CN207623276U - Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation - Google Patents
Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation Download PDFInfo
- Publication number
- CN207623276U CN207623276U CN201721918835.0U CN201721918835U CN207623276U CN 207623276 U CN207623276 U CN 207623276U CN 201721918835 U CN201721918835 U CN 201721918835U CN 207623276 U CN207623276 U CN 207623276U
- Authority
- CN
- China
- Prior art keywords
- fuel cell
- waste water
- device body
- cathode chamber
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A20/00—Water conservation; Efficient water supply; Efficient water use
- Y02A20/20—Controlling water pollution; Waste water treatment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Fuel Cell (AREA)
Abstract
The utility model discloses a kind of devices using microbiological fuel cell evaluating water quality organic contamination situation, belong to monitoring water environment technical field, including open-topped device body, which is placed on the outside of waste water；Water inlet pipe, outlet pipe, microbial fuel cell unit, the microbial fuel cell unit include the anode chamber connected by conducting wire and cathode chamber, and current monitoring device and external resistance are equipped between anode chamber and cathode chamber；Anode chamber and cathode chamber are respectively placed in both sides in device body, and anode chamber is placed in waste water bottom in device body, cathode chamber be placed in device body waste water at air interface.The present apparatus is simple in structure, easy to operate, using microbial degradation principle in organic wastewater, organic contamination situation in timely original position Real-Time Evaluation waste water；Waste water continually and steadily updates in device body, and anode chamber and cathode chamber are placed in device body, it is possible to prevente effectively from because accident generating means is impaired, monitoring accuracy is high.
Description
Technical field
The utility model belongs to monitoring water environment technical field, is specifically related to a kind of utilization microbiological fuel cell evaluation
The device of water quality organic contamination situation.
Background technology
Organic wastewater is the waste water based on organic pollution, which easily causes the eutrophication of water quality, deposited to environment
In certain harm.Wherein COD (COD) can directly reflect that water body is water quality by the degree of reproducibility organic contamination
The important indicator of contamination monitoring and organic contamination degree in highly important Testing index in improvement and evaluating water quality.Tradition
COD assay methods it is very complicated, need under certain condition use strong oxidizer handle waste water, by reductive organic matter institute in water
The amount conversion for consuming strong oxidizer is the content of oxygen, cannot be evaluated in time the organic contamination situation of waste water.
Chinese patent CN2013100446893, data of publication of application are that the patent application document on January 31st, 2013 discloses
A kind of dual wavelength ultraviolet method organic wastewater COD detection devices and method, the measuring flume of the invention respectively with the first monochromator, second
Monochromator, ultraviolet detector, visible-light detector be connected, the first monochromator is connected with ultraviolet source, the second monochromator with it is visible
Light source is connected, and subtracter, amplifying circuit, A/D conversion circuits, PLC control system, display device are sequentially connected, and realize measurement
Full-automation carries out on-line analysis and measurement to the COD of all kinds of organic wastewaters.Disadvantage is that this method management process is multiple
Miscellaneous, experimental precision requires height, builds and operating cost is high, be unfavorable for longtime running.
Chinese patent CN201310150795X, data of publication of application are that the patent application document on July 10th, 2013 discloses
A kind of microbial fuel cell unit suitable for high concentrated organic wastewater processing, it is anti-in order to solve existing continuous flow stirring slot type
Answer device water outlet COD removal rates low, reflecting time is long, and after high concentrated organic wastewater enters CSTR systems, water outlet also needs under entering
The lower end of the problem of one unit carries out subsequent processing, the MFC reflection containers of the invention reflects that the upper end of container is connected to CSTR,
The lower end of the output axis connection of the upper end of agitating shaft and the lower end of stirring motor, agitating shaft passes through MFC reflection container settings to exist
In CSTR reaction vessels, the lower end of anode is inserted into MFC reaction vessels, and the upper end of anode passes through the upper table of MFC reflection containers
Face, solid-liquid separator are mounted in CSTR reflection containers, can be used for handling high concentrated organic wastewater.But the apparatus structure is multiple
It is miscellaneous, it is cumbersome, it is not suitable for original place and monitors in real time, does not have scalability.
In conclusion the problem of organic wastewater monitoring is primarily present in the prior art is not to be completely suitable for reality in situ
When the device that monitors, device in the prior art is unfavorable for operating on the spot, and complex for operation step, complicated；Existing assessment
The conventional method of organic wastewater cannot efficiently, it is long-term, in time, steadily organic wastewater is assessed, new technique management step
Rapid complicated, experimental precision requires height, expensive, is unfavorable for long-run development.It is, therefore, desirable to provide a kind of novel device and skill
Art.
