CN207980871U - Rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system - Google Patents

Rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system Download PDF

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Publication number
CN207980871U
CN207980871U CN201721430116.4U CN201721430116U CN207980871U CN 207980871 U CN207980871 U CN 207980871U CN 201721430116 U CN201721430116 U CN 201721430116U CN 207980871 U CN207980871 U CN 207980871U
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ammonia
rectangular nozzle
spraying grid
pipe
spraying
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曾文兵
石壮
于瑶
俱虎良
李利军
马静园
刘林洋
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China National Petroleum Corp
China Kunlun Contracting and Engineering Corp
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China Kunlun Environmental Engineering Co Ltd
China Kunlun Contracting and Engineering Corp
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Abstract

The utility model is related to a kind of rectangular nozzle formula ammonia-spraying grids suitable for flue gas SCR denitration technique ammonia spraying system, including ammonia-spraying grid and static mixing device, the ammonia-spraying grid includes the spray ammonia pipe that several are equipped with rectangular nozzle, the static mixing device is located at the rear of the ammonia-spraying grid, if including dried layer disturbed flow pipe, plane where each layer disturbed flow pipe is parallel with plane where the ammonia-spraying grid, the static mixing device includes static mixer I and static mixer II, the static mixer I includes at least one layer of disturbed flow pipe parallel with the spray ammonia pipe, the static mixer II includes at least two layers of disturbed flow pipe vertical with the spray ammonia pipe, the disturbed flow pipe of the static mixer I is equipped with several turbulence blades groups corresponding with the rectangular nozzle.The utility model can improve mixing efficiency, and the uniformly mixed purpose of reducing agent can be realized in shorter flue length.

