CN207330752U - A kind of golden yellow can temperable di-silver low-emissivity coated glass - Google Patents
A kind of golden yellow can temperable di-silver low-emissivity coated glass Download PDFInfo
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- CN207330752U CN207330752U CN201721042681.3U CN201721042681U CN207330752U CN 207330752 U CN207330752 U CN 207330752U CN 201721042681 U CN201721042681 U CN 201721042681U CN 207330752 U CN207330752 U CN 207330752U
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Abstract
The utility model is related to a kind of golden yellow can temperable di-silver low-emissivity coated glass; the composite film on glass matrix surface is located at including glass matrix and plating; composite film is faced out to stack gradually and formed by first medium layer, the first functional layer, the first protective layer, second dielectric layer, the second functional layer, the second protective layer and the 3rd dielectric layer from the air of glass matrix, and first medium layer is by Si3N4Layer and ZnO layer composition, the thickness of first medium layer is 20 28nm；Second dielectric layer is by Si3N4Layer, ZnSnxLayer and ZnO layer composition, the thickness of second dielectric layer is 45 55nm；3rd dielectric layer is Si3N4Layer, thickness is 55 65nm；First protective layer and the second protective layer are NiCr layers, and the thickness of the first protective layer is 1 3nm, and the thickness of the second protective layer is 1 2nm；First functional layer and the second functional layer are Ag layers, the utility model is by adjusting the membrane system framework of composite film and the thickness proportion of each film layer of optimization, not only make the radiance of the double-silver low-emissivity coated glass low, and can tempering processing, in golden yellow before and after tempering.
Description
Technical field
It the utility model is related to field of glass production technology, and in particular to a kind of golden yellow can the double silver low-emissivity coateds of tempering
Glass.
Background technology
Coated glass is also referred to as reflecting glass.Coated glass is in glass surface coating one or more layers metal, alloy or gold
Belong to compound film, to change the optical property of glass, meet certain particular requirement.Coated glass presses the different qualities of product,
Following a few classes can be divided into：Heat-reflecting glass, low emissivity glass (Low-E), electropane etc..
Low emissivity glass (Low-E) is to plate the film that is made of the metals such as multilayer silver or other compounds in glass surface
Form, to realize the energy-saving glass of some optically and thermally performances.Double silver Low-E glass highlight glass to sun heat radiation
Shaded effects, the low permeability of the high light transmittance of glass and sun heat radiation is dexterously combined together, and is had higher visible
Light transmission rate, the thermal background emission that can effectively limit outside summer room are got in.
With expanding economy, requirement of the market to double silver Low-E glass is higher and higher, does not require nothing more than it with higher
Performance, stronger practicality, it is necessary to integrate beautiful, comfortable, inexpensive, golden yellow glass is due to its rich and honour luxurious appearance
And enjoy liking for people.But golden yellow on existing market is mostly single silver low-radiation coated glass and heat reflection plated film glass
Glass.For traditional double-silver low-emissivity coated glass larger there are one in terms of color the shortcomings that, this kind of glass is mostly partially green, face
Color is not soft enough and neutral.
The content of the invention
The utility model provide a kind of golden yellow can temperable di-silver low-emissivity coated glass, by adjusting the film of composite film
The thickness proportion of system structure and each film layer of optimization, not only makes the radiance of the double-silver low-emissivity coated glass low, but also can steel
Change is handled, and golden yellow is presented before and after tempering, and in beautiful color generous, overall manufacturing energy consumption is low, and production efficiency is high, can effectively reduce
Production cost.