Utility model content
Goal of the invention：In order to overcome the deficiencies in the prior art, organic wastewater monitoring in the prior art is primarily present
The problem of be not to be completely suitable for the device monitored in real time in situ, device in the prior art is unfavorable for operating on the spot, and
It is complex for operation step, it is complicated；The conventional method of existing assessment organic wastewater cannot efficiently, it is long-term, in time, steadily to having
Machine waste water is assessed, and new technique management process is complicated, and experimental precision requires height, expensive, is unfavorable for long-run development.This
Utility model provides a kind of device using microbiological fuel cell evaluating water quality organic contamination situation, and the apparatus structure is simple,
Using microbial degradation principle in organic wastewater, monitoring organic wastewater concentration in real time in situ, strong applicability are realized.
Technical solution：In order to solve the above technical problems, a kind of of the utility model evaluates water using microbiological fuel cell
The device of matter organic contamination situation, including：Open-topped device body, the device body are placed on the outside of waste water；
Water inlet pipe, the water inlet pipe one end are placed in waste water, which is connected to device body；
Outlet pipe, the outlet pipe one end are connect with device body, which is placed in waste water；
Microbial fuel cell unit, the microbial fuel cell unit include the anode chamber connected by conducting wire and cathode
Room is equipped with current monitoring device and external resistance between anode chamber and cathode chamber；
The anode chamber and cathode chamber are respectively placed in both sides in device body, and the anode chamber is placed in waste water in device body
Bottom, the cathode chamber are placed in device body at waste water and air interface.
Further, described water inlet pipe one end extends to 1~2m below the waste water water surface.
Further, including the peristaltic pump that is located on water inlet pipe.
Further, the downflow weir of device body top outer, the outlet pipe one end being connect with device body are located at including
It is connect with downflow weir.
Further, the anode chamber and cathode chamber are all made of graphite felt electrode, and stainless steel is all made of outside graphite felt electrode
Net is coated.
Further, including closed thermostat, the current monitoring device are placed in the closed thermostat.
Further, including cathode aerator, the cathode aerator one end are placed in device body in waste water and position
In cathode chamber side.
Further, including dissolved oxygen meter, the dissolved oxygen meter one end are placed in device body in waste water and position
In cathode chamber side.
Further, including long-distance monitorng device, the long-distance monitorng device are connect with current monitoring device.
Advantageous effect：
The utility model compared with the prior art, this have the advantage that：
Anode and cathode is placed in organic wastewater by 1, utility model device, and anode and cathode is distinguished two in device
Side, and anode, close to liquid bottom, cathode ensures that the good oxidation-reduction potential of generation is poor close to gas-liquid interface；
2, utility model device is used as design principle using the Electrocatalysis Degradation of microbiological fuel cell, will be organic
Substance resolves into proton and electronics, and form electron transmission between the electrodes as electron donor under the action of microorganism, from
And electric current is formed, the electronics that system generates is transferred to cathode from anode by conducting wire, forms electric current, while the height of organic concentrations
The electricity production of system can be caused to directly affect, the pollution level of organic wastewater is evaluated in time by observing its size of current；
3, situations such as directly anode and cathode being placed in waste water in the prior art, torrent is usually will appear in waste water, leads
Negative and positive the two poles of the earth job insecurity is caused, and the utility model is by the way that anode chamber and cathode chamber to be placed in device body, so that it may with
It effectively avoids because accident generating means is impaired；On the other hand, waste water continually and steadily updates in device body, ensure that original
Position monitors waste water dynamic in real time；
4, utility model device is simple in structure, using microbial degradation principle in organic wastewater, realizes prison in real time in situ
Organic wastewater concentration, strong applicability are surveyed, which takes full advantage of microorganism in organic wastewater and produce electricity property to the degradation of organic matter
Can, it is measured by the curent change to external circuit, the organic contamination situation of waste water is evaluated in time, realized even
Under the conditions of reforwarding row, the purpose of organic contamination situation in waste water is evaluated in time；
5, the utility model can efficiently, long-term, in time, steadily organic wastewater is assessed, and easy to operate, assessment
Precision is high, at low cost, there is larger promotional value；
6, this method is rich in this characteristic of a large amount of microorganisms with live organic wastewater, effectively enhances Microbial fuel
Reaction of the battery to pollution.And microbiological fuel cell not will produce secondary dirt not only while being monitored to water quality
Dye, can also consume Organic substance in water, and then repair to quality of groundwater.