Description

Rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system
Technical field
The utility model is related to a kind of ammonia-spraying grids, more particularly to a kind of to be suitable for flue gas SCR denitration technique ammonia spraying system Rectangular nozzle formula ammonia-spraying grid.
Background technology
Selective catalytic reduction SCR(Selective Catalytic Reduction)It is control boiler nitrogen oxides The important technical of discharge.SCR technology principle is in 320-400 DEG C of temperature range, and the NOx in flue gas is in catalyst Under effect, with the reducing agent in penetrating flue(Ammonium hydroxide, liquefied ammonia or urea etc.)Reaction generates N2, to realize NOx abatement Purpose.The technique has denitration efficiency high(Generally up to 80-95%), mature production technology, non-secondary pollution, to boiler transport Row influences the features such as smaller.From current technology both domestic and external apply and development trend from the point of view of, in particular with minimum discharge technology Most of areas are gradually promoted at home, and SCR techniques denitration efficiency is high, and the market demand constantly expands, and in the flue gas of application The overwhelming majority is occupied in denitrification apparatus, it is considered to be most important denitrating flue gas administers skill now or even in suitable long-term later Art.
The key of SCR technological designs is to realize being sufficiently mixed for nitrogen oxides in effluent and reducing agent.If catalyst inlet Locate ammonia nitrogen mixing unevenness and the problem of not only reducing the efficiency of denitrating flue gas, can also bring the escaping of ammonia, does not participate in going back for reaction Former agent ammonia enters downstream and the SO in flue gas3Reaction production ammonium hydrogen sulfate.Ammonium hydrogen sulfate has very strong adsorptivity, easily causes A large amount of ash-depositions cause to block in air preheater surfaces, and reduce the heat transfer efficiency of air preheater;In addition, hydrogen sulfate Ammonium also has very strong corrosivity, and accumulation for a long time can reduce the service life of air preheater.It can be seen that flue gas and reducing agent The uniform mixing of ammonia extends catalyst service life, reduces investment and operational management cost, ensure dress for improving denitration efficiency Stable operation is set to be of great significance.The mixing of flue gas and reducing agent ammonia is mainly realized by ammonia-spraying grid.
The ammonia-spraying grid based on round nozzle that SCR denitration technique uses at this stage, have it is simple for process, reducing agent ammonia with The features such as flue gas mixing efficiency is not high.So in order to ensure that the mass concentration mixing of the first floor catalyst inlet ammonia in SCR is equal It is even, extension is mostly used greatly from ammonia-spraying grid to the means of catalyst inlet flue using the engineering of this type ammonia-spraying grid, is carried The means such as panel flow-disturbing realization above-mentioned purpose is arranged in high nozzle ammonia/sky mixer flow velocity before each nozzle, and this is undoubtedly The problems such as increase of design cost of investment and the pressure drop of denitrating system can be brought to become larger.
Utility model content
In order to solve the above technical problems, the utility model, which provides one kind, being suitable for flue gas SCR denitration technique ammonia spraying system Rectangular nozzle formula ammonia-spraying grid, mixing efficiency can be improved, can be realized in shorter flue length reducing agent be uniformly mixed Purpose.
The technical solution of the utility model is:
A kind of rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system, including ammonia-spraying grid and Static mixing device, the ammonia-spraying grid include the spray ammonia pipe that several are equipped with rectangular nozzle, are used for reducing agent ammonia/air group At gaseous mixture spray into flue, for jet velocity between 12~19m/s, which is 2~4 times of velocity of flue gas, and Meet design requirement of the ammonia-spraying grid about velocity of flue gas, the static mixing device is located at the rear of the ammonia-spraying grid, packet If including dried layer disturbed flow pipe, plane where each layer disturbed flow pipe is parallel with plane where the ammonia-spraying grid, due to rectangular nozzle More traditional round nozzle has stronger flow-disturbing to act on, and coordinates and acted on the flow-disturbing of disturbed flow pipe described in multilayer, may make also The mass concentration of former agent ammonia is evenly distributed in SCR catalyst inlet.
Preferably, the static mixing device includes forming static mixer I and static mixer II, the static mixing Device I includes at least one layer of disturbed flow pipe parallel with the spray ammonia pipe, and the static mixer II includes at least two layers and the spray The vertical disturbed flow pipe of ammonia pipe, the static mixer I are described quiet between the ammonia-spraying grid and the static mixer II The disturbed flow pipe of state mixer I is parallel to the spray ammonia pipe, reduces the resistance of mixed gas to the greatest extent, keeps higher speed, described Two layers of disturbed flow pipe main function of static mixer II is flow-disturbing, and uniform mixed gas, each flow-disturbing are obtained by flow-disturbing Pipe uses square tube or pipe.
