CN207726912U - A kind of high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment - Google Patents

A kind of high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment Download PDF

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Publication number
CN207726912U
CN207726912U CN201721834882.7U CN201721834882U CN207726912U CN 207726912 U CN207726912 U CN 207726912U CN 201721834882 U CN201721834882 U CN 201721834882U CN 207726912 U CN207726912 U CN 207726912U
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evaporator
tubulation
water
cycle
air
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CN201721834882.7U
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翟俊
杨忠平
肖海文
柳沛松
陈忠礼
姚婧梅
李伟
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Chongqing University
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Chongqing University
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Abstract

The utility model announces a kind of high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment, tubulation atmospheric evaporation concentration is recycled using chemical coagulation physical filtering, the atmospheric evaporation tower especially used is entered in tower under high-power shaft flow fan effect by the air of dry higher enthalpy value, gas transfers heat to waste water in tower, partial heat needed for waste water evaporation is provided, the air of low enthalpy value high humility is extracted out by wind turbine later, the evaporation capacity that recycling waste water is improved with this, achievees the purpose that concentration.It can effectively solve the problems, such as that high-salt wastewater is handled in economic and technical using this equipment.

Description

A kind of high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment
Technical field
The utility model is related to industrial wastewater pollution processing, environmental protection technical fields, more particularly at high-salt wastewater decrement Technology and equipment.
Background technology
High-salt wastewater refer to from the total salinity of sanitary sewage and industrial wastewater be more than 1% waste discharge, containing compared with It is high such as Cl-, SO4 2-, Na+, Ca2+Equal inorganic ions, also contain some organic matters such as glycerine, middle low-carbon chain compound etc..Mainly From the acquisition for directly utilizing industrial production, domestic water and the food processing factory of seawater, chemical plant and oil and natural gas Processing etc..These high-salt wastewaters will certainly give birth to aqueous bio, Drinking Water and industrial or agricultural if unprocessed direct emission Fisheries water generates greatly harm.But since its complicated component is various, salinity is high, therefore the wastewater processing technology difficulty is more than general Logical sewage disposal is much greater.
Research and common high-salt wastewater method have electroosmose process, membrane separation process, evaporation and bioanalysis etc. at present.Electric osmose Analysis method is applied much in the industrial production, but electroosmose process is very high to raw water requirement, and in general oil content will be less than 2mg/ L must be limited to one to salt content and be scheduled on concentration hereinafter, otherwise production cost increases rapidly;Membrane separation process is an advanced place Reason technology, there is certain potentiality in high-salt wastewater treatment technology, and current main problem is equipment costliness, processing procedure is easily stifled, It is easy to pollute, and the processing of high concentration salt bearing liquid wastes is difficult;Biochemical method facility is huge, complex treatment process, operating cost increase, and is The drawbacks of can not be ignored;Evaporation such as negative pressure evaporation, mechanical pressurization evaporate, and also have energy consumption larger when being handled, and invest The problems such as higher.
China's high-salt wastewater generates quantity in total waste water up to 5%, is still increased every year with 2% rate.Therefore, with high salt useless Water process has critical role in sewage disposal, is the emphasis and difficult point of wastewater treatment research.With domestic increasingly serious The requirement of environmental problem and Environmental control carries out efficient, low-cost processes to high-salt wastewater and compels as industrial development It is essential and asks.This method is intended to have the characteristics that complicated component, variability and dispersibility for high-salt wastewater itself, from economy and skill It is feasible in art to develop a kind of practical, effective and inexpensive high-salt wastewater atmospheric evaporation technology and device, realize the big of waste liquid Width minimizing.
Invention content
The purpose of this utility model is that for the big problem of existing high-salt wastewater treating capacity, a kind for the treatment of effect is provided The high-salt wastewater good, easy to operate, easy to remove, processing cost is low, applicability is wide evaporates decrement treatment processing equipment, and emphasis is Wastewater reduction is realized, to solve the problems, such as that high-salt wastewater is handled.
