CN2071643U - Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system - Google Patents

Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system Download PDF

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Publication number
CN2071643U
CN2071643U CN 90216299 CN90216299U CN2071643U CN 2071643 U CN2071643 U CN 2071643U CN 90216299 CN90216299 CN 90216299 CN 90216299 U CN90216299 U CN 90216299U CN 2071643 U CN2071643 U CN 2071643U
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CN
China
Prior art keywords
resin layer
water
regenerated
alkali
waste liquid
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Pending
Application number
CN 90216299
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Chinese (zh)
Inventor
张澄信
夏中明
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WUHAN WATER CONSERVANCY AND ELECTRIC POWER COLLEGE
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WUHAN WATER CONSERVANCY AND ELECTRIC POWER COLLEGE
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Publication date
Application filed by WUHAN WATER CONSERVANCY AND ELECTRIC POWER COLLEGE filed Critical WUHAN WATER CONSERVANCY AND ELECTRIC POWER COLLEGE
Priority to CN 90216299 priority Critical patent/CN2071643U/en
Publication of CN2071643U publication Critical patent/CN2071643U/en
Pending legal-status Critical Current

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  • Treatment Of Water By Ion Exchange (AREA)

Abstract

The utility model relates to an alkalinity-decreasing softener regenerated by regenerated waste liquid, which is filled with positive and negative layers of ion exchanging resins. The height of the positive resin layer is not lower than 1.2m; a main pipe branch pipe-type middle liquid drainage and water intake apparatus is installed on a plane surface which is approximately adjacent to the boundary surface of the negative and the positive resins; the alkalinity of influent water can be decreased when influent water passes through the upper chlorine type negative resin downward, and the hardness of the influent water can be removed when the influent water passes through the lower sodium type positive resin. When the effect is lost, the regenerated waste liquid of the ion exchanging salt removing system can be used for regeneration.

Description

Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system
The utility model belongs to water-treatment technology field.
Chlorine one sodium ion exchange process in the water treatment, be that water is continued by chlorine type anionite-exchange resin and sodium type Zeo-karb, thereby reach the purpose that reduces basicity in the water and remove hardness (148 pages of " boiler water processing " of publishing in 1989 referring to Hubei science tech publishing house).Usually, the yin, yang resin is to be placed in two interchangers, the back of losing efficacy with sodium chloride solution to two kinds of resins series connection regeneration.The ion exchange reaction of its system water and regenerative process as shown in the formula:
Negative resin: 2RCl+2HCO - 3, SO 2- 4(system water)/(regeneration) + 2CL -(1)
The ion-exchange demineralization water treatment system generally adopts HCl and NaOH to make the regenerator of sun bed and cloudy bed respectively.Its sun bed regenerating spent acid contains a large amount of Cl -, can be used as the regenerator of negative resin in above-mentioned (1) formula; Contain a large amount of Na in its cloudy bed regeneration waste lye +, can be used as the agent of above-mentioned (2) formula middle-jiao yang, function of the spleen and stomach regeneration of resin.Be provided with ion-exchange salt removing system at the same time and fall under the situation of alkali melded system, as adopt above-mentioned desalting system regeneration waste liquid, can save a large amount of working costs undoubtedly, and save the sodium chloride solution preparation system as the regenerator that falls the alkali melded system.
The utility model designs for this purpose.
Its constructional feature of alkali softening agent (referring to accompanying drawing) of falling of spent solution regeneration is, in falling alkali softening agent cylindrical shell [ 1 ], the cation exchange resin layer [ 11 ] that anion exchange resin layer [ 5 ] and floor height are not less than 1.2m is housed, being roughly yin, yang resin separation surface place, is the middle discharge opeing and the water feed apparatus [ 8 ] of a female pipe tubular type.Should be not less than half of yin and yang resin total height to the spatial altitude between the top water inlet water-freeing arrangement in the negative resin aspect.
During system water, processed water is entered by top through valve [ 6 ] and falls the alkali softening agent, downwards successively through the yin, yang resin layer, finishes and falls the softening ion exchange process of alkali, is discharged by the bottom then, delivers to main water outlet pipe through valve [ 16 ] again.In service, stable as using alkalinity of water, also can make the part water yield directly enter positive resin layer through valve [ 7 ].In service at one-period, along with negative resin reduces slowly weakening of basicity ability, reduce the aperture of valve [ 7 ] gradually.
When water outlet was leaked hardness and after losing efficacy, can locate water inlet by middle discharge opeing and water feed apparatus [ 8 ], a backwash negative resin layer also can be through valve [ 13 ] by the whole resin layer of bottom water inlet backwash.Under a backwash negative resin layer situation, bottom sun resin layer is to be in the counter-current regeneration operating mode, so effluent quality is better, operating capacity is also higher.But after operation some cycles number (as the 10-20 cycle), must carry out once big reverse washing, to remove resin in small, broken bits and the long-pending dirt of filter in the positive resin layer to whole resin layer.Be to improve the backwash effect, also can be installed into pneumatic plant, so that clean at the big reverse washing line space gas that advances at place, positive resin layer bottom.
Regenerate after the backwash.The spent acid that makes regeneration desalting system sun bed enters and falls the alkali softening agent by advancing spent acid device [ 4 ] through valve [ 15 ], downwards co-current regeneration negative resin layer; The waste lye of the cloudy bed of regeneration desalting system is entered by the bottom through valve [ 17 ] fall the alkali softening agent, bottom-up counter-current regeneration sun resin layer.Upper and lower two strands of regeneration waste liquids are located to converge after valve [ 10 ] is discharged in middle discharge opeing and water feed apparatus [ 8 ].
In regeneration negative resin layer process, the HCO that part is displaced - 3In acid waste liquid, will become H 2CO 3So, have a large amount of CO 2Gas is by separating out in the liquid.For regenerative process is normally carried out, need to get rid of CO by valve [ 3 ] continuously 2Gas simultaneously, notes regulating its aperture, in the control interchanger certain liquid level and pressure to be arranged.
In the positive resin layer process of regeneration, for preventing OH in the waste lye -And CO 2- 3With regeneration product Mg 2+, Ca 2+Generate Mg(OH) 2And CaCO 3Precipitation should avoid making the strong basicity waste lye directly to enter positive resin layer.
Above-mentioned desalting system regeneration waste liquid can be discharged at desalting system positive and negative bed and be fallen the synchronizing regeneration of alkali softening agent after pipeline is directly delivered to, and also can deliver to special exhausted bath box and store, when the need time spent is pumped to and falls the alkali softening agent.
The above-mentioned alkali softening agent principal feature of falling is:
1, utilize the desalting system regeneration waste liquid, the yin, yang resin in the alkali softening installation falls in regeneration, both can save the sodium chloride solution preparation system, can save a large amount of salt again, thereby reduces investment and working cost greatly.
2, anion and cation exchange resin is placed in the same interchanger, can reduce the table of equipment number, thereby saves floor space and facility investment.
3, counter-current regeneration sun resin layer helps guaranteeing effluent quality and improves operating capacity.
4, negative resin can adopt the waste and old negative resin that desalting system should not continue to use, and does not influence result of use, thereby can reduce the resin expense.
In the accompanying drawing: 1 is the interchanger cylindrical shell, 2 are the water inlet water-freeing arrangement, 3 is vent valve, 4 for advancing the spent acid device, 5 is the negative resin layer, and 6 is water intaking valve, and 7 is the negative resin backwash valve, 8 is discharge opeing and water feed apparatus in the middle of the female pipe tubular type, 9 are the backwash water discharge valve, and 10 is middle tapping valve, and 11 is positive resin layer, 12 for bottom water outlet water inlet and advance waste lye device (as water cap porous plate or quartz sand thickness etc.), 13 is the bottom backwash valve, and 14 is the bottom discharge valve, and 15 for advancing the spent acid valve, 16 is outlet valve, and 17 for advancing the salkali waste valve.

