CN207726911U - A kind of shale gas exploitation fracturing fluid cycle tubulation evaporation minimizing processing equipment - Google Patents

A kind of shale gas exploitation fracturing fluid cycle tubulation evaporation minimizing processing equipment Download PDF

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CN207726911U
CN207726911U CN201721834862.XU CN201721834862U CN207726911U CN 207726911 U CN207726911 U CN 207726911U CN 201721834862 U CN201721834862 U CN 201721834862U CN 207726911 U CN207726911 U CN 207726911U
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evaporator
water
cycle
shale gas
tubulation
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翟俊
杨忠平
肖海文
李锋超
陈忠礼
姚婧梅
李伟
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Chongqing University
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Abstract

一种页岩气开采压裂返排废液循环列管蒸发减量化处理设备,包括依次由管道连通的混凝灌、Fenton反应罐、压滤机、沉淀池、砂滤罐、循环列管大气蒸发器、蒸汽锅炉、水软化设备和软化水箱;还包括与混凝灌相联的碳酸钠和PAC加药装置、与Fenton反应罐相联的双氧水和硫酸铁以及硫酸加药装置、与静态混合器相联的氢氧化钠加药装置、静态混合器、抽水泵以及在管道上设置相应阀门。本实用新型各个工艺段环环相扣,工艺完备,对进水的适用性广泛。同时流程简单、高效节能,运行成本低,系统结构紧凑,可以大幅降低外运处理的废水量。

A shale gas mining fracturing flowback waste liquid circulation tube evaporation reduction treatment equipment, including coagulation irrigation, Fenton reaction tank, filter press, sedimentation tank, sand filter tank, and circulation tube connected by pipelines in sequence Atmospheric evaporator, steam boiler, water softening equipment and softened water tank; also includes sodium carbonate and PAC dosing device connected with coagulation tank, hydrogen peroxide, ferric sulfate and sulfuric acid dosing device connected with Fenton reaction tank, and static The sodium hydroxide dosing device connected to the mixer, the static mixer, the water pump and the corresponding valves are set on the pipeline. Each process section of the utility model is interlocking with each other, the process is complete, and the utility model has wide applicability to water inflow. At the same time, the process is simple, efficient and energy-saving, the operating cost is low, and the system structure is compact, which can greatly reduce the amount of wastewater treated by Sinotrans.

Description

一种页岩气开采压裂返排废液循环列管蒸发减量化处理设备A shale gas mining fracturing flowback waste liquid circulation tube evaporation reduction treatment equipment

技术领域technical field

本实用新型涉及工业污废水处理领域,特别涉及页岩气开采压裂返排废液减量化的处理工艺。The utility model relates to the field of industrial sewage and waste water treatment, in particular to a treatment process for reducing the volume of shale gas mining and fracturing waste liquid flowback.

背景技术Background technique

页岩气开采压裂返排废液是在页岩气开采过程中产生的一种“特殊作(工)业废水”。我国页岩气开采每年排放的压裂废液高达100万吨左右。具有关统计,每口页岩气生产井压裂返排废液约30~50m3/d。其组分十分复杂,主要含有油类、各种胍胶、甲醛等多种有机添加剂、硫酸盐等各类化学处理剂、细菌等多种物质。因此页岩气的压裂返排废液具有高COD值、高含盐量、高稳定性、高粘度、刺激气味强烈,难降解等特点,对环境的危害极大。这些物质进入环境后,尤其是进入地下水和地表水环境后,将会给水、土环境系统带来持久性的污染,对页岩气的生产和长远发展造成不可估量的损失。因此,其压裂返排废液处理成为制约页岩气开发过程中的关键环境问题之一。Shale gas exploitation fracturing flowback waste liquid is a kind of "special industrial (industrial) wastewater" produced in the process of shale gas exploitation. my country's shale gas mining discharges as much as 1 million tons of fracturing waste fluid every year. According to relevant statistics, the fracturing flowback waste fluid of each shale gas production well is about 30-50m 3 /d. Its components are very complex, mainly containing various organic additives such as oil, various guar gums, formaldehyde, various chemical treatment agents such as sulfate, bacteria and other substances. Therefore, shale gas fracturing flowback waste fluid has the characteristics of high COD value, high salt content, high stability, high viscosity, strong pungent smell, and difficult to degrade, which is extremely harmful to the environment. After these substances enter the environment, especially the groundwater and surface water environment, they will bring persistent pollution to the water and soil environment system, and cause immeasurable losses to the production and long-term development of shale gas. Therefore, the treatment of fracturing flowback waste fluid has become one of the key environmental issues restricting the development of shale gas.

然而,受现场条件和技术水平限制,我国页岩气压裂废液的处理技术尚不成熟,甚至有些未经处理就直接将废液回注或排放到环境中,这更进一步加剧了页岩气压裂废液处理的紧迫性。目前,常用的压裂废液处理工艺主要有“Fenton氧化-絮凝-SBR联合处理”,“絮凝-隔油-光催化氧化”,“Fenton氧化-絮凝回注处理”,“絮凝-隔油-沉淀-双级氧化”,“化学脱稳-过滤-O3/H2O2-复合催化氧化-深度氧化”等。上述组合工艺,可以实现单项技术的优势互补,提高处理效果、减少化学药剂用量、降低成本等。但这些工艺都注重对于废水中悬浮物质和有机物的处理,对于废水中盐的处理效果并不明显。又由于页岩气压裂废液中含盐量十分高,因此,对于废液中盐的处理成为页岩气压裂废液处理的一道难题。并且这些处理工艺大多停留在试验研究阶段,实际工程运用较少,即使少数应用,处理后外运回注水或排放水量仍然较大,导致外运、回注成本居高不下。However, limited by site conditions and technical level, the treatment technology of shale gas fracturing waste fluid in my country is not yet mature, and some waste fluids are even directly reinjected or discharged into the environment without treatment, which further aggravates the shale gas fracturing process. The urgency of gas fracturing wastewater treatment. At present, the commonly used fracturing waste treatment processes mainly include "Fenton oxidation-flocculation-SBR combined treatment", "flocculation-oil separation-photocatalytic oxidation", "Fenton oxidation-flocculation reinjection treatment", "flocculation-oil separation- Precipitation - two-stage oxidation", "chemical destabilization - filtration - O 3 /H 2 O 2 - composite catalytic oxidation - deep oxidation", etc. The above combined process can realize the complementary advantages of individual technologies, improve the treatment effect, reduce the amount of chemical agents, and reduce costs. However, these processes all focus on the treatment of suspended matter and organic matter in wastewater, and the treatment effect on salt in wastewater is not obvious. And because the salt content in shale gas fracturing waste fluid is very high, the treatment of salt in waste fluid has become a difficult problem in the treatment of shale gas fracturing waste fluid. Moreover, most of these treatment processes are still in the experimental research stage, and the actual engineering application is seldom. Even if a small number of applications are used, the amount of re-injection or discharge water after treatment is still large, resulting in high costs for re-injection and re-injection.