Description of the drawings
Fig. 1 is utility model device structural schematic diagram.
Drawing reference numeral explanation：
1, device body；2, water inlet pipe；3, outlet pipe；4, anode chamber；5, cathode chamber；6, current monitoring device；7, dispatch from foreign news agency
Resistance；8, peristaltic pump；9, downflow weir；10, closed thermostat；11, cathode aerator；12, dissolved oxygen meter；13, conducting wire；
14, long-distance monitorng device.
Specific implementation mode
The utility model is further described with reference to the accompanying drawings and examples.
Embodiment one：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment, referring to Fig.1, packet
Include microbial fuel cell unit, water feed apparatus, discharging device, current monitoring device, device body；
Device body 1 is fixedly mounted on the outside of waste water, using device body 1 to waste water by open-topped device body 1
Water quality is monitored；
Water inlet pipe 2,2 one end of water inlet pipe are placed in waste water, which is connected to device body 1, will intake
2 one end of pipe extends to 1~2m below the waste water water surface, and peristaltic pump 8 is equipped on water inlet pipe 2, by opening peristaltic pump 8, waste water meeting
Entered in device body 1 by water inlet pipe 2, ensures the waste water real-time update in device body 1, in order to further realize organic waste
The real-time in-situ of water monitors；
Outlet pipe 3,3 one end of outlet pipe are connect with device body 1, which is placed in waste water, outlet pipe
3 for the waste water in device body 1 to be discharged in wastewater disposal basin, downflow weir 9 is equipped in 1 top outer of device body, with device
3 one end of outlet pipe that ontology 1 connects is connect with downflow weir 9, and when opening peristaltic pump 8, waste water enters device sheet from water inlet pipe 2
In body 1, wait for that waste water horizontal plane reaches highest point in device body 1, the waste water being higher by flows into outlet pipe 3 by downflow weir 9 again
In, it is finally discharged in wastewater disposal basin with outlet pipe 3, ensure that the waste water real-time update in device body 1, further ensure useless
The real-time monitoring of water；
Microbial fuel cell unit, microbial fuel cell unit include the anode chamber 4 connected by conducting wire 13 and the moon
Pole room 5, the two poles of the earth are respectively placed in both sides in device body 1, poor in order to generate good oxidation-reduction potential, and anode chamber 4 is close to dress
The waste water bottom in ontology 1 is set, cathode chamber 5 is connected between the two poles of the earth by conducting wire, at waste water and air interface in anode chamber
Current monitoring device 6 and external resistance 7 are equipped between 4 and cathode chamber 5；It is used as using the Electrocatalysis Degradation work of microbiological fuel cell
For design principle, using organic substance as electron donor, resolve into proton and electronics under the action of microorganism, and electrode it
Between form electron transmission, to form electric current, the electronics that system generates is transferred to cathode from anode by conducting wire, forms electric current,
The height of organic concentrations can cause to directly affect to the electricity production of system simultaneously, evaluated in time by observing its size of current
The pollution level of machine waste water, size of current are monitored in real time by current monitoring device 6；The cathode chamber 5,4 the two poles of the earth, anode chamber
It is connected by conducting wire 13, to produce electricity the formation of biomembrane in quickening system, and adds the outer of one 100~500 Ω on conducting wire 13
Resistance 7.
Embodiment two：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment, referring to Fig.1, base
Further include closed thermostat 10 and long-distance monitorng device 14 in embodiment one；
Closed thermostat, it is contemplated that the precision too high or too low for temperature that current monitoring device can be influenced, in order to reduce or
It avoids generating error to the reading for producing electricity numerical value, therefore current monitoring device 6 need to be placed in closed thermostat 10, closed perseverance
Temperature need to be maintained at 20~25 DEG C or so in warm device 10；
Long-distance monitorng device 14, assesses waste water to realize in time, and current monitoring device 6 is placed in closed constant temperature
In device 10, which connect with current monitoring device 6, by right with the remote monitoring system 14 of external connection
Waste water quality is monitored.
Embodiment three：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment, referring to Fig.1, base
In embodiment two, anode chamber 4 and cathode chamber 5 are all made of graphite felt electrode, and being all made of stainless (steel) wire outside graphite felt electrode is wrapped
It covers, cathode chamber 5, anode chamber 4 select the graphite felt electrode of 10 × 10 × 5mm, and by 12~15 mesh outside graphite felt electrode
Stainless (steel) wire as current-collector, accelerate electron transport rate；
Different organic wastewater is handled, needs suitable cathode and anode spacing, main organic wastewater to be processed includes underground
Water, sanitary wastewater, waste water of livestock poultry and industrial wastewater, anode chamber 4 and 5 spacing range of cathode chamber are set in 20~50cm；Foundation
Microbial degradation principle in organic wastewater, the microbial metabolism decomposing organic pollutant in organic wastewater generate electronics in anode
Room 4 enters cathode chamber 5 by conducting wire 13, constitutes complete current loop.
