CN207614625U - A kind of ship tail gas wash mill - Google Patents

A kind of ship tail gas wash mill Download PDF

Info

Publication number
CN207614625U
CN207614625U CN201721467873.9U CN201721467873U CN207614625U CN 207614625 U CN207614625 U CN 207614625U CN 201721467873 U CN201721467873 U CN 201721467873U CN 207614625 U CN207614625 U CN 207614625U
Authority
CN
China
Prior art keywords
liquid
outlet
coolant
lye
alkali liquor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn - After Issue
Application number
CN201721467873.9U
Other languages
Chinese (zh)
Inventor
杨国华
况敏
尚政伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo University
Original Assignee
Ningbo University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo University filed Critical Ningbo University
Priority to CN201721467873.9U priority Critical patent/CN207614625U/en
Application granted granted Critical
Publication of CN207614625U publication Critical patent/CN207614625U/en
Withdrawn - After Issue legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)

Abstract

The utility model discloses a kind of ship tail gas wash mills,It includes washing tower body,It is equipped with ship tail gas air inlet from bottom to top,Evaporate cooling zone,First and second scrubbing sections and ship tail gas gas outlet,It evaporates and is equipped with the first ventilation liquid-preventing device between cooling zone and the first scrubbing section,The second ventilation liquid-preventing device is equipped between first scrubbing section and the second scrubbing section,It evaporates cooling zone and is furnished with independent coolant circulation system,First scrubbing section is connected with the first alkali liquor circulating system,First scrubbing section carries out first time washing using the lye that the first alkali liquor circulating system is supplied to ship tail gas,Second scrubbing section is connected with the second alkali liquor circulating system,The lye that second scrubbing section is supplied using the second alkali liquor circulating system carries out second to ship tail gas and washs,The concentration for the lye that the concentration for the lye that first alkali liquor circulating system is supplied is supplied with the second alkali liquor circulating system differs;Advantage is their ability to carry out step washing to ship tail gas, and desulfurization is good except particle effect.

