CN202909629U - Reversed-injection ammonia injection element - Google Patents
Reversed-injection ammonia injection element Download PDFInfo
- Publication number
- CN202909629U CN202909629U CN 201220546218 CN201220546218U CN202909629U CN 202909629 U CN202909629 U CN 202909629U CN 201220546218 CN201220546218 CN 201220546218 CN 201220546218 U CN201220546218 U CN 201220546218U CN 202909629 U CN202909629 U CN 202909629U
- Authority
- CN
- China
- Prior art keywords
- injection
- ammonia
- spray ammonia
- anemostat
- nozzle
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 238000002347 injection Methods 0.000 title abstract description 18
- 239000007924 injection Substances 0.000 title abstract description 18
- UGFAIRIUMAVXCW-UHFFFAOYSA-N carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000003546 flue gas Substances 0.000 claims abstract description 26
- 210000003284 Horns Anatomy 0.000 claims abstract description 17
- 210000000214 Mouth Anatomy 0.000 claims abstract description 17
- 239000007921 spray Substances 0.000 claims description 49
- 230000000875 corresponding Effects 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 8
- 238000009792 diffusion process Methods 0.000 abstract description 7
- 230000002349 favourable Effects 0.000 abstract 1
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitric oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 18
- GQPLMRYTRLFLPF-UHFFFAOYSA-N nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 11
- 229910052813 nitrogen oxide Inorganic materials 0.000 description 8
- 238000005516 engineering process Methods 0.000 description 7
- 230000002411 adverse Effects 0.000 description 3
- 239000003638 reducing agent Substances 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- ZWWCURLKEXEFQT-UHFFFAOYSA-N Dinitrogen pentoxide Chemical compound [O-][N+](=O)O[N+]([O-])=O ZWWCURLKEXEFQT-UHFFFAOYSA-N 0.000 description 2
- WFPZPJSADLPSON-UHFFFAOYSA-N Dinitrogen tetroxide Chemical compound [O-][N+](=O)[N+]([O-])=O WFPZPJSADLPSON-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000010531 catalytic reduction reaction Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- JCXJVPUVTGWSNB-UHFFFAOYSA-N nitrogen dioxide Chemical compound O=[N]=O JCXJVPUVTGWSNB-UHFFFAOYSA-N 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000002224 dissection Methods 0.000 description 1
- 238000005755 formation reaction Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 238000010574 gas phase reaction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000003068 static Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Abstract
The utility model discloses a reversed-injection ammonia injection element. The reversed-injection ammonia injection element comprises ammonia injection pipes, injection nozzles and diffusion pipes, wherein the diffusion pipes comprise straight pipe sections, horn mouths and diversion cylinders; a plurality of injection nozzles are arranged on each ammonia injection pipe; openings of the injection nozzles face upwards; one diffusion pipe corresponds to the upper part of each injection nozzle; and each injection nozzle extends into each diffusion pipe. Compared with the prior art, the reversed-injection ammonia injection element disclosed by the utility model has the characteristics that the injection nozzles are densely arranged along the section of a flue, so that flue gas suction areas of various diffusion pipes are superposed and further the uniformity in distribution of ammonia is ensured; the openings of the injection nozzles face upwards and are opposite to flue gas in flow direction; ammonia gas and the flue gas form a reverse flow state; and the diversion cylinders are arranged in the diffusion pipes and used for limiting the flow direction of the ammonia, and form a favorable mixing effect with the ammonia gas.
Description
Technical field
The utility model relates to a kind of spray ammonia element of oil plant FCC regenerated flue gas denitrification apparatus, particularly relates to a kind of spray ammonia element of refinery FCC regenerated flue gas SCR SCR denitrating technique.
Background technology
Nitrogen oxide (NOx) is one of primary pollution source of atmosphere pollution.Nitrogen oxide comprises multiple compounds such as nitrous oxide, nitric oxide, nitrogen dioxide, nitrogen trioxide, dinitrogen tetroxide and dinitrogen pentoxide etc.Oil plant is one of main discharged nitrous oxides source, and the NOx amount in the FCC flue gas generally accounts for 50% of the full NOx of factory discharge capacity, is the NOx emission source of oil plant maximum.
The FCC gas denitrifying technology mainly comprises at present: the selective catalytic reduction of gas-phase reaction (SCR method) and SNCR method (SNCR method), liquid absorption method, solid absorption method and high energy electron active oxidation method etc.
The SCR method is under catalyst action, utilize reducing agent selectively with flue gas in NOx reaction, and generate the N of nonhazardous effect
2And H
2The technology of O, its reducing agent can be ammonia, ammoniacal liquor or urea, also can select CO or H
2, also can select little molecule alkane.The SCR technology is compared with other technologies, has a denitration efficiency high, and thermal discharge is little, and the advantages such as technology maturation are to use maximum technology in the Flue Gas Denitrification Engineering both at home and abroad at present.
