A kind of glass electrode protective
Technical field
The utility model is related to a kind of electrode protecting devices, relate more particularly to a kind of glass electrode protective, belong to
Test equipment technology field.
Background technology
Glass electrode formula manufactured membrane electrode with the glass film for having potential response to hydrogen ion activity, is common hydrogen
Ion indicator electrode, has been applied in multiple fields at present, has important use in many aspects such as research work, data monitorings
On the way.
Glass electrode is usually spheroidal, built-in hydrochloric acid solution and silver chloride electrode or calomel electrode.Before use, usually
Glass electrode is immersed in pure water so that its surface forms a thin layer swell layer, and when in use then by it and another reference electrode
It is put into solution to be measured and forms battery, cell voltage potential is directly related with solution ph.Since glass electrode is not by oxidant, reduction
The influence of agent and other impurity, it is broad to the measurement range of pH, it is widely used.
And in chemical field, a large amount of research usually can all be related to synthetic reaction, and in synthetic reaction, in order to protect
Card reaction system is uniformly dispersed, reacts abundant, it usually needs is carried out in the state of lasting stirring.And in order to preferably monitor
The variation of reactiveness, it is sometimes desirable to monitor all multi informations such as reaction solution pH, oxidation-reduction potential on-line, and these are monitored on-line
Probe used much just belongs to glass electrode, more accurate and expensive.But during the reaction, these glass electrodes are held
It is easily stirred son to encounter and broken or damage, causes test failure, while also having damaged experiment instrument.
Therefore, it is based on drawbacks described above, for how realizing the protection of glass electrode, and how to research and develop novel vitreous electricity
For electrode protector there are still research and improved demand, this is also a research hotspot in current experiment instrument field and again
Where starting point and power that point, even more the utility model are accomplished.
Utility model content
For the novel glass electrode protective of above-mentioned many defects and research and development, the present inventor is by a large amount of
Further investigation, after having paid sufficient creative work, so as to complete the utility model.
Specifically, technical problem to be solved in the utility model is:A kind of glass electrode protective is provided, the glass
Glass electrode protecting device can effectively protect glass electrode, so as to being smoothed out for guarantee test.
In order to solve the above technical problems, the technical solution of the utility model is to provide a kind of glass electrode protective, institute
It includes reaction vessel to state glass electrode protective, and stirrer and glass electrode are equipped in the reaction vessel, and the reaction is held
Protective cover is equipped in device, the stirrer is isolated by the protective cover with glass electrode, and the protective cover is equipped with several logical
Hole, the sectional area of the through-hole are less than the sectional area of the stirrer.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the protective cover be by
Protective cover made of polytetrafluoroethylene (PTFE).
Since the protective cover is to be tried in strong acid and strong base solution made of polytetrafluoroethylene (PTFE) so as to meet
It tests, and makes the protective cover that there is certain intensity, can have fixed shape in the solution, it is described to ensure that
Stirrer has enough stirring spaces, and then ensure that the smooth acquisition of experiment being smoothed out with data.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the protective cover is fixed
It is installed in a rigid support ring, the rigid support ring is set to the bottom of the reaction vessel, in the rigid support ring
Equipped with several liquid drain holes, the sectional area of the liquid drain hole is less than the sectional area of the stirrer.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the rigid support ring
It is to be made of stainless steel.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the protective cover cover is buckled
In the periphery of the rigid support ring, or it is fixed on the top of the rigid support ring.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the rigid support ring
Expansion shape is rectangle, is linked together by fastener between two edges of the rigid support ring, the fastener passes through
Wear the liquid drain hole.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the fastener is not
The combination of rust steel bolts and nuts.
By structure design so, to by changing the rigidity branch through the position of the different liquid drain holes
The perimeter of pushing out ring, so be applicable to it is different size of it is described answer container, there is preferably practicability and adaptability.
In the glass electrode protective of the utility model, as a kind of optimal technical scheme, the rigid support ring
Bottom be installed with several suckers, the sucker is evenly distributed on the periphery of the rigid support ring and is adsorbed in described
The bottom of reaction vessel.
By so designing, the sucker can play the role of fixing sucking disk rigid support ring position, especially inhale
After being attached to the bottom of sucker reaction vessel, by injecting reaction solution into sucker reaction vessel, under hydraulic pressure effect, these suctions
The sealing performance of disk is more preferable, and absorption property is stronger, so as to avoid the rigid support ring and the protective cover in reaction solution
Interior movement ensure that smoothly completing for experiment.