Description

A kind of ship tail gas wash mill
Technical field
The utility model is related to a kind of ship tail gas purifiers, more particularly, to a kind of ship tail gas wash mill.
Background technology
Patent of invention " a kind of ship tail gas scrubbing tower and its application method " (Patent No. of China's bulletin ZL201310343654.X), it discloses a kind of ship tail gas scrubbing tower and its application method, which includes scrubbing tower Body, washing tower body are equipped with ship tail gas air inlet and ship tail gas gas outlet, and main washing section is equipped in scrubbing tower body and is washed with secondary Section, major and minor washing section are shared using seawater as the cleaning solution open system of cleaning solution and are recycled by the cleaning solution of cleaning solution of lye System, main washing section and pair wash the intersegmental ventilation liquid-preventing device for being equipped with and allowing gas to circulate and preventing liquid communication, ventilation liquid-preventing device It is connect with cleaning solution open system and washing fluid circulation, ship tail gas by master by washing successively after ship tail gas air inlet It is discharged again from ship tail gas gas outlet after washing the washing of section and secondary washing section completion ship tail gas;Advantage is that major and minor washing section can Cleaning solution open system or washing fluid circulation are selected respectively, such as main washing section is washed with seawater, secondary washing section is washed with lye, To make full use of sea water desulfuration, alkali lye consumption amount is reduced.But the ship tail gas scrubbing tower has the following disadvantages:Do not allowing Using the marine site of seawer washing, i.e., when major and minor washing section needs simultaneous selection to wash fluid circulation, the first of main washing section Second washing nozzle of washing nozzle and secondary washing section is all that the identical lye of alkalinity is extracted from same liquid storage device, is not had Play the effect of the step washing of major and minor washing section.
Invention content
The technical problem to be solved by the utility model is to provide a kind of ship tail gas wash mills, can be to ship tail Gas carries out step washing, and desulfurization is good except particle effect.
Technical solution is used by the utility model solves above-mentioned technical problem:A kind of ship tail gas wash mill, packet Include washing tower body, the washing tower body be provided with from bottom to top ship tail gas air inlet, evaporation cooling zone, the first scrubbing section, Second scrubbing section and ship tail gas gas outlet, it is characterised in that:The ship tail gas air inlet and the evaporation cooling zone Connection, being provided between the evaporation cooling zone and first scrubbing section can allow gas to circulate and prevent liquid communication First ventilation liquid-preventing device, being provided between first scrubbing section and second scrubbing section can allow gas to circulate and prevent Second ventilation liquid-preventing device of liquid communication, second scrubbing section are connected to the ship tail gas gas outlet, the steaming It sends out cooling zone and is configured with independent coolant circulation system, the evaporation cooling zone utilizes the coolant circulation system institute The coolant liquid of supply makes the temperature of ship tail gas reduce, humidity increases to be washed close to adiabatic saturation state, described first Area is connected with the first alkali liquor circulating system, the alkali that first scrubbing section is supplied using first alkali liquor circulating system Liquid carries out washing for the first time to remove most of sulphur in ship tail gas to ship tail gas, and second scrubbing section is connected with the Two alkali liquor circulating systems, the lye that second scrubbing section is supplied using second alkali liquor circulating system is to ship tail Gas carries out second and washs to remove the residual sulfur in ship tail gas, the lye that first alkali liquor circulating system is supplied The concentration for the lye that concentration is supplied with second alkali liquor circulating system differs.
First alkali liquor circulating system is connected with fresh for continuously being added for first alkali liquor circulating system First lye device for supplying of lye and for the first alkali liquor circulating system described in the described evaporation cooling zone continuous conveying First overflow passage of the extra cleaning solution provided is provided with alkali solution cooler in first alkali liquor circulating system;Setting First lye device for supplying be in order to continuously add fresh lye to the first alkali liquor circulating system, it is adjustable by adding fresh lye Save the alkali concentration that the first alkali liquor circulating system supplies the lye of the first scrubbing section;First overflow passage is set, while being evaporated cold But area is provided with independent coolant circulation system, and evaporation capacity is big, on the one hand, the first alkali liquor circulating system passes through the first overflow pipe Road is by steam in ship tail gas in the condensate liquid of the first scrubbing section, the fresh lye of supplement, from the second alkali liquor circulating system The extra cleaning solution that the reasons such as overflow lye generate is discharged into evaporation cooling zone, with the endless form of evaporation-condensation-overflow, continuously Ground displaces the desulfurization product of the first scrubbing section, make the first liquid storage device in the first alkali liquor circulating system liquid level and cleaning solution at Divide and reaches dynamic stability;Simultaneously so that a large amount of steam are condensed from evaporation cooling zone to the first scrubbing section, are recycled for the first lye System is automatically replenished enough fresh water, eliminates the light expense of system of the first alkali liquor circulating system;On the other hand, not for waste liquid The case where allowing in line sea and the waste liquid pool on ship must be temporarily stored within, the extra cleaning solution row of the first alkali liquor circulating system Enter to evaporate cooling zone and be evaporated concentration, it is possible to reduce discharging any waste liquor amount is to reduce the size of required waste liquid pool;In addition, first It is cold that overflow passage can also make the desulfurization product of the first scrubbing section with the extra cleaning solution of overflow automatically, continuously be transferred to evaporation But area the particle in the first scrubbing section is all discharged;Setting alkali solution cooler can be such that the first alkali liquor circulating system is supplied The temperature of lye be less than the high humidity tail gas for coming spontaneous evaporation cooling zone, keep a large amount of steam in ship tail gas cold in microparticle surfaces It is solidifying, promote the weightening of particle humidification and remove, and can be that the first alkali liquor circulating system supplements enough condensed waters without in addition Fresh water can also be such that washing tower body washs at a lower temperature, improve desulfurization effect;
Second alkali liquor circulating system is connected with fresh for continuously being added for second alkali liquor circulating system Second lye device for supplying of lye and for being followed to the second lye described in the first alkali liquor circulating system continuous conveying Second overflow passage of the extra cleaning solution that loop system provides;It is to be recycled to the second lye that the second lye device for supplying, which is arranged, System continuously adds fresh lye, and the alkali that the second alkali liquor circulating system supplies the second scrubbing section is adjusted by adding fresh lye The alkali concentration of liquid;The extra of the reasons generations such as the fresh lye that the second overflow passage can be such that the discharge of the second scrubbing section adds is set Cleaning solution overflow to the first alkali liquor circulating system continues to use up its residual alkalinity, keeps and the desulfurization of the second scrubbing section can be made to produce Object automatically, is continuously transferred to the first scrubbing section with the extra cleaning solution of overflow so that the liquid level of the second liquid storage device and Cleaning solution ingredient reaches dynamic stability.
First scrubbing section uses spray void tower structure either filler tower structure or rotating stream tray scrubber structure etc.;
When first scrubbing section is using spray void tower structure, structure is by the first washing nozzle and the first spraying zone Composition, first washing nozzle are located at the top of first spraying zone, and the first ventilation liquid-preventing device is located at The lower section of first spraying zone;The first ventilation liquid-preventing device uses funnel-cap type structure comprising the first bottom plate and peace Loaded on the first blast cap on first bottom plate, it is provided with the first fluid-through port on first bottom plate, by the first fluid-through port Be set on the first bottom plate is to enable the particle for washing to get off from ship tail gas that the first scrubbing section is all discharged;
When first scrubbing section uses filler tower structure, structure is by the first washing nozzle and the first packing layer group At first washing nozzle is located at the top of first packing layer, and the first ventilation liquid-preventing device is located at institute The lower section for the first packing layer stated;The first ventilation liquid-preventing device uses funnel-cap type structure comprising the first bottom plate and installation The first blast cap on first bottom plate is provided with the first fluid-through port on first bottom plate, the first fluid-through port is set Be placed on the first bottom plate is to enable the particle for washing to get off from ship tail gas that the first scrubbing section is all discharged.
First alkali liquor circulating system includes being set to external the first liquid storage device and first of the scrubbing tower to follow Ring pumps, and first fluid-through port is by being serially connected with the inlet communication of the pipeline of the first valve and first liquid storage device, institute The inlet communication that the outlet for the first liquid storage device stated is pumped by being serially connected with the pipeline of the second valve with the first circulation, it is described First circulation pump import and second overflow passage outlet, the import of first circulation pump with it is described The first lye device for supplying outlet, the outlet of first circulation pump passes through pipeline and the alkali solution cooler Inlet communication, the outlet of the alkali solution cooler passes through the pipeline for being serially connected with third valve and first cleaning solution sprays Mouth is connected to, described first of the outlet of first liquid storage device and the liquid level for automatically controlling first liquid storage device The outlet of the inlet communication of overflow passage, first overflow passage is connected to the evaporation cooling zone, and described first Extra cleaning solution is discharged to the evaporation cooling zone by first overflow passage in alkali liquor circulating system, and described first The outlet of liquid storage device is connected with the pipeline for being serially connected with the first liquid storage exhaust-valve, and the first liquid storage exhaust-valve of setting is in order in maintenance Empty the first liquid storage device.
First alkali liquor circulating system includes the first liquid storage tank being set in first scrubbing section and setting In the external first circulation pump of the scrubbing tower, first liquid storage tank is located at the lower section of first spraying zone, institute The bottom of pond for the first liquid storage tank stated is first bottom plate, and first fluid-through port is by being serially connected with the pipeline of the first valve The inlet communication pumped with the first circulation, the outlet of the import and second overflow passage of first circulation pump Connection, the outlet of the import and the first lye device for supplying of first circulation pump, the first circulation The outlet of pump is by the inlet communication of pipeline and the alkali solution cooler, and the outlet of the alkali solution cooler is by being serially connected with The pipeline of third valve is connected to first washing nozzle, first fluid-through port with it is described for automatically controlling The inlet communication of first overflow passage of the liquid level of first liquid storage tank, the outlet of first overflow passage with it is described The connection of evaporation cooling zone, first alkali liquor circulating system cooled down by first overflow passage to the evaporation Extra cleaning solution is discharged in area.First alkali liquor circulating system is more simple with respect to the first alkali liquor circulating system of the first structure, It replaces being set to the first external liquid storage device of scrubbing tower with the first liquid storage tank in the first scrubbing section, reduces equipment, if but When first scrubbing section is also configured with seawer washing open system, when seawater and lye switching wash, seawater and lye can be caused Mutually mix.