The technical solution of the utility model is as follows:
The utility model provides a kind of high-salt wastewater that processing cost is low evaporation decrement treatment equipment comprising successively by pipe The sewage pump of road connection, coagulation fillings, space-changeable type filter, regulating tank, recycle tubulation atmospheric evaporator, water circulating pump, Respective valves and suction pump are arranged on pipeline, is set automatically in base of evaporator for steam boiler, water softening plant and softening water tank Water compensating valve and drainpipe.PAC chemicals feeders, sodium carbonate (Na is respectively adopted simultaneously2CO3) chemicals feeder and sodium hydroxide (NaOH) and peace Static mixer on pipeline is connected, and dosing is filled to coagulation by static mixer.
Equipment uses the cycle tubulation atmospheric evaporator of special construction, is square or round tower structure, evaporator Tower in setting wind turbine, water collection device, water distributor, cycle tube still heater, packing area and cycle header tank, be arranged outside tower and draw water Pump.
Wind turbine is axial-flow type high-power blower, is located at evaporator top exit, wind turbine model and power are by required evaporation Air quantity determines, but the power of wind turbine must assure that evaporator outlet wind speed reaches 12-20m/s.
Water distributor is located at evaporator top, is made of with water conduit tube and branch pipe and nozzle what is arranged in dendroid, nozzle is adopted With big flow atomizer, moisturizing pipe diameter and nozzle specification are selected according to design water, and nozzle quantity and arrangement are by cloth Water flow and single-nozzle spray flow determine.
Water collection device is mounted between water distributor and wind turbine, is corrosion-resistant material, is made as waveform.
It recycles in the packing area that tube still heater is mounted in the middle part of evaporator, using band fin anti-corrosion and high temperature resistant, high pressure Stainless steel or copper tube make, and use shape for disc or U-typed coil arrangement, it is ensured that and the fluid of big flow suppresses cycle, Tube still heater and tower external heat source unicom are recycled, the length and the number of plies for recycling tubulation are calculated by required heat exchange amount.
The filler of packing area is made of heat safe anti-corrosion material, honeycomb structure, is filled in cycle tubulation heating Between device coil pipe, cycle tube still heater is surrounded.
Air inlet is arranged in evaporator lower part, and bottom sets cycle header tank.
It is encapsulated using anti-corrosion material outside above structure, forms cycle tubulation atmospheric evaporator unit casing.
The utility model compared with prior art, has the characteristics that:
1, place before the utility model is concentrated using chemical coagulation-physical filtering combination technique as cycle tubulation atmospheric evaporation Manage step.It is discharged after coagulation pretreatment and is directly sent into regulating tank after the filtering of space-changeable type filter, standby be concentrated by evaporation is used.This work Skill flow is simple, at low cost, efficient.The overwhelming majority in waste water can be effectively removed by chemical coagulation and depth-type filtration processing Suspended solid and colloid are realized and are separated by solid-liquid separation, and the evaporation efficiency of waste water can be effectively improved, and mitigate fouling of evaporator.
2, the utility model especially use containing cycle column tube evaporimeter atmospheric evaporator as evaporation concentration equipment, it is right Waste water carries out low-temperature evaporation concentration after materializing strategy, and the outer freight volume of waste water is greatly reduced, can effectively reduce processing cost.This practicality The evaporator or cooling tower that novel atmospheric evaporator and the prior art are often used are structurally different, also there is essence in principle Difference.Common evaporator or cooling tower are entered in tower by the air of low break value, are carried out with the higher processing flow of temperature After heat exchange, the hot wind of high break value is extracted out from top, achievees the purpose that cooling processing water water temperature;And the cycle row of the utility model Pipe atmospheric evaporator is entered in tower under high-power shaft flow fan effect by the air of dry higher enthalpy value, and gas is in tower Waste water is inside transferred heat to, provides the partial heat needed for waste water evaporation, the air of low enthalpy value high humility is by wind turbine later Extraction, the evaporation capacity of recycling waste water is improved with this, achievees the purpose that concentration.This atmospheric evaporator has several apparent structure wounds Newly, it makes a concrete analysis of as follows:
(1) this evaporator has to use high-power blower, i.e., to ensure that evaporator outlet wind speed reaches 12-20m/s, this It is because this evaporator purpose to be achieved is:The required energy of waste water evaporation is not all of to be provided by heating tubulation, but Design heating tubulation only provides part evaporation institute calorific requirement, and another part is higher by a large amount of enthalpies that high-power blower is pumped into Air provides.I.e. in atmospheric evaporator, a required heat part for waste liquid evaporation is conducted heat by air to be provided, and a part is by following The heating of circular row pipe provides.Since liquid evaporation speed is related with liquid surface air velocity, the flowing velocity of moisture film liquid level air It is bigger, be more conducive to accelerate evaporation rate, therefore by high-power blower, the advantage high using its wind speed, gas flux is big adds Keen draft is logical, improves the flowing velocity of water surface air, the water vapour molecule of effusion is made to spread rapidly, maintains evaporation and diffusion power For constant, do not make its reduction, gas flow and gas flow rate in evaporator can be improved, to improve evaporation efficiency, can save in this way Heating energy consumption is saved, the energy consumption that total energy consumption is heated offer waste water evaporation institute calorific requirement by heating tubulation more entirely is greatly reduced, this essence It is the innovation in this evaporator principle.
