CN207164020U - Sampling device - Google Patents

Sampling device Download PDF

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Publication number
CN207164020U
CN207164020U CN201721084233.XU CN201721084233U CN207164020U CN 207164020 U CN207164020 U CN 207164020U CN 201721084233 U CN201721084233 U CN 201721084233U CN 207164020 U CN207164020 U CN 207164020U
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China
Prior art keywords
sample introduction
sampling device
needle
testing sample
sampling
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CN201721084233.XU
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Inventor
余占武
张雅欣
陈蕾
王清峰
贺秀成
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China Shenhua Coal to Liquid Chemical Co Ltd
China Shenhua Energy Co Ltd
Shenhua Baotou Coal Chemical Industry Co Ltd
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China Shenhua Coal to Liquid Chemical Co Ltd
China Shenhua Energy Co Ltd
Shenhua Baotou Coal Chemical Industry Co Ltd
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Abstract

The utility model provides a kind of sampling device.The sampling device includes:Sampling needle, sample introduction needle and flow regulating unit.Sampling needle is used to gather testing sample;Sample introduction needle is used to be detected at least part testing sample feeding reaction system;And flow regulating unit is connected with sampling needle and sample introduction needle respectively, for adjusting the flow of testing sample in sample introduction needle.Flow control valve is set to adjust the flow velocity of testing sample in sample introduction needle as needed between sample introduction needle and sampling needle, so that sample introduction speed is relatively stable and easily controllable, this advantageously reduces sample introduction error, so as to improve the stability and accuracy of analysis result during moisture measurement.Above-mentioned sampling device can also close flow regulating unit to prevent the entrance of the moisture in air after analysis terminates simultaneously.In addition above-mentioned sampling device provided by the utility model also has the advantages such as simple in construction, manufacturing cost is low.