Preferably, the disturbed flow pipe of the static mixer I is equipped with several turbulence blades corresponding with the rectangular nozzle Group obtains better flow-disturbing effect.
Preferably, the turbulence blades group includes the turbulence blades of several distributions, and preferred amount is 4 and the flow-disturbing Projection of the axis of the axis of blade and the disturbed flow pipe on flue cross section is in 45 ° of angles.
Preferably, it is connecting pin that the shape of the turbulence blades, which is trapezoidal and smaller one end, the turbulence blades and institute The setting angle that ammonia-spraying grid is kept for 0 ° -90 ° is stated, preferably 45 °, this angle can ensure maximum movement velocity and minimum Resistance.
Preferably, two layers of disturbed flow pipe interlaced arrangement of the static mixer II, preferably below a layer number than in described The quantity of layer disturbed flow pipe is one more, and the gas in gap can all bump against one below across two fronts, one layer of disturbed flow pipe in this way The mixed effect of one layer of disturbed flow pipe, gas can be more preferable.
Preferably, the rectangular nozzle is connected to the spray ammonia pipe by the way that the through-hole on the spray ammonia pipe is arranged, described logical Hole is less than the endoporus of the rectangular nozzle, and the rectangular nozzle is connected to the outside of the spray orifice by welding, described The axis direction of rectangular nozzle is vertical with the plane where the ammonia-spraying grid and towards the rear, ensures the reduction that the nozzle sprays Agent ammonia is consistent with the direction of flue gas.
Preferably, the rectangular nozzle is the rectangle of 15~50mm of the length of side, and chamfering is equipped on the outside of outlet end, guiding outside Flue gas moves to the front of the rectangular nozzle along the inclined-plane of chamfering, and the gas sprayed with the rectangular nozzle is mixed, institute It is 80~200mm to state rectangular nozzle and stretch into flue length, and clipping room is away from for 400~800mm, according to the reduction in the spray ammonia pipe The pressure and speed of agent ammonia/air gas mixture select suitable parameter, and the gas that the rectangular nozzle sprays is enable to cover The cross section of flue.
Preferably, one end of the spray ammonia pipe is equipped with the fixing device for connecting flue, and the other end is equipped with for connecting The interface of regulating valve realizes that the fixed point of ammonia/air Mixture is precisely sprayed, to match cigarette by regulating valve according to the variation of operating mode The concentration distribution of nitrogen oxides in gas.
Preferably, the spray ammonia pipe is the stainless steel tube of DN25~100, and the disturbed flow pipe is the stainless steel tubes of DN50~200.
The beneficial effects of the utility model are:
The utility model provides a kind of nozzle design of the ammonia-spraying grid based on hydrodynamic analysis, using square Shape nozzle replaces existing round nozzle, can shorten the spacing of ammonia-spraying grid and catalyst inlet, for site layout project complexity Boiler improvement project it is with the obvious advantage.The beneficial effects of the utility model are also embodied in the following aspects:
One, rectangular nozzle formula ammonia-spraying grids spray the turbulence dissipation rate higher of fluid, and the turbulence effects itself generated are more preferable, Flue length can be reduced in the SCR denitration transformation of miniature boiler, improves the utilization rate of denitrating catalyst;
The system stability of two, rectangular nozzle formula ammonia-spraying grids is good;
Three, static mixers obtain the mixing of better flue gas and reducing agent ammonia under the premise of not increasing flue gas pressure drop Effect;
Four, the utility model have good thermal expansivity, thermal denaturation resistant and vibration resistance;
Five, ammonia-spraying grids every spray the included regulating valve of ammonia pipe, can realize ammonia/air Mixture according to the variation of operating mode Fixed point precisely spray, to match the concentration distribution of nitrogen oxides in effluent;
Six, often sweep along the flying dust of certain content, the utility model to be mainly characterized by view of SCR flue gas denitrification systems flue gas It is simple in structure, distributed effect is good, be not easy dust stratification, and can be with the abrasion of effective protection ammonia-spraying grid nozzle;
The mixing resistance of seven, the utility model is low, and entire flue gas denitrification system resistance is brought to reduce, thus reduces cigarette The unit cost of qi exhaustion nitre.
Description of the drawings
Fig. 1 is one side schematic view of the utility model embodiment;
Fig. 2 is another side schematic view of Fig. 1 illustrated embodiments;
Fig. 3 is the utility model turbulence blades schematic diagram;
Fig. 4 is the utility model rectangular nozzle schematic diagram.
Specific implementation mode
The utility model is described further below in conjunction with the accompanying drawings.