(2) in order to improve the enthalpy for the air that high-power blower is pumped into, the air inlet of evaporator can first pass through evaporator side Be arranged into air duct, into air duct in be provided with air dry combustion method pipe, to enter evaporator in air heat, further increase The enthalpy of air and air inlet is made to keep drying, is improved to be conducive to evaporation efficiency inside evaporator.
(3) the cycle tubulation of this evaporator is arranged in packing area, rather than arranged apart, when waste water is drenched into packing area A longer residence time can be obtained, this time can be utilized by circulating-heating tubulation simultaneously, when lengthening the heating to waste water Between, while packing area surface area is big, heat transfer area increases after waste water forms moisture film, can improve the efficiency of heating surface.
(4) this evaporator does not carry out additional heating first and is steamed to improve to the waste water by water circulating pump promotion circulated sprinkling Efficiency is sent out, is because if waste water is first heated, waste water temperature can be more much higher than air themperature, and the heat of water can pass to temperature Lower air causes thermal loss, and waste water evaporation process is an endothermic process, and such case appearance can be unfavorable for waste water Evaporation, this evaporator waste water cycle be use circulating pump Natural Circulation, while by steam heating tubulation be put into packing area, The temperature difference between air and waste water will not be caused, to reduce unnecessary heat loss.It is carried in addition, atmospheric evaporator is provided with Air dry combustion method pipe into air duct, the air for entering evaporator can be heated one step ahead, improve the enthalpy into evaporator air Value, the air of entrance, which transfers heat to waste water, can be more advantageous to waste water evaporation endothermic.
(5) filler of honeycomb structure and high-temperature resistant anti-corrosive material is used in this atmospheric evaporator, service life is long, bee Nest shape structured packing large specific surface area, the contact area that on the one hand can be effectively increased between waste water and air make hydrone escape machine It can increase, on the other hand, increase heat exchange area, accelerate evaporation rate.
3, the utility model operational efficiency is high, and clean moisture is directly evaporate into air, processing procedure non-secondary pollution Object generates.
4, the utility model is compact-sized, and using skid-mounted type platform, dismounting is easy to assembly, realizes mobile operational process, operation effect Rate is higher.
5, the utility model operation expense is low, and equipment is simple, and flow is short, easy to maintain, and service life is long, a whole set of work Automation control may be implemented in skill flow, greatly reduces personnel depaly.
The utility model is a kind of to handle high-salt wastewater using chemical coagulation-physical filtering-high-efficiency evaporating concentration technique Physical chemistry combined treatment equipment, using this equipment can effectively be solved in economic and technical high-salt wastewater processing difficulty Topic.
Description of the drawings
Fig. 1 is the schematic diagram of the utility model high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment.
Fig. 2 is a kind of structural schematic diagram of the cycle tubulation atmospheric evaporator of concrete structure of the utility model.
Fig. 3 is the structural schematic diagram of the cycle tubulation atmospheric evaporator of the utility model another kind concrete structure.
In figure, 1-sewage pump;2-static mixers;3-coagulations fill;4-space-changeable type filters;5-PAC chemicals feeders; 6-sodium carbonate chemicals feeders;7-sodium hydroxide chemicals feeders;8-regulating tanks;9-cycle tubulation atmospheric evaporators, 10-steam Boiler;11-softening water tanks;12-water softening plants;901-axial flow blowers;902-shells;903-water collection devices;904-cloth Hydrophone;905-nozzles;906-cycle tubular heat exchangers;907-fillers;908-air-inlet grilles;909-flowmeters;910— Water circulating pump;911-make-up cooling water casees;912-automatic water replenishing devices;913-discharge outlet;914-pedestals;915-pressure gauges; 916-observation windows;917-air inlet tube stents;918-into air duct;919-air dry combustion method pipes.