To reach above-mentioned purpose, the technical solution adopted in the utility model is：A kind of golden yellow can the double silver low radiations of tempering
Coated glass, including glass matrix and plating are located at the composite film on the glass matrix surface, and the composite film is situated between by first
Matter layer, the first functional layer, the first protective layer, second dielectric layer, the second functional layer, the second protective layer and the 3rd dielectric layer are described in
The air of glass matrix is faced out to stack gradually and formed,
Wherein, the first medium layer is by Si3N4Layer and ZnO layer composition, the thickness of the first medium layer is 20-28nm；
The second dielectric layer is by Si3N4Layer, ZnSnxLayer and ZnO layer composition, the thickness of the second dielectric layer is 45-55nm；It is described
3rd dielectric layer is Si3N4Layer, the thickness of the 3rd dielectric layer is 55-65nm；First protective layer and second protection
Layer is NiCr layers, and the thickness of first protective layer is 1-3nm, and the thickness of second protective layer is 1-2nm；Described first
Functional layer and second functional layer are Ag layers, and the thickness of first functional layer and second functional layer is 10-
14nm。
Further, the Si in the first medium layer3N4Layer and ZnO layer are outside successively by the surface of the glass matrix
It is laminated, the Si in the first medium layer3N4The thickness ratio of layer and ZnO layer is 1:0.7-1:1.3.
Preferably, the Si in the first medium layer3N4The thickness ratio of layer and ZnO layer is 1:1.
Further, the Si in the second dielectric layer3N4Layer, ZnSnxLayer and ZnO layer by first protective layer table
Face out and stack gradually, the Si in the second dielectric layer3N4Layer and ZnSnxThe thickness ratio of layer is 1:0.8-1:1.2, described
ZnSn in second medium layerxThe thickness ratio of layer and ZnO layer is 1:0.9-1:1.1, the Si in the second dielectric layer3N4Layer and ZnO
The thickness ratio of layer is 1:0.8-1:1.2.
Preferably, the Si in the second dielectric layer3N4Layer, ZnSnxThe thickness ratio of layer and ZnO layer is 1:1:1.
Further, the composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO
Layer/Ag layers/NiCr layers/Si3N4Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, each film in the composite film
The thickness of layer is respectively 10nm/10nm/10nm/1nm/15nm/15nm/15nm/10nm/1nm/55nm.
Further, the composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO
Layer/Ag layers/NiCr layers/Si3N4Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, each film in the composite film
The thickness of layer is respectively 12nm/12nm/12nm/2nm/16nm/17nm/17nm/12nm/1.5nm/60nm.
Further, the composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO
Layer/Ag layers/NiCr layers/Si3N4Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, each film in the composite film
The thickness of layer is respectively 14nm/14nm/12nm/3nm/18nm/18nm/19nm/14nm/2nm/65nm.
Further, the composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO
Layer/Ag layers/NiCr layers/Si3N4Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, each film in the composite film
The thickness of layer is respectively 10nm/12nm/11nm/1.5nm/16nm/16nm/16nm/12nm/2nm/58nm.
Further, the composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO
Layer/Ag layers/NiCr layers/Si3N4Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, each film in the composite film
The thickness of layer is respectively 12nm/14nm/13nm/2nm/18nm/18nm/18nm/13nm/1.8nm/63nm.
After the above technical solution is adopted, the double-silver low-emissivity coated glass shading coefficient Sc of the utility model is 0.3-0.4,
Radiance e is 0.04-0.1, and solar infrared thermal energy total transmittance is 8%-12%, by adjusting composite film membrane system framework with
And the thickness proportion of each film layer of optimization, relatively thin, the 3rd medium that first medium layer and the thickness of second dielectric layer are designed
Layer design it is relatively thick, two layers Ag layers be designed to that thickness is moderate, not only make the optical property of the double-silver low-emissivity coated glass
It is accurate to reach double silver labels, and can tempering processing, present before and after tempering golden yellow, in beautiful color generous, overall manufacturing energy consumption is low,
Production efficiency is high, can effectively reduce production cost.
Brief description of the drawings
Attached drawing 1 for the utility model it is golden yellow can temperable di-silver low-emissivity coated glass structure diagram.
Wherein, 100, glass matrix；200th, composite film；201st, first medium layer；202nd, the first functional layer；203rd, first
Protective layer；204th, second dielectric layer；205th, the second functional layer；206th, the second protective layer；207th, the 3rd dielectric layer.