随着国内日益严峻的环境问题,对页岩气开采过程中所产生的压裂废液进行高效、低成本减量处理成为其发展的迫切需求。With the increasingly severe environmental problems in the country, it is an urgent need for the development of fracturing waste fluid produced in the process of shale gas exploitation with high efficiency and low cost.

发明内容Contents of the invention

本实用新型的目的在于针对现有页岩气开采压裂返排废液处理量大的问题,提供一种效率高、操作简便、便于移动、处理成本低的页岩气开采压裂返排废液循环列管蒸发减量化处理设备,针对压裂返排废液本身具有成分复杂、多变性和分散性的特点,重点实现废液减量化,以解决我国页岩气开采行业压裂返排废液处理的难题。The purpose of the utility model is to provide a shale gas mining fracturing and flowback waste solution with high efficiency, easy operation, easy movement and low processing cost in view of the problem of large amount of waste liquid treatment in fracturing and blowback of existing shale gas mining. Liquid circulation tube evaporation reduction treatment equipment, in view of the characteristics of complex composition, variability and dispersion of fracturing flowback waste liquid itself, focuses on reducing waste liquid to solve the problem of fracturing flowback in my country's shale gas mining industry. The problem of waste water treatment.

本实用新型采用的技术方案如下:The technical scheme that the utility model adopts is as follows:

一种页岩气开采压裂返排废液循环列管蒸发减量化处理设备,包括依次由管道连通的混凝灌、Fenton反应罐、压滤机、沉淀池、砂滤罐、循环列管大气蒸发器、蒸汽锅炉、水软化设备和软化水箱;还包括与混凝灌相联的碳酸钠和PAC加药装置、与Fenton反应罐相联的双氧水和硫酸铁以及硫酸加药装置、与静态混合器相联的氢氧化钠加药装置、静态混合器、抽水泵以及在管道上设置相应阀门。A shale gas mining fracturing flowback waste liquid circulation tube evaporation reduction treatment equipment, including coagulation irrigation, Fenton reaction tank, filter press, sedimentation tank, sand filter tank, and circulation tube connected by pipelines in sequence Atmospheric evaporator, steam boiler, water softening equipment and softened water tank; also includes sodium carbonate and PAC dosing device connected with coagulation tank, hydrogen peroxide, ferric sulfate and sulfuric acid dosing device connected with Fenton reaction tank, and static The sodium hydroxide dosing device connected to the mixer, the static mixer, the water pump and the corresponding valves are set on the pipeline.

设备采用了特殊结构的循环列管大气蒸发器,其为方型或圆形塔状结构,蒸发器的塔内设置风机、收水器、布水器、循环列管加热器、填料区和循环集水箱,塔外设置抽水泵。The equipment adopts a special structure of circulating tube atmospheric evaporator, which is a square or circular tower structure. The tower of the evaporator is equipped with a fan, a water eliminator, a water distributor, a circulating tube heater, a packing area and a circulating The water collecting tank and the water pump are arranged outside the tower.

风机为轴流式大功率风机,设在蒸发器顶部出口处,风机型号及功率由所需蒸发风量确定,但风机的功率必须保证蒸发器出口风速达到12-20m/s。The fan is an axial-flow high-power fan, which is installed at the top outlet of the evaporator. The type and power of the fan are determined by the required evaporation air volume, but the power of the fan must ensure that the wind speed at the outlet of the evaporator reaches 12-20m/s.

布水器设在蒸发器上部,由呈树枝状布置的配水干管和支管及喷嘴组成,喷嘴采用大流量雾化喷嘴,补水管直径和喷嘴规格根据设计水量选用,喷嘴数量及布置方式由布水流量和单个喷嘴喷水流量确定。The water distributor is located on the upper part of the evaporator, and is composed of branch pipes and nozzles arranged in a branch shape. The nozzles adopt large-flow atomizing nozzles. The diameter of the water supply pipe and the specifications of the nozzles are selected according to the design water volume. The flow rate and individual nozzle spray flow are determined.

收水器安装在布水器与风机之间,为耐腐蚀材质,制作为波浪形。The water eliminator is installed between the water distributor and the fan, and is made of corrosion-resistant material and made into a wave shape.

循环列管加热器安装在蒸发器中部的填料区中,采用带翅片防腐且耐高温、高压不锈钢或紫铜管制作,采用外形为圆盘形或“U”型盘管结构,确保大流量的流体强压循环,循环列管加热器与塔外热源联通,循环列管的长度及层数由所需换热量计算得到。The circulating tube heater is installed in the packing area in the middle of the evaporator. It is made of anti-corrosion, high-temperature resistant, high-pressure stainless steel or copper tubes with fins. It adopts a disc-shaped or "U"-shaped coil structure to ensure large flow The fluid is forced to circulate, the circulation tube heater is connected with the heat source outside the tower, and the length and the number of layers of the circulation tube are calculated from the required heat exchange.

填料区的填料采用耐高温的防腐材料制成,蜂窝状结构,其充填于循环列管加热器盘管间,包围住循环列管加热器。The packing in the packing area is made of high temperature resistant anti-corrosion material with a honeycomb structure, which is filled between the coils of the circulating tube heater and surrounds the circulating tube heater.