Example IV：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment, referring to Fig.1, base
In embodiment three, including cathode aerator 11 and dissolved oxygen meter 12, which is placed in device sheet
In waste water and positioned at 5 side of cathode chamber in body 1, which is placed in device body 1 in waste water and is located at
5 side of cathode chamber, the dissolved oxygen concentration in waste water can influence degradation of 5 ambient microorganisms of cathode chamber to organic matter, therefore in the moon
5 surrounding of pole room places cathode aerator 11, and the dissolved oxygen around cathode is made to remain at 2~6mg/L in the process of running,
And the real time measure is carried out by dissolved oxygen meter 12.
Embodiment five：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment, when in use,
Firstly the need of the device built on the outside of wastewater disposal basin using microbiological fuel cell evaluating water quality organic contamination situation, dress is being built
Before setting, for the reasonable experiment parameter of each component in selection device, first various organic wastewaters can be carried out preliminary organic negative
The measurement of lotus concentration, by conventional method, measurement result shows the underground water polluted by organic machine to Preliminary Determination, organic negative
Lotus range is placed between 300~400mg/L；Contaminated sanitary wastewater, organic loading are placed between 400~500mg/L；It is dirty
The waste water of livestock poultry of dye, organic loading are placed between 500~700mg/L；Contaminated industrial wastewater, organic loading is placed in 700~
Between 1000mg/L；
The detailed process for building device is：
Referring to Fig.1, the apparatus for placing ontology 1 on the outside of wastewater disposal basin；2 one end of water inlet pipe is placed in wastewater disposal basin, water inlet pipe 2 one
End extends to 1~2m below the waste water water surface, which is connected to device body 1；By 3 one end of outlet pipe and device
Ontology 1 connects, which is placed in wastewater disposal basin；By the anode chamber 4 of microbial fuel cell unit and cathode chamber 5
Both sides in device body 1 are respectively placed in, anode chamber 4 are placed in waste water bottom in device body 1, cathode chamber 5 is placed in device body 1
At interior waste water and air interface；The microbial fuel cell unit includes the anode chamber 4 connected by conducting wire 13 and cathode chamber 5,
Current monitoring device 6 and external resistance 7 are equipped between anode chamber 4 and cathode chamber 5；Water inlet pipe 2 is equipped with peristaltic pump 8；Device sheet
1 top outer of body is equipped with downflow weir 9, and 3 one end of outlet pipe being connect with device body 1 is connect with downflow weir 9；Anode chamber 4 and the moon
Pole room 5 is all made of graphite felt electrode, and being all made of stainless (steel) wire outside graphite felt electrode is coated；Current monitoring device 6 is placed in
In the closed thermostat 10；11 one end of cathode aerator is placed in device body 1 in waste water and is located at cathode chamber 5 one
Side；12 one end of dissolved oxygen meter is placed in device body 1 in waste water and is located at 5 side of cathode chamber；By long-distance monitorng device
14 connect with current monitoring device 6；
Water inlet pipe 2,2 one end of water inlet pipe are placed in waste water, which is connected to device body 1, will intake
2 one end of pipe extends to 1~2m below the waste water water surface, and peristaltic pump 8 is equipped on water inlet pipe 2, by opening peristaltic pump 8, waste water meeting
Entered in device body 1 by water inlet pipe 2, ensures the waste water real-time update in device body 1, in order to further realize organic waste
The real-time in-situ of water monitors；
Outlet pipe 3,3 one end of outlet pipe are connect with device body 1, which is placed in waste water, outlet pipe
3 for the waste water in device body 1 to be discharged in wastewater disposal basin, downflow weir 9 is equipped in 1 top outer of device body, with device
3 one end of outlet pipe that ontology 1 connects is connect with downflow weir 9, and when opening peristaltic pump 8, waste water enters device sheet from water inlet pipe 2
In body 1, wait for that waste water horizontal plane reaches highest point in device body 1, the waste water being higher by flows into outlet pipe 3 by downflow weir 9 again
In, it is finally discharged in wastewater disposal basin with outlet pipe 3, ensure that the waste water real-time update in device body 1, further ensure useless
The real-time monitoring of water；
Microbial fuel cell unit, microbial fuel cell unit include the anode chamber 4 connected by conducting wire 13 and the moon
Pole room 5, the two poles of the earth are respectively placed in both sides in device body 1, poor in order to generate good oxidation-reduction potential, and anode chamber 4 is close to dress
The waste water bottom in ontology 1 is set, cathode chamber 5 is connected between the two poles of the earth by conducting wire, at waste water and air interface in anode chamber
Current monitoring device 6 and external resistance 7 are equipped between 4 and cathode chamber 5；It is used as using the Electrocatalysis Degradation work of microbiological fuel cell
For design principle, using organic substance as electron donor, resolve into proton and electronics under the action of microorganism, and electrode it
Between form electron transmission, to form electric current, the electronics that system generates is transferred to cathode from anode by conducting wire, forms electric current,
The height of organic concentrations can cause to directly affect to the electricity production of system simultaneously, evaluated in time by observing its size of current
The pollution level of machine waste water, size of current are monitored in real time by current monitoring device 6；The cathode chamber 5,4 the two poles of the earth, anode chamber
It is connected by conducting wire 13.
