CN208087255U - A kind of high-efficiency ammonia-nitrogen deamination apparatus - Google Patents

A kind of high-efficiency ammonia-nitrogen deamination apparatus Download PDF

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Publication number
CN208087255U
CN208087255U CN201820384391.5U CN201820384391U CN208087255U CN 208087255 U CN208087255 U CN 208087255U CN 201820384391 U CN201820384391 U CN 201820384391U CN 208087255 U CN208087255 U CN 208087255U
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Prior art keywords
stripper
ammonia
ammonium hydroxide
nitrogen
caustic soda
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CN201820384391.5U
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金实建
王强
梁震
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JIANGMEN CHANCSUN UMICORE INDUSTRY Co Ltd
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JIANGMEN CHANCSUN UMICORE INDUSTRY Co Ltd
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Abstract

The utility model discloses a kind of high-efficiency ammonia-nitrogen deamination apparatus, including heat exchanger and stripper, the heat exchanger is mounted in stripper bottom, and ammonia nitrogen waste water is connected by waste pipe, the stripper is equipped with caustic soda adding mouth, vapour inlet and bottom of tower water outlet, the caustic soda adding mouth and vapour inlet are separately connected caustic soda adding set and steam pipeline, and the steam pipeline connects steam air source;Include multilayer column plate in the stripper, top is equipped with overhead condenser, and the overhead condenser is connected with return duct and ammonium hydroxide recovery tube, and the return duct is respectively connected to stripper and ammonium hydroxide recycling can with ammonium hydroxide recovery tube.By being that ammonium hydroxide recycling utilizes again by the ammonia condensing in waste water, resource is saved, pollution is reduced, there is significant environmental benefit and economic benefit;It occupies in addition, the utility model effectively reduces equipment investment and place, simplify technological operation, flow is simpler, more convenient operation, does not generate the secondary pollutions such as solid waste or exhaust gas.

