CN207958053U - A kind of heterotrophism short distance nitration system of matching Anammox - Google Patents

A kind of heterotrophism short distance nitration system of matching Anammox Download PDF

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Publication number
CN207958053U
CN207958053U CN201721317500.3U CN201721317500U CN207958053U CN 207958053 U CN207958053 U CN 207958053U CN 201721317500 U CN201721317500 U CN 201721317500U CN 207958053 U CN207958053 U CN 207958053U
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short distance
pond
heterotrophism
distance nitration
anammox
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金展
郑悦尔
杜雨
张业健
黄先锋
郑向勇
刘玉香
王传花
柯强
王奇
薛遥
黄卉林
臧亚轩
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SCHOOL & HOSPITAL OF STOMATOLOGY WENZHOU MEDICAL UNIVERSITY
Wenzhou University
First Affiliated Hospital of Wenzhou Medical University
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SCHOOL & HOSPITAL OF STOMATOLOGY WENZHOU MEDICAL UNIVERSITY
Wenzhou University
First Affiliated Hospital of Wenzhou Medical University
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Abstract

The utility model is related to a kind of heterotrophism short distance nitration systems of matching Anammox, include for the organic nitrogen in high nitrogen low carbon-nitrogen ratio sewage to be converted to NH4+The anaerobic fermentation and acid production pond of N, for receiving the waste water from anaerobic fermentation and acid production pond and carrying out the heterotrophism short distance nitration pond of heterotrophism short distance nitration, for the water outlet in heterotrophism short distance nitration pond to be carried out ultrafiltration and the condensed water after ultrafiltration is back to the ultrafiltration pond in heterotrophism short distance nitration pond, the ANAMMOX reaction tanks of sufficient electron acceptor are provided for reverse osmosis/anion-exchange membrane upgrading unit of nitrite nitrogen concentration in the water outlet in enrichment method ultrafiltration pond and to the condensed water progress ANAMMOX reactions to reverse osmosis/anion-exchange membrane upgrading unit for anaerobic ammonia oxidizing bacteria.Technical solutions of the utility model aoxidize ammonia nitrogen in sewage to nitrite nitrogen using heterotrophism nitrococcus, while utilizing reverse osmosis technology/anion-exchange membrane enrichment method short distance nitration reactor water outlet Central Asia nitrate.