Closed thermostat, it is contemplated that the precision too high or too low for temperature that current monitoring device can be influenced, in order to reduce or
It avoids generating error to the reading for producing electricity numerical value, therefore current monitoring device 6 need to be placed in closed thermostat 10, closed perseverance
Temperature need to be maintained at 20~25 DEG C or so in warm device 10；
Long-distance monitorng device 14, assesses waste water to realize in time, and current monitoring device 6 is placed in closed constant temperature
In device 10, which connect with current monitoring device 6, by right with the remote monitoring system 14 of external connection
Waste water quality is monitored；
In experimentation, organic loading concentration in organic wastewater is tentatively considered first, the rational device of reselection
Parameter is tested, and is realized the accurate measurement to organic wastewater, is determined waste water, further determine that organic loading is dense in waste water
Degree, further selects rational device parameter；
It needs to build the device using microbiological fuel cell evaluating water quality organic contamination situation on the outside of wastewater disposal basin, open
Peristaltic pump 8 makes waste water pass through water inlet pipe 2 and continues to flow into device body 1；It is compacted by passing through away from the underground organic wastewater at water surface 1m
Dynamic pump 8, water inlet pipe 2 are out of bottom bleeder ontology 1, after water reaches the top of device body 1, then by downflow weir 9,
Outlet pipe 3 is back in waste water；
To ensure that the dissolved oxygen near cathode chamber 5 is kept in a certain range, in the process of running, near cathode chamber 5
Noncontinuity aeration is carried out using cathode aerator 11；
It after organic wastewater stops 3 days in device body 1, tends towards stability, and every by the record system of current monitoring device 6
The curent change of minute, the electric current generated by 14 real-time monitoring system of long-distance monitorng device, realizes the real-time prison of organic contamination
It surveys；
It is used as design principle using the Electrocatalysis Degradation of microbiological fuel cell, is supplied organic substance as electronics
Body resolves into proton and electronics under the action of microorganism, and forms electron transmission between the electrodes, to form electric current, is
The electronics generated of uniting is transferred to cathode from anode by conducting wire, forms electric current, while the height of organic concentrations can be to the production of system
Electricity causes to directly affect, and evaluates the pollution level of organic wastewater in time by observing its size of current, electric current is bigger, waste water
Organic contamination situation it is more serious.
Embodiment six：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment is based on embodiment
Five, when in use, between tentatively judging a concentration of 300~400mg/L of the organic loading of wastewater disposal basin in the embodiment, which is
By the underground water that organic machine pollutes, rational device parameter is thus selected to be tested；Referring to Fig.1,
Wherein, device body 1 is made of Ф 20cm, the organic glass of high 40cm, and cathode chamber 5 is apart from gas-liquid interface 5cm, sun
The electrode spacing of 4 distance means ontology of pole room, 1 bottom 5cm, the two are 20cm, and 2 one end of water inlet pipe extends to below the waste water water surface
1m, the organic loading range of waste water is between 300~400mg/L.
Wherein, in order to ensure that the microbes around cathode chamber 5 effectively degrade to useless Organic substance in water, and and anode
Room 4 keeps good oxidation-reduction potential, and cathode aerator 11 need to be disposed around cathode chamber 5, is carried out to 5 surrounding of cathode chamber
Noncontinuity is aerated, and the dissolved oxygen concentration around cathode chamber 5 is made to be maintained at 2~3mg/L.