Description

A kind of high-efficiency ammonia-nitrogen deamination apparatus
Technical field
The utility model is related to technical field of sewage, more particularly to a kind of processing unit of ammonia nitrogen waste water.
Background technology
Ammonia nitrogen waste water is mainly derived from chemical fertilizer, coking, petrochemical industry, pharmacy, food, refuse landfill etc., a large amount of ammonia nitrogen waste waters It is discharged into water body not only and can cause body eutrophication, cause black and odorous water, the difficulty and added cost of Water purification, or even to people Group and biology generate toxic action, it is therefore desirable to carry out deamination processing to ammonia nitrogen waste water;The ammonia one of existing deamination apparatus separation As directly arrange into air, not only create discarded equal secondary pollutions, also lead to the waste of resource, and equipment investment is larger and field Ground occupancy is more, and technological process is also long, and operation is more inconvenient, and treatment effeciency is also very low.Therefore, it is necessary to the prior art It is transformed and optimizes.
Utility model content
A kind of high-efficiency ammonia-nitrogen deamination processing unit that in order to overcome the deficiencies of the prior art, the utility model provides, To carry out recycling to the ammonia in waste water, deamination treatment effeciency is improved.
Technical solution adopted by the utility model to solve its technical problems is:
A kind of high-efficiency ammonia-nitrogen deamination apparatus, including heat exchanger and stripper, the heat exchanger are mounted in stripper bottom, And ammonia nitrogen waste water is connected by waste pipe, the stripper is equipped with caustic soda adding mouth, vapour inlet and bottom of tower water outlet, described Caustic soda adding mouth and vapour inlet are separately connected caustic soda adding set and steam pipeline, and the steam pipeline connects steam air source; Include multilayer column plate in the stripper, top is equipped with overhead condenser, and the overhead condenser is connected with return duct and ammonia Water recovery tube, the return duct are respectively connected to stripper and ammonium hydroxide recycling can with ammonium hydroxide recovery tube.
Preferably, the caustic soda adding set includes hopper and by motor-driven automatic stirring feed mechanism, described The conveying speed of automatic stirring feed mechanism and the flow of ammonia nitrogen waste water are correspondingly arranged.
Preferably, the waste pipe is equipped with flowmeter, and the motor is connected with frequency converter, the flowmeter and frequency conversion Device signal connects.
Preferably, the overhead condenser includes the cold water pipes of several dense arrangements, and the cold water pipes both ends pass through High-pressure cold water pipe connects water cooling pond and cooling device with cold water recovery tube respectively, and high-pressure cold water is housed on the high-pressure cold water pipe Pump, the cooling device are arranged on water cooling pond.
Preferably, the cooling device includes the cooling tower being arranged on water cooling pond, and cooling is equipped at the top of the cooling tower Wind turbine.
The effective of the utility model be:By using stripper come handle preheated by heat exchanger after enter its in ammonia Nitrogen waste water, under the steam heating being passed through, the ammonia in ammonia nitrogen waste water is evaporated out, the ammonia of gas form upwards with stripper The liquid that last layer column plate flows down establishes vapor liquid equilibrium, and after multiple gas-liquid phase equilibrium, the ammonia density in gas phase is raised to Then design requirement enters overhead condenser by tower top, the concentrated ammonia liquor being fully liquefied, partly from overhead reflux to tower In, remainder is transported in ammonium hydroxide recycling can by ammonium hydroxide recovery tube as product and is stored, to be used in production again In, resource has been saved, it is effective to ensure water outlet ammonia nitrogen stably reaching standard, the secondary pollutions such as solid waste or exhaust gas are not generated, reduce dirt Dye has significant environmental benefit and economic benefit;In addition, the utility model effectively reduce equipment investment and place occupy, Simplify technological operation, flow is simpler, more convenient operation, effectively improves deamination treatment effeciency.
Description of the drawings
Fig. 1 is the layout drawing of the utility model.
Specific implementation mode
The utility model is further illustrated with reference to the accompanying drawings and examples.
Referring to Fig.1, a kind of high-efficiency ammonia-nitrogen deamination apparatus of the utility model, including heat exchanger 1 and stripper 2, institute It states heat exchanger 1 and is mounted in 2 bottom of stripper, and ammonia nitrogen waste water is connected by waste pipe, the stripper 2 is added equipped with caustic soda Mouth, vapour inlet and bottom of tower water outlet, the caustic soda adding mouth and vapour inlet are separately connected caustic soda adding set and steam pipe Road, the steam pipeline connect steam air source;Include multilayer column plate in the stripper 2, top is equipped with overhead condenser 3, The overhead condenser 3 is connected with return duct and ammonium hydroxide recovery tube, and the return duct is respectively connected to strip with ammonium hydroxide recovery tube Tower 2 and ammonium hydroxide recycling can.
The ionization equilibrium of ammonia in water is as follows:
Ammonia i.e. in waste water mainly exists in the form of ammonium ion, when increasing OH- concentration, balances and is moved to the direction for generating NH3 It is dynamic, it is heated by steam, the ammonia in waste water is constantly evaporating, and is detached from from waste water, and balance constantly moves right, final ammonia point It separates out and, and cooling becomes ammonium hydroxide under the action of condensation, be back to production again, and the waste water after deamination then enters follow-up place Science and engineering sequence.The utility model handles the ammonia nitrogen waste water entered by heat exchanger 1 in it by using stripper 2, what is be passed through Under steam heating, the ammonia in ammonia nitrogen waste water is evaporated out, and the ammonia of gas form is flowed down with the last layer column plate of stripper 2 upwards Liquid establish vapor liquid equilibrium, after multiple gas-liquid phase equilibrium, the ammonia density in gas phase is raised to design requirement, then by Tower top enters overhead condenser 3, the concentrated ammonia liquor being fully liquefied, partly from overhead reflux to tower in, remainder conduct Product, which is transported to by ammonium hydroxide recovery tube in ammonium hydroxide recycling can, to be stored, to be used in production again, by actually using, By using the device, the ammonia deviate from waste water need not reuse absorption tower recycling, and can directly generate 18% or more dense ammonia Water carries out reuse, and the ammonia nitrogen concentration in waste water can be reduced to 8mg/L hereinafter, being better than the level-one mark of Water in Guangdong Province disposal of pollutants limit value It is accurate;And the process equipment effectively reduces equipment investment and place occupies, simplifies technological operation, and realize in waste water 99.9% (with influent concentration, processing requirement in relation to) more than ammonia recycled all in the form of ammonium hydroxide, have significant environmental benefit And economic benefit;In addition, while ensureing to be discharged ammonia nitrogen stably reaching standard, there is the device flow to be simple and convenient to operate, equipment Small investment, occupation area of equipment are small, the advantages of not generating the secondary pollutions such as solid waste or exhaust gas, each so as to be widely used in In the ammonia nitrogen waste water processing of each industry of row.
Preferably, the caustic soda adding set includes hopper and by motor-driven automatic stirring feed mechanism, described The conveying speed of automatic stirring feed mechanism and the flow of ammonia nitrogen waste water are correspondingly arranged.It can be certainly by automatic stirring feed mechanism Caustic soda is added in trend waste water, so that ammonia is evaporated from waste water in steam heating process, only needs timing to be added into hopper and burns Alkali, and by the way that the flow of the conveying speed of automatic stirring feed mechanism and ammonia nitrogen waste water to be correspondingly arranged, can keep suitable The addition of amount avoids causing to waste.In addition, flowmeter can be arranged on waste pipe, motor connects a frequency converter, then will stream Gauge is connect with frequency converter signal, to automatically adjust the conveying speed of automatic stirring feed mechanism according to wastewater flow, more preferably Adaptation waste water processing speed.
Preferably, it is preferable that the overhead condenser includes the cold water pipes of several dense arrangements, the cold water pipes two End connects water cooling pond and cooling device with cold water recovery tube by high-pressure cold water pipe respectively, and high pressure is housed on the high-pressure cold water pipe Water supply pump, the cooling device are arranged on water cooling pond, so as to lasting offer low-temperature cold water, keep cold water pipes surface relatively low Temperature, so that the ammonia of evaporation is quickly condensed into ammonium hydroxide.Further, it is preferable to ground, the cooling device includes being arranged in cold water Cooling tower on pond, the cooling tower top is equipped with cooling blower can efficiently reduce return water temperature through this structure Degree, to keep the stabilization of water cooling pond water temperature.
The above is the better embodiment of the utility model, but the utility model is not limited to above-described embodiment, As long as it reaches the technique effect of the utility model with any same or similar means, the protection model of the utility model should be all fallen into Within enclosing.