Second scrubbing section either sprays void tower structure or rotating stream tray scrubber structure etc. using filler tower structure;
Second scrubbing section use filler tower structure when, structure by the second demister, the second washing nozzle and Second packing layer forms, and second demister is located at the top of second washing nozzle, the described second washing Nozzle for liquid is located at the top of second packing layer, and the second ventilation liquid-preventing device is located under second packing layer Side;The second ventilation liquid-preventing device uses funnel-cap type structure comprising the second bottom plate and is installed on second bottom plate The second blast cap, be provided with the second fluid-through port on second bottom plate, the second fluid-through port is set on the second bottom plate be for Enable the particle for washing to get off from ship tail gas the second scrubbing section is all discharged;
When second scrubbing section is using spray void tower structure, structure is by the second demister, the second washing nozzle It is formed with the second spraying zone, second demister is located at the top of second washing nozzle, and described second washes The top that nozzle for liquid is located at second spraying zone is washed, the second ventilation liquid-preventing device is located at second spraying zone Lower section;The second ventilation liquid-preventing device uses funnel-cap type structure comprising the second bottom plate and is installed on second bottom plate On the second blast cap, be provided with the second fluid-through port on second bottom plate, the second fluid-through port, which is set on the second bottom plate, is In order to enable the particle for washing to get off from ship tail gas that the second scrubbing section is all discharged.
Second alkali liquor circulating system includes being set to external the second liquid storage device and second of the scrubbing tower to follow Ring pumps, and second fluid-through port is by being serially connected with the inlet communication of the pipeline of the 4th valve and second liquid storage device, institute The inlet communication that the outlet for the second liquid storage device stated is pumped by being serially connected with the pipeline of the 5th valve with the second circulation, it is described Second circulation pump import and the second lye device for supplying outlet, the outlet of second circulation pump is logical Cross and be serially connected with the pipeline of the 6th valve and be connected to second washing nozzle, the outlet of second liquid storage device be used for Automatically control the inlet communication of second overflow passage of the liquid level of second liquid storage device, second overflow pipe The outlet on road is connected to first alkali liquor circulating system, and second alkali liquor circulating system passes through second overflow Extra cleaning solution is discharged to first alkali liquor circulating system in pipeline, and the outlet of second liquid storage device, which is connected with, to be serially connected with The pipeline of second liquid storage exhaust-valve, the second liquid storage exhaust-valve of setting are to empty the second liquid storage device in maintenance.
Second alkali liquor circulating system includes the second liquid storage tank being set in second scrubbing section and setting In the external second circulation pump of the scrubbing tower, second liquid storage tank is located at the lower section of second packing layer, institute The bottom of pond for the second liquid storage tank stated is second bottom plate, and second fluid-through port is by being serially connected with the pipeline of the 4th valve The inlet communication pumped with the second circulation, import and the second lye device for supplying of second circulation pump The outlet of outlet, second circulation pump passes through the pipeline for being serially connected with the 6th valve and second washing nozzle Connection, second overflow passage of second fluid-through port and the liquid level for automatically controlling second liquid storage tank Inlet communication, the outlet of second overflow passage is connected to first alkali liquor circulating system, second alkali Extra cleaning solution is discharged to first alkali liquor circulating system by second overflow passage in fluid circulation.This second Alkali liquor circulating system is more simple with respect to the second alkali liquor circulating system of the first structure, with the second storage in the second scrubbing section Liquid pool replaces being set to the second external liquid storage device of scrubbing tower, reduces equipment, if but the second scrubbing section be also configured with seawater and wash When washing open system, when seawater and lye switching wash, mutually mixing for seawater and lye can be caused.
First alkali liquor circulating system and second alkali liquor circulating system share a shared lye cyclic system System, the shared alkali liquor circulating system include being set to the external common reservoir of the scrubbing tower and common recycle pump, First fluid-through port is by being serially connected with the inlet communication of the pipeline of the first valve and the common reservoir, and described the Two fluid-through ports are by being serially connected with the inlet communication of the pipeline of the 4th valve and the common reservoir, the common reservoir The inlet communication that is pumped with the common recycle by being serially connected with the pipeline of the second valve of outlet, common recycle pump The outlet of import and the first lye device for supplying, the alkali solution cooler is as shared alkali solution cooler, institute The inlet communication of the outlet and the shared alkali solution cooler of the common recycle pump stated, the shared alkali solution cooler go out Mouth is connected to by being serially connected with the pipeline of third valve with first washing nozzle, and the shared alkali solution cooler goes out Mouth is connected to by being serially connected with the pipeline of the 6th valve with second washing nozzle, is serially connected with pipeline and the institute of the 6th valve The outlet for the second lye device for supplying stated, the outlet of the common reservoir are connected with described for automatically controlling The shared overflow passage of the liquid level of common reservoir, outlet and the evaporation cooling zone or the institute of the shared overflow passage The coolant circulation system connection stated, the shared alkali liquor circulating system is by the shared overflow passage to the steaming It sends out cooling zone or extra cleaning solution is discharged in the coolant circulation system, the outlet of the common reservoir is connected with concatenation There is the pipeline of shared liquid storage exhaust-valve.The program reduces system equipment, but because the first alkali liquor circulating system and the second lye follow The lye of loop system mutually mixes, and the particle to get off is washed from the first scrubbing section can also take the second scrubbing section to, and the second scrubbing section is caused to deposit In the risk of particles holography, therefore when the use program, the filler or selection spray that the second scrubbing section preferably selects anti-blocking good are empty Tower structure.
The evaporation cooling zone is using spray void tower structure or using the void tower knot of external venturi devaporizer Structure;
When the evaporation cooling zone is using spray void tower structure, structure is stored up by the cooling zone set gradually from bottom to top Liquid pool, void tower area, coolant nozzle and the first demister composition, the coolant circulation system is by coolant recirculation pump group At, be provided on the cooling zone liquid storage tank coolant liquid circulating outlet being connected to the coolant circulation system, use In the cooling liquid inlet of fresh coolant liquid is supplemented to the cooling zone liquid storage tank, for being discharged in the cooling zone liquid storage tank The coolant outlet of extra coolant liquid or the emptying cooling zone liquid storage tank, the coolant outlet pass through coolant liquid Overflow pipe or coolant liquid evacuated tube are connected to the outer discharge pipe of waste liquid, coolant liquid overflow pipe by the coolant liquid concentrated in an overflow manner Continuous discharge cooling zone liquid storage tank, makes coolant liquid concentration stablize, and make the level stability of cooling zone liquid storage tank, and lead to when needed Supercooling liquid evacuated tube empties cooling zone liquid storage tank, the import of the coolant recirculation pump and the coolant liquid cyclic water outlet Mouth connection, the outlet of the coolant recirculation pump are connected to the coolant nozzle, and the coolant recirculation pump is with alkali Liquid or seawater are the coolant nozzle feed flow described in coolant liquid is, the coolant recirculation pump is institute by coolant liquid of lye When the coolant nozzle feed flow stated, the cooling zone liquid storage tank is connected to or described cold with first alkali liquor circulating system But the import of liquid circulating pump is connected to first alkali liquor circulating system, to make full use of first alkali liquor circulating system The extra cleaning solution of continuous conveying;
When the evaporation cooling zone uses the void tower structure of external venturi devaporizer, structure is by from bottom to top The cooling zone liquid storage tank, void tower area and the first demister that set gradually and it is set to the external venturi evaporation of the scrubbing tower Cooler forms, and the coolant circulation system is made of coolant recirculation pump, is provided on the cooling zone liquid storage tank The coolant liquid circulating outlet that is connected to the coolant circulation system, for fresh to the cooling zone liquid storage tank supplement The cooling liquid inlet of coolant liquid, for extra coolant liquid in the cooling zone liquid storage tank or the emptying cooling zone storage to be discharged The coolant outlet of liquid pool, the coolant outlet are arranged by coolant liquid overflow pipe or coolant liquid evacuated tube with outside waste liquid Pipeline is connected to, and cooling zone liquid storage tank is continuously discharged in the coolant liquid concentrated by coolant liquid overflow pipe in an overflow manner, makes coolant liquid Concentration is stablized, and makes the level stability of cooling zone liquid storage tank, and empties cooling zone liquid storage when required by coolant liquid evacuated tube Pond, the venturi devaporizer include coolant liquid spray in Venturi tube and the pipe being set in the Venturi tube Mouth, the outlet of the air inlet and ship tail gas pipe of the Venturi tube, the gas outlet of the Venturi tube with it is described The connection of void tower area, the import of the coolant recirculation pump is connected to the coolant liquid circulating outlet, the cooling The outlet of liquid circulating pump is connected to coolant nozzle in the pipe, and the coolant recirculation pump is cold with lye or seawater But liquid is coolant nozzle feed flow in the pipe, and the coolant recirculation pump is cold in the pipe by coolant liquid of lye But when nozzle for liquid feed flow, the cooling zone liquid storage tank is connected to first alkali liquor circulating system or the coolant liquid is followed The import of ring pump is connected to first alkali liquor circulating system, to make full use of first alkali liquor circulating system continuously defeated The extra cleaning solution sent.
First scrubbing section and second scrubbing section can also be connected separately with cleaning solution open system, described Cleaning solution open system includes solution feed pump and the outer discharge pipe of waste liquid, and the water inlet of the solution feed pump accesses external dynamic sea, described Solution feed pump the water outlet flooding nozzle with the flooding nozzle of first demister and second demister respectively Connection, the water outlet of the solution feed pump are connected to by being serially connected with the pipeline of the 7th valve with first washing nozzle, The water outlet of the solution feed pump is connected to by being serially connected with the pipeline of the 8th valve with second washing nozzle, described First fluid-through port is connected to by being serially connected with the pipeline of the 9th valve with discharge pipe outside the waste liquid, and second fluid-through port is logical It crosses and is serially connected with the pipeline of the tenth valve and is connected to the outer discharge pipe of the waste liquid.Here, the first scrubbing section and the second scrubbing section are each One cleaning solution open system of connection can be switched to seawer washing or the first scrubbing section be in this way when allowing seawer washing Seawer washing, the second scrubbing section are alkali liquid washing, to reduce alkali lye consumption.
The course of work of the ship tail gas wash mill is as follows:
(1) coolant circulation system is coolant liquid to evaporation cooling zone feed flow using seawater or lye, and ship tail gas is from ship Vessel exhaust air inlet enters evaporation cooling zone and caloic exchange is contacted and carried out with coolant liquid, and coolant liquid absorbs the heat of ship tail gas After evaporate, promote that the temperature of ship tail gas reduces, humidity increases and approach adiabatic saturation state;