蒸发器下部设置进风口,底部设循环集水箱。An air inlet is provided at the lower part of the evaporator, and a circulating water collecting tank is provided at the bottom.

上述结构外部采用防腐材料封装,形成循环列管大气蒸发器机组外壳。The exterior of the above structure is encapsulated with anti-corrosion materials to form the casing of the circulating tube atmospheric evaporator unit.

本实用新型的特点如下:The features of the utility model are as follows:

1、本实用新型采用化学混凝-Fenton深度氧化-物理压滤组合技术作为循环列管蒸发浓缩前处理步骤。混凝预处理后出水直接经压滤机压滤后进行后续Fenton深度氧化处理。深度氧化后的出水经沉淀后再循环回带式压滤机压滤。此工艺流程简单,通过化学混凝+Fenton深度氧化处理能有效去除废水中的绝大多数的有机物污染物和悬浮固体,经压滤实现固液分离,能够有效提高废水的蒸发效率,防止蒸发器结垢。1. The utility model adopts the combination technology of chemical coagulation-Fenton deep oxidation-physical pressure filtration as the pretreatment step of circulation tube evaporation and concentration. After coagulation pretreatment, the effluent is directly filtered by a filter press and then undergoes subsequent Fenton deep oxidation treatment. The effluent after deep oxidation is precipitated and then circulated back to the belt filter press for filtration. This process is simple, through chemical coagulation + Fenton deep oxidation treatment can effectively remove most of the organic pollutants and suspended solids in wastewater, and achieve solid-liquid separation through pressure filtration, which can effectively improve the evaporation efficiency of wastewater and prevent evaporators Fouling.

2、本实用新型特别采用了含循环列管蒸发器的大气蒸发器作为蒸发浓缩设备,对物化处理后废水进行低温蒸发浓缩,大幅度减少废水外运量,能有效降低处理成本。本实用新型的大气蒸发器与现有技术常使用的蒸发器或冷却塔在结构上不同,在原理上也有本质区别。通常的蒸发器或冷却塔是通过低晗值的空气进入塔内,与温度较高的处理水流进行热交换后,高晗值的热风从顶部抽出,达到降温处理水水温的目的;而本实用新型的大气蒸发器是通过干燥的较高焓值的空气在大功率轴流风机作用下进入塔内,气体在塔内将热量传递给废水,提供废水蒸发所需的部分热量,之后低焓值高湿度的空气在被风机抽出,以此提高循环废水的蒸发量,达到浓缩的目的。循环列管大气蒸发器与传统蒸发器相比能大幅降低加热能耗。与用生物法进行后续处理相比,本方法的优点为处理设施较小、处理工艺简单、运行成本降低,对进水水质适用范围较广。用生物法处理时,高含盐量的废液可能会对微生物的生长有抑制作用,影响处理效果,而采用蒸发浓缩法则能避免此问题。且进行蒸发处理一方面能将废水进行减量化,有效降低处理成本,大幅度减少废水外运量;另一方面,将页岩气压裂废液浓缩,有利于后续外运处理时将废液中的金属盐类回收再利用,能有效解决页岩气压裂废液中含盐量较高的问题,将废液中的金属盐类资源化。2. The utility model specially adopts an atmospheric evaporator with a circular tube evaporator as the evaporation concentration equipment, which performs low-temperature evaporation concentration on the waste water after physical and chemical treatment, greatly reduces the amount of waste water transported out, and can effectively reduce the treatment cost. The atmospheric evaporator of the utility model is different in structure from the evaporator or cooling tower commonly used in the prior art, and also has essential differences in principle. The usual evaporator or cooling tower enters the tower through the air with low H value, and after heat exchange with the high temperature treatment water flow, the hot air with high H value is pumped out from the top to achieve the purpose of lowering the temperature of the treated water; and this utility model The new atmospheric evaporator enters the tower through the dry air with high enthalpy under the action of a high-power axial flow fan. The gas transfers heat to the waste water in the tower, providing part of the heat required for the evaporation of waste water, and then the low enthalpy value The air with high humidity is drawn out by the fan, so as to increase the evaporation of the circulating wastewater and achieve the purpose of concentration. Compared with the traditional evaporator, the circulating tubular atmospheric evaporator can greatly reduce the heating energy consumption. Compared with subsequent treatment by biological methods, this method has the advantages of smaller treatment facilities, simple treatment process, lower operating costs, and a wider range of application to influent water quality. When biological treatment is used, the waste liquid with high salt content may inhibit the growth of microorganisms and affect the treatment effect, but the use of evaporation and concentration can avoid this problem. Moreover, on the one hand, the evaporation treatment can reduce the waste water, effectively reduce the treatment cost, and greatly reduce the amount of waste water transported; on the other hand, the shale gas fracturing waste liquid is concentrated, which is beneficial to the waste The recovery and reuse of metal salts in the liquid can effectively solve the problem of high salt content in the shale gas fracturing waste liquid, and turn the metal salts in the waste liquid into resources.

本大气蒸发器具有几个明显的结构创新,具体分析如下:This atmospheric evaporator has several obvious structural innovations, the specific analysis is as follows:

(1)本蒸发器必须要采用大功率风机,即要保证蒸发器出口风速达到12-20m/s,这是因为本蒸发器要达到的目的是:废水蒸发所需要的能量不是全部由加热列管提供,而是设计加热列管仅提供一部分蒸发所需热量,另一部分由大功率风机抽入的大量焓值较高的空气提供。即在大气蒸发器中,废液蒸发的所需的热量一部分由空气传热提供,一部分由循环列管加热提供。由于液体蒸发速度与液体表面空气流速有关,水膜液面空气的流动速度越大,越有利于加快蒸发速率,因此通过大功率风机,利用其风速高、气体通量大的优势,加强空气流通,提高水面空气的流动速度,使逸出的水蒸气分子迅速扩散,维持蒸发扩散动力为常数,不使其降低,可提高蒸发器内气体流量与气体流速,从而提高蒸发效率,这样能节省加热能耗,总能耗较全由加热列管加热提供废水蒸发所需热量的能耗大幅降低,这实质是本蒸发器原理上的创新。(1) The evaporator must use a high-power fan, that is, to ensure that the wind speed at the outlet of the evaporator reaches 12-20m/s. This is because the purpose of this evaporator is: the energy required for the evaporation of waste water is not all provided by the heating column. Instead, the heating tubes are designed to provide only a part of the heat required for evaporation, and the other part is provided by a large amount of air with a high enthalpy drawn in by a high-power fan. That is, in the atmospheric evaporator, part of the heat required for the evaporation of waste liquid is provided by air heat transfer, and part of it is provided by the heating of circulating tubes. Since the liquid evaporation rate is related to the air flow rate on the liquid surface, the greater the flow rate of the air on the surface of the water film, the more conducive to speeding up the evaporation rate. Therefore, the high-power fan takes advantage of its high wind speed and large gas flux to enhance air circulation. , increase the flow velocity of the air on the water surface, make the escaped water vapor molecules diffuse rapidly, maintain the evaporation diffusion power as a constant, do not reduce it, and increase the gas flow rate and gas flow rate in the evaporator, thereby increasing the evaporation efficiency, which can save heating Energy consumption, the total energy consumption is greatly reduced compared with the energy consumption of the heating tube heating to provide the heat required for the evaporation of waste water, which is essentially an innovation in the principle of this evaporator.

(2)为了提高大功率风机抽入的空气的焓值,蒸发器的进风先会经过蒸发器一侧设置的进风筒,进风筒内设置有空气干烧管,对进入蒸发器内的空气进行加热,进一步提高空气的焓值且使进风保持干燥,从而有利于蒸发器内部的蒸发效率提高。(2) In order to increase the enthalpy value of the air sucked in by the high-power fan, the air intake of the evaporator will first pass through the air intake tube installed on one side of the evaporator. The air is heated to further increase the enthalpy of the air and keep the incoming air dry, which is conducive to improving the evaporation efficiency inside the evaporator.

(3)本蒸发器的循环列管布置在填料区中,而不是分开布置,当废水淋入填料区时会获得一个较长的滞留时间,这个时间能同时被循环加热列管利用,加长对废水的加热时间,同时填料区表面积大,废水形成水膜后传热面积增大,能提高加热效率。(3) The circulation tubes of this evaporator are arranged in the packing area instead of being arranged separately. When the waste water is poured into the packing area, a longer residence time will be obtained. The heating time of the waste water is shortened. At the same time, the surface area of the filler area is large, and the heat transfer area increases after the waste water forms a water film, which can improve the heating efficiency.

(4)本蒸发器对通过循环水泵提升循环喷淋的废水,不先进行额外加热来提高蒸发效率,是因为如果废水先被加热,废水温度会比空气温度高很多,水的热量会传递给温度较低的空气,造成热量损失,而废水蒸发过程是一个吸热过程,这种情况出现会不利于废水的蒸发,本蒸发器的废水循环是采用循环泵自然循环,同时将蒸汽加热列管放入填料区中,不会造成空气与废水之间的温差,从而减少不必要的热损失。另外,大气蒸发器设置有带有空气干烧管的进风筒,能对进入蒸发器的空气先一步进行加热,提高进入蒸发器空气的焓值,进入的空气将热量传递给废水会更有利于废水蒸发吸热。(4) This evaporator does not perform additional heating to improve the evaporation efficiency of the wastewater that is circulated and sprayed through the circulating water pump, because if the wastewater is heated first, the temperature of the wastewater will be much higher than the air temperature, and the heat of the water will be transferred to Air with a lower temperature causes heat loss, and the process of evaporating waste water is a heat-absorbing process. This situation will not be conducive to the evaporation of waste water. The waste water circulation of this evaporator adopts the natural circulation of the circulation pump, and at the same time, the steam heats the tubes. Putting it in the packing area will not cause a temperature difference between the air and the waste water, thereby reducing unnecessary heat loss. In addition, the atmospheric evaporator is equipped with an air inlet tube with an air dry-burning tube, which can heat the air entering the evaporator first, and increase the enthalpy of the air entering the evaporator, and the incoming air will transfer heat to the waste water. Conducive to waste water evaporation heat absorption.

(5)本大气蒸发器内采用了蜂窝状结构且耐高温防腐材料的填料,使用寿命长,蜂窝状结构填料比表面积大,一方面能有效增加废水与空气间的接触面积,使水分子逸出机会增多,另一方面,增大了换热面积,加快了蒸发速度。(5) The atmospheric evaporator adopts honeycomb structure and high temperature resistant and anti-corrosion material packing, which has a long service life, and the honeycomb structure packing has a large specific surface area. On the other hand, the heat exchange area is increased and the evaporation rate is accelerated.

3、本实用新型运行上采用连续进水,通过阀门控制,实现废水在混凝池、Fenton氧化池、压滤机、砂滤罐和蒸发器之间连续运行状态,避免间歇运行带来的延迟性,提高运行效率;3. The utility model adopts continuous water inlet in operation, and realizes the continuous operation state of wastewater between the coagulation tank, Fenton oxidation tank, filter press, sand filter tank and evaporator through valve control, avoiding the delay caused by intermittent operation performance, improve operating efficiency;

4、本实用新型设备简单,流程短,维护方便,无需现场构建反应池和其它构建筑物;使用寿命长;整套工艺流程可以实现自动化控制,大大减少人员配置;4. The utility model has simple equipment, short process, convenient maintenance, and no need to build reaction pools and other structures on site; it has a long service life; the entire process flow can be automatically controlled, greatly reducing staffing;

本实用新型是一种采用化学混凝-物理压滤-高效蒸发浓缩技术来处理页岩气压裂返排废液的物理化学组合系统,采用本系统可以在经济和技术上有效解决我国页岩气开采过程中压裂返排液处理的难题。The utility model is a physical and chemical combined system that uses chemical coagulation-physical pressure filtration-high-efficiency evaporation and concentration technology to process shale gas fracturing waste liquid. The system can effectively solve the problem of shale in my country in terms of economy and technology. Difficulties in the treatment of fracturing flowback fluid in the process of gas production.