Description

A kind of heterotrophism short distance nitration system of matching Anammox
Technical field
Utility model is related to technical field of sewage, more particularly to a kind of heterotrophism short distance nitration of matching Anammox System, suitable for providing electron acceptor nitrite nitrogen for short-cut denitrification technique or anaerobic ammonia oxidation process(NO2 --N).
Background technology
Anaerobic ammonia oxidation process is also known as Anammox techniques, its principle is to control nitrifying process in the nitrite stage And it is short distance nitration to terminate, then Anammox bacterium under anaerobic(AnAOB)With NO2 -As electron acceptor by NH4+Directly It is oxidized to N2, it is the most short biological denitrificaion approach being currently known.Compared with complete nitrification-anti-nitration reaction approach, have aerobic Low, the characteristics of nitric efficiency is high and does not need additional COD is measured, there is apparent advantage at energy-saving aspect.Currently, technique is Actual sewage through being successfully applied to the high nitrogen low-carbon such as sludge liquid, landfill leachate handles and obtains preferable effect.However NO as oxidant2 -It needs pre- to first pass through NH4 +Short distance nitration obtain.However realize short distance nitration steady in a long-term always It is one of the difficult point in denitrogenation of waste water technology.
Short-cut nitrification technology uses enriching ammonia oxidation bacteria at present(AOB)And inhibit nitrite nitrogen oxidation bacteria(NOB)The side of growth Formula realizes NO2 -The accumulation of-N mainly has following several respects problem:(1)Short sludge age is utilized under high temperature(SRT)Selective enrichment AOB and the mode for washing away superseded NOB is only applicable to the relatively low situation of sewage load because high temperature needs to consume a large amount of energy Source.(2)Low dissolved oxygen(DO)Inhibit NOB activity that can then lead to low denitrification percent, this external system is in for a long time under low dissolved oxygen state, Activated sludge is easy disintegration and filamentous bulking.(3)Utilize free ammonia(FA)Although inhibiting the mode of NOB that can obtain the NO at initial stage2 -- N is accumulated, but since NOB may gradually adapt to high FA concentration, effect cannot maintain for a long time.In addition, FA can also be right Anammox bacterium generate inhibiting effect, and the removal rates of system is caused to decline.In addition to this, waste water more or less all contains a certain concentration Organic matter, this so that the growth of the AOB of autotrophic type can be influenced by heterotroph.
There are these above-mentioned disadvantages for short-cut nitrification technology based on autotrophy nitrococcus, have scholar to attempt with energy significantly at present Realize NO2 -The heterotrophism nitrococcus of-N accumulation completes short distance nitration reaction instead of autotrophy AOB.However current heterotrophism nitrococcus Realize the NO of short distance nitration accumulation2 -- N concentration is limited, and highest accumulated concentrations are only 30.1mg/L(Water inlet NH4 +- N is a concentration of 100mg/L), and not matching technique.
RO reverse osmosis technologies are that the solvent in solution is made to separate by reverse osmosis membrane with enough pressure, direction with Infiltration direction is on the contrary, mainly separation object is the ion range in solution.The hyperfiltration more than osmotic pressure can be used to be divided From, purification and concentrate solution.And anion-exchange membrane has selective penetrated property effect to anion, generally with-NH3 +、-NR2H+ Or-PR3 +Active exchange groups are used as Deng cation, and OH- is generated as carrier, by anion-exchange membrane in cathode Selective penetrated property effect be moved to anode.
Utility model content
Based on the above issues, the utility model provides a kind of using heterotrophism nitrococcus oxidation ammonia nitrogen in sewage to nitrous state Nitrogen, while utilizing reverse osmosis technology/anion-exchange membrane enrichment method short distance nitration reactor water outlet Central Asia nitrate System.
To achieve the above object, the utility model provides following technical solution:
A kind of heterotrophism short distance nitration system of matching Anammox, includes for by having in high nitrogen low carbon-nitrogen ratio sewage Machine nitrogen is converted to NH4+The anaerobic fermentation and acid production pond of-N, for receiving the waste water from anaerobic fermentation and acid production pond and to carry out heterotrophism short The heterotrophism short distance nitration pond of journey nitrification, for the water outlet in heterotrophism short distance nitration pond to be carried out ultrafiltration and by the condensed water after ultrafiltration time Flow to heterotrophism short distance nitration pond ultrafiltration pond, in the water outlet in enrichment method ultrafiltration pond nitrite nitrogen concentration it is reverse osmosis/cloudy from Proton exchange upgrading unit and ANAMMOX reactions are carried out to the condensed water of reverse osmosis/anion-exchange membrane upgrading unit and are Anaerobic ammonia oxidizing bacteria provides the ANAMMOX reactors of sufficient electron acceptor, and the anaerobic fermentation and acid production pond is short with heterotrophism respectively Journey nitrification tank and ANAMMOX reactors are connected, and heterotrophism short distance nitration pond is connected with the ultrafiltration pond, the ultrafiltration Pond is connected with the reverse osmosis/anion-exchange membrane upgrading unit, the reverse osmosis/anion-exchange membrane upgrading unit and institute ANAMMOX reactors are stated to be connected.
The utility model is further arranged:The heterotrophism short distance nitration bottom of pond portion is equipped with and is provided for abnormal short distance nitration process The aeration plate of oxygen.
The utility model is further arranged:Heterotrophism short distance nitration pond is about 28 equipped with holding system wastewater processing temperatures DEG C heating device.
This system is used to match the heterotrophism short distance nitration of Anammox, includes the following steps:
Step 1: pretreatment:The high nitrogen low carbon-nitrogen ratio sewage of required processing first passes through anaerobic fermentation and acid production pond and carries out anaerobism Pretreatment, NH4 is converted to by the organic nitrogen in sewage+- N facilitates follow-up heterotrophism short distance nitration bacterium by the NH in sewage4 +- N is abundant It is oxidizing to NO2 --N;Control system anaerobic fermentation is acidified pH value simultaneously, so that heterotrophism short distance nitration pond pH is maintained at 6 or so, anaerobism hair The sour pond water outlet part of ferment production is directly entered ANAMMOX reactors, and remaining anaerobic fermentation and acid production pond water outlet enters abnormal short distance In nitrification tank;
Step 2: heterotrophism short distance nitration:Heterotrophism short distance nitration pond receives from the waste water through anaerobic pretreatment, while in pond In add abnormal short distance nitration microbial inoculum;The heterotrophism short distance nitration bottom of pond portion is equipped with aeration plate, is carried for abnormal short distance nitration process Oxygen;Set heating device again simultaneously, it is about 28 DEG C to keep system wastewater processing temperatures;In addition, object of reborning in reaction tank is filled out Material improves abnormal short distance nitration bacteria microorganism amount in heterotrophism short distance nitration pond;
Step 3: nitrite nitrogen concentrates:Ultrafiltration pretreatment is passed through in the water outlet of abnormal short distance nitration, by sewage suspended matter, The macromolecular substances such as colloid, protein and microorganism retain, and ultrafiltration pond condensed water is back in heterotrophism short distance nitration pond, be discharged into Enter reverse osmosis/anion-exchange membrane upgrading unit, counter-infiltration system is arranged in nitrite nitrogen concentration in the water outlet in enrichment method ultrafiltration pond The rate of recovery is 50%/anion exchange;Condensed water enters ANAMMOX reactors, for anaerobic ammonia oxidizing bacteria provide sufficient electronics by Body.
Microbial inoculum described in the step 2 is mainly organized as Bacillus foecalis alkaligenes.
Reverse osmosis pond effluent reuse is in the backwash of ultrafiltration membrane or reverse osmosis membrane in the step 3.
The utility model has an advantageous effect in that:
(1)Replace the autotrophic ammonia oxidizing bacterium of tradition to complete the oxidation process of ammonia nitrogen using heterotrophism short distance nitration microbial inoculum, avoid be System start the period it is long and cannot decarburization simultaneously the shortcomings that, reduce system operation and control maintenance requirement, while improving system stability, It is allowed to more easily match ANAMMOX techniques.
(2)Utilize nitrous in the pond water outlet of the physical means such as reverse osmosis technology/anion-exchange membrane concentration heterotrophism short distance nitration Hydrochlorate concentration solves the weak defect of heterotrophism short distance nitration bacterium nitrite accumulation ability, sufficient electricity can be provided for follow-up AnAOB Sub- receptor improves ANAMMOX nitric efficiencies so that heterotrophism short distance nitration technology is more suitable for the application of Practical Project.
(3)Compared with autotrophy AOB, the COD that heterotrophic nitrification engineering bacteria not only will not be in by sewage is influenced, moreover it is possible in denitrogenation It is completed at the same time decarburization, short-cut nitrification technology practical implementation value is improved, reduces system response volumetric loading, and have Conducive to the stabilization of system.