Wherein anode chamber 4 and cathode chamber 5 is all made of the graphite felt of 10 × 10 × 5mm as electrode material, in order to effectively plus
The delivery rate of fast electronics, need to wrap up the stainless (steel) wire of one layer of 12 mesh as current-collector, two electrodes are by leading outside graphite felt
Line is attached, and adds the external resistance 7 of 100 Ω in external circuit, to accelerate the formation of biomembrane in system.
Wherein consider the precision too high or too low for temperature that can influence current monitoring device 6, the reading to producing electricity numerical value is produced
Raw error, need to be by current monitoring device 6 in closed thermostat 10, and temperature need to be maintained at 20 DEG C or so.
After the completion of whole system, microbiological fuel cell needs 3 days startup and stabilization time, Microbial fuel after stablizing
Battery can stablize electricity production, -0.18 ± 0.26uA of magnitude of current average out to that system is monitored.Wherein the reason of generation negative current, is
Yin, yang two-stage is all placed in liquid in system, and the direction of electron stream is unpredictable.
Embodiment seven：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment is based on embodiment
Five, when in use, between tentatively judging a concentration of 400~500mg/L of the organic loading of wastewater disposal basin in the embodiment, which is
Thus contaminated sanitary wastewater selects rational device parameter to be tested；Referring to Fig.1,
Wherein, device body 1 is made of Ф 20cm, the organic glass of high 50cm, and cathode chamber 5 is apart from gas-liquid interface 5cm, sun
The electrode spacing of 4 distance means ontology of pole room, 1 bottom 5cm, the two are 30cm, and 2 one end of water inlet pipe extends to below the waste water water surface
1m, the organic loading range of waste water is between 400~500mg/L.
Wherein, in order to ensure that the microbes around cathode chamber 5 effectively degrade to useless Organic substance in water, and and anode
Room 4 keeps good oxidation-reduction potential, and cathode aerator 11 need to be disposed around cathode chamber 5, is carried out to 5 surrounding of cathode chamber
Noncontinuity is aerated, and the dissolved oxygen concentration around cathode chamber 5 is made to be maintained at 3~4mg/L.
Wherein anode chamber 4 and cathode chamber 5 is all made of the graphite felt of 10 × 10 × 5mm as electrode material, in order to effectively plus
The delivery rate of fast electronics, need to wrap up the stainless (steel) wire of one layer of 13 mesh as current-collector, two electrodes are by leading outside graphite felt
Line is attached, and adds the external resistance 7 of 200 Ω in external circuit, to accelerate the formation of biomembrane in system.
Wherein consider the precision too high or too low for temperature that can influence current monitoring device 6, the reading to producing electricity numerical value is produced
Raw error, need to be by current monitoring device 6 in closed thermostat 10, and temperature need to be maintained at 22 DEG C or so.
After the completion of whole system, microbiological fuel cell needs 4 days startup and stabilization time, Microbial fuel after stablizing
Battery can stablize electricity production, 0.45 ± 0.32uA of magnitude of current average out to that system is monitored.
Embodiment eight：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment is based on embodiment
Five, when in use, between tentatively judging a concentration of 500~700mg/L of the organic loading of wastewater disposal basin in the embodiment, which is
Thus waste water of livestock poultry selects rational device parameter to be tested；Referring to Fig.1,
Wherein, device body 1 is made of Ф 20cm, the organic glass of high 60cm, and cathode chamber 5 is apart from gas-liquid interface 5cm, sun
The electrode spacing of 4 distance means ontology of pole room, 1 bottom 5cm, the two are 40cm, and 2 one end of water inlet pipe extends to below the waste water water surface
2m, the organic loading range of waste water is between 500~700mg/L.
Wherein, in order to ensure that the microbes around cathode chamber 5 effectively degrade to useless Organic substance in water, and and anode
Room 4 keeps good oxidation-reduction potential, and cathode aerator 11 need to be disposed around cathode chamber 5, is carried out to 5 surrounding of cathode chamber
Noncontinuity is aerated, and the dissolved oxygen concentration around cathode chamber 5 is made to be maintained at 4~5mg/L.
Wherein anode chamber 4 and cathode chamber 5 is all made of the graphite felt of 10 × 10 × 5mm as electrode material, in order to effectively plus
The delivery rate of fast electronics, need to wrap up the stainless (steel) wire of one layer of 14 mesh as current-collector, two electrodes are by leading outside graphite felt
Line is attached, and adds the external resistance 7 of 300 Ω in external circuit, to accelerate the formation of biomembrane in system.