Description

Sampling device
Technical field
Moisture measurement field is the utility model is related to, in particular to a kind of sampling device.
Background technology
The 1- butylene and ethene, propylene of one of important source material monomer as production polyolefin, its impurity content require pole To be strict, the especially content of moisture.After the moisture in above-mentioned hydro carbons exceeds certain limit, reactor can be caused A series of problems, such as reaction fluctuation, electrostatic become phenomena such as big, and this easily causes polymerization efficiency to decline, sheeting blocking pipeline.Therefore, Need to be measured the micro-moisture in above-mentioned hydro carbons using Karl_Fischer method according to national regulations.Its principle is:Water, iodine And sulfur dioxide reacts in the presence of organic base and methanol, the iodine number of consumption in the gold titration of storehouse by solution in iodide ion Oxidation reaction occurs in anode to supplement, the amount of caused iodine with it is by the electricity of electrolytic cell proportional.Therefore, according to farad Law, you can obtain the water content in sample.Reaction equation is as follows:
H2O+I2+SO2+3C5H5N→2C5H5N·HI+C5H5N·SO3
C5H5N·SO3+CH3OH→C5H5N·HSO4CH3
Existing method is mainly directly connected to that the pressure-resistant steel cylinder sample introduction of hydro carbons is housed using sample introduction cleansing pin, and its principle is to enter Sample cleansing pin is directly inserted into below karl Fischer liquid level, direct injected after then pressure-resistant steel cylinder is connected with sample introduction cleansing pin, blindly By experience control sample introduction flow velocity, take out pressure-resistant sampling bottle, weighed, record weigh after quality.This can cause to try one's best Flow velocity is difficult to control, and sample introduction error is larger, in sample the problems such as the analysis result inaccuracy of moisture.
Utility model content
Main purpose of the present utility model is to provide a kind of sampling device, to solve to enter existing for existing sampling device The problem of sample flow velocity is difficult to control.
To achieve these goals, the utility model provides a kind of sampling device, and sampling device includes:Sampling needle, use In collection testing sample;Sample introduction needle, at least part testing sample feeding reaction system to be detected;And Flow-rate adjustment Unit, flow regulating unit are connected with sampling needle and sample introduction needle respectively, for adjusting the flow of testing sample in sample introduction needle.
Further, flow regulating unit includes:Testing sample transfer pipeline, the arrival end of testing sample transfer pipeline with Sampling needle is connected, and the port of export of testing sample transfer pipeline is connected with sample introduction needle;Flow control valve, flow control valve are set On testing sample transfer pipeline.
Further, flow control valve includes:Tee pipe fitting, including the first communication port, the second communication port and the 3rd circulation Mouthful, tee pipe fitting is arranged on testing sample transfer pipeline, the first communication port and the second communication port with testing sample delivery pipe Road is connected;Dividing plate, dividing plate are arranged on the inside of tee pipe fitting, for the inside of tee pipe fitting to be divided into first chamber and second Chamber;
Connecting rod, connecting rod are connected through the 3rd communication port with dividing plate, and connecting rod is used relative to the rotatable setting of tee pipe fitting With the circulation area between adjusting between first chamber and second chamber.
Further, connecting rod and the 3rd communication port screw thread coordinate.
Further, the arrival end of testing sample transfer pipeline coordinates with sampling needle for screw thread, testing sample transfer pipeline The port of export and sample introduction needle be screw thread cooperation.
Further, one or more spray-holes are provided with sample introduction needle, for testing sample to be sprayed.
Further, spray-hole is multiple, and multiple spray-holes are along the circumferential or axially arranged of sample introduction needle.
Further, spray-hole is arranged at 1~3cm of the port of export away from sample introduction needle.
Further, sampling device also includes fixture, and fixture includes first end and the second end, and first end, which is fixed, to be connected It is connected on tee pipe fitting, the second end is used to fix sampling device when carrying out sample introduction operation.
Further, first end is set in the outside of the 3rd communication port.
Using the technical solution of the utility model, testing sample is gathered from testing sample feeding mechanism by sampling needle, Testing sample is delivered in reaction system to the detection for carrying out moisture by sample introduction needle.Flow is set between sample introduction needle and sampling needle Regulating valve can adjust the flow velocity of testing sample in sample introduction needle as needed so that and sample introduction speed is relatively stable and easily controllable, This advantageously reduces sample introduction error, so as to improve the stability and accuracy of analysis result during moisture measurement.It is simultaneously above-mentioned Sampling device can also close flow regulating unit to prevent the entrance of the moisture in air after analysis terminates.In addition this practicality is new The above-mentioned sampling device that type provides also has the advantages such as simple in construction, manufacturing cost is low.
Brief description of the drawings
A part of Figure of description of the present utility model is formed to be used for providing further understanding to of the present utility model, this The schematic description and description of utility model is used to explain the utility model, does not form to improper limit of the present utility model It is fixed.In the accompanying drawings:
Fig. 1 shows the front view of the sampling device provided according to a kind of preferred embodiment of the present utility model;
Fig. 2 shows the side view of the sampling device provided according to a kind of preferred embodiment of the present utility model.
Wherein, above-mentioned accompanying drawing marks including the following drawings:
10th, sampling needle;20th, sample introduction needle;30th, flow regulating unit;31st, testing sample transfer pipeline;32nd, Flow-rate adjustment Valve;321st, tee pipe fitting;322nd, dividing plate;323rd, connecting rod;40th, fixture.
Embodiment