(2) ship tail gas close to adiabatic saturation state of evaporation cooling zone is left by the first demister and by first Ventilation liquid-preventing device enters the first scrubbing section and either the first alkali liquor circulating system or shared lye follow by cleaning solution open system The cold washing liquid of loop system supply contacts, and the acidic materials in ship tail gas based on oxysulfide are washed liquid and absorb, and And since cleaning solution temperature is low, the temperature difference is big between ship tail gas, therefore ship tail gas forms satiety during gas-liquid contact And moisture state, and then promote a large amount of vapour molecules in ship tail gas solidifying by nucleation centre phase transformation of the surface of the particle in tail gas Knot promotes cleaning solution by particle capture along with the effect of diffusiophoresis and thermophoresis makes particle collision reunite and then the thickening that increases weight And it efficiently removes;
(3) ship tail gas after the washing of the first scrubbing section is washed by the second ventilation liquid-preventing device into the second scrubbing section It washs liquid further to wash, cleaning solution is by cleaning solution open system either the second alkali liquor circulating system or shared alkali liquor circulating system Supply;
Wherein, when the desulfurization of ship's navigation marine site is of less demanding and allows outer row's cleaning solution, the first scrubbing section and cleaning solution Open system is connected to, and cleaning solution open system is cleaning solution to the first scrubbing section feed flow using seawater, the second scrubbing section also can with wash The connection of liquid open system is washed, cleaning solution open system is cleaning solution to the second scrubbing section feed flow using seawater, when ship tail gas sulphur contains When amount is not high, the second scrubbing section can not also be connected to cleaning solution open system;When the desulfurization of ship's navigation marine site requires high and allows outer When arranging cleaning solution, the first scrubbing section is connected to cleaning solution open system, the second scrubbing section and the second alkali liquor circulating system or shared Alkali liquor circulating system is connected to, and cleaning solution open system is cleaning solution to the first scrubbing section feed flow, the second lye cyclic system using seawater System or shared alkali liquor circulating system are cleaning solution to the second scrubbing section feed flow using lye;When ship's navigation marine site does not allow outer row to wash When washing liquid, the first scrubbing section is connected to the first alkali liquor circulating system or shared alkali liquor circulating system, the first alkali liquor circulating system or It is cleaning solution to the first scrubbing section feed flow that alkali liquor circulating system, which is shared, using lye, and the second scrubbing section can not be connected to the second lye and recycle System and shared alkali liquor circulating system, and when desulfurization require it is very high when, the second scrubbing section also can with the second alkali liquor circulating system or Alkali liquor circulating system connection is shared, the second alkali liquor circulating system or shared alkali liquor circulating system are washed using lye as cleaning solution to second Wash area's feed flow;
(4) ship tail gas after above-mentioned washing passes sequentially through after the second demister and heater exhaust gas from ship tail gas Gas outlet is discharged.
Compared with prior art, the utility model has the advantage of:
1) the first scrubbing section and the second scrubbing section are provided in scrubbing tower body, the first scrubbing section is connected with the first lye cycle System, the second scrubbing section are connected with the second alkali liquor circulating system, and the concentration of lye that is supplied of the first alkali liquor circulating system with The concentration for the lye that second alkali liquor circulating system is supplied differs, and the ship tail gas of sulfur-bearing is made first to wash away it through the first scrubbing section Most sulphur, then wash away its residual sulfur through the second scrubbing section, that is, step washing is carried out, and can be by improving the second lye cycle The concentration for the lye that system is supplied makes desulfuration efficiency reach intimate 100%, to realize minimum discharge.
2) evaporation cooling zone uses independent coolant circulation system, i.e., is washed with the mainstream of the low temperature of the first scrubbing section It washs liquid not mix mutually, coolant circulation system is supplied to the thermal insulation of temperature close to the ship tail gas of the coolant liquid of evaporation cooling zone full And temperature, ship tail gas waste heat are mainly used for the evaporation of cooling water, the evaporation capacity for evaporating cooling zone is big, leaves evaporation cooling zone The saturation temperature of ship tail gas and the temperature difference of the cleaning solution of the first scrubbing section are big, enhance the ship tail gas in the first scrubbing section Effect of the steam in condensation, promotion particle the humidification weightening and washout of microparticle surfaces.
Description of the drawings
Fig. 1 is the structural schematic diagram of the ship tail gas wash mill of embodiment one;
Fig. 2 is the structural schematic diagram of the ship tail gas wash mill of embodiment two;
Fig. 3 is the structural schematic diagram of the ship tail gas wash mill of embodiment three.
Specific implementation mode
The utility model is described in further detail below in conjunction with attached drawing embodiment.
Embodiment one:
A kind of ship tail gas wash mill that the present embodiment proposes, as shown in Figure 1 comprising washing tower body 1 washs tower body 1 is provided with ship tail gas air inlet A, evaporation cooling zone 2, the first scrubbing section 3, the second scrubbing section 4 and ship tail gas from bottom to top Gas outlet B, ship tail gas air inlet A are connected to evaporation cooling zone 2, and being provided between evaporation cooling zone 2 and the first scrubbing section 3 can It allows gas to circulate and prevents the first ventilation liquid-preventing device 5 of liquid communication, be provided between the first scrubbing section 3 and the second scrubbing section 4 Gas can be allowed to circulate and prevent the second ventilation liquid-preventing device 6 of liquid communication, the second scrubbing section 4 is connected to ship tail gas gas outlet B, It evaporates cooling zone 2 and is configured with independent coolant circulation system, evaporation cooling zone 2 is supplied cold using coolant circulation system But liquid makes the temperature of ship tail gas reduce, humidity increases so that close to adiabatic saturation state, the first scrubbing section 3 is connected with the first alkali Fluid circulation, the lye that the first scrubbing section 3 is supplied using the first alkali liquor circulating system to ship tail gas wash for the first time It washs to remove most of sulphur in ship tail gas, the second scrubbing section 4 is connected with the second alkali liquor circulating system, 4 profit of the second scrubbing section The lye supplied with the second alkali liquor circulating system carries out second to ship tail gas and washs to remove the remnants in ship tail gas Sulphur, the concentration of the lye that the concentration for the lye that the first alkali liquor circulating system is supplied is supplied with the second alkali liquor circulating system not phase Together.
In the present embodiment, the first alkali liquor circulating system is connected with fresh for continuously being added for the first alkali liquor circulating system First lye device for supplying 71 of lye and for evaporation 2 the first alkali liquor circulating system of continuous conveying of cooling zone provide it is extra First overflow passage 72 of cleaning solution is provided with alkali solution cooler 73 in the first alkali liquor circulating system;The supply of first lye is set Device 71 is that the first lye is adjusted by adding fresh lye in order to continuously add fresh lye to the first alkali liquor circulating system The circulatory system supplies the alkali concentration of the lye of the first scrubbing section 3;First overflow passage 72 is set, while evaporating cooling zone 2 and setting Independent coolant circulation system is set, evaporation capacity is big, on the one hand, the first alkali liquor circulating system will by the first overflow passage 72 Steam is in the condensate liquid of the first scrubbing section 3, the fresh lye of supplement, the overflow from the second alkali liquor circulating system in ship tail gas The extra cleaning solution that the reasons such as lye generate is discharged into evaporation cooling zone 2 and is continuously set with the endless form of evaporation-condensation-overflow Swap out the desulfurization product of the first scrubbing section 3, make the first liquid storage device 74 in the first alkali liquor circulating system liquid level and cleaning solution at Divide and reaches dynamic stability;Simultaneously so that a large amount of steam take the condensation of the first scrubbing section 3 to from evaporation cooling zone 2, are followed for the first lye Loop system is automatically replenished enough fresh water, eliminates the light expense of system of the first alkali liquor circulating system;On the other hand, for waste liquid The case where not allowing in line sea and the waste liquid pool on ship must be temporarily stored within, the extra cleaning solution of the first alkali liquor circulating system It is discharged into evaporation cooling zone 2 and is evaporated concentration, it is possible to reduce discharging any waste liquor amount is to reduce the size of required waste liquid pool;In addition, First overflow passage 72 can also be such that the desulfurization product of the first scrubbing section 3 automatically, is continuously shifted with the extra cleaning solution of overflow To evaporation cooling zone 2, i.e., the particle in the first scrubbing section 3 is all discharged, does not make particle accumulation in the first scrubbing section 3;If The temperature for setting the lye that alkali solution cooler 73 can be such that the first alkali liquor circulating system is supplied is less than the high humidity for coming spontaneous evaporation cooling zone 2 Tail gas makes a large amount of steam in ship tail gas be condensed in microparticle surfaces, promotes the weightening of particle humidification and removes, and can be the first alkali Fluid circulation supplements enough condensed waters without other fresh water, also washing tower body 1 can be made to wash at a lower temperature, carried High desulfurization effect.
In the present embodiment, the second alkali liquor circulating system is connected with fresh for continuously being added for the second alkali liquor circulating system Second lye device for supplying 81 of lye and for first the second alkali liquor circulating system of alkali liquor circulating system continuous conveying provide Extra cleaning solution the second overflow passage 82;It is to connect to the second alkali liquor circulating system that the second lye device for supplying 81, which is arranged, It is continuous to add fresh lye, the lye that the second alkali liquor circulating system supplies the second scrubbing section 4 is adjusted by adding fresh lye Alkali concentration;The extra of the reasons generations such as the fresh lye that the second overflow passage 82 can be such that the discharge of the second scrubbing section 4 adds is set Cleaning solution overflow to the first alkali liquor circulating system continues to use up its residual alkalinity, keeps and can make the desulfurization of the second scrubbing section 4 Product automatically, is continuously transferred to the first scrubbing section 3 with the extra cleaning solution of overflow, so that the liquid of the second liquid storage device 84 Position and cleaning solution ingredient reach dynamic stability.
In the present embodiment, the first scrubbing section 3 is using spray void tower structure, and structure is by the first washing nozzle 31 and the One spraying zone 32 forms, and the first washing nozzle 31 is located at the top of the first spraying zone 32, and the first ventilation liquid-preventing device 5 is located at first The lower section of spraying zone 32;First ventilation liquid-preventing device 5 uses funnel-cap type structure comprising the first bottom plate 51 and is installed on the first bottom plate The first blast cap 52 on 51 is provided with the first fluid-through port 53 on first bottom plate 51, the first fluid-through port 53 is set to the first bottom plate It is to enable the particle for washing to get off from ship tail gas that the first scrubbing section 3 is all discharged on 51.
In the present embodiment, the first alkali liquor circulating system includes the first liquid storage device 74 and the being set to outside washing tower body 1 One circulating pump 75, the first fluid-through port 53 is by being serially connected with the inlet communication of the pipeline and the first liquid storage device 74 of the first valve 101, and The outlet of one liquid storage device 74 pumps 75 inlet communication, first circulation by the pipeline and first circulation that are serially connected with the second valve 102 The outlet of the import and the second overflow passage 82 of pump 75, import and the first lye device for supplying 71 of first circulation pump 75 The outlet of outlet, first circulation pump 75 passes through the inlet communication of pipeline and alkali solution cooler 73, and alkali solution cooler 73 goes out Mouthful be connected to the first washing nozzle 31 by being serially connected with the pipeline of third valve 103, the outlet of the first liquid storage device 74 be used for Automatically control the inlet communication of the first overflow passage 72 of the liquid level of the first liquid storage device 74, the outlet and steaming of the first overflow passage 72 Cooling zone 2 to be sent out to be connected to, extra cleaning solution is discharged to evaporation cooling zone 2 by the first overflow passage 72 in the first alkali liquor circulating system, The outlet of first liquid storage device 74 is connected with the pipeline for being serially connected with the first liquid storage exhaust-valve 201, and the first liquid storage exhaust-valve 201 of setting is In order to empty the first liquid storage device 74 in maintenance.