As Figure 1-Figure 4, the utility model is related to a kind of rectangle sprays suitable for flue gas SCR denitration technique ammonia spraying system Mouth formula ammonia-spraying grid, including ammonia-spraying grid and static mixing device, the ammonia-spraying grid include that several are equipped with rectangular nozzle Ammonia stainless steel tubing is sprayed, the static mixing device is located at the rear of the ammonia-spraying grid, including static mixer I and static state are mixed Clutch II.
By taking size is the flue of 2000 × 1300mm as an example, in the spray for arranging four DN50 on flue long side direction Ammonia stainless steel tubing(Spray ammonia pipe)7, the two neighboring spacing sprayed between ammonia stainless steel tubing 7 is 500mm, the every spray Ammonia stainless steel tubing 7 arranges that 3 length of sides are the rectangular nozzle 4 of 20mm, and the spacing between the two neighboring rectangular nozzle 4 is 432mm, totally 12 nozzles, one end of the spray ammonia stainless steel tubing 7 are equipped with the fixing device 5 for connecting flue, the other end Equipped with the interface 6 for connecting regulating valve;Thereafter arrange static mixer I and static mixer II, the static mixer I by Four with above-mentioned pipeline at a distance of the stainless steel tubing of 300mm(Lower layer's disturbed flow pipe)3 compositions, every lower layer's stainless steel tubing 3 3 turbulence blades groups of upper installation, each hybrid blade group include four turbulence blades 8 and with the position of the rectangular nozzle 4 Corresponding, 3 installation direction of stainless steel tubing of the static mixer I is consistent with spray ammonia 7 installation directions of stainless steel tubing And installation site is corresponding, static mixer II is then by the stainless steel tubing of the 7 piece DN80 vertical with I direction of the mixer Divide two layers of composition, respectively one layer of front stainless steel tubing(One layer of front disturbed flow pipe)2 and one layer of stainless steel tubing below(Below One layer of disturbed flow pipe)1, primarily serve the effect of flue gas flow-disturbing, one layer of stainless steel tubing 2 below and the spray ammonia stainless steel tube Spacing between line 3 is 500mm, it is described below between one layer of stainless steel tubing 1 and one layer of front stainless steel tubing 2 between Away from for 500mm.
Ammonia/air Mixture that volume fraction is 5% enters by rectangular nozzle formula ammonia-spraying grid in flue, is sprayed in rectangle Under the flow-disturbing effect that mouth generates, cooperation is acted on the turbulent closure scheme of flue static mixer I and II, in SCR reactor catalysts Inlet realize the effect that is evenly distributed of mass fraction of ammonia.By CFD flow field simulations calculate, the novel ammonia-spraying grid and The pressure drop that static mixer generates is 180Pa, is less than the requirement of ammonia spraying system design mark 200Pa, it is entire to be conducive to control The pressure drop that denitrating system is brought is within the scope of 1000Pa.In addition, analysis shows using round nozzle type ammonia-spraying grid SCR denitration System needs the flue distance from ammonia-spraying grid to first floor catalyst inlet to exist to realize that first floor catalyst inlet ammonia is evenly distributed 10 m or more.Under same flue gas scale, flue length 22% or so will then be saved using the system of novel ammonia-spraying grid.
Related experiment is analyzed as follows:
Under identical equipment arrangement, respectively to rectangular nozzle formula ammonia-spraying grid(Aerodynamic diameter 20mm)And circle Nozzle-type ammonia-spraying grid(Φ=20mm)CFD flow field simulation analyses are carried out, find the cigarette in novel rectangular nozzle formula ammonia-spraying grid At road catalyst inlet, the mass fraction root-mean-square-deviation rate Cv ≈ 4.5% of reducing agent ammonia, traditional round nozzle formula sprays ammonia lattice The mass fraction root-mean-square-deviation rate of grid reducing agent ammonia is then 12%.In addition to this, in maximum temperature deviation, flue gas incidence catalysis Agent angle(With the angle of vertical direction)The novel ammonia-spraying grid of aspect all shows preferably.
Compared to round nozzle, when the mixer of reducing agent ammonia/air enters flue gas by square nozzle high speed, due to square The corner angle of shape nozzle make the turbulence dissipation rate bigger of gaseous mixture, and it is more violent that reducing agent ammonia enters the turbulent flow after flue, with cigarette The mixability of gas is more excellent.The flow-disturbing of the static mixer of hybrid blade and straight tube beam is coordinated to act on again, ammonia/nitrogen molar ratio Distribution at the first layer catalyst inlet of SCR reactors can be more uniform, avoids bringing because ammonia/nitrogen local area distribution is excessively high The problems such as the escaping of ammonia is significantly, the catalytic efficiency of catalyst is not high.
It is disclosed by the utility model it is each preferably with optional technological means, unless otherwise indicated and a preferred or optional skill Art means are that further limiting for another technological means is outer, can form several different technical solutions in any combination.