Embodiment
The utility model is described in further detail with reference to the accompanying drawings and embodiments.
As shown in Figure 1, a kind of golden yellow can temperable di-silver low-emissivity coated glass, including glass matrix 100, glass matrix
100 side surface is air surface, and another side surface is tin face, is plated in the air surface of glass matrix 100 and is equipped with composite film
200, composite film 200 is by first medium layer 201, the first functional layer 202, the first protective layer 203, second dielectric layer 204, second
The air of functional layer 205, the second protective layer 206 and the 3rd dielectric layer 207 from the glass matrix 100 face out stack gradually and
Into, wherein, the first medium layer 201 is by Si3N4Layer and ZnO layer composition, the thickness of the first medium layer 201 is 20-
28nm；The second dielectric layer 204 is by Si3N4Layer, ZnSnxLayer and ZnO layer composition, the thickness of the second dielectric layer 204 are
45-55nm；3rd dielectric layer 207 is Si3N4Layer, the thickness of the 3rd dielectric layer 207 is 55-65nm；Described first protects
Sheath 203 and second protective layer 206 are NiCr layers, and the thickness of first protective layer 203 is 1-3nm, and described second
The thickness of protective layer 206 is 1-2nm；First functional layer 202 and second functional layer 205 are Ag layers, and described first
The thickness of functional layer 202 and second functional layer 205 is 10-14nm.
Si in the first medium layer 2013N4Layer and ZnO layer by the glass matrix 100 the outside layer successively in surface
It is folded, the Si in the first medium layer 2013N4The thickness ratio of layer and ZnO layer is 1:0.7-1:1.3.Preferably, described first is situated between
Si in matter layer 2013N4The thickness ratio of layer and ZnO layer is 1:1.
Si in the second dielectric layer 2043N4Layer, ZnSnxLayer and ZnO layer from the surface of first protective layer 203 to
Stack gradually outside, the Si in the second dielectric layer 2043N4Layer and ZnSnxThe thickness ratio of layer is 1:0.8-1:1.2, described second
ZnSn in dielectric layer 204xThe thickness ratio of layer and ZnO layer is 1:0.9-1:1.1, the Si in the second dielectric layer 2043N4Layer
Thickness ratio with ZnO layer is 1:0.8-1:1.2.Preferably, the Si in the second dielectric layer 2043N4Layer, ZnSnxLayer and ZnO
The thickness ratio of layer is 1:1:1.
In above-mentioned each film layer, ZnO layer and Ag layers of combination power are big, and NiCr layers protecting Ag layers, prevent that Ag layers are aoxidized,
Si3N4Layer is to increase the mechanical strength of the double-silver low-emissivity coated glass, and ZnSnxLayer then to increase translucency, and
ZnSnxThe hardness of layer is of a relatively high, can further lift the mechanical strength of the double-silver low-emissivity coated glass.
The utility model preferred embodiment is given below to be explained：
Embodiment 1
The concrete structure of composite film 200 and each is shown in the double-silver low-emissivity coated glass of the embodiment referring to table 1
The thickness value of film layer：
Table 1
Note：X in table 1 is positive number.
Above-mentioned film layer is plated successively according to respective thickness and is set to glass matrix 100, obtaining golden yellow can the double silver of tempering
Low radiation coated glass product, through measurement, the shading coefficient Sc of the glass product is 0.39, and radiance e is 0.09, solar infrared
Thermal energy total transmittance is 11.7%；Glass product glass surface a* is 0, b* 24；Glass product side a* is 0, b* 20.
Embodiment 2
The concrete structure of composite film 200 and each is shown in the double-silver low-emissivity coated glass of the embodiment referring to table 2
The thickness value of film layer：
Table 2
Note：X in table 2 is positive number.