Wherein, the quantity of the sucker is 3-10, may be, for example, 3,4,5,6,7,8,9 or 10
A, those skilled in the art can be according to actual demand (such as whether fixed dynamics, leakproofness are excellent, size of adsorption strength etc.)
And suitably selected, this is that it has read the conventional capability that should have after the utility model, is no longer retouched in detail herein
It states.
In the glass electrode protective of the utility model, as another optimal technical scheme, the rigid support
It is to hang with weight on ring.
Wherein, the weight can be resistance to strong acid or highly basic and can be sunken to the object of reaction solution bottom, for example, ceramics, no
Become rusty bloom etc., by the tenesmus active force of the weight, so that the rigid support ring to be fixed in the reaction vessel
It is not subjected to displacement.
As described above, the utility model provides a kind of glass electrode protective, the glass electrode protective is logical
Unique structure design is crossed, to achieve many beneficial technique effects, such as:
1, stirrer is isolated with glass electrode due to protective cover, in reaction process, stirrer moves within the scope of protective cover
It is dynamic, glass electrode will not be caused to collide, effective protection glass electrode ensure that being smoothed out for experiment.
2, due to being linked together by fastener between two edges of rigid support ring, fastener runs through liquid drain hole,
It can be by changing the perimeter of rigid support ring through the position of different liquid drain holes, to be applicable in making for differential responses container
With.
3, since the bottom of rigid support ring is installed with sucker, play the role of fixed rigid support ring position, especially
It is to inject reaction solution in reaction vessel again after adsorbing, and under hydraulic pressure effect, sealing performance is more preferable, and absorption property is stronger,
It avoids rigid support ring and protective cover moves in reaction solution;Or by be in the rigid support ring hang up it is described
Weight, to which the rigid support ring to be fixed in the reaction vessel without displacement.
The use principle and process of the glass electrode protective of the utility model are specific as follows:When in use, first
The stirrer is positioned in the protective cover and the rigid support ring, then by the sucker suction in the reaction vessel
Bottom (or in the rigid support ring be to hang up the weight, it is described anti-to which the rigid support ring to be fixed on
Answer in container without displacement), reaction solution then is added in the reaction vessel, institute is located in the reaction vessel
State the glass electrode of the external setting detection of protective cover, in reaction process, the stirrer is in the protective cover and institute
It states within the scope of rigid support ring and moves, the glass electrode will not be caused to collide, the effective protection glass electrode, to
It ensure that being smoothed out for experiment.
As described above, the glass electrode protective of the utility model is by unique structure design, to obtain
Many beneficial technique effects, have a good application prospect and extensive productive potentialities in testing equipment technology field.
Description of the drawings
Fig. 1 is the structural schematic diagram of the glass electrode protective of the embodiments of the present invention 1;
Fig. 2 be the utility model embodiment 1 glass electrode protective in rigid support ring structural schematic diagram;
Fig. 3 is the structural schematic diagram of the glass electrode protective of the utility model embodiment 2;.
Wherein, in figs. 1 to 3, each number designation is respectively referred to for following concrete meaning, element or component.
In figure:1, reaction vessel;2, protective cover;3, glass electrode;4, rigid support ring;401, liquid drain hole;402, it fastens
Part;5, stirrer;6, sucker;7, weight.
Specific implementation mode
Below in conjunction with the accompanying drawings, the utility model is described in detail by specific embodiment, but these particularizations
The purposes and purpose of embodiment are only used for enumerating the utility model, not constitute and appoint to the real protection scope of the utility model
Any restriction of what form, it is more non-that the scope of protection of the utility model is confined to this.
Embodiment 1
As Fig. 1 and Fig. 2 jointly shown in, the utility model provides a kind of glass electrode protective, the glass electrode
Protective device includes reaction vessel 1, and stirrer 5 and glass electrode 3 are equipped in reaction vessel 1, protective cover is equipped in reaction vessel 1
2, stirrer 5 and glass electrode 3 are isolated by protective cover 2, and protective cover 2 is equipped with several through-holes, and the sectional area of through-hole, which is less than, to be stirred
Mix the sectional area of son 5.