附图说明Description of drawings

图1是本实用新型的页岩气开采压裂返排废液循环列管蒸发减量化处理设备示意图。Fig. 1 is a schematic diagram of the shale gas mining fracturing flowback waste liquid circulation tube evaporation reduction treatment equipment of the present utility model.

图2是本实用新型一种具体结构的循环列管大气蒸发器的结构示意图。Fig. 2 is a schematic structural view of a circulating tubular atmospheric evaporator with a specific structure of the present invention.

图3是本实用新型另一种具体结构的循环列管大气蒸发器的结构示意图。Fig. 3 is a structural schematic diagram of another specific structure of the circulating tubular atmospheric evaporator of the present invention.

图中,1—混凝灌;2—Fenton反应罐;3—压滤机;4—沉淀池;5—砂滤罐;6—氢氧化钠加药装置;7—碳酸钠和PAC加药装置;8—双氧水、硫酸铁和硫酸加药装置;9—循环列管大气蒸发器;10—静态混合器;11—抽水泵;901—轴流风机;902—外壳;903—收水器;904—布水器;905—喷嘴;906—循环列管换热器;907—填料;908—进风格栅;909—流量计;910—循环水泵;911—循环给水箱;912—自动补水器;913—排水口;914—底座;915—压力表;916—观察窗;917—进风筒支架;918—进风筒;919—空气干烧管。In the figure, 1—coagulation tank; 2—Fenton reaction tank; 3—filter press; 4—sedimentation tank; 5—sand filter tank; 6—sodium hydroxide dosing device; 7—sodium carbonate and PAC dosing device ;8—hydrogen peroxide, ferric sulfate and sulfuric acid dosing device; 9—circulation tube atmospheric evaporator; 10—static mixer; 11—pump; 901—axial fan; 902—shell; 903—water eliminator; —Water distributor; 905—Nozzle; 906—Circulating tube heat exchanger; 907—Filler; 908—Inlet grille; 909—Flow meter; 910—Circulating water pump; 911—Circulating water supply tank; ; 913—drain outlet; 914—base; 915—pressure gauge; 916—observation window; 917—air intake tube bracket; 918—air intake tube;

具体实施方式Detailed ways

以下结合附图对本实用新型做进一步描述Below in conjunction with accompanying drawing, the utility model is further described

参阅附图1,本实用新型提出的页岩气开采压裂返排废液循环列管蒸发减量化处理设备包括依次由管道连通的混凝灌1、Fenton反应罐2、压滤机3、沉淀池4、砂滤罐5、循环列管蒸发器9、与混凝灌相联的碳酸钠和PAC加药装置7、与Fenton反应罐相联的双氧水、硫酸铁和硫酸加药装置8、与静态混合器相联的氢氧化钠加药装置6、静态混合器10、抽水泵11,在管道上设置相应阀门。Referring to the accompanying drawing 1, the shale gas mining fracturing flowback waste liquid circulation tube evaporation reduction treatment equipment proposed by the utility model includes a coagulation irrigation 1, a Fenton reaction tank 2, a filter press 3, Sedimentation tank 4, sand filter tank 5, circulating tube evaporator 9, sodium carbonate and PAC dosing device 7 connected with coagulation tank, hydrogen peroxide, ferric sulfate and sulfuric acid dosing device 8 connected with Fenton reaction tank, The sodium hydroxide dosing device 6, the static mixer 10, and the water pump 11 connected with the static mixer are provided with corresponding valves on the pipelines.

参见图2,循环列管大气蒸发器9的外壳902为方柱型塔状结构,塔内设置轴流风机901、收水器903、布水器904、循环列管加热器906、填料床907和循环集水箱911,塔外设置抽水泵910。Referring to Fig. 2, the shell 902 of the circulating tube atmospheric evaporator 9 is a square column tower structure, and the tower is equipped with an axial flow fan 901, a water eliminator 903, a water distributor 904, a circulating tube heater 906, and a packed bed 907 And a circulating water collection tank 911, and a water pump 910 is arranged outside the tower.

其中,轴流风机901设在蒸发器顶部,为轴流式大功率风机,风机功率需要保证蒸发器出口风速达到12-20m/s。Among them, the axial flow fan 901 is set on the top of the evaporator, which is an axial flow high-power fan, and the fan power needs to ensure that the wind speed at the outlet of the evaporator reaches 12-20m/s.

布水器904设在蒸发器上部,由呈树枝状布置的配水干管和支管及喷嘴组成,喷嘴采用大流量雾化喷嘴,补水管直径和喷嘴规格根据设计水量选用,喷嘴数量及布置方式由布水流量和单个喷嘴喷水流量确定。The water distributor 904 is located on the upper part of the evaporator, and is composed of branch pipes and nozzles arranged in a dendrite shape. The nozzles adopt large-flow atomizing nozzles. The diameter of the water supply pipe and the specifications of the nozzles are selected according to the design water volume. Water flow rate and individual nozzle spray water flow rate determination.

收水器903安装在布水器904与轴流风机901之间,为耐腐蚀材质,制作为波浪形。The water eliminator 903 is installed between the water distributor 904 and the axial flow fan 901, and is made of corrosion-resistant material in a wave shape.

循环列管加热器906安装在蒸发器中部,采用带翅片防腐且耐高温、高压不锈钢或紫铜管制作,外形为“U”型盘管结构,循环列管的长度及层数由所需换热量计算得到,确保大流量的流体强压循环,循环列管加热器与塔外的热源蒸汽锅炉10联通,热源来自于蒸汽锅炉。The circulating tube heater 906 is installed in the middle of the evaporator, and is made of anti-corrosion, high-temperature resistant, high-pressure stainless steel or copper tubes with fins. The shape is a "U"-shaped coil structure. The heat exchange is calculated to ensure the high-flow fluid pressure circulation, and the circulation tube heater is connected with the heat source steam boiler 10 outside the tower, and the heat source comes from the steam boiler.