Specific implementation mode
The utility model is further illustrated below in conjunction with attached drawing:
Referring to Fig. 1, it includes the sewage being connected to successively by pipeline that high-salt wastewater, which recycles tubulation atmospheric evaporation decrement treatment equipment, Pump 1, coagulation fill 3, space-changeable type filter 4, regulating tank 8, cycle tubulation atmospheric evaporator 9, steam boiler 10, water softening plant 12 and softening water tank 11.PAC chemicals feeders 5, sodium carbonate (Na is respectively adopted in equipment2CO3) chemicals feeder 6 and sodium hydroxide (NaOH) plus Medicine machine 7 is connected with the static mixer 2 on pipeline, and 3 dosings are filled to coagulation by static mixer 2.Equipment is in pipeline Upper setting respective valves and suction pump set automatic water compensating valve and drainpipe steaming 9 hair tower bottom of cycle tubulation atmospheric evaporator.
Referring to Fig. 2, the shell 902 of cycle tubulation atmospheric evaporator 9 is round tower structure, and axial flow blower is arranged in tower 901, pumping is arranged outside in water collection device 903, water distributor 904, cycle tube still heater 906, packed bed 907 and cycle header tank 911, tower Water pump 910.
Wherein, axial flow blower 901 is located at the top of evaporator, is axial-flow type high-power blower, and power of fan needs to ensure to steam Hair device air outlet velocity reaches 12-20m/s.
Water distributor 904 is located at evaporator top, is made of with water conduit tube and branch pipe and nozzle what is arranged in dendroid, nozzle Using big flow atomizer, moisturizing pipe diameter and nozzle specification are selected according to design water, nozzle quantity and arrangement by Cloth water flow and single-nozzle spray flow determine.
Water collection device 903 is mounted between water distributor 904 and axial flow blower 901, is corrosion-resistant material, is made as waveform.
Recycle tube still heater 906 be mounted on evaporator in the middle part of, using band fin anti-corrosion and high temperature resistant, high pressure stainless steel or Copper tube makes, and shape is U-typed coil arrangement, and the length and the number of plies for recycling tubulation are calculated by required heat exchange amount, it is ensured that The fluid of big flow suppresses cycle, cycle tube still heater and 10 unicom of heat source stream boiler outside tower.
Packed bed 907 is made of heat safe anti-corrosion material, honeycomb structure, is filled in cycle tube still heater Between coil pipe.Evaporation packed bed has wider passages, and crystallization condition is not achieved in entire evaporation process, and packed bed will not be caused stifled Plug is readily disassembled, rinses and daily maintenance.
Portion is arranged the setting of air-inlet grille 908 under the vaporizers, and cycle header tank 911 is located at base of evaporator.
The above structural outer is encapsulated using anti-corrosion material, forms cycle tubulation atmospheric evaporator unit casing 902.
Fig. 3 is that another structure type of cycle tubulation atmospheric evaporator 9 increases on the basis of Fig. 2 into air duct 918, it is therefore an objective to improve the temperature for the air being pumped into tower.It is connected at evaporator lower inlet with evaporator into air duct 918, into Air duct shell is sealed with evaporator shell junction but detachably, disconnected side is sealed with anti-corrosion material, into air duct by holder 917 supports need to install air-inlet grille simultaneously into air duct top, into installation air dry combustion method pipe 919 in air duct.
High-salt wastewater is handled using the above equipment and is as follows:
1, high-salt wastewater is pumped into tubular static mixer 2 and sodium carbonate (Na by sewage pump 12CO3) and aluminium system polymerization chlorine After the medicaments such as change aluminium (PAC) and sodium hydroxide (NaOH) are mixed, coagulation is carried out into dosing coagulation tank 3, is removed in waste water Ca2+、Mg2+The impurity such as ion, turbidity, suspended matter, oils.When the coagulation pretreatment, the hydraulic detention time of flocculation process For 15 ± 5min.