Wherein consider the precision too high or too low for temperature that can influence current monitoring device 6, the reading to producing electricity numerical value is produced
Raw error, need to be by current monitoring device 6 in closed thermostat 10, and temperature need to be maintained at 23 DEG C or so.
After the completion of whole system, microbiological fuel cell needs 7 days startup and stabilization time, Microbial fuel after stablizing
Battery can stablize electricity production, 1.35 ± 0.51uA of magnitude of current average out to that system is monitored.
Embodiment nine：
A kind of device using microbiological fuel cell evaluating water quality organic contamination situation of the present embodiment is based on embodiment
Five, when in use, between tentatively judging a concentration of 700~1000mg/L of the organic loading of wastewater disposal basin in the embodiment, the waste water
For industrial wastewater, rational device parameter is thus selected to be tested；Referring to Fig.1,
Wherein, device body 1 is made of Ф 20cm, the organic glass of high 70cm, and cathode chamber 5 is apart from gas-liquid interface 5cm, sun
The electrode spacing of 4 distance means ontology of pole room, 1 bottom 5cm, the two are 40cm, and 2 one end of water inlet pipe extends to below the waste water water surface
2m, the organic loading range of waste water is between 700~1000mg/L.
Wherein, in order to ensure that the microbes around cathode chamber 5 effectively degrade to useless Organic substance in water, and and anode
Room 4 keeps good oxidation-reduction potential, and cathode aerator 11 need to be disposed around cathode chamber 5, is carried out to 5 surrounding of cathode chamber
Noncontinuity is aerated, and the dissolved oxygen concentration around cathode chamber 5 is made to be maintained at 5~6mg/L.
Wherein anode chamber 4 and cathode chamber 5 is all made of the graphite felt of 10 × 10 × 5mm as electrode material, in order to effectively plus
The delivery rate of fast electronics, need to wrap up the stainless (steel) wire of one layer of 15 mesh as current-collector, two electrodes are by leading outside graphite felt
Line is attached, and adds the external resistance 7 of 500 Ω in external circuit, to accelerate the formation of biomembrane in system.
Wherein consider the precision too high or too low for temperature that can influence current monitoring device 6, the reading to producing electricity numerical value is produced
Raw error, need to be by current monitoring device 6 in closed thermostat 10, and temperature need to be maintained at 25 DEG C or so.
After the completion of whole system, microbiological fuel cell needs 5 days startup and stabilization time, Microbial fuel after stablizing
Battery can stablize electricity production, 2.31 ± 0.38uA of magnitude of current average out to that system is monitored.
Thus according to actual conditions, the organic loading range of waste water is can be predicted substantially in 300~1000mg/L, it is corresponding
Microbial fuel cell unit generate average current range in -0.44~2.69uA.
The above is only the preferred embodiment of the utility model, it should be pointed out that：For the common skill of the art
For art personnel, without departing from the principle of this utility model, several improvements and modifications can also be made, these improve and
Retouching also should be regarded as the scope of protection of the utility model.
Claims (9)
1. utilizing the device of microbiological fuel cell evaluating water quality organic contamination situation, which is characterized in that including：
Open-topped device body (1), the device body (1) are placed on the outside of waste water；
Water inlet pipe (2), water inlet pipe (2) one end are placed in waste water, which is connected to device body (1)；
Outlet pipe (3), outlet pipe (3) one end are connect with device body (1), which is placed in waste water；
Microbial fuel cell unit, the microbial fuel cell unit include by conducting wire (13) connect anode chamber (4) and
Cathode chamber (5) is equipped with current monitoring device (6) and external resistance (7) between anode chamber (4) and cathode chamber (5)；
The anode chamber (4) and cathode chamber (5) are respectively placed in device body (1) interior both sides, and the anode chamber (4) is placed in device sheet
The interior waste water bottom of body (1), the cathode chamber (5) are placed at device body (1) interior waste water and air interface.
2. the device according to claim 1 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, described water inlet pipe (2) one end extends to 1~2m below the waste water water surface.
3. the device according to claim 1 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including the peristaltic pump (8) being located on water inlet pipe (2).
4. the device according to claim 3 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including is located at the downflow weir (9) of device body (1) top outer, outlet pipe (3) one end being connect with device body (1)
It is connect with downflow weir (9).
5. the device according to claim 4 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, the anode chamber (4) and cathode chamber (5) are all made of graphite felt electrode, and stainless (steel) wire progress is all made of outside graphite felt electrode
Cladding.