Description of the drawings
Fig. 1 is the functional block diagram of Tthe utility model system.
Specific implementation mode:
Referring to attached drawing 1, a kind of heterotrophism short distance nitration system of matching Anammox, including be used for high nitrogen low ratio of carbon to ammonium Organic nitrogen in sewage is converted to NH4+The anaerobic fermentation and acid production pond 1 of-N, for receiving the waste water from anaerobic fermentation and acid production pond 1 And carry out the heterotrophism short distance nitration pond 2 of heterotrophism short distance nitration, for the water outlet in heterotrophism short distance nitration pond 2 to be carried out ultrafiltration and will be surpassed Condensed water after filter is back to the ultrafiltration pond 3 in heterotrophism short distance nitration pond 2, for nitrite nitrogen in the water outlet in enrichment method ultrafiltration pond 3 Reverse osmosis/anion-exchange membrane upgrading unit 4 of concentration and condensed water to reverse osmosis/anion-exchange membrane upgrading unit 4 It carries out ANAMMOX reactions and the ANAMMOX reactors 5 of sufficient electron acceptor is provided for anaerobic ammonia oxidizing bacteria.
The utility model is further arranged:2 bottom of heterotrophism short distance nitration pond is equipped with to be carried for abnormal short distance nitration process The aeration plate of oxygen.
The utility model is further arranged:Heterotrophism short distance nitration pond 2 is about equipped with holding system wastewater processing temperatures 28 DEG C of heating device.
This system is used to match the heterotrophism short distance nitration of Anammox, by taking livestock breeding wastewater as an example, including following step Suddenly:
Step 1: pretreatment:The livestock breeding wastewater of required processing first passes through the progress anaerobism of anaerobic fermentation and acid production pond 1 and locates in advance Reason, NH4 is converted to by the organic nitrogen in sewage+- N facilitates follow-up heterotrophism short distance nitration bacterium by the NH in sewage4 +- N is fully oxidized To NO2 --N;Control system anaerobic fermentation is acidified pH value simultaneously, so that heterotrophism short distance nitration pond 2pH is maintained at 6 or so, anaerobic fermentation Production acid pond 1 is discharged a part and is directly entered ANAMMOX reactors 5, and the remaining water outlet of anaerobic fermentation and acid production pond 1 enters abnormal short distance In nitrification tank;It is 530mg/L to measure ammonia nitrogen concentration in water after pretreatment;A concentration of 550 mg/L of COD.
Step 2: heterotrophism short distance nitration:Heterotrophism short distance nitration pond 2 receives from the waste water through anaerobic pretreatment, while Abnormal short distance nitration microbial inoculum is added in pond;2 bottom of heterotrophism short distance nitration pond is equipped with aeration plate, is abnormal short distance nitration process Oxygen is provided;Set heating device again simultaneously, it is about 28 DEG C to keep system wastewater processing temperatures;In addition, object of reborning in reaction tank Filler improves abnormal short distance nitration bacteria microorganism amount in heterotrophism short distance nitration pond 2;NO in the water outlet of heterotrophism nitrosation pond2 -- N concentration For 11.3 ± 0.6mg/L.
Step 3: nitrite nitrogen concentrates:Ultrafiltration pretreatment is passed through in the water outlet of abnormal short distance nitration, by sewage suspended matter, The macromolecular substances such as colloid, protein and microorganism retain, and 3 condensed water of ultrafiltration pond is back in heterotrophism short distance nitration pond 2, are discharged Into reverse osmosis/anion-exchange membrane upgrading unit 4, nitrite nitrogen concentration in the water outlet in enrichment method ultrafiltration pond 3 is arranged reverse osmosis The system rate of recovery is 50%/anion exchange;NO in water outlet2 -- N concentration rises to 21 ± 1.9mg/L.Condensed water enters ANAMMOX Reactor 5 provides sufficient electron acceptor for anaerobic ammonia oxidizing bacteria.
Microbial inoculum described in the step 2 is mainly organized as Bacillus foecalis alkaligenes.
Reverse osmosis pond effluent reuse is in the backwash of ultrafiltration membrane or reverse osmosis membrane in the step 3.
Certainly, the above description is not intended to limit the present invention, and the utility model is also not limited to the example above, this The those of ordinary skill of technical field, in the essential scope of the utility model, the variations, modifications, additions or substitutions made, all The scope of protection of the utility model should be belonged to.