Above-mentioned film layer is plated successively according to respective thickness and is set to glass matrix 100, obtaining golden yellow can the double silver of tempering
Low radiation coated glass product, through measurement, the shading coefficient Sc of the glass product is 0.34, and radiance e is 0.06, solar infrared
Thermal energy total transmittance is 9.8%；Glass product glass surface a* is 3, b* 35；Glass product side a* is 0.5, b* 29.
Embodiment 3
The concrete structure of composite film 200 and each is shown in the double-silver low-emissivity coated glass of the embodiment referring to table 3
The thickness value of film layer：
Table 3
Note：X in table 3 is positive number.
Above-mentioned film layer is plated successively according to respective thickness and is set to glass matrix 100, obtaining golden yellow can the double silver of tempering
Low radiation coated glass product, through measurement, the shading coefficient Sc of the glass product is 0.31, and radiance e is 0.04, solar infrared
Thermal energy total transmittance is 8.7%,；Glass product glass surface a* is 3, b* 38；Glass product side a* is 7, b* 40.
Double-silver low-emissivity coated glass in the utility model, by adjusting the membrane system framework of composite film 200 and excellent
Change the thickness proportion of each film layer, first medium layer and the thickness of second dielectric layer are designed relatively thin, the 3rd dielectric layer is set
Meter it is relatively thick, two layers Ag layers be designed to that thickness is moderate, not only reach the optical property of the double-silver low-emissivity coated glass
Double silver labels are accurate, and since the combination power of ZnO layer and Ag layer is big, the double-silver low-emissivity coated glass can tempering handle, before tempering
Golden yellow is presented afterwards, in beautiful color generous, overall manufacturing energy consumption is low, and production efficiency is high, can effectively reduce production cost.
Above-described embodiment is only the technical concepts and features for illustrating the utility model, and its object is to allow be familiar with technique
Personage can understand the content of the utility model and implement according to this, the scope of protection of the utility model can not be limited with this.
All equivalent change or modifications made according to the utility model Spirit Essence, should all cover the scope of protection of the utility model it
It is interior.
Claims (10)
1. a kind of golden yellow can temperable di-silver low-emissivity coated glass, including glass matrix and plating be located at the glass matrix surface
Composite film, it is characterised in that：The composite film is by first medium layer, the first functional layer, the first protective layer, second medium
The air of layer, the second functional layer, the second protective layer and the 3rd dielectric layer from the glass matrix, which faces out to stack gradually, to be formed,
Wherein, the first medium layer is by Si3N4Layer and ZnO layer composition, the thickness of the first medium layer is 20-28nm；It is described
Second dielectric layer is by Si3N4Layer, ZnSnxLayer and ZnO layer composition, the thickness of the second dielectric layer is 45-55nm；Described 3rd
Dielectric layer is Si3N4Layer, the thickness of the 3rd dielectric layer is 55-65nm；First protective layer and second protective layer are equal
For NiCr layers, the thickness of first protective layer is 1-3nm, and the thickness of second protective layer is 1-2nm；First function
Layer and second functional layer are Ag layers, and the thickness of first functional layer and second functional layer is 10-14nm.
2. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：Described
Si in one dielectric layer3N4Layer and ZnO layer are outwards laminated successively by the surface of the glass matrix, in the first medium layer
Si3N4The thickness ratio of layer and ZnO layer is 1:0.7-1:1.3.
3. a kind of golden yellow according to claim 1 or 2 can temperable di-silver low-emissivity coated glass, it is characterised in that：Institute
State the Si in first medium layer3N4The thickness ratio of layer and ZnO layer is 1:1.
4. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：Described
Si in second medium layer3N4Layer, ZnSnxLayer and ZnO layer are outwards stacked gradually by the surface of first protective layer, and described second
Si in dielectric layer3N4Layer and ZnSnxThe thickness ratio of layer is 1:0.8-1:1.2, the ZnSn in the second dielectric layerxLayer and ZnO
The thickness ratio of layer is 1:0.9-1:1.1, the Si in the second dielectric layer3N4The thickness ratio of layer and ZnO layer is 1:0.8-1:1.2.