6. the device according to claim 5 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including closed thermostat (10), the current monitoring device (6) is placed in the closed thermostat (10).
7. the device according to claim 6 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including cathode aerator (11), which is placed in device body (1) interior waste water and is located at
Cathode chamber (5) side.
8. the device according to claim 7 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including dissolved oxygen meter (12), which is placed in device body (1) interior waste water and is located at
Cathode chamber (5) side.
9. the device according to claim 8 using microbiological fuel cell evaluating water quality organic contamination situation, feature
It is, including long-distance monitorng device (14), which connect with current monitoring device (6).
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721918835.0U CN207623276U (en) | 2017-12-29 | 2017-12-29 | Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201721918835.0U CN207623276U (en) | 2017-12-29 | 2017-12-29 | Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN207623276U true CN207623276U (en) | 2018-07-17 |
Family
ID=62830711
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201721918835.0U Expired - Fee Related CN207623276U (en) | 2017-12-29 | 2017-12-29 | Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN207623276U (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108007983A (en) * | 2017-12-29 | 2018-05-08 | 环境保护部南京环境科学研究所 | Utilize the apparatus and method of microbiological fuel cell evaluating water quality organic contamination situation |
| CN114965611A (en) * | 2021-02-26 | 2022-08-30 | 上海理工大学 | Microbial fuel cell sensor |
-
2017
- 2017-12-29 CN CN201721918835.0U patent/CN207623276U/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108007983A (en) * | 2017-12-29 | 2018-05-08 | 环境保护部南京环境科学研究所 | Utilize the apparatus and method of microbiological fuel cell evaluating water quality organic contamination situation |
| CN108007983B (en) * | 2017-12-29 | 2024-02-20 | 环境保护部南京环境科学研究所 | Device and method for evaluating organic pollution condition of water quality by using microbial fuel cell |
| CN114965611A (en) * | 2021-02-26 | 2022-08-30 | 上海理工大学 | Microbial fuel cell sensor |
| CN114965611B (en) * | 2021-02-26 | 2023-08-25 | 上海理工大学 | Microbial fuel cell sensor |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108007983A (en) | Utilize the apparatus and method of microbiological fuel cell evaluating water quality organic contamination situation | |
| Di Lorenzo et al. | A single-chamber microbial fuel cell as a biosensor for wastewaters | |
| CN103843184B (en) | Biological aerobic quantity sensor | |
| CN201392346Y (en) | Colorimetry ammonia nitrogen on-line automatic monitoring device | |
| CN101907596A (en) | Method for monitoring and estimating inlet water toxicity of urban wastewater treatment plant on line | |
| CN207623276U (en) | Utilize the device of microbiological fuel cell evaluating water quality organic contamination situation | |
| Burge et al. | Microbial potentiometric sensor: A new approach to longstanding challenges | |
| CN103592334B (en) | Monitoring method based on batch-type biological toxicity tests early warning system | |
| CN104330455B (en) | Utilize the method and apparatus of microorganism electrolysis cell technology on-line monitoring nitrate | |
| CN204424375U (en) | The microbiological fuel cell of in-situ remediation of underground water azotate pollution | |
| CN104062345A (en) | Device based on microorganism electrolytic tank technique for on-line biochemical oxygen demand measurement | |
| CN207623279U (en) | The device of Organic Contamination of Groundwater is monitored based on microbiological fuel cell | |
| CN113899792A (en) | System for monitoring heavy metal and microbial electrochemical sensor | |
| CN103336045A (en) | Device for on-line detection and automatic alarm of toxic substances and detection method of toxic substances | |
| CN105552466B (en) | A kind of p-nitrophenol concentration detection method based on microbiological fuel cell | |
| CN104034785A (en) | On-line biologic detection and automatic alarm device for toxic substances in water body | |
| CN208454612U (en) | Ecosystem restoration system for river | |
| CN107024521B (en) | Detect sewage concentration's biosensor | |
| CN202837232U (en) | Online heavy metal early-warning detection system | |
| RU2650634C1 (en) | Biosensor for determining presence of organic substances in water | |
| CN109696427A (en) | A method of determining river microbe condition and selection control techniques | |
| CN214310266U (en) | Wetland blocks up detection device based on microbial fuel cell | |
| CN202204535U (en) | Water quality automatic detection device | |
| CN108152352A (en) | Device and method based on microbiological fuel cell monitoring Organic Contamination of Groundwater | |
| CN213903401U (en) | Calibrating device of multi-parameter water quality analyzer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20180717 Termination date: 20201229 |