2, the suspension after coagulation, which is pumped into, becomes precipitation (suspension) substance that gap pressure filter 4 is gone in water removal, goes out space-changeable type mistake The waste water of filter enters regulating tank 8.
3, high-salt wastewater self-regulated water-saving box after pretreatment is pumped to cycle tubulation atmospheric evaporator 9 by water and is steamed Hair concentration, enters softening water tank 11 by the water of softening equipment 12, enters back into steam boiler 10, the circulating-heating into evaporator High-temperature vapour is passed through in tubulation.
4, the waste liquid after evaporation and concentration, the cycle set water tank bottom pipeline through recycling tubulation atmospheric evaporator lower part are arranged It removes, outward transport processing.Sludge caused by backwash space-changeable type filter carries out outward transport sanitary landfills processing.
Waste water is as follows in the concentration and evaporation processing step of cycle tubulation atmospheric evaporator 9:High-salt wastewater after pretreatment When into atmospheric evaporator, waste water is first pumped into the spray system 905 of 906 top of circulating-heating tubulation through water circulating pump 910, passes through Water distributor 904 equably sprays into suitable waste water being fully atomized into tower, and atomization waste water flows through under the effect of gravity to be added Thermal cycle tubulation 906 is filled with honeycomb padding 907 between heat cycles tubulation, forms thin film shape flow, to increase heat exchange Area and heat-exchange time improve heat exchange efficiency.Spent shower water passes through rapid vapour after fully exchanging heat with air and heat cycles tubulation Chemical conversion vapor enters gas phase, and the vapor after vaporization is taken away by high-power blower 901, to realize the evaporation and concentration of waste water. Remaining waste water falls back to the cycle header tank 911 of base of evaporator, then is sent into spray system 905 by water circulating pump 910 and recycles It uses.The water droplet carried secretly in air is stopped by water collection device 903, falls after rise in cycle tube still heater through in heating evaporation.Cycle It is passed into high-temperature vapour in heating tubulation, high-temperature vapour enters cycle tubulation by coil pipe upper steam entrance, with cycle tubulation pipe Outer spent shower water and air carry out heat exchange, and liquid is gradually condensed by gaseous state, export and flow out from lower steam, pass back into Softening water tank.Meanwhile dry temperature higher air is entered by bottom inlet air grid 908 in tower (Fig. 2) under the action of wind turbine, Or enter into air duct 918 (Fig. 3), the packing area of evaporator is entered after the heating of air dry combustion method pipe 919, waste water flows through filler table Moisture film is formed when face and air carries out heat exchange, and the lower air of high humility temperature is extracted out from top, and waste liquid evaporates required A heat part is conducted heat by air to be provided, and a part is heated by cycle tubulation and provided.Remaining water of waste liquid instills bottom cycle and catchments In case.The waste water for instilling bottom cycle header tank is pumped into spray system again through water circulating pump, and water cycle is got up, and cycle sprinkling is useless Water improves evaporation efficiency.In evaporator, the ratio of design treatment water and quantity of circulating water is 1:10, evaporation efficiency 50%.
Compared with the wind turbine used by the common evaporator of high-power blower used by this evaporator, difference lies in:Commonly Only there are one drainages for the fan action of evaporator, only aspirate the steam in tower by wind turbine and draw evaporator;And This evaporator uses high-power blower, can improve gas flow and gas flow rate in evaporator, and evaporation rate is empty with liquid level surface Gas velocity is related, and air velocity is bigger, is more conducive to evaporate;And in this evaporator principle also with conventional evaporator different from, The required energy of conventional evaporator evaporation is substantially all to be provided by heating tubulation, and an energy part needed for the evaporation of this evaporator It is provided by heating tube, another part is provided by the higher air of enthalpy, can be saved heating energy consumption, therefore is also required to using more powerful Wind turbine to provide the gas flow of bigger, but more common evaporator is greatly reduced on total energy consumption;Evaporator fan power needs According to evaporator packing area height, designed rating size determines, evaporator outlet wind speed need to be ensured about in 12- depending on actual conditions 20m/s, exit wind speed when air outlet velocity is much larger than common evaporator operation.In energy consumption, common evaporator often evaporates 1kg water The quantity of steam being actually needed is about in 1.2-1.6kg, and this evaporator often evaporates the quantity of steam that 1kg water is actually needed and about exists 0.6-0.8kg, this evaporator overall energy consumption are about the 50%-60% of common evaporator overall energy consumption, and specific effect regards live ring Border temperature, humidity variation have certain fluctuation.