Below in conjunction with the accompanying drawing in the utility model embodiment, the technical scheme in the embodiment of the utility model is carried out Clearly and completely describing, it is clear that described embodiment is only the utility model part of the embodiment, rather than whole Embodiment.The description only actually at least one exemplary embodiment is illustrative to be never used as to this practicality below New and its application or any restrictions used.Based on the embodiment in the utility model, those of ordinary skill in the art are not having There is the every other embodiment made and obtained under the premise of creative work, belong to the scope of the utility model protection.
It should be noted that term used herein above is merely to describe embodiment, and be not intended to restricted root According to illustrative embodiments of the present utility model.As used herein, unless the context clearly indicates otherwise, otherwise odd number Form is also intended to include plural form, additionally, it should be understood that, when in this manual use term "comprising" and/or During " comprising ", it indicates existing characteristics, step, operation, device, component and/or combinations thereof.
As described by background technology, sample introduction flow velocity existing for existing sampling device is difficult to control problem.To understand Certainly above-mentioned technical problem, the utility model provide a kind of sampling device, as shown in figure 1, the sampling device includes:Sampling needle 10th, sample introduction needle 20 and flow regulating unit 30.Sampling needle 10 is used to gather testing sample;Sample introduction needle 20 is used at least partly to treat Test sample product are sent into reaction system and detected;And flow regulating unit 30 is connected with sampling needle 10 and sample introduction needle 20 respectively, For adjusting the flow of testing sample in sample introduction needle 20.
In sampling device provided by the utility model, gathered by sampling needle 10 from testing sample feeding mechanism and treat test sample Product, testing sample is delivered in reaction system to the detection for carrying out moisture by sample introduction needle 20.Sample introduction needle 20 and sampling needle 10 it Between set flow control valve 32 to adjust the flow velocity of testing sample in sample introduction needle 20 as needed so that sample introduction speed is more steady Fixed and easily controllable, this advantageously reduces sample introduction error, so as to improve the stability and standard of analysis result during moisture measurement True property.Above-mentioned sampling device can also be entered closing flow regulating unit 30 after analysis terminates with the moisture prevented in air simultaneously Enter.In addition above-mentioned sampling device provided by the utility model also has the advantages such as simple in construction, manufacturing cost is low.
Above-mentioned sampling device provided by the utility model can efficiently control the flow velocity of testing sample in sample introduction needle 20.Tool Body, flow regulating unit 30 includes:Testing sample transfer pipeline 31 and flow control valve 32.As shown in figure 1, testing sample is defeated The arrival end of pipeline 31 is sent to be connected with sampling needle 10, the port of export of testing sample transfer pipeline 31 is connected with sample introduction needle 20. Flow control valve 32 is arranged on testing sample transfer pipeline 31.
In description of the present utility model, it is to be understood that the noun of locality such as " forward and backward, upper and lower, left and right ", " horizontal, Vertically, vertically, it is horizontal " and " pushing up, bottom " etc. indicated by orientation or position relationship be normally based on orientation or position shown in the drawings Relation is put, description the utility model is for only for ease of and simplifies description, in the case where not making opposite explanation, these nouns of locality Do not indicate that and imply that the device of meaning or element there must be specific orientation or with specific azimuth configuration and operation, because This is it is not intended that limitation to scope of protection of the utility model;The noun of locality " inside and outside " refers to the wheel relative to each part in itself Wide is inside and outside.
In sampling device provided by the utility model, flow control valve 32 can use existing commercially available prod.In one kind In preferred embodiment, as shown in figure 1, flow control valve 32 includes:Tee pipe fitting 321, dividing plate 322 and connecting rod 323.Three-way pipe Part 321 includes the first communication port, the second communication port and the 3rd communication port, and tee pipe fitting 321 is arranged on testing sample transfer pipeline On 31, the first communication port and the second communication port are connected with testing sample transfer pipeline 31;Dividing plate 322 is arranged on tee pipe fitting 321 inside, for the inside of tee pipe fitting 321 to be divided into first chamber and second chamber;Connecting rod 323 circulates through the 3rd Mouthful it is connected with dividing plate 322, and connecting rod 323 is relative to 321 rotatable setting of tee pipe fitting, to adjust first chamber and second Circulation area between chamber.
In above-mentioned flow control valve 32, dividing plate 322 is arranged in tee pipe fitting 321, and connecting rod 323 is connected with dividing plate 322 Connect, so relative to the rotation of tee pipe fitting 321 dividing plate 322 can be made to occur correspondingly to rotate by connecting rod 323, and then realize Circulation area between regulation first chamber and second chamber.So also it is achieved that the mesh of the flow velocity of regulation testing sample 's.
Preferably, as shown in figure 1, the communication port screw thread of connecting rod 323 and the 3rd coordinates.
In a kind of preferred embodiment, as shown in figure 1, the arrival end of testing sample transfer pipeline 31 is with sampling needle 10 Screw thread coordinates, and the port of export of testing sample transfer pipeline 31 coordinates with sample introduction needle 20 for screw thread.
The arrival end of testing sample transfer pipeline 31 and sampling needle 10 are coordinated for screw thread, testing sample transfer pipeline 31 The port of export coordinates with sample introduction needle 20 for screw thread, and this enables sampling needle 10 and sample introduction needle 20 to enter with testing sample transfer pipeline 31 Row dismounting separation, so as to select the sample introduction needle 20 of different model and sampling needle 10 as needed.In addition by the He of sampling needle 10 Sample introduction needle 20 carries out screw thread cooperation with testing sample transfer pipeline 31 respectively, also helps and occurs in sample introduction needle 20 and sampling needle 10 During damage, it is only necessary to sample introduction needle 20 and sampling needle 10 are replaced, without changing whole sampling device.Thus relative to The cost of whole sampling device, the existing only mode of replacement sampling needle 10 and sample introduction needle 20 significantly reduce the dimension of sampling device Protect cost.