In the present embodiment, the second scrubbing section 4 uses filler tower structure, structure to be washed by the second demister 41, second Nozzle for liquid 42 and the second packing layer 43 composition, the second demister 41 are located at the top of the second washing nozzle 42, the second cleaning solution Nozzle 42 is located at the top of the second packing layer 43, and the second ventilation liquid-preventing device 6 is located at the lower section of the second packing layer 43;Second ventilation resistance Liquid device 6 uses funnel-cap type structure comprising the second bottom plate 61 and the second blast cap 62 being installed on the second bottom plate 61, the second bottom plate The second fluid-through port 63 is provided on 61, it is to make to wash from ship tail gas that the second fluid-through port 63, which is set on the second bottom plate 61, The second scrubbing section 4 can be all discharged by washing the particle to get off.
In the present embodiment, the second alkali liquor circulating system includes the second liquid storage device 84 and the being set to outside washing tower body 1 Two circulating pumps 85, the second fluid-through port 63 is by being serially connected with the inlet communication of the pipeline and the second liquid storage device 84 of the 4th valve 104, and The outlet of two liquid storage devices 84 pumps 85 inlet communication, second circulation by the pipeline and second circulation that are serially connected with the 5th valve 105 The outlet of the import and the second lye device for supplying 81 of pump 85, the outlet of second circulation pump 85 is by being serially connected with the 6th valve 106 pipeline is connected to the second washing nozzle 42, the outlet of the second liquid storage device 84 with for automatically controlling the second liquid storage device 84 Liquid level the second overflow passage 82 inlet communication, the outlet of the second overflow passage 82 is connected to the first alkali liquor circulating system, Extra cleaning solution, the second liquid storage device is discharged to the first alkali liquor circulating system by the second overflow passage 82 in second alkali liquor circulating system 84 outlet is connected with the pipeline for being serially connected with the second liquid storage exhaust-valve 202, and the second liquid storage exhaust-valve 202 of setting is to overhaul When empty the second liquid storage device 84.
In the present embodiment, using spray void tower structure, structure is cold by what is set gradually from bottom to top for evaporation cooling zone 2 But area's liquid storage tank 21, void tower area 22, coolant nozzle 23 and the first demister 24 composition, coolant circulation system are followed by coolant liquid Ring pump 25 forms, and the coolant liquid circulating outlet 291 being connected to coolant circulation system is provided on cooling zone liquid storage tank 21, is used In supplementing the cooling liquid inlet 292 of fresh coolant liquid, extra in cooling zone liquid storage tank 21 for being discharged to cooling zone liquid storage tank 21 Coolant liquid or the coolant outlet 293 for emptying cooling zone liquid storage tank 21, coolant outlet 293 pass through coolant liquid overflow pipe 294 or the outer discharge pipe of coolant liquid evacuated tube 295 and waste liquid 11 be connected to, coolant liquid overflow pipe 294 is by the coolant liquid concentrated with excessive Cooling zone liquid storage tank 21 is continuously discharged in stream mode, so that coolant liquid concentration is stablized, and make the level stability of cooling zone liquid storage tank 21, and Cooling zone liquid storage tank 21 is emptied when required by coolant liquid evacuated tube 295, import and the coolant liquid of coolant recirculation pump 25 are followed Ring water outlet 291 is connected to, and the outlet of coolant recirculation pump 25 is connected to coolant nozzle 23, coolant recirculation pump 25 with lye or Person's seawater is that coolant liquid is 23 feed flow of coolant nozzle, and coolant recirculation pump 25 is that coolant nozzle 23 supplies by coolant liquid of lye When liquid, cooling zone liquid storage tank 21 is connected to the first alkali liquor circulating system, to make full use of the first alkali liquor circulating system continuous conveying Extra cleaning solution.Here, the import of coolant recirculation pump 25 can also be connected to the first alkali liquor circulating system.
In the present embodiment, the first scrubbing section 3 and the second scrubbing section 4 can also be connected separately with cleaning solution open system, wash It includes solution feed pump 12 and the outer discharge pipe 11 of waste liquid to wash liquid open system, and the water inlet of solution feed pump 12 accesses external dynamic sea, solution feed pump 12 water outlet is connected to the flooding nozzle 411 of the flooding nozzle 241 of the first demister 24 and the second demister 41 respectively, feed flow The water outlet of pump 12 is connected to by being serially connected with the pipeline of the 7th valve 107 with the first washing nozzle 31, the water outlet of solution feed pump 12 It mouthful is connected to the second washing nozzle 42 by being serially connected with the pipeline of the 8th valve 108, the first fluid-through port 53 is by being serially connected with the The outer discharge pipe of the pipeline of nine valves 109 and waste liquid 11 be connected to, the second fluid-through port 63 by be serially connected with the tenth valve 110 pipeline and The outer discharge pipe 11 of waste liquid is connected to.Here, the first scrubbing section 3 and the second scrubbing section 4 respectively connect a cleaning solution open system, in this way When allowing seawer washing, it can be switched to that seawer washing or the first scrubbing section 3 are seawer washing, the second scrubbing section 4 is lye Washing, to reduce alkali lye consumption.
In the present embodiment, the first scrubbing section 3 also can be replaced filler tower structure, and structure is by the first washing nozzle 31 It is formed with the first packing layer (not shown), the first washing nozzle 31 is located at the top of the first packing layer, the first ventilation resistance Liquid device 5 is located at the lower section of the first packing layer;First ventilation liquid-preventing device 5 uses funnel-cap type structure comprising the first bottom plate 51 and peace Loaded on the first blast cap 52 on the first bottom plate 51, it is provided with the first fluid-through port 53 on the first bottom plate 51, the first fluid-through port 53 is set Be placed on the first bottom plate 51 is to enable the particle for washing to get off from ship tail gas that the first scrubbing section 3 is all discharged;It steams Hair cooling zone 2 also can be replaced the void tower structure of external venturi devaporizer.
Embodiment two:
The present embodiment propose a kind of ship tail gas wash mill as shown in Fig. 2, its structure and embodiment one ship tail The structure of gas washing device is essentially identical, the difference is that:
In the present embodiment, the structure of the first alkali liquor circulating system is made an adjustment, specially:First alkali liquor circulating system Including the first liquid storage tank 35 being set in the first scrubbing section 3 and the first circulation pump 75 being set to outside washing tower body 1, the first storage Liquid pool 35 is located at the lower section of the first spraying zone 32, and the bottom of pond of the first liquid storage tank 35 is the first bottom plate 51, and the first fluid-through port 53 passes through It is serially connected with the inlet communication of the pipeline and first circulation pump 75 of the first valve 101, the import and the second overflow of first circulation pump 75 The outlet of pipeline 82, the outlet of the import and the first lye device for supplying 71 of first circulation pump 75, first circulation pump 75 outlet is by the inlet communication of pipeline and alkali solution cooler 73, and the outlet of alkali solution cooler 73 is by being serially connected with third valve 103 pipeline is connected to the first washing nozzle 31, the first fluid-through port 53 and the liquid level for automatically controlling the first liquid storage tank 35 The first overflow passage 72 inlet communication, the outlet of the first overflow passage 72 be connected to evaporation cooling zone 2, and the first lye recycles Extra cleaning solution is discharged to evaporation cooling zone 2 by the first overflow passage 72 in system.First alkali liquor circulating system is opposite to be implemented The first alkali liquor circulating system in example one is more simple, replaces being set to washing with the first liquid storage tank 35 in the first scrubbing section 3 The first liquid storage device 74 outside tower body 1 is washed, equipment is reduced, if but the first scrubbing section 3 when being also configured with seawer washing open system, When seawater and lye switching wash, mutually mixing for seawater and lye can be caused.
In the present embodiment, the structure of the second alkali liquor circulating system is made an adjustment, specially:Second alkali liquor circulating system Including the second liquid storage tank 45 being set in the second scrubbing section 4 and the second circulation pump 85 being set to outside washing tower body 1, the second storage Liquid pool 45 is located at the lower section of the second packing layer 43, and the bottom of pond of the second liquid storage tank 45 is the second bottom plate 61, and the second fluid-through port 63 passes through It is serially connected with the inlet communication of the pipeline and second circulation pump 85 of the 4th valve 104, the import of second circulation pump 85 and the second lye It is washed by the pipeline and second for being serially connected with the 6th valve 106 outlet of the outlet of device for supplying 81, second circulation pump 85 Nozzle for liquid 42 is connected to, the second fluid-through port 63 and the second overflow passage 82 of the liquid level for automatically controlling the second liquid storage tank 45 into Mouth connection, the outlet of the second overflow passage 82 are connected to the first alkali liquor circulating system, and the second alkali liquor circulating system overflows by second Extra cleaning solution is discharged to the first alkali liquor circulating system in flow tube road 82.Second alkali liquor circulating system is with respect in embodiment one Two alkali liquor circulating systems are more simple, replace being set to outside washing tower body 1 with the second liquid storage tank 45 in the second scrubbing section 4 Second liquid storage device 84, reduces equipment, if but the second scrubbing section 4 when being also configured with seawer washing open system, in seawater and alkali When liquid switching washing, mutually mixing for seawater and lye can be caused.
In the present embodiment, evaporation cooling zone 2 is using the void tower structure of external venturi devaporizer, and structure is by certainly The cooling zone liquid storage tank 21, void tower area 22 and the first demister 24 that are set gradually on down and the text being set to outside washing tower body 1 Devaporizer 28 forms in mound, and coolant circulation system is made of coolant recirculation pump 25, is arranged on cooling zone liquid storage tank 21 There is the coolant liquid circulating outlet 291 being connected to coolant circulation system, for supplementing fresh cooling to cooling zone liquid storage tank 21 The cooling liquid inlet 292 of liquid, for the cold of extra coolant liquid in cooling zone liquid storage tank 21 or emptying cooling zone liquid storage tank 21 to be discharged But liquid outlet 293, coolant outlet 293 pass through coolant liquid overflow pipe 294 or coolant liquid evacuated tube 295 and comb outside waste liquid Road 11 is connected to, and cooling zone liquid storage tank 21 is continuously discharged in the coolant liquid concentrated by coolant liquid overflow pipe 294 in an overflow manner, is made cold But liquid concentration is stablized, and makes the level stability of cooling zone liquid storage tank 21, and empties when required by coolant liquid evacuated tube 295 cold But area's liquid storage tank 21, venturi devaporizer 28 include cooling in Venturi tube 281 and the pipe being set in Venturi tube 281 Nozzle for liquid 282, the outlet of the air inlet and ship tail gas pipe (not shown) of Venturi tube 281, Venturi tube 281 Gas outlet is connected to void tower area 22, and the import of coolant recirculation pump 25 is connected to coolant liquid circulating outlet 291, coolant liquid cycle The interior coolant nozzle of the outlet of pump 25 and pipe 282 is connected to, and coolant recirculation pump 25 is in pipe by coolant liquid of lye or seawater It is cooling when 282 feed flow of coolant nozzle, coolant recirculation pump 25 by coolant liquid of lye are 282 feed flow of coolant nozzle in pipe Area's liquid storage tank 21 is connected to the first alkali liquor circulating system, to make full use of the extra washing of the first alkali liquor circulating system continuous conveying Liquid.Here, the import of coolant recirculation pump 25 can also be connected to the first alkali liquor circulating system.