Claims (6)

1. a kind of high-salt wastewater recycles tubulation atmospheric evaporation decrement treatment equipment, which is characterized in that including being connected to successively by pipeline Sewage pump, coagulation filling, filter, regulating tank, cycle tubulation atmospheric evaporator, steam boiler, water tank, on pipeline Respective valves and suction pump are set, automatic water compensating valve and drainpipe are set in base of evaporator;Added using PAC chemicals feeders, sodium carbonate Medicine machine and sodium hydroxide are connected with the static mixer on pipeline, and dosing is filled to coagulation by static mixer;
The cycle tubulation atmospheric evaporator is square or round tower structure, and the high-power wind of axial-flow type is arranged in the tower of evaporator Suction pump is arranged outside in machine, water collection device, water distributor, cycle tube still heater, packing area and cycle header tank, tower;The axial-flow type High-power blower is located at evaporator top exit, and the power of wind turbine need to ensure that evaporator outlet wind speed reaches 12-20m/s;Cloth Hydrophone is located at evaporator top, and water collection device is mounted between water distributor and axial-flow type high-power blower;It is filler in the middle part of evaporator Area is filled with the heat safe anti-corrosion material of honeycomb structure, and cycle tube still heater is arranged in packing area, around by filler It surrounds, the cycle tube still heater and tower external heat source unicom, the length and the number of plies for recycling tubulation are calculated by required heat exchange amount It arrives;Air inlet, base of evaporator setting cycle header tank is arranged in evaporator lower part.
2. high-salt wastewater as described in claim 1 recycles tubulation atmospheric evaporation decrement treatment equipment, it is characterised in that:It is described into Be also associated at air port into air duct, into air dry combustion method pipe is equipped in air duct, be tightly connected into air duct and evaporator air inlet and For detachable structure.
3. high-salt wastewater as described in claim 1 recycles tubulation atmospheric evaporation decrement treatment equipment, it is characterised in that:Evaporator Air inlet and the air inlet of air duct is provided with air-inlet grille.
4. high-salt wastewater as described in claim 1 recycles tubulation atmospheric evaporation decrement treatment equipment, it is characterised in that:The receipts Hydrophone is corrosion-resistant material, is made as waveform.
5. high-salt wastewater as described in claim 1 recycles tubulation atmospheric evaporation decrement treatment equipment, it is characterised in that:The cloth Hydrophone is to be made of with water conduit tube and branch pipe and nozzle what is arranged in dendroid, and nozzle uses big flow atomizer, nozzle number Amount and arrangement are determined by cloth water flow and single-nozzle spray flow.
6. high-salt wastewater as described in claim 1 recycles tubulation atmospheric evaporation decrement treatment equipment, it is characterised in that:It is described to follow Circular row pipe heater uses band fin anti-corrosion and high temperature resistant, high pressure stainless steel or copper tube make, use shape for disc or U-typed coil arrangement.
CN201721834882.7U 2017-12-25 2017-12-25 A kind of high-salt wastewater cycle tubulation atmospheric evaporation decrement treatment equipment Expired - Fee Related CN207726912U (en)

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Application Number Priority Date Filing Date Title
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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109110848A (en) * 2018-09-14 2019-01-01 广州中环万代环境工程有限公司 A kind of high-salt wastewater air energy low-temperature vaporising device and air energy low-temperature method of evaporating

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109110848A (en) * 2018-09-14 2019-01-01 广州中环万代环境工程有限公司 A kind of high-salt wastewater air energy low-temperature vaporising device and air energy low-temperature method of evaporating
CN109110848B (en) * 2018-09-14 2019-04-30 广州中环万代环境工程有限公司 A kind of high-salt wastewater air energy low-temperature vaporising device and air energy low-temperature method of evaporating
US11192802B2 (en) 2018-09-14 2021-12-07 Depei Liu Desalinization device and method of using the same

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Granted publication date: 20180814