Above-mentioned sampling device provided by the utility model can not only control sample rate, improve water analysis knot in sample Fruit stability, it is low to also help reduction maintenance cost.In a kind of preferred embodiment, one or more is provided with sample introduction needle 20 Individual spray-hole, for testing sample to be sprayed.One or more spray-holes are set in sample introduction needle 20, are advantageous to make to enter karr Take the not sample of liquid and karl Fischer reagent is corresponsively more complete, and then measurement result can be made more accurate.
In a kind of preferred embodiment, spray-hole is multiple, and circumference or axial direction of multiple spray-holes along sample introduction needle 20 are set Put.By multiple spray-holes along the circumferential or axially arranged of sample introduction needle 20, be advantageous to improve in testing sample penetrating karl Fischer liquid Sample rate it is more uniform, so as to be advantageous to further improve precision of analysis.
In above-mentioned sampling device, the position of spray-hole can arbitrarily be set in sample introduction needle 20.In a kind of preferable implementation In example, spray-hole is arranged at 1~3cm of the port of export away from sample introduction needle 20.Set at 1~3cm of the port of export away from sample introduction needle 20 Spray-hole, the time delay of the sample introduction speed of testing sample is advantageously reduced, so as to be advantageous to further improve the accurate of analysis knot Property.
In a kind of preferred embodiment, as illustrated in fig. 1 and 2, sampling device also includes fixture 40, and fixture 40 wraps First end and the second end are included, first end is fixedly connected on tee pipe fitting 321, and the second end is used to fix when carrying out sample introduction operation Sampling device.Set fixture 40 to be advantageous to fix sampling device during sample introduction, exist so as to be advantageous to improve sample introduction process Steadily, carry out in an orderly manner.
Preferably, first end is set in the outside of the 3rd communication port.
For the ease of description, space relative terms can be used herein, as " ... on ", " ... top ", " ... upper surface ", " above " etc., for describing such as a device shown in the figure or feature and other devices or spy The spatial relation of sign.It should be appreciated that space relative terms are intended to comprising the orientation except device described in figure Outside different azimuth in use or operation.For example, if the device in accompanying drawing is squeezed, it is described as " in other devices It will be positioned as " under other devices or construction after the device of part or construction top " or " on other devices or construction " Side " or " under other devices or construction ".Thus, exemplary term " ... top " can include " ... top " and " in ... lower section " two kinds of orientation.The device can also other different modes positioning (being rotated by 90 ° or in other orientation), and And respective explanations are made to the relative description in space used herein above.
Embodiment 1
It is sampled using device as illustrated in fig. 1 and 2, to be detected to the moisture in 1- butylene.Specific behaviour It is as follows to make process:
A. the fixture 40 of sampling device is screwed on karl Fischer instrument.
B. karl Fischer instrument power supply, the air-tightness of inspection apparatus are opened, and waits instrument to reach balance.
C. karl Fischer instrument is demarcated with syringe draw standard water 10uL.Demarcation returns karl Fischer instrument after terminating Measuring state is returned to, is waited to be measured.
D. pressure bottle is dried with pure nitrogen gas, drying time 5min.And check whether the sealing gasket of pressure bottle is complete It is good.
E. it is standby with 3/4ths volumes of dried (3) collection liquid phase 1- butylene of pressure bottle about bottle.
F. each pressure bottle is accurately weighed on balance, returned to zero.
G. testing sample (1- butylene) is gathered from pressure bottle by sampling needle 10.Then through testing sample transfer pipeline 31 Into testing sample in flow control valve 32.Then testing sample sprays into below the liquid level of detection liquid (card through sample introduction needle 20 Er Feixiu solution), carry out the detection of moisture.Sample introduction needle 20 should abut bottle wall simultaneously.In an experiment, flow control valve 32 is passed through Control flow velocity of the testing sample in sample introduction needle 20.After continuing sample introduction 1min, pressure-resistant sampling bottle is removed, closes flow control valve 32, weighed, the mass M after record weighing.
H. after Instrument measuring terminates, register instrument shows the content of water.
Parallel determination is three times.Testing result is shown in Table 1.
Comparative example 1
It is put into and is distinguished as with embodiment 1, one end of sampling needle is connected with the pressure-resistant steel cylinder containing testing sample, with collection Testing sample.The other end of sampling needle is inserted into below the liquid level of detection liquid, i.e., sample introduction needle and sampling needle are same root pin.
Table 1
Embodiment Sample introduction mass M, g Moisture, mg/kg
1st time 0.77 16
2nd time 0.73 18
3rd time 0.82 18
Comparative example 1 1.0 26
As can be seen from the above description, the utility model the above embodiments realize following technique effect:
In sampling device provided by the utility model, gathered by sampling needle from testing sample feeding mechanism and treat test sample Product, testing sample is delivered in reaction system to the detection for carrying out moisture by sample introduction needle.Set between sample introduction needle and sampling needle Flow control valve can adjust the flow velocity of testing sample in sample introduction needle as needed so that sample introduction speed is relatively stable and is easy to control System, this advantageously reduces sample introduction error, so as to improve the stability and accuracy of analysis result during moisture measurement.On simultaneously Flow regulating unit can also be closed to prevent the entrance of the moisture in air after analysis terminates by stating sampling device.In addition this practicality The above-mentioned sampling device of new offer also has the advantages such as simple in construction, manufacturing cost is low.
Preferred embodiment of the present utility model is the foregoing is only, is not limited to the utility model, for this For the technical staff in field, the utility model can have various modifications and variations.It is all in the spirit and principles of the utility model Within, any modification, equivalent substitution and improvements made etc., it should be included within the scope of protection of the utility model.