In the SCR gas denitrifying technology, ammonia (NH
3) and nitrogen oxide (NO
x) mixed effect and the denitration efficiency of denitrification apparatus close relationship is arranged, if reducing agent and NO
xThat mixes is insufficient, can cause NH in the regional area
3/ NO
xMol ratio is excessively low, will greatly reduce system's denitration efficiency.In the case, want to reach NO
xThe discharge capacity index request certainly will increase the consumption of catalyst or the consumption of ammonia, causes operating cost to increase or the amount of ammonia slip increase, forms secondary pollution.
Traditional NH
3And NO
xUtilize NH in the mixed method
3And NO
xBetween concentration difference, mix by natural diffusion way, therefore need very long mixing distance and NH
3And NO
xUndercompounding.
CN201394414Y has introduced a kind of ejection ammonia mixed organization of SCR reaction unit, comprises a charging house steward and several distributing pipe; Lower surface at distributing pipe is provided with some nozzles, and is provided with accordingly the deflector that is comprised of several static mixing blades below nozzle; Nozzle is tubaeform, sprays resistance to reduce ammonia; The nozzle below is provided with induction tunnel accordingly, and this induction tunnel is the Venturi tube of large aditus laryngis, forms secondary drainage.The weak point of this mechanism is, generally, the flue gas that participates in mixing only accounts for 30% ~ 70% of total flue gas, impact spray ammonia effect.
CN101601965A has introduced a kind of ammonia-spraying grid device of SCR method denitrating flue gas, includes the ammonia-spraying grid that the metal tube bank forms, and the footpath of each root metal tube upwards is provided with nozzle; The angle of the opening direction of nozzle and flow of flue gas direction is 0～90 °.The weak point of this structure is, lacks turbulent element, causes linearly flowing along injection direction through the ammonia of nozzle ejection, only can mix with partial fume impact spray ammonia effect.
Summary of the invention
Not enough for prior art, the utility model provides the reverse spray type spray ammonia element of a kind of FCC flue gas selective reduction denitration (SCR) reactor, is intended to solve in the prior art ammonia and mixes inhomogeneously with flue gas, affects the problem of spraying the ammonia effect.
The reverse spray type spray ammonia element of the selective-catalytic-reduction denitrified reactor of the utility model comprises spray ammonia pipe, nozzle and anemostat; Be provided with some nozzles at every spray ammonia pipe, nozzle opening upwards, and is opposite with flue gas flow direction; Each corresponding anemostat in nozzle top, wherein said anemostat comprises straight length, horn mouth and guide shell, described nozzle extends in the anemostat.
In the reverse spray type spray ammonia element of the utility model SCR reactor, nozzle opening is upwards, and is opposite with flue gas flow direction, its axis and anemostat dead in line, and extend in the anemostat.Described nozzle is along the intensive layout in flue cross section, to guarantee the even distribution of ammonia; Anemostat is fixed on spray ammonia pipe top, is the broadening formation structure with straight length.Guide shell is set in anemostat, and guide shell bus subtended angle and anemostat horn mouth subtended angle are identical or different, and the subtended angle scope is 10 ° ~ 60 °.
Compare with spray ammonia element of the prior art, the utility model nozzle makes each anemostat suction flue gas area coincidence along the intensive layout in flue cross section, guarantees the even distribution of ammonia.Nozzle opening upwards, and is opposite with flue gas flow direction, and ammonia and flue gas form the adverse current fluidised form.Guide shell is set in anemostat, the flow direction of restriction ammonia, thus form good mixed effect with flue gas.
Description of drawings
Fig. 1 is the utility model spray ammonia element front view.
Fig. 2 is the utility model spray ammonia element anemostat structural representation.
Fig. 3 is the utility model spray ammonia element work schematic diagram.
The specific embodiment
Further specify concrete structure and the occupation mode of reverse spray type spray ammonia element of the present utility model below in conjunction with accompanying drawing.
As depicted in figs. 1 and 2, the structure of reverse spray type spray ammonia element of the present utility model is as follows: described spray ammonia element comprises spray ammonia pipe 1, nozzle 2 and anemostat 3.Described spray ammonia pipe 1 is evenly arranged along the flue cross section is intensive.Wherein anemostat 3 comprises straight length 31, horn mouth 32 and guide shell 33.Be equipped with some nozzles 2 at every spray ammonia pipe 1, the opening upwards of nozzle 2 is opposite with flue gas flow direction.The all corresponding anemostat 3 in the top of each nozzle 2, the lower end of nozzle 2 connects with spray ammonia pipe upper surface, and nozzle 2 upper ends extend in the anemostat 3.