填料床907采用耐高温的防腐材料制成,蜂窝状结构,其充填于循环列管加热器的盘管间。蒸发填料床有较宽通道,并且整个蒸发过程中达不到结晶条件,不会造成填料床堵塞,易于拆卸、冲洗和日常维护。The packed bed 907 is made of high temperature resistant anti-corrosion material with a honeycomb structure, which is filled between the coils of the circulating tube heater. The evaporating packed bed has a wide channel, and the crystallization condition cannot be reached during the whole evaporation process, which will not cause the packed bed to be blocked, and is easy to disassemble, wash and maintain routinely.

进风格栅908设置在蒸发器下部设置,循环集水箱911位于蒸发器底部。The air intake grille 908 is arranged at the lower part of the evaporator, and the circulating water collection tank 911 is located at the bottom of the evaporator.

以上结构外部采用防腐材料封装,形成循环列管大气蒸发器机组外壳902。The exterior of the above structure is packaged with anti-corrosion materials to form the casing 902 of the circulating tubular atmospheric evaporator unit.

图3为循环列管大气蒸发器9的另一种结构形式,其在图2的基础上,增加了进风筒918,目的是提高抽入塔内的空气的温度。进风筒918与蒸发器于蒸发器下部进口处连通,进风筒外壳与蒸发器外壳连接处密封但可拆卸,非连接一侧用防腐材料密封,进风筒由支架917支撑,进风筒顶部同时需安装进风格栅,进风筒中安装空气干烧管919。Fig. 3 is another structural form of the circulating tubular atmospheric evaporator 9, on the basis of Fig. 2, an air inlet tube 918 is added to increase the temperature of the air drawn into the tower. The air inlet cylinder 918 communicates with the evaporator at the entrance of the lower part of the evaporator. The connection between the air inlet cylinder shell and the evaporator shell is sealed but detachable. The non-connecting side is sealed with anti-corrosion materials. The air inlet cylinder is supported by the bracket 917. At the same time, the air intake grille needs to be installed on the top, and the air dry heating pipe 919 is installed in the air intake cylinder.

压裂返排废液处理主要由四个处理流程组成:The treatment of fracturing flowback waste fluid mainly consists of four treatment processes:

(1)混凝沉淀预处理:将压裂返排液泵入混凝预处理罐中,用加药装置7向压裂返排液废水中加入铝系聚合氯化铝(PAC)和碳酸钠(Na2CO3)进行混凝预处理,使Ca2+、Mg2+离子形成沉淀,同时去除废水中的浊度、悬浮物压裂液残余成分、原油等杂质。所述混凝预处理絮凝过程的水力停留时间为15±5min。(1) Coagulation and sedimentation pretreatment: pump the fracturing flowback fluid into the coagulation pretreatment tank, and add aluminum-based polyaluminum chloride (PAC) and sodium carbonate to the fracturing flowback fluid wastewater with the dosing device 7 (Na 2 CO 3 ) for coagulation pretreatment to form precipitates of Ca 2+ and Mg 2+ ions, and at the same time remove impurities such as turbidity, suspended solids, residual components of fracturing fluid, and crude oil in wastewater. The hydraulic retention time of the coagulation pretreatment flocculation process is 15±5min.

(2)Fenton氧化:混凝预处理后出水采用螺杆泵泵入压滤机压滤,实现固液分离,滤出废水自流进入Fenton反应罐,用加药装置8向Fenton反应罐投加过氧化氢、硫酸铁、硫酸,采用阀门控制进药时间和进药量。H2O2在Fe2+离子的催化作用下通过Fenton氧化进一步将废水中的难降解有机物深度氧化降解,反应时间为1.25±0.25h。(2) Fenton oxidation: After the coagulation pretreatment, the effluent is pumped into the filter press by a screw pump to achieve solid-liquid separation, and the filtered waste water flows into the Fenton reaction tank by itself, and the peroxidation is added to the Fenton reaction tank with the dosing device 8 Hydrogen, ferric sulfate, sulfuric acid, using valves to control the feeding time and dosage. Under the catalysis of Fe 2+ ions, H 2 O 2 further oxidized and degraded the refractory organic matter in wastewater through Fenton oxidation, and the reaction time was 1.25±0.25h.

(3)沉淀过滤:将经过Fenton氧化后的废水流入沉淀池4,流动过程中通过安装在管路中的静态混合器10向Fenton反应后的废水中投加NaOH沉淀水中的Fe3+离子,溶液经沉淀池沉淀后通过压滤机再次进行固液分离,滤液流入砂滤罐5过滤。(3) precipitation filtration: the waste water after Fenton oxidation will flow into sedimentation tank 4, in the flow process by being installed in the static mixer 10 in the pipeline, add Fe in the waste water after Fenton reaction in the Fe 3+ ion in the precipitation water of Fenton, After the solution is precipitated in the sedimentation tank, the solid-liquid separation is carried out again through the filter press, and the filtrate flows into the sand filter tank 5 for filtration.

(4)蒸发浓缩:出砂滤罐后的废水泵入循环列管蒸发器9进行蒸发浓缩。废水在循环列管大气蒸发器9的浓缩蒸发处理步骤如下:(4) Evaporation and concentration: the waste water after leaving the sand filter tank is pumped into the circulation tube evaporator 9 for evaporation and concentration. The concentrated evaporation treatment steps of the waste water in the circulating tubular atmospheric evaporator 9 are as follows:

经预处理后的高盐废水进入大气蒸发器时,废水先经循环水泵910泵入循环加热列管906上方的喷淋系统905,通过布水器904向塔内均匀地喷入适量的充分雾化的废水,雾化废水在重力作用下流经加热循环列管906,加热循环列管间充填有蜂窝状填料907,形成一层薄膜状水流,以增加换热面积和换热时间,提高换热效率。喷淋废水通过与大气及加热循环列管充分换热后迅速汽化成水蒸气进入气相,汽化后的水蒸气被大功率风机901带走,从而实现废水的蒸发浓缩。其余的废水回落到蒸发器底部的循环集水箱911,再由循环水泵910送入喷淋系统905循环使用。空气中夹带的水滴被收水器903阻挡,回落入循环列管加热器中经在加热蒸发。循环加热列管中被通入高温蒸气,高温蒸气由盘管上部蒸汽入口进入循环列管,与循环列管管外的喷淋废水和空气进行热交换,由气态逐渐被冷凝为液态,从下部蒸汽出口流出,回流入软化水箱。同时,干燥的温度较高空气在风机的作用下由底部入风格栅908进入塔内(图2),或者进入进风筒18(图3),经空气干烧管919加热后进入蒸发器的填料区,废水流经填料表面时形成水膜和空气进行热交换,高湿度温度较低的空气从顶部抽出,废液蒸发的所需的热量一部分由空气传热提供,一部分由循环列管加热提供。废液其余水滴入底部循环集水箱内。滴入底部循环集水箱的废水经循环水泵再抽入喷淋系统,将水循环起来,循环喷洒废水,提高蒸发效率。蒸发器中,设计处理水量与循环水量的比例为1:10,蒸发效率为50%。When the pretreated high-salt wastewater enters the atmospheric evaporator, the wastewater is first pumped into the spray system 905 above the circulating heating tube 906 through the circulating water pump 910, and an appropriate amount of sufficient mist is evenly sprayed into the tower through the water distributor 904. The atomized wastewater flows through the heating circulation tubes 906 under the action of gravity, and the heating circulation tubes are filled with honeycomb fillers 907 to form a layer of film-like water flow to increase the heat transfer area and heat transfer time, and improve the heat transfer performance. efficiency. The spray wastewater is quickly vaporized into water vapor and enters the gas phase after fully exchanging heat with the atmosphere and the heating cycle tubes. The vaporized water vapor is taken away by the high-power fan 901, thereby realizing the evaporation and concentration of the wastewater. The rest of the waste water falls back to the circulating water collection tank 911 at the bottom of the evaporator, and then sent to the spraying system 905 by the circulating water pump 910 for recycling. The water droplets entrained in the air are blocked by the water eliminator 903, and fall back into the circulation tube heater to evaporate after being heated. The high-temperature steam is fed into the circulating heating tubes, and the high-temperature steam enters the circulating tubes from the steam inlet on the upper part of the coil, and exchanges heat with the spray wastewater and air outside the circulating tubes, and is gradually condensed from a gaseous state to a liquid state. The steam outlet flows out and flows back into the softened water tank. At the same time, the dry air with a higher temperature enters the tower through the air inlet grid 908 at the bottom under the action of the fan (Fig. 2), or enters the air inlet cylinder 18 (Fig. 3), and enters the evaporator after being heated by the air dry heating pipe 919 When the wastewater flows through the surface of the filler, a water film is formed to exchange heat with the air. The air with high humidity and low temperature is drawn from the top, and part of the heat required for the evaporation of the waste liquid is provided by air heat transfer, and part of it is provided by the circulation tube. Heating provided. The rest of the waste liquid drips into the bottom circulating water collection tank. The waste water dripped into the bottom circulating water collection tank is pumped into the spraying system through the circulating water pump, the water is circulated, and the waste water is sprayed circularly to improve the evaporation efficiency. In the evaporator, the ratio of designed treatment water volume to circulating water volume is 1:10, and the evaporation efficiency is 50%.

蒸发器所采用的大功率风机与普通蒸发器所采用的风机相比,区别在于:普通蒸发器的风机作用只有一个引流作用,仅仅是将塔内的蒸汽通过风机抽吸引出蒸发器;而本蒸发器采用大功率风机,能提高蒸发器内气体流量与气体流速,蒸发速度与液面表面空气流速有关,空气流速越大,越有利于蒸发;且本蒸发器原理上也与传统蒸发器有所区别,传统蒸发器蒸发所需要的能量基本全部由加热列管提供,而本蒸发器蒸发所需能量一部分由加热管提供,另一部分由焓值较高的空气提供,能节省加热能耗,故也需要采用功率更大的风机以提供更大的气体流量,但在总能耗上较普通蒸发器大幅降低;蒸发器风机功率需根据蒸发器填料区高度,设计蒸发量大小确定,视实际情况需保证蒸发器出口风速约在12-20m/s,出口风速远大于普通蒸发器工作时出口处风速。在能耗上,普通蒸发器每蒸发1kg水所实际需要的蒸汽量约在1.2-1.6kg,而本蒸发器每蒸发1kg水所实际需要的蒸汽量约在0.6-0.8kg,本蒸发器总体能耗约为普通蒸发器总体能耗的50%-60%,具体效果视现场环境温度、湿度变化会有一定波动。The difference between the high-power fan used in the evaporator and the fan used in the ordinary evaporator is that the fan function of the ordinary evaporator only has a drainage function, which only draws the steam in the tower out of the evaporator through the fan; The evaporator adopts a high-power fan, which can increase the gas flow rate and gas flow rate in the evaporator. The evaporation rate is related to the air flow rate on the liquid surface. The greater the air flow rate, the more conducive to evaporation; and the principle of this evaporator is also different from the traditional evaporator. The difference is that the energy required for the evaporation of the traditional evaporator is basically provided by the heating tube, while part of the energy required for the evaporation of the evaporator is provided by the heating tube, and the other part is provided by the air with a higher enthalpy value, which can save heating energy consumption. Therefore, it is also necessary to use a fan with a higher power to provide a larger gas flow, but the total energy consumption is significantly lower than that of an ordinary evaporator; the fan power of the evaporator needs to be determined according to the height of the evaporator filling area and the design evaporation, depending on the actual situation The situation needs to ensure that the wind speed at the outlet of the evaporator is about 12-20m/s, and the wind speed at the outlet is much higher than the wind speed at the outlet when the ordinary evaporator is working. In terms of energy consumption, the actual amount of steam required for evaporating 1 kg of water in an ordinary evaporator is about 1.2-1.6 kg, while the actual amount of steam required for evaporating 1 kg of water in this evaporator is about 0.6-0.8 kg. The energy consumption is about 50%-60% of the overall energy consumption of ordinary evaporators, and the specific effect will fluctuate depending on the ambient temperature and humidity of the site.

采用本实用新型处理设备对四川省某页岩气开采井压裂返排废液进行处理,处理过程中各阶段水质情况见表1。The treatment equipment of the utility model is used to treat the fracturing flowback waste liquid of a shale gas production well in Sichuan Province. The water quality of each stage in the treatment process is shown in Table 1.