Claims (10)

1. a kind of sampling device, it is characterised in that the sampling device includes:
Sampling needle (10), for gathering testing sample;
Sample introduction needle (20), detected at least partly described testing sample to be sent into reaction system;And
Flow regulating unit (30), the flow regulating unit (30) respectively with the sampling needle (10) and the sample introduction needle (20) It is connected, for adjusting the flow of testing sample described in the sample introduction needle (20).
2. sampling device according to claim 1, it is characterised in that the flow regulating unit (30) includes:
Testing sample transfer pipeline (31), the arrival end of the testing sample transfer pipeline (31) are connected with the sampling needle (10) Logical, the port of export of the testing sample transfer pipeline (31) is connected with the sample introduction needle (20);
Flow control valve (32), the flow control valve (32) are arranged on the testing sample transfer pipeline (31).
3. sampling device according to claim 2, it is characterised in that the flow control valve (32) includes:
Tee pipe fitting (321), including the first communication port, the second communication port and the 3rd communication port, the tee pipe fitting (321) are set On the testing sample transfer pipeline (31), first communication port and second communication port are defeated with the testing sample Pipeline (31) is sent to be connected;
Dividing plate (322), the dividing plate (322) are arranged on the inside of the tee pipe fitting (321), for by the tee pipe fitting (321) inside is divided into first chamber and second chamber;
Connecting rod (323), the connecting rod (323) is connected through the 3rd communication port with the dividing plate (322), and the connecting rod (323) relative to the tee pipe fitting (321) rotatable setting, to adjust between the first chamber and the second chamber it Between circulation area.
4. sampling device according to claim 3, it is characterised in that the connecting rod (323) is matched somebody with somebody with the 3rd communication port screw thread Close.
5. sampling device according to claim 4, it is characterised in that the arrival end of the testing sample transfer pipeline (31) Coordinate with the sampling needle (10) for screw thread, the port of export and the sample introduction needle (20) of the testing sample transfer pipeline (31) are Screw thread coordinates.
6. sampling device according to claim 1, it is characterised in that be provided with one or more on the sample introduction needle (20) Spray-hole, for the testing sample to be sprayed.
7. sampling device according to claim 6, it is characterised in that the spray-hole is multiple, multiple spray-holes Along the circumferential or axially arranged of the sample introduction needle (20).
8. the sampling device according to claim 6 or 7, it is characterised in that the spray-hole is arranged on away from the sample introduction needle (20) at 1~3cm of the port of export.
9. sampling device according to claim 3, it is characterised in that the sampling device also includes fixture (40), The fixture (40) includes first end and the second end, and the first end is fixedly connected on the tee pipe fitting (321), described Second end is used to fix the sampling device when carrying out sample introduction operation.
10. sampling device according to claim 9, it is characterised in that the first end is set in the 3rd communication port Outside.
CN201721084233.XU 2017-08-28 2017-08-28 Sampling device Active CN207164020U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201721084233.XU CN207164020U (en) 2017-08-28 2017-08-28 Sampling device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201721084233.XU CN207164020U (en) 2017-08-28 2017-08-28 Sampling device

Publications (1)

Publication Number Publication Date
CN207164020U true CN207164020U (en) 2018-03-30

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ID=61719304

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201721084233.XU Active CN207164020U (en) 2017-08-28 2017-08-28 Sampling device

Country Status (1)

Country Link
CN (1) CN207164020U (en)

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