid ice crystals by using L NG cold energy
CN108332507B (en) * 2018-03-28 2023-07-25 南京工业大学 Device and method for preparing fluid ice crystals by utilizing LNG cold energy

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