5. a kind of golden yellow according to claim 1 or 4 can temperable di-silver low-emissivity coated glass, it is characterised in that：Institute
State the Si in second dielectric layer3N4Layer, ZnSnxThe thickness ratio of layer and ZnO layer is 1:1:1.
6. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：It is described multiple
It is the Si by outwards being stacked gradually from the surface of the glass matrix to close film layer3N4Layer/ZnO layer/Ag layers/NiCr layers/Si3N4
Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, and the thickness of each film layer is respectively 10 nm in the composite film
/10nm /10nm /1nm /15nm/15nm /15nm /10 nm /1nm /55nm。
7. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：It is described multiple
It is the Si by outwards being stacked gradually from the surface of the glass matrix to close film layer3N4Layer/ZnO layer/Ag layers/NiCr layers/Si3N4
Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, and the thickness of each film layer is respectively 12 nm in the composite film
/12nm /12nm /2nm /16nm /17nm /17nm /12nm /1.5nm /60nm。
8. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：It is described multiple
It is the Si by outwards being stacked gradually from the surface of the glass matrix to close film layer3N4Layer/ZnO layer/Ag layers/NiCr layers/Si3N4
Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, and the thickness of each film layer is respectively 14 nm in the composite film
/14nm /12nm /3nm /18nm/18nm/19nm /14nm /2nm /65nm。
9. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：It is described multiple
It is the Si by outwards being stacked gradually from the surface of the glass matrix to close film layer3N4Layer/ZnO layer/Ag layers/NiCr layers/Si3N4
Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, and the thickness of each film layer is respectively 10 nm in the composite film
/12nm /11nm /1.5nm /16nm/16nm/16nm /12nm /2nm /58nm。
10. a kind of golden yellow according to claim 1 can temperable di-silver low-emissivity coated glass, it is characterised in that：It is described
Composite film is the Si by outwards being stacked gradually from the surface of the glass matrix3N4Layer/ZnO layer/Ag layers/NiCr layers/Si3N4
Layer/ZnSnxLayer/ZnO layer/Ag layers/NiCr layers/Si3N4Layer forms, and the thickness of each film layer is respectively 12nm in the composite film
/14nm /13nm /2nm /18nm/18nm/18nm/13nm /1.8nm /63nm。
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328942A (en) * | 2018-05-15 | 2018-07-27 | 浙江旗滨节能玻璃有限公司 | High low anti-double-silver low-emissivity coated glass and preparation method thereof thoroughly |
| CN108455878A (en) * | 2018-05-15 | 2018-08-28 | 浙江旗滨节能玻璃有限公司 | No color differnece low radiation coated glass and preparation method thereof before and after tempering |
| CN110627374A (en) * | 2019-09-27 | 2019-12-31 | 吴江南玻华东工程玻璃有限公司 | Amber medium-transmittance low-reflection double-silver energy-saving coated glass and preparation method thereof |
-
2017
- 2017-08-18 CN CN201721042681.3U patent/CN207330752U/en active Active
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108328942A (en) * | 2018-05-15 | 2018-07-27 | 浙江旗滨节能玻璃有限公司 | High low anti-double-silver low-emissivity coated glass and preparation method thereof thoroughly |
| CN108455878A (en) * | 2018-05-15 | 2018-08-28 | 浙江旗滨节能玻璃有限公司 | No color differnece low radiation coated glass and preparation method thereof before and after tempering |
| CN110627374A (en) * | 2019-09-27 | 2019-12-31 | 吴江南玻华东工程玻璃有限公司 | Amber medium-transmittance low-reflection double-silver energy-saving coated glass and preparation method thereof |
| CN110627374B (en) * | 2019-09-27 | 2024-01-12 | 吴江南玻华东工程玻璃有限公司 | Amber middle-permeation low-reflection double-silver energy-saving coated glass and preparation method thereof |
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