Claims (2)

1, a kind ofly in water treatment, uses, adopt ion-exchange salt removing system acid, alkali regeneration waste liquid regenerated to fall the alkali softening agent, its structure be water water-freeing arrangement [2] be housed in cylindrical shell [1] into from top to bottom, advance spent acid device [4], discharge opeing and water feed apparatus [8], positive resin layer [11] and bottom water outlet are intake and are advanced waste lye device [12] in the middle of the negative resin layer [5], a female pipe tubular type, it is characterized in that: described positive resin floor height is not less than 1.2m; Discharge opeing and water feed apparatus are placed in and roughly are positioned near the plane of yin, yang resin separation surface in the middle of the described female pipe tubular type, in order to compile and to discharge two strands of regeneration waste liquids by the yin, yang resin layer, link to each other with water inlet pipe through valve [7] again simultaneously, in order to the bypass water inlet of resin layer introducing on the sunny side or to negative resin layer water inlet backwash.
2, the alkali softening agent that falls as claimed in claim 1, it is characterized in that: described anion and cation exchange resin layer can be positioned over respectively in two conventional ion interchangers, falls the alkali melded system thereby constitute with ion-exchange salt removing system acid, alkali regeneration waste liquid regenerated.
CN 90216299 1990-07-14 1990-07-14 Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system Pending CN2071643U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 90216299 CN2071643U (en) 1990-07-14 1990-07-14 Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 90216299 CN2071643U (en) 1990-07-14 1990-07-14 Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system

Publications (1)

Publication Number Publication Date
CN2071643U true CN2071643U (en) 1991-02-20

Family

ID=4895473

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 90216299 Pending CN2071643U (en) 1990-07-14 1990-07-14 Alkalinity-decreasing softener regenerated by regenerated waste liquid of salt removing system

Country Status (1)

Country Link
CN (1) CN2071643U (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105347558A (en) * 2015-11-19 2016-02-24 四川省宜宾惠美线业有限责任公司 Application system for cation exchanger failure and water outlet
CN105439317A (en) * 2015-11-19 2016-03-30 四川省宜宾惠美线业有限责任公司 Application method of cation bed failure outlet water
CN117326637A (en) * 2023-08-31 2024-01-02 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105347558A (en) * 2015-11-19 2016-02-24 四川省宜宾惠美线业有限责任公司 Application system for cation exchanger failure and water outlet
CN105439317A (en) * 2015-11-19 2016-03-30 四川省宜宾惠美线业有限责任公司 Application method of cation bed failure outlet water
CN117326637A (en) * 2023-08-31 2024-01-02 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof
CN117326637B (en) * 2023-08-31 2024-04-26 惠州金茂源环保科技有限公司 Ion exchange resin tank and regeneration treatment method thereof

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