Claims (5)

1. a kind of high-efficiency ammonia-nitrogen deamination apparatus, including heat exchanger and stripper, it is characterised in that:The heat exchanger is mounted in vapour Stripper bottom, and ammonia nitrogen waste water is connected by waste pipe, the stripper goes out equipped with caustic soda adding mouth, vapour inlet and bottom of tower The mouth of a river, the caustic soda adding mouth and vapour inlet are separately connected caustic soda adding set and steam pipeline, the steam pipeline connection Steam air source;Include multilayer column plate in the stripper, top is equipped with overhead condenser, and the overhead condenser is connected with back Flow tube and ammonium hydroxide recovery tube, the return duct are respectively connected to stripper and ammonium hydroxide recycling can with ammonium hydroxide recovery tube.
2. a kind of high-efficiency ammonia-nitrogen deamination apparatus according to claim 1, it is characterised in that:The caustic soda adding set Including hopper and pass through motor-driven automatic stirring feed mechanism, the conveying speed and ammonia nitrogen of the automatic stirring feed mechanism The flow of waste water is correspondingly arranged.
3. a kind of high-efficiency ammonia-nitrogen deamination apparatus according to claim 2, it is characterised in that:It is set on the waste pipe There are flowmeter, the motor to be connected with frequency converter, the flowmeter is connect with frequency converter signal.
4. according to a kind of any high-efficiency ammonia-nitrogen deamination apparatus of claims 1 to 3, it is characterised in that:The tower top Condenser includes the cold water pipes of several dense arrangements, and the cold water pipes both ends are recycled by high-pressure cold water pipe and cold water respectively Pipe connects water cooling pond and cooling device, is pumped equipped with high-pressure cold water on the high-pressure cold water pipe, the cooling device is arranged in cold water Chi Shang.
5. a kind of high-efficiency ammonia-nitrogen deamination apparatus according to claim 4, it is characterised in that:The cooling device includes The cooling tower being arranged on water cooling pond, the cooling tower top are equipped with cooling blower.
CN201820384391.5U 2018-03-20 2018-03-20 A kind of high-efficiency ammonia-nitrogen deamination apparatus Active CN208087255U (en)

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Application Number Priority Date Filing Date Title
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125369A (en) * 2020-08-11 2020-12-25 河南开祥精细化工有限公司 A ammonia nitrogen desorption system in waste water for coal gasification
CN115818757A (en) * 2023-02-20 2023-03-21 深圳永清水务有限责任公司 System and method for recycling ammonia in wastewater at low temperature
CN115849478A (en) * 2022-10-28 2023-03-28 安徽华塑股份有限公司 Ammonia nitrogen treatment process in water of acetylene purification system

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112125369A (en) * 2020-08-11 2020-12-25 河南开祥精细化工有限公司 A ammonia nitrogen desorption system in waste water for coal gasification
CN115849478A (en) * 2022-10-28 2023-03-28 安徽华塑股份有限公司 Ammonia nitrogen treatment process in water of acetylene purification system
CN115818757A (en) * 2023-02-20 2023-03-21 深圳永清水务有限责任公司 System and method for recycling ammonia in wastewater at low temperature

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