表1压裂返排液各阶段处理后水质分析表Table 1 Water quality analysis of fracturing flowback fluid after treatment in each stage

原水COD为565mg/L,硬度3710mg/L,总溶解性固体1.52×104g/L,氯化物1.72×104mg/L,设计处理量为5m3/h。混凝预处理和带式压滤机部分,混凝池水力停留时间为15min,投加聚合氯化铝为3.75kg/h,Na2CO3投加量为18.55kg/h。Fenton氧化处理部分,FeSO4·7H2O投加量为1.25kg/h,H2O2投加量为3.14kg/h,H2SO4投加量为0.25g/h,NaOH投加量为0.54kg/h,氧化反应时间为1.25h,斜板沉淀池停留时间为3h,处理后出水水质为COD为72mg/L,硬度31.32mg/L,总溶解性固体为16.06g/L。循环列管蒸发器进行蒸发浓缩处理部分,废液处理水量与循环水量的比例为1:10,设计蒸发量为50%。The COD of the raw water is 565mg/L, the hardness is 3710mg/L, the total dissolved solids are 1.52×10 4 g/L, the chloride is 1.72×10 4 mg/L, and the designed treatment capacity is 5m 3 /h. For the coagulation pretreatment and belt filter press part, the hydraulic retention time of the coagulation tank is 15min, the dosage of polyaluminum chloride is 3.75kg/h, and the dosage of Na 2 CO 3 is 18.55kg/h. For the Fenton oxidation treatment part, the dosage of FeSO 4 7H 2 O is 1.25kg/h, the dosage of H 2 O 2 is 3.14kg/h, the dosage of H 2 SO 4 is 0.25g/h, and the dosage of NaOH is 0.54kg/h, the oxidation reaction time is 1.25h, and the residence time in the inclined plate sedimentation tank is 3h. The effluent quality after treatment is 72mg/L COD, 31.32mg/L hardness, and 16.06g/L total dissolved solids. In the evaporation and concentration treatment part of the circulating tube evaporator, the ratio of waste liquid treatment water to circulating water is 1:10, and the design evaporation is 50%.

Claims (6)

1. a kind of shale gas exploitation fracturing fluid cycle tubulation evaporates minimizing processing equipment, which is characterized in that including according to The secondary coagulation filling being connected to by pipeline, cycle tubulation atmospheric evaporator, is steamed Fenton retort, filter press, sedimentation basin, sandfiltration pot Boiler furnace, water softening plant and softening water tank;Further include filling the sodium carbonate being connected and PAC chemicals dosing plants and Fenton with coagulation Hydrogen peroxide and ferric sulfate and sulfuric acid chemicals dosing plant that retort is connected and the sodium hydroxide dosing that static mixer is connected fill It sets, static mixer, suction pump and the valve being accordingly arranged on pipeline;
The cycle tubulation atmospheric evaporator is square or round tower structure, and the high-power wind of axial-flow type is arranged in the tower of evaporator Suction pump is arranged outside in machine, water collection device, water distributor, cycle tube still heater, packing area and cycle header tank, tower;The axial-flow type High-power blower is located at evaporator top exit, and the power of wind turbine need to ensure that evaporator outlet wind speed reaches 12-20m/s;Cloth Hydrophone is located at evaporator top, and water collection device is mounted between water distributor and axial-flow type high-power blower;It is filler in the middle part of evaporator Area is filled with the heat safe anti-corrosion material of honeycomb structure, and cycle tube still heater is arranged in packing area, around by filler It surrounds, the cycle tube still heater and tower external heat source unicom, the length and the number of plies for recycling tubulation are calculated by required heat exchange amount It arrives;Air inlet, base of evaporator setting cycle header tank is arranged in evaporator lower part.
2. shale gas exploitation fracturing fluid cycle tubulation as described in claim 1 evaporates minimizing processing equipment, special Sign is:The air inlet is also associated with into air duct, into air dry combustion method pipe is equipped in air duct, is entered the wind into air duct and evaporator Mouth is tightly connected and is detachable structure.
3. shale gas exploitation fracturing fluid cycle tubulation as described in claim 1 evaporates minimizing processing equipment, special Sign is:The air inlet of evaporator and the air inlet of air duct is provided with air-inlet grille.
4. shale gas exploitation fracturing fluid cycle tubulation as described in claim 1 evaporates minimizing processing equipment, special Sign is:The water collection device is corrosion-resistant material, is made as waveform.
5. shale gas exploitation fracturing fluid cycle tubulation as described in claim 1 evaporates minimizing processing equipment, special Sign is:The water distributor is to be made of with water conduit tube and branch pipe and nozzle what is arranged in dendroid, and nozzle uses big flow mist Change nozzle, nozzle quantity and arrangement are determined by cloth water flow and single-nozzle spray flow.
6. shale gas exploitation fracturing fluid cycle tubulation as described in claim 1 evaporates minimizing processing equipment, special Sign is:The cycle tube still heater uses band fin anti-corrosion and high temperature resistant, high pressure stainless steel or copper tube to make, using outer Shape is disc or U-typed coil arrangement.
CN201721834862.XU 2017-12-25 2017-12-25 A kind of shale gas exploitation fracturing fluid cycle tubulation evaporation minimizing processing equipment Withdrawn - After Issue CN207726911U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117214A (en) * 2017-12-25 2018-06-05 重庆大学 Shale gas exploitation fracturing fluid Xun Huan tubulation evaporation minimizing processing method and equipment
CN111573944A (en) * 2020-05-22 2020-08-25 郝福利 Wet differential evaporation method sewage and wastewater treatment device and method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108117214A (en) * 2017-12-25 2018-06-05 重庆大学 Shale gas exploitation fracturing fluid Xun Huan tubulation evaporation minimizing processing method and equipment
CN108117214B (en) * 2017-12-25 2021-02-26 重庆大学 Method and equipment for evaporative reduction treatment of shale gas exploitation fracturing flowback waste liquid circulation tube
CN111573944A (en) * 2020-05-22 2020-08-25 郝福利 Wet differential evaporation method sewage and wastewater treatment device and method

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