As a kind of perferred technical scheme, the protective cover 2 is made of polytetrafluoroethylene (PTFE), so as to meet
It is tested in strong acid and strong base solution, and makes the protective cover 2 that there is certain intensity, can had in the solution and fix
Shape, to ensure that the stirrer 5 have enough stirring spaces, and then ensure that experiment be smoothed out and data
Smooth acquisition.
As a kind of optimal technical scheme, the protective cover 2 is fixedly installed in a rigid support ring 4, rigid support ring 4
It is set to the bottom of reaction vessel 1, rigid support ring 4 is equipped with several liquid drain holes 401, and the sectional area of liquid drain hole 401, which is less than, to be stirred
Mix the sectional area of son 5.
As a kind of perferred technical scheme, the rigid support ring 4 is to be made of stainless steel.
As a kind of perferred technical scheme, the protective cover 2 covers the periphery for being buckled in rigid support ring 4, or is fixed on
The top of rigid support ring 4 (in the present embodiment, the protective cover 2 is integrally fixed at the top of rigid support ring 4).
As a kind of perferred technical scheme, 4 expansion shape of the rigid support ring be rectangle, the two of rigid support ring 4
It is linked together by fastener 402 between a edge, fastener 402 runs through liquid drain hole 401.
The fastener 402 is preferably the combination of stainless steel bolt and nut, by through the position of different liquid drain holes 401
And change the perimeter of rigid support ring 4, so as to be suitable for different size of reaction vessel 1, there is preferably practicability and fit
Ying Xing.
As a kind of perferred technical scheme, the bottom of the rigid support ring 4 is installed with several suckers 6, this
A little suckers 6 are evenly distributed on the periphery of rigid support ring 4 and are adsorbed in the bottom of reaction vessel 1.
By so designing, these suckers 6 can play the role of 4 position of fixed rigid support ring, especially adsorb
Behind the bottom of reaction vessel 1, by injecting reaction solution into reaction vessel 1, hydraulic pressure effect under, these suckers 6 it is close
Sealing property is more preferable, and absorption property is stronger, moves, ensure that in reaction solution so as to avoid rigid support ring 4 and protective cover 2
Experiment smoothly completes.
Wherein, the quantity of the sucker 6 is 3-10, may be, for example, 3,4,5,6,7,8,9 or 10
A, those skilled in the art can be according to actual demand (such as whether fixed dynamics, leakproofness are excellent, size of adsorption strength etc.)
And suitably selected, this is that it has read the conventional capability that should have after the utility model, is no longer retouched in detail herein
It states.
Embodiment 2
As shown in figure 3, the utility model provides a kind of glass electrode protective, structure and 1 basic phase of embodiment
Together, difference lies in:It is to hang with weight 7 (to be namely fixed and rely on described heavy without using sucker 6 in rigid support ring 4
Object 7 is fixed).
Wherein, the weight 7 can be resistance to strong acid or highly basic and be deposited in the object of reaction solution bottom, such as ceramics,
Piece of stainless steel etc., by the tenesmus active force of the weight 7, to which the rigid support ring 4 is fixed on the reaction vessel 1
It is interior without displacement.
Use principle and process
The use principle and process of the glass electrode protective of the utility model are specific as follows:When in use, first
The stirrer 5 is positioned in the protective cover 2 and the rigid support ring 4, then the sucker 6 is adsorbed on the reaction
The bottom of container 1 (or in the rigid support ring 4 is to hang up the weight 7, to fix the rigid support ring 4
Without displacement in the reaction vessel 1), reaction solution then is added in the reaction vessel 1, is held in the reaction
In device 1 in the glass electrode 3 of the external setting detection of the protective cover 2, reaction process, the stirrer 5 exists
It is moved in 4 range of the protective cover 2 and the rigid support ring, the glass electrode 3 will not be caused to collide, effective protection
The glass electrode 3, to ensure that being smoothed out for experiment.
As described above, the glass electrode protective of the utility model is by unique structure design, to obtain
Many beneficial technique effects, have a good application prospect and extensive productive potentialities in testing equipment technology field.
Although for the purpose illustrated and described, and describing the above embodiment and the shown knot of attached drawing of the utility model
Structure and processing procedure.But it is to describe in detail that these, which are not, can not the scope of the utility model be confined to this.To this field
For technical staff, numerous modifications and variations can be made to the above embodiment of the utility model, and these all modifications
And/or variation is included within the claim limited range such as the utility model, without departing from such as claim institute
The scope of the utility model and spirit of restriction.