Claims (3)

1. a kind of heterotrophism short distance nitration system of matching Anammox, it is characterised in that:Including being used for high nitrogen low ratio of carbon to ammonium Organic nitrogen in sewage is converted to NH4+The anaerobic fermentation and acid production pond of-N, for receiving the waste water from anaerobic fermentation and acid production pond simultaneously Carry out the heterotrophism short distance nitration pond of heterotrophism short distance nitration, for the water outlet in heterotrophism short distance nitration pond being carried out ultrafiltration and will be after ultrafiltration Condensed water be back to heterotrophism short distance nitration pond ultrafiltration pond, in the water outlet in enrichment method ultrafiltration pond nitrite nitrogen concentration it is anti- Infiltration/anion-exchange membrane upgrading unit and ANAMMOX is carried out to the condensed water of reverse osmosis/anion-exchange membrane upgrading unit React and provided for anaerobic ammonia oxidizing bacteria the ANAMMOX reactors of sufficient electron acceptor, the anaerobic fermentation and acid production pond difference It is connected with heterotrophism short distance nitration pond and ANAMMOX reactors, heterotrophism short distance nitration pond is connected with the ultrafiltration pond, The ultrafiltration pond is connected with the reverse osmosis/anion-exchange membrane upgrading unit, the reverse osmosis/anion-exchange membrane concentration Unit is connected with the ANAMMOX reactors.
2. the heterotrophism short distance nitration system of matching Anammox according to claim 1, it is characterised in that:The heterotrophism Short distance nitration bottom of pond portion is equipped with the aeration plate that oxygen is provided for abnormal short distance nitration process.
3. the heterotrophism short distance nitration system of matching Anammox according to claim 1 or 2, it is characterised in that:It is described Heterotrophism short distance nitration pond is equipped with the heating device that holding system wastewater processing temperatures are 28 DEG C.
CN201721317500.3U 2017-10-13 2017-10-13 A kind of heterotrophism short distance nitration system of matching Anammox Expired - Fee Related CN207958053U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109095733A (en) * 2018-10-31 2018-12-28 北京安国水道自控工程技术有限公司 A kind of deep denitrogenation device and method of low ratio of carbon to ammonium city domestic sewage
CN109264850A (en) * 2018-11-09 2019-01-25 河北大学 Integral anaerobic ammoxidation film bioelectrochemical system and sewage water denitrification remove the treatment process of carbon
CN109502748A (en) * 2018-11-20 2019-03-22 江苏科技大学 Based on nitrosation-anaerobic ammoxidation-induction crystallization phosphorus recycling sewage disposal system and method
CN109553247A (en) * 2018-12-28 2019-04-02 中国人民大学 A method of Anammox is realized based on heterotrophic nitrification process
CN111410311A (en) * 2020-03-26 2020-07-14 同济大学 Efficient denitrification method for coupling membrane filtration and anaerobic ammonia oxidation process

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109095733A (en) * 2018-10-31 2018-12-28 北京安国水道自控工程技术有限公司 A kind of deep denitrogenation device and method of low ratio of carbon to ammonium city domestic sewage
CN109264850A (en) * 2018-11-09 2019-01-25 河北大学 Integral anaerobic ammoxidation film bioelectrochemical system and sewage water denitrification remove the treatment process of carbon
CN109264850B (en) * 2018-11-09 2023-10-13 河北大学 Integrated anaerobic ammonia oxidation membrane bioelectrochemical system and sewage denitrification and decarbonization treatment process
CN109502748A (en) * 2018-11-20 2019-03-22 江苏科技大学 Based on nitrosation-anaerobic ammoxidation-induction crystallization phosphorus recycling sewage disposal system and method
CN109502748B (en) * 2018-11-20 2021-05-25 江苏科技大学 Sewage treatment system and method based on nitrosation-anaerobic ammonium oxidation-induced crystallized phosphorus recovery
CN109553247A (en) * 2018-12-28 2019-04-02 中国人民大学 A method of Anammox is realized based on heterotrophic nitrification process
CN109553247B (en) * 2018-12-28 2021-08-31 中国人民大学 Method for realizing anaerobic ammonia oxidation based on heterotrophic nitrification process
CN111410311A (en) * 2020-03-26 2020-07-14 同济大学 Efficient denitrification method for coupling membrane filtration and anaerobic ammonia oxidation process

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