The present embodiment eliminates the first liquid storage device 74 and the second liquid storage device 84 outside washing tower body 1, reduces equipment, when washing 1 configuration alkali liquid washing system of tower body is washed, when not configuring seawer washing system, the present embodiment can be selected, and in order to reduce More equipment and investment, the present embodiment can also further save the second scrubbing section 4 and its second alkali liquor circulating system, wash tower body 1 setting evaporation cooling zone 2 and the first scrubbing section 3 and its first alkali liquor circulating system.
Embodiment three:
The present embodiment propose a kind of ship tail gas wash mill as shown in figure 3, its structure and embodiment one ship tail The structure of gas washing device is essentially identical, the difference is that:
In the present embodiment, the second scrubbing section 4 is washed using spray void tower structure, structure by the second demister 41, second Nozzle for liquid 42 and the second spraying zone 46 composition are washed, the second demister 41 is located at the top of the second washing nozzle 42, the second washing Nozzle for liquid 42 is located at the top of the second spraying zone 46, and the second ventilation liquid-preventing device 6 is located at the lower section of the second spraying zone 46;Second ventilation Liquid-resisting device 6 uses funnel-cap type structure comprising the second bottom plate 61 and the second blast cap 62 being installed on the second bottom plate 61, the second bottom The second fluid-through port 63 is provided on plate 61, it is to make from ship tail gas that the second fluid-through port 63, which is set on the second bottom plate 61, The second scrubbing section 4 can be all discharged in the particle washed.
In the present embodiment, the first alkali liquor circulating system and the second alkali liquor circulating system share a shared lye cyclic system System, shared alkali liquor circulating system include the common reservoir 91 being set to outside washing tower body 1 and common recycle pump 92, the first logical liquid Mouthfuls 53 by being serially connected with the inlet communication of the pipeline and common reservoir 91 of the first valve 101, and the second fluid-through port 63 passes through concatenation There is the inlet communication of the pipeline and common reservoir 91 of the 4th valve 104, the outlet of common reservoir 91 is by being serially connected with second The inlet communication of the pipeline of valve 102 and shared circulating pump 92, the import of common recycle pump 92 and the first lye device for supplying 71 Outlet, alkali solution cooler 73 cools down as alkali solution cooler 73, outlet and the shared lye of common recycle pump 92 is shared The inlet communication of device 73 shares the outlet of alkali solution cooler 73 by being serially connected with the pipeline and the first cleaning solution of third valve 103 Nozzle 31 is connected to, and shares the outlet of alkali solution cooler 73 by being serially connected with the pipeline and the second washing nozzle of the 6th valve 106 42 connections, are serially connected with the outlet of the pipeline and the second lye device for supplying 81 of the 6th valve 106, common reservoir 91 goes out Mouth is connected with the shared overflow passage 93 of the liquid level for automatically controlling common reservoir 91, and the outlet for sharing overflow passage 93 is cold But fluid circulation is connected to, and shares alkali liquor circulating system by sharing overflow passage 93 and extra wash is discharged to coolant circulation system Liquid is washed, the outlet of common reservoir 91 is connected with the pipeline for being serially connected with shared liquid storage exhaust-valve 94.The program reduces system and sets It is standby, but because the lye of the first alkali liquor circulating system and the second alkali liquor circulating system mutually mixes, the particle to get off is washed from the first scrubbing section 3 Also the second scrubbing section 4 can be taken to, causing the second scrubbing section 4, there are the risks of particles holography, therefore when the use program, second washes Wash the filler or selection spray void tower structure that area 4 preferably selects anti-blocking good.
In the present embodiment, alkali liquor circulating system is shared can be also discharged to evaporation cooling zone 2 by sharing overflow passage 93 Extra cleaning solution.
In conjunction with the embodiments one, the operation principle of the ship tail gas wash mill is made described further below:
(1) coolant circulation system is coolant liquid to evaporation 2 feed flow of cooling zone using seawater or lye, and ship tail gas is from ship Vessel exhaust air inlet A enters the coolant liquid that evaporation cooling zone 2 is sprayed with coolant nozzle 23 through cooling zone ventilation liquid-preventing device 26 and connects Caloic exchange is touched and carried out, is evaporated after the heat of coolant liquid absorption ship tail gas, promotes the temperature of ship tail gas to reduce, humidity increases The close adiabatic saturation state of adduction;Coolant liquid is sprayed under the action of coolant recirculation pump 25 in cooling zone liquid storage tank 21, coolant liquid It is recycled between mouth 23, void tower area 22, in the process, there are two types of modes to leave evaporation cooling zone 2 for coolant liquid, first, passing through evaporation The condensation of the first scrubbing section 3 is taken in the form of water vapor, second is that the cooling concentrated by evaporation is discharged from coolant liquid overflow pipe 294 Liquid, also there are two types of modes supplements coolant liquid to evaporation cooling zone 2, first, add fresh coolant liquid from cooling liquid inlet 292, two It is, when the first alkali liquor circulating system is the first 3 feed flow of scrubbing section, the extra cleaning solution of also the first alkali liquor circulating system discharge Evaporation cooling zone 2 is flowed into from the first overflow passage 72, by adjusting the liquid measure for the fresh coolant liquid that cooling liquid inlet 292 is added, The coolant liquid stable components for making cooling zone liquid storage tank 21 ensure that the liquid level of cooling zone liquid storage tank 21 is steady by coolant liquid overflow pipe 294 It is fixed.
(2) ship tail gas close to adiabatic saturation state for leaving evaporation cooling zone 2 removes defogging by the first demister 24 The first scrubbing section 3 is entered by the first ventilation liquid-preventing device 5 after drop, and by cleaning solution open system or the first alkali liquor circulating system Or the cold washing liquid of shared alkali liquor circulating system supply contacts, the acidic materials quilt in ship tail gas based on oxysulfide Cleaning solution absorbs, and since cleaning solution temperature is low, the temperature difference is big between ship tail gas, and ship tail gas is during gas-liquid contact Supersaturated vapor state is formed, and then promotes in ship tail gas a large amount of vapour molecules using the surface of the particle in tail gas as in coring Heart phase transformation condenses, and along with the effect of diffusiophoresis and thermophoresis makes particle collision reunite and then the thickening that increases weight, promotes cleaning solution will Particle capture simultaneously efficiently removes.
(3) ship tail gas after the washing of the first scrubbing section 3 enters the second scrubbing section 4 by the second ventilation liquid-preventing device 6 Washed liquid further washs, and by cleaning solution open system, either the second alkali liquor circulating system or shared lye recycle cleaning solution System supplies;
Wherein, when allowing outer row's cleaning solution, according to seawater situation, sulphur content of fuel oil situation and emission request, divide three kinds Situation:
1) the first alkali liquor circulating system closes, the second alkali liquor circulating system closes, the cleaning solution open system of the second scrubbing section 4 It closes, the cleaning solution open system of the first scrubbing section 3 is opened, i.e., first circulation pump 75 closes, the first lye device for supplying 71 closes, the first valve Door 101 close, third valve 103 close, second circulation pump 85 close, the second lye device for supplying 81 close, the 4th valve 104 close, the 6th Valve 106 closes, and the 8th valve 108 closes, and solution feed pump 12 is opened, and the 7th valve 107 is opened, the 9th valve 109 is opened, cleaning solution open system It is cleaning solution to 3 feed flow of the first scrubbing section using seawater, the comb outside waste liquid of the waste seawater after washing is discharged.The program be suitable for through After the seawer washing of first scrubbing section 3, the case where exhaust emissions requirement can be reached.
2) the first alkali liquor circulating system closes, the second alkali liquor circulating system closes, the cleaning solution open system of the first scrubbing section 3 Open, the cleaning solution open system of the second scrubbing section 4 is opened, i.e., first circulation pump 75 close, the first lye device for supplying 71 close, the first valve Door 101 close, third valve 103 close, second circulation pump 85 close, the second lye device for supplying 81 close, the 4th valve 104 close, the 6th Valve 106 closes, and solution feed pump 12 is opened, and the 7th valve 107 is opened, the 9th valve 109 is opened, and the 8th valve 108 is opened, the tenth valve 110 is opened, Cleaning solution open system is cleaning solution to 4 feed flow of the first scrubbing section 3 and the second scrubbing section using seawater, and the waste seawater after washing is from useless The outer comb discharge of liquid.The program is suitable for after the seawer washing of the first scrubbing section 3, cannot still reach exhaust emissions requirement, and After the seawer washing of the seawer washing of the first scrubbing section 3 and the second scrubbing section 4, the case where exhaust emissions requirement can be reached.
3) the first alkali liquor circulating system closes, the cleaning solution open system of the second scrubbing section 4 is closed, the washing of the first scrubbing section 3 Liquid open system is opened, and the second alkali liquor circulating system is opened, i.e., first circulation pump 75 closes, the first lye device for supplying 71 closes, the first valve Door 101 closes, third valve 103 closes, and the 8th valve 108 closes, the tenth valve 110 closes, and solution feed pump 12 opens, and the 7th valve 107 opens, the Nine valves 109 are opened, and are washed to 3 feed flow of the first scrubbing section using seawater as cleaning solution, second circulation pump 85 is opened, the supply of the second lye fills Set 81 open, the 4th valve 104 is opened, the 6th valve 106 is opened, washed to 4 feed flow of the second scrubbing section using lye as cleaning solution.The program It is suitable for the seawer washing through the first scrubbing section 3, then after the alkali liquid washing of the second scrubbing section 4, can be only achieved exhaust emissions and want The case where asking.
When ship's navigation marine site does not allow outer row's cleaning solution, the cleaning solution open system of the first scrubbing section 3 is closed, and second washes The cleaning solution open system for washing area 44 is closed, i.e., solution feed pump 12 closes, and the 7th valve 107 closes, the 9th valve 109 closes, the 8th valve 108 It closes, the tenth valve 110 pass, according to emission request, opens alkali liquor circulating system in two kinds of situation:
1) the first alkali liquor circulating system is opened, and the second alkali liquor circulating system closes, i.e., first circulation pump 75 is opened, the first lye is fed Device 71 is opened, the first valve 101, third valve 103 are opened, and second circulation pump 85 closes, the second lye device for supplying 81 closes, the 4th valve Door 104 closes, the 6th valve 106 closes, and is washed to 3 feed flow of the first scrubbing section using lye as cleaning solution, the program is suitable for through first After the alkali liquid washing of scrubbing section 3, the case where exhaust emissions requirement can be reached.
2) the first alkali liquor circulating system is opened, and the second alkali liquor circulating system is opened, i.e., first circulation pump 75 is opened, the first lye is fed Device 71 is opened, the first valve 101 is opened, third valve 103 is opened, and second circulation pump 85 is opened, the second lye device for supplying 81 is opened, the 4th Valve 104 is opened, the 6th valve 106 is opened, and is washed to the first scrubbing section 3 and 4 feed flow of the second scrubbing section using lye as cleaning solution, especially It is that can reach ship tail gas minimum discharge requirement by the concentration for the lye that the second alkali liquor circulating system of raising is supplied.
(4) ship tail gas after above-mentioned washing passes sequentially through after the second demister 41 and heater exhaust gas 13 from ship Tail gas gas outlet B is discharged.
Based on the principles of the present invention, embodiment is not limited to above example, evaporate cooling zone 2 the type of cooling, The pyramidal structure of first scrubbing section 3 and the second scrubbing section 4 can have various combination.