In conjunction with Fig. 2 and Fig. 3, in the reverse spray type spray ammonia element of the present utility model, nozzle opening upwards, and is opposite with flue gas flow direction.The axis of nozzle 2 and anemostat dead in line, its upper end extends in the anemostat straight length 31, and nozzle 2 can guarantee the even distribution of ammonia along the intensive layout in flue cross section.Anemostat 3 is fixed on spray ammonia pipe 1 top, and by straight length 31, horn mouth 32 and guide shell 33 form.Wherein said guide shell 33 is the cone cylindrical structure, and its vertex of a cone is positioned at horn mouth, and the cone end stretch goes out horn mouth.Described guide shell 3 becomes the inclination fluidised form with the vertically upward fluidised form of ammonia, forms adverse current with flue gas, is conducive to fully mixing of ammonia and flue gas.Conical flow guiding cylinder bus subtended angle and anemostat horn mouth subtended angle are identical or different, preferably adopt identical subtended angle, and subtended angle α scope is 10 °～60 °; The cone floor space of conical flow guiding cylinder is generally 0.5～0.8 times of horn mouth sectional area.The length of described straight length is generally 1～4 times of straight length diameter.
Reverse spray type spray ammonia element of the present utility model in use, flue gas is flowed through from the top down and is sprayed the ammonia element, ammonia sprays into and is sprayed by nozzle through spray ammonia pipe, flow from bottom to top, behind the water conservancy diversion of horn mouth inner draft tube, form the adverse current fluidised form with flue gas, be issued to good mixed effect in the dissection of flue gas.
Claims (9)
1. a reverse spray type spray ammonia element is characterized in that, described spray ammonia element comprises spray ammonia pipe, nozzle and anemostat; Be provided with some nozzles at every spray ammonia pipe, nozzle opening upwards, and is opposite with flue gas flow direction; Each corresponding anemostat in nozzle top, wherein said anemostat comprises straight length, horn mouth and guide shell, described nozzle extends in the anemostat.
2. according to spray ammonia element claimed in claim 1, it is characterized in that, described guide shell is arranged in the horn mouth.
3. according to spray ammonia element claimed in claim 2, it is characterized in that, described guide shell is the cone barrel structure, and wherein the vertex of a cone is positioned at horn mouth, and the cone end stretch goes out horn mouth.
4. according to spray ammonia element, the axis of wherein said nozzle and anemostat dead in line claimed in claim 1.
5. according to spray ammonia element claimed in claim 3, it is characterized in that, the bus subtended angle of described guide shell is 10 ° ~ 60 °, and the horn mouth subtended angle of described anemostat is 10 ° ~ 60 °.
6. according to claim 3 or 5 described spray ammonia elements, it is characterized in that, described guide shell bus subtended angle and anemostat horn mouth subtended angle are identical or different.
7. according to spray ammonia element claimed in claim 1, it is characterized in that the axis of described guide shell and the dead in line of anemostat.
8. according to spray ammonia element claimed in claim 1, it is characterized in that, the cone floor space of described conical flow guiding cylinder is 0.5～0.8 times of horn mouth sectional area.
9. according to spray ammonia element claimed in claim 1, it is characterized in that, the length of described straight length is 1～4 times of straight length diameter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220546218 CN202909629U (en) | 2012-10-24 | 2012-10-24 | Reversed-injection ammonia injection element |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201220546218 CN202909629U (en) | 2012-10-24 | 2012-10-24 | Reversed-injection ammonia injection element |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN202909629U true CN202909629U (en) | 2013-05-01 |
Family
ID=48157977
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201220546218 Expired - Lifetime CN202909629U (en) | 2012-10-24 | 2012-10-24 | Reversed-injection ammonia injection element |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN202909629U (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105311959A (en) * | 2015-12-09 | 2016-02-10 | 光大环保（中国）有限公司 | Ammonia spraying grid for low-temperature SCR denitrification system |
| CN107081055A (en) * | 2017-04-17 | 2017-08-22 | 山东大学 | A kind of eddy flow combined type SCR static mixers |
| CN113559705A (en) * | 2021-08-05 | 2021-10-29 | 西安热工研究院有限公司 | Drainage type SCR denitration urea direct injection system |
-
2012
- 2012-10-24 CN CN 201220546218 patent/CN202909629U/en not_active Expired - Lifetime
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105311959A (en) * | 2015-12-09 | 2016-02-10 | 光大环保（中国）有限公司 | Ammonia spraying grid for low-temperature SCR denitrification system |
| CN107081055A (en) * | 2017-04-17 | 2017-08-22 | 山东大学 | A kind of eddy flow combined type SCR static mixers |
| CN107081055B (en) * | 2017-04-17 | 2019-08-23 | 山东大学 | A kind of eddy flow combined type SCR static mixer |
| CN113559705A (en) * | 2021-08-05 | 2021-10-29 | 西安热工研究院有限公司 | Drainage type SCR denitration urea direct injection system |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20130501 |