Claims (15)

1. a kind of rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system, including ammonia-spraying grid and quiet State mixing arrangement, it is characterised in that the ammonia-spraying grid includes the spray ammonia pipe that several are equipped with rectangular nozzle, the static mixing Device is located at the rear of the ammonia-spraying grid, if including dried layer disturbed flow pipe, each layer disturbed flow pipe place plane and the spray ammonia Plane where grid is parallel.
2. rectangular nozzle formula ammonia-spraying grid according to claim 1, it is characterised in that the static mixing device includes quiet State mixer I and static mixer II, the static mixer I include at least one layer of disturbed flow pipe parallel with the spray ammonia pipe, The static mixer II includes at least two layers of disturbed flow pipe vertical with the spray ammonia pipe, and the static mixer I is located at described Between ammonia-spraying grid and the static mixer II.
3. rectangular nozzle formula ammonia-spraying grid according to claim 2, it is characterised in that the disturbed flow pipe of the static mixer I Equipped with several turbulence blades groups corresponding with the rectangular nozzle.
4. rectangular nozzle formula ammonia-spraying grid according to claim 3, it is characterised in that the turbulence blades group includes several A equally distributed turbulence blades.
5. according to any rectangular nozzle formula ammonia-spraying grids of claim 1-4, it is characterised in that the shape of the turbulence blades Shape is that trapezoidal and smaller one end is connecting pin, and the turbulence blades keep 0 ° -90 ° of setting angle with the ammonia-spraying grid.
6. rectangular nozzle formula ammonia-spraying grid according to claim 5, it is characterised in that two layers of the static mixer II Disturbed flow pipe interlaced arrangement.
7. rectangular nozzle formula ammonia-spraying grid according to claim 6, it is characterised in that the rectangular nozzle is existed by setting Through-hole on the spray ammonia pipe is connected to the spray ammonia pipe, and the through-hole is less than the endoporus of the rectangular nozzle, the rectangular nozzle Be connected to the outside of the spray orifice by welding, the axis direction of the rectangular nozzle with where the ammonia-spraying grid Plane is vertical and towards rear.
8. rectangular nozzle formula ammonia-spraying grid according to claim 7, it is characterised in that the rectangular nozzle be the length of side 15~ The rectangle of 50mm, and outlet end on the outside of be equipped with chamfering, the rectangular nozzle stretch into flue length be 80~200mm, clipping room away from For 400~800mm.
9. rectangular nozzle formula ammonia-spraying grid according to claim 8, it is characterised in that one end of the spray ammonia pipe, which is equipped with, to be used In the fixing device of connection flue, the other end is equipped with the interface for connecting regulating valve.
10. rectangular nozzle formula ammonia-spraying grid according to claim 9, it is characterised in that the spray ammonia pipe is DN25~100 Stainless steel tube, the disturbed flow pipe be the stainless steel tubes of DN50~200.
11. rectangular nozzle formula ammonia-spraying grid according to claim 6, it is characterised in that the quantity ratio of one layer of disturbed flow pipe below The quantity of the one layer of disturbed flow pipe in front is one more.
12. rectangular nozzle formula ammonia-spraying grid according to claim 11, it is characterised in that the rectangular nozzle passes through setting Through-hole on the spray ammonia pipe is connected to the spray ammonia pipe, and the through-hole is less than the endoporus of the rectangular nozzle, the rectangle spray Mouth is connected to the outside of the spray orifice, the axis direction of the rectangular nozzle and ammonia-spraying grid place by welding Plane it is vertical and towards rear.
13. rectangular nozzle formula ammonia-spraying grid according to claim 12, it is characterised in that the rectangular nozzle is the length of side 15 The rectangle of~50mm, and chamfering is equipped on the outside of outlet end, it is 80~200mm, clipping room that the rectangular nozzle, which stretches into flue length, Away from for 400~800mm.
14. rectangular nozzle formula ammonia-spraying grid according to claim 13, it is characterised in that one end of the spray ammonia pipe is equipped with Fixing device for connecting flue, the other end are equipped with the interface for connecting regulating valve.
15. rectangular nozzle formula ammonia-spraying grid according to claim 14, it is characterised in that the spray ammonia pipe is DN25~100 Stainless steel tube, the disturbed flow pipe be the stainless steel tubes of DN50~200.
CN201721430116.4U 2017-11-01 2017-11-01 Rectangular nozzle formula ammonia-spraying grid suitable for flue gas SCR denitration technique ammonia spraying system Active CN207980871U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109432978A (en) * 2018-12-28 2019-03-08 启明星宇节能科技股份有限公司 A kind of denitration flue gas disturbance device
CN110193285A (en) * 2019-07-12 2019-09-03 中电华创(苏州)电力技术研究有限公司 A kind of ammonia injection flow mixing device of SCR denitration system
CN112742232A (en) * 2019-10-29 2021-05-04 中国石油化工股份有限公司 Ammonia spraying static mixer
CN113144896A (en) * 2021-01-26 2021-07-23 成都易态科技有限公司 Flue gas dust removal and denitration device

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109432978A (en) * 2018-12-28 2019-03-08 启明星宇节能科技股份有限公司 A kind of denitration flue gas disturbance device
CN110193285A (en) * 2019-07-12 2019-09-03 中电华创(苏州)电力技术研究有限公司 A kind of ammonia injection flow mixing device of SCR denitration system
CN112742232A (en) * 2019-10-29 2021-05-04 中国石油化工股份有限公司 Ammonia spraying static mixer
CN113144896A (en) * 2021-01-26 2021-07-23 成都易态科技有限公司 Flue gas dust removal and denitration device

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Effective date of registration: 20201224

Address after: 100007 No. 9 North Main Street, Dongcheng District, Beijing, Dongzhimen

Patentee after: CHINA NATIONAL PETROLEUM Corp.

Patentee after: CHINA KUNLUN CONTRACTING & ENGINEERING Corp.

Address before: 100037 No. 21, shining road, Beijing, Haidian District

Patentee before: CHINA KUNLUN CONTRACTING & ENGINEERING Corp.

Patentee before: CHINA KUNLUN ENVIRONMENTAL ENGINEERING Co.,Ltd.

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