Claims (10)

1. a kind of ship tail gas wash mill, including washing tower body, the washing tower body are provided with ship tail gas from bottom to top Air inlet, evaporation cooling zone, the first scrubbing section, the second scrubbing section and ship tail gas gas outlet, it is characterised in that:The ship Tail gas air inlet is connected to the evaporation cooling zone, is provided between the evaporation cooling zone and first scrubbing section Gas can be allowed to circulate and prevent the first ventilation liquid-preventing device of liquid communication, first scrubbing section and second scrubbing section Between be provided with gas can be allowed to circulate and prevent the second ventilation liquid-preventing device of liquid communication, second scrubbing section with it is described Ship tail gas gas outlet is connected to, and the evaporation cooling zone is configured with independent coolant circulation system, evaporation cooling Area makes the temperature of ship tail gas reduce using the coolant liquid that the coolant circulation system is supplied, humidity increase with close to Adiabatic saturation state, first scrubbing section are connected with the first alkali liquor circulating system, described in first scrubbing section utilizes The lye that is supplied of the first alkali liquor circulating system washing for the first time is carried out to remove the big portion in ship tail gas to ship tail gas Sulphur, second scrubbing section is divided to be connected with the second alkali liquor circulating system, second scrubbing section utilizes second alkali The lye that fluid circulation is supplied carries out second to ship tail gas and washs to remove the residual sulfur in ship tail gas, described The concentration for the lye that the concentration for the lye that first alkali liquor circulating system is supplied is supplied with second alkali liquor circulating system It differs.
2. a kind of ship tail gas wash mill according to claim 1, it is characterised in that:The first lye cyclic system System is connected with the first lye device for supplying for continuously adding fresh lye for first alkali liquor circulating system and is used for First overflow pipe of the extra cleaning solution provided to the first alkali liquor circulating system described in the evaporation cooling zone continuous conveying Road is provided with alkali solution cooler in first alkali liquor circulating system;
Second alkali liquor circulating system is connected with for continuously adding fresh lye for second alkali liquor circulating system The second lye device for supplying and for the second lye cyclic system described in the first alkali liquor circulating system continuous conveying Second overflow passage of the extra cleaning solution that system provides.
3. a kind of ship tail gas wash mill according to claim 2, it is characterised in that:First scrubbing section uses Spray void tower structure either filler tower structure or rotating stream tray scrubber structure;
When first scrubbing section is using spray void tower structure, structure is by the first washing nozzle and the first spray district's groups At first washing nozzle is located at the top of first spraying zone, and the first ventilation liquid-preventing device is located at institute The lower section for the first spraying zone stated;The first ventilation liquid-preventing device uses funnel-cap type structure comprising the first bottom plate and installation The first blast cap on first bottom plate is provided with the first fluid-through port on first bottom plate;
When first scrubbing section uses filler tower structure, structure is made of the first washing nozzle and the first packing layer, First washing nozzle is located at the top of first packing layer, and the first ventilation liquid-preventing device is located at described The lower section of first packing layer;The first ventilation liquid-preventing device uses funnel-cap type structure comprising the first bottom plate and is installed on institute The first blast cap on the first bottom plate stated is provided with the first fluid-through port on first bottom plate.
4. a kind of ship tail gas wash mill according to claim 3, it is characterised in that:The first lye cyclic system System includes being set to the first external liquid storage device of the scrubbing tower and first circulation pump, and first fluid-through port passes through concatenation There is the inlet communication of the pipeline and first liquid storage device of the first valve, the outlet of first liquid storage device is by being serially connected with The inlet communication that the pipeline of second valve is pumped with the first circulation, the import of first circulation pump and described second The outlet of overflow passage, the outlet of the import and the first lye device for supplying of first circulation pump, The outlet of the first circulation pump passes through the inlet communication of pipeline and the alkali solution cooler, the alkali solution cooler Outlet is connected to by being serially connected with the pipeline of third valve with first washing nozzle, the outlet of first liquid storage device With the inlet communication of first overflow passage of the liquid level for automatically controlling first liquid storage device, described first The outlet of overflow passage is connected to the evaporation cooling zone, and first alkali liquor circulating system passes through first overflow Extra cleaning solution is discharged to the evaporation cooling zone in pipeline, and the outlet of first liquid storage device, which is connected with, is serially connected with the first storage The pipeline of liquid exhaust-valve.
5. a kind of ship tail gas wash mill according to claim 3, it is characterised in that:The first lye cyclic system System includes the first liquid storage tank being set in first scrubbing section first circulation external with the scrubbing tower is set to Pump, first liquid storage tank are located at the lower section of first spraying zone, and the bottom of pond of first liquid storage tank is described First bottom plate, first fluid-through port are connected by being serially connected with the pipeline of the first valve with the import that the first circulation pumps It is logical, the outlet of the import and second overflow passage of the first circulation pump, first circulation pump into The outlet of the outlet of mouth and the first lye device for supplying, first circulation pump passes through pipeline and the alkali The inlet communication of liquid cooler, the outlet of the alkali solution cooler is by being serially connected with the pipeline and described first of third valve Washing nozzle is connected to, and described the of first fluid-through port and the liquid level for automatically controlling first liquid storage tank The outlet of the inlet communication of one overflow passage, first overflow passage is connected to the evaporation cooling zone, and described Extra cleaning solution is discharged to the evaporation cooling zone by first overflow passage in one alkali liquor circulating system.
6. a kind of ship tail gas wash mill according to claim 3, it is characterised in that:Second scrubbing section uses Filler tower structure either sprays void tower structure or rotating stream tray scrubber structure;
When second scrubbing section uses filler tower structure, structure is by the second demister, the second washing nozzle and second Packing layer forms, and second demister is located at the top of second washing nozzle, second cleaning solution spray Mouth is located at the top of second packing layer, and the second ventilation liquid-preventing device is located at the lower section of second packing layer; The second ventilation liquid-preventing device uses funnel-cap type structure comprising the second bottom plate and be installed on second bottom plate the Two blast caps are provided with the second fluid-through port on second bottom plate;
When second scrubbing section is using spray void tower structure, structure is by the second demister, the second washing nozzle and the Two spraying zones form, and second demister is located at the top of second washing nozzle, second cleaning solution Nozzle is located at the top of second spraying zone, and the second ventilation liquid-preventing device is located under second spraying zone Side;The second ventilation liquid-preventing device uses funnel-cap type structure comprising the second bottom plate and is installed on second bottom plate The second blast cap, be provided with the second fluid-through port on second bottom plate.
7. a kind of ship tail gas wash mill according to claim 6, it is characterised in that:The second lye cyclic system System includes being set to the second external liquid storage device of the scrubbing tower and second circulation pump, and second fluid-through port passes through concatenation There is the inlet communication of the pipeline and second liquid storage device of the 4th valve, the outlet of second liquid storage device is by being serially connected with The inlet communication that the pipeline of 5th valve is pumped with the second circulation, the import of second circulation pump and described second The outlet of lye device for supplying, the outlet of second circulation pump by be serially connected with the pipeline of the 6th valve with it is described Second washing nozzle is connected to, outlet and the liquid level for automatically controlling second liquid storage device of second liquid storage device Second overflow passage inlet communication, outlet and the first lye cyclic system of second overflow passage System connection, second alkali liquor circulating system are arranged by second overflow passage to first alkali liquor circulating system Go out extra cleaning solution, the outlet of second liquid storage device is connected with the pipeline for being serially connected with the second liquid storage exhaust-valve.
8. a kind of ship tail gas wash mill according to claim 6, it is characterised in that:The second lye cyclic system System includes the second liquid storage tank being set in second scrubbing section second circulation external with the scrubbing tower is set to Pump, second liquid storage tank are located at the lower section of second packing layer, and the bottom of pond of second liquid storage tank is described Second bottom plate, second fluid-through port are connected by being serially connected with the pipeline of the 4th valve with the import that the second circulation pumps It is logical, the outlet of the import and the second lye device for supplying of the second circulation pump, second circulation pump Outlet be connected to second washing nozzle by being serially connected with the pipeline of the 6th valve, second fluid-through port with use In the inlet communication of second overflow passage for the liquid level for automatically controlling second liquid storage tank, second overflow The outlet of pipeline is connected to first alkali liquor circulating system, and second alkali liquor circulating system overflows by described second Extra cleaning solution is discharged in the first alkali liquor circulating system described in flow tube road direction.
9. a kind of ship tail gas wash mill according to claim 6, it is characterised in that:The first lye cyclic system System and second alkali liquor circulating system share a shared alkali liquor circulating system, and the shared alkali liquor circulating system includes It is set to the external common reservoir of the scrubbing tower and common recycle pump, first fluid-through port is by being serially connected with first The inlet communication of the pipeline of valve and the common reservoir, second fluid-through port is by being serially connected with the pipe of the 4th valve The inlet communication on road and the common reservoir, the outlet of the common reservoir is by being serially connected with the pipeline of the second valve The inlet communication pumped with the common recycle, import and the first lye device for supplying of common recycle pump Outlet, the alkali solution cooler are total to as alkali solution cooler, the outlet of common recycle pump is shared with described With the inlet communication of alkali solution cooler, the outlet of the shared alkali solution cooler is by being serially connected with pipeline and the institute of third valve The the first washing nozzle connection stated, the outlet of the shared alkali solution cooler is by being serially connected with pipeline and the institute of the 6th valve The the second washing nozzle connection stated, the outlet of the pipeline and the second lye device for supplying that are serially connected with the 6th valve connect Logical, the outlet of the common reservoir is connected with the shared overflow pipe of the liquid level for automatically controlling the common reservoir The outlet on road, the shared overflow passage is connected to the evaporation cooling zone or the coolant circulation system, described Shared alkali liquor circulating system recycled to the evaporation cooling zone or the coolant liquid by the shared overflow passage Extra cleaning solution is discharged in system, and the outlet of the common reservoir is connected with the pipeline for being serially connected with shared liquid storage exhaust-valve.
10. a kind of ship tail gas wash mill according to claim 2, it is characterised in that:It adopts the evaporation cooling zone With spray void tower structure or using the void tower structure of external venturi devaporizer;
When the evaporation cooling zone is using spray void tower structure, structure is by the cooling zone liquid storage that sets gradually from bottom to top Pond, void tower area, coolant nozzle and the first demister composition, the coolant circulation system are made of coolant recirculation pump, Be provided on the cooling zone liquid storage tank coolant liquid circulating outlet being connected to the coolant circulation system, for The cooling zone liquid storage tank supplements the cooling liquid inlet, extra in the cooling zone liquid storage tank for being discharged of fresh coolant liquid The coolant outlet of coolant liquid or the emptying cooling zone liquid storage tank, the coolant outlet pass through coolant liquid overflow Pipe or coolant liquid evacuated tube are connected to the outer discharge pipe of waste liquid, and the import of the coolant recirculation pump is recycled with the coolant liquid Water outlet is connected to, and the outlet of the coolant recirculation pump is connected to the coolant nozzle, the coolant recirculation pump Take coolant liquid as the coolant nozzle feed flow of lye or seawater, the coolant recirculation pump is using lye as coolant liquid For the coolant nozzle feed flow when, the cooling zone liquid storage tank is connected to or described with first alkali liquor circulating system The import of coolant recirculation pump be connected to first alkali liquor circulating system, to make full use of first lye to recycle The extra cleaning solution of system continuous conveying;
When the described evaporation cooling zone uses the void tower structure of external venturi devaporizer, structure is by from bottom to top successively Cooling zone liquid storage tank, void tower area and the first demister of setting and it is set to the external venturi evaporation cooling of the scrubbing tower Device forms, and the coolant circulation system is made of coolant recirculation pump, is provided on the cooling zone liquid storage tank and institute The coolant liquid circulating outlet for the coolant circulation system connection stated, for supplementing fresh cooling to the described cooling zone liquid storage tank The cooling liquid inlet of liquid, for extra coolant liquid in the cooling zone liquid storage tank or the emptying cooling zone liquid storage tank to be discharged Coolant outlet, the coolant outlet passes through coolant liquid overflow pipe or coolant liquid evacuated tube and discharge pipe outside waste liquid Connection, the venturi devaporizer include coolant liquid spray in Venturi tube and the pipe being set in the Venturi tube Mouth, the outlet of the air inlet and ship tail gas pipe of the Venturi tube, the gas outlet of the Venturi tube with it is described The connection of void tower area, the import of the coolant recirculation pump is connected to the coolant liquid circulating outlet, the cooling The outlet of liquid circulating pump is connected to coolant nozzle in the pipe, and the coolant recirculation pump is cold with lye or seawater But liquid is coolant nozzle feed flow in the pipe, and the coolant recirculation pump is cold in the pipe by coolant liquid of lye But when nozzle for liquid feed flow, the cooling zone liquid storage tank is connected to first alkali liquor circulating system or the coolant liquid is followed The import of ring pump is connected to first alkali liquor circulating system, to make full use of first alkali liquor circulating system continuously defeated The extra cleaning solution sent.
CN201721467873.9U 2017-11-06 2017-11-06 A kind of ship tail gas wash mill Withdrawn - After Issue CN207614625U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201721467873.9U CN207614625U (en) 2017-11-06 2017-11-06 A kind of ship tail gas wash mill

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201721467873.9U CN207614625U (en) 2017-11-06 2017-11-06 A kind of ship tail gas wash mill

Publications (1)

Publication Number Publication Date
CN207614625U true CN207614625U (en) 2018-07-17

Family

ID=62827732

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201721467873.9U Withdrawn - After Issue CN207614625U (en) 2017-11-06 2017-11-06 A kind of ship tail gas wash mill

Country Status (1)

Country Link
CN (1) CN207614625U (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107812447A (en) * 2017-11-06 2018-03-20 宁波大学 A kind of ship tail gas wash mill
CN109668463A (en) * 2018-12-26 2019-04-23 青岛双瑞海洋环境工程股份有限公司 Marine exhaust washing system and steamer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107812447A (en) * 2017-11-06 2018-03-20 宁波大学 A kind of ship tail gas wash mill
CN107812447B (en) * 2017-11-06 2024-04-12 宁波大学 Ship tail gas washing device
CN109668463A (en) * 2018-12-26 2019-04-23 青岛双瑞海洋环境工程股份有限公司 Marine exhaust washing system and steamer

Similar Documents

Publication Publication Date Title
CN107812447A (en) A kind of ship tail gas wash mill
CN103432886B (en) The desulfurization of a kind of ship tail gas one tower is except particle device and using method
CN103432885B (en) A kind of ship tail gas scrubbing tower and using method thereof
CN105189354B (en) Salt making apparatus
CN207614625U (en) A kind of ship tail gas wash mill
CN103411469B (en) A kind of cooling tower water steam and heat energy recovering method and system
CN105148712A (en) Multi-stage absorbing desulfurizing device by adopting ammonia-ammonium sulfate method
CN102343205B (en) Centralized purification treatment process and device of waste gas in spandex production process
CN103740567A (en) High-temperature steam cooling system
CN108775595A (en) Coal-fired flue-gas disappears white, emission reduction and waste heat depth retracting device and system
CN107606826A (en) Evaporative condenser based on plate pipe indirect evaporating-cooling precooling
CN205495232U (en) Next door tower gas -liquid mixed -flow cooling scrubber
CN205073865U (en) Hierarchical absorption desulphurization unit of ammonia - ammonium sulfate method
CN208694680U (en) High-efficient washing Tower System suitable for marine exhaust desulfurization
CN107355925A (en) Vertical board pipe adds direct evaporative cooling air conditioner group indirectly
CN107158918A (en) A kind of nitrate method phosphoric acid tail gas defluorinate denitration process system and processing method
CN206016870U (en) A kind of generating set steam discharge cooling device
CN206935095U (en) A kind of nitrate method phosphoric acid tail gas defluorinate denitration process system
CN109381988A (en) A kind of device preventing ammonia process desulfuration tower Crystallization Plugging
CN204051020U (en) A kind of two-part methyl alcohol evaporating column
CN109589750A (en) Fluorine technique is gone in a kind of economical desulfurization of aluminium electrolytic flue
CN108981416A (en) Scrubbing tower tail gas cooling device and gas purge system
CN209060878U (en) A kind of ship flue gas desulfurization device
CN209501312U (en) A kind of device preventing ammonia process desulfuration tower Crystallization Plugging
CN207786279U (en) Coal-burning power plant aoxidizes magnesium fortified Deuslfurizing system for sea water

Legal Events

Date Code Title Description
GR01 Patent grant
GR01 Patent grant
AV01 Patent right actively abandoned
AV01 Patent right actively abandoned
AV01 Patent right actively abandoned

Granted publication date: 20180717

Effective date of abandoning: 20240412

AV01 Patent right actively abandoned

Granted publication date: 20180717

Effective date of abandoning: 20240412