CN207159159U - A kind of hydrogasification stove with semicoke refrigerated separation function - Google Patents

A kind of hydrogasification stove with semicoke refrigerated separation function Download PDF

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CN207159159U
CN207159159U CN201721157546.3U CN201721157546U CN207159159U CN 207159159 U CN207159159 U CN 207159159U CN 201721157546 U CN201721157546 U CN 201721157546U CN 207159159 U CN207159159 U CN 207159159U
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semicoke
outer barrel
inner cylinder
nozzle
quench
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CN201721157546.3U
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冯浩
张刚
王凤彬
张正旺
唐佳慧
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Xinneng Energy Co Ltd
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Xinneng Energy Co Ltd
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Abstract

The utility model discloses a kind of hydrogasification stove with semicoke refrigerated separation function, it is related to coal chemical industry equipment technical field.The hydrogasification stove, by the inner cylinder that upper and lower opening is set in the inside of outer barrel, and inner cylinder is set gradually from top to bottom for wide path, undergauge section, narrow footpath section and extension diameter section, and it is symmetrical arranged multiple Quench nozzles ring week in the side wall of outer barrel, and Quench nozzle is installed obliquely, not only realize cooling in gasification furnace bottom semicoke, without using semicoke cooling bed, it is difficult to avoid the Stress control in course of conveying, phenomena such as collaborating, and realize the gas solid separation of semicoke and synthesis gas, reduce and carry semicoke in synthesis gas secretly, reduce the heat-energy losses that entrainment carries, generally effectively reduce consumption when heat energy needed for gasification reaction provides thing hydrogen and oxygen combustion.

Description

A kind of hydrogasification stove with semicoke refrigerated separation function
Technical field
It the utility model is related to coal chemical industry equipment technical field, more particularly to a kind of adding with semicoke refrigerated separation function Hydrogen gasification furnace.
Background technology
Hydrogasification refers to that carbon compound and hydrogen are anti-under the conditions of medium temperature (700-1000 DEG C) and high pressure (5-10MPa) Should, the process of raw gas of the generation rich in methane, high added value aromatic hydrocarbons oil product and high heating value semicoke.The high temperature of hydrogasification generation Semicoke product needs cooling down, is sent outside after energy recovery processing.
At present, gasification furnace does not have semicoke Cooling Design in itself, and semicoke cooling is not carried out in gasification furnace, is to pass through gas Semicoke is sent to semicoke cooling bed and cooled down by change stove conveyance conduit, and conveyance conduit uses refractory liner structure, is needed simultaneously Pressure difference control is adjusted to gasification furnace and semicoke cooling bed by rear system.
But control extremely difficult, gasification furnace and semicoke stream for the pressure difference between gasification furnace and semicoke cooling bed The risk collaborated be present between change bed cooler;And semicoke cooling bed is carried out using fluidized gas and water cooling heat exchanger tube to semicoke Cooling, a large amount of semicoke heat energy can not recycle, and heat-energy losses are larger, while the risk of the damaged leakage of heat exchanger tube be present;In addition, Using existing hydrogasification device, the gas-solid separating effect of gasification product synthesis gas and semicoke in gasification furnace reative cell is poor, Substantial amounts of semicoke product is often entrained with synthesis gas.
Utility model content
The purpose of this utility model is to provide a kind of hydrogasification stove with semicoke refrigerated separation function, so as to solve Foregoing problems present in prior art.
To achieve these goals, the technical solution adopted in the utility model is as follows:
A kind of hydrogasification stove with semicoke refrigerated separation function, including:Outer barrel, thing is provided with the top of the outer barrel Expect nozzle, the inner cylinder for being internally provided with upper and lower opening of the outer barrel, the inner cylinder is located at the middle and lower part of the outer barrel;
Space is provided between the outer barrel and the inner cylinder, syngas outlet, institute are provided with the side wall of the outer barrel State syngas outlet to connect with the space, the outer of the upper port of the inner cylinder is arranged in the side wall of the outer barrel, described The lower port of inner cylinder connects with the space;
The inner cylinder is followed successively by wide path, undergauge section, narrow footpath section and extension diameter section from top to bottom;
It is symmetrical arranged multiple Quench nozzles in the side wall of the outer barrel ring week, the Quench nozzle is installed obliquely, and institute The jet for stating Quench nozzle is close to the lower section setting of the extension diameter section.
Preferably, the Quench nozzle is installed with downward 45 ° of angle.
Preferably, itself spray angle of each Quench nozzle is 30 °.
Preferably, the Quench nozzle is arranged to 8-16.
Preferably, the shock chilling medium used in the Quench nozzle is coal dust.
Preferably, the spatial altitude below the extension diameter section accounts for the 2/5 of gasification furnace total height.
The beneficial effects of the utility model are:One kind that the utility model embodiment provides has semicoke refrigerated separation function Hydrogasification stove, by setting the inner cylinder of upper and lower opening in the inside of outer barrel, and inner cylinder is set gradually as width from top to bottom Footpath section, undergauge section, narrow footpath section and extension diameter section, and it is symmetrical arranged multiple Quench nozzles ring week in the side wall of outer barrel, and Quench is sprayed Mouth is installed obliquely, is not only realized cooling in gasification furnace bottom semicoke, without using semicoke cooling bed, is avoided Stress control is difficult in course of conveying, phenomena such as collaborating, and realizes the gas solid separation of semicoke and synthesis gas, subtracts Lack and carried semicoke in synthesis gas secretly, reduced the heat-energy losses that entrainment carries, generally effectively reduced hot needed for gasification reaction Consumption when thing hydrogen and oxygen combustion can be provided.
Brief description of the drawings
Fig. 1 is the structural representation for the hydrogasification stove that this practicality newly provides;
Fig. 2 is the arrangement schematic diagram of Quench nozzle.
In figure, the implication of each symbol is as follows:
1 outer barrel, 2 substance nozzles, 3 inner cylinders, 4 syngas outlets, 5 wide paths, 6 undergauge sections, 7 narrow footpath sections, 8 extension diameter sections, 9 swash Cold nozzle, 10 coke discharging mouths, 11 heat exchanging segments.
Embodiment
In order that the purpose of this utility model, technical scheme and advantage are more clearly understood, below in conjunction with accompanying drawing, to this reality It is further elaborated with new.It should be appreciated that embodiment described herein is only explaining this practicality It is new, it is not used to limit the utility model.
As shown in Figure 1-2, the utility model embodiment provides a kind of hydrogasification with semicoke refrigerated separation function Stove, including:Outer barrel 1, the top of outer barrel 1 are provided with substance nozzle 2, and the inner cylinder 3 for being internally provided with upper and lower opening of outer barrel 1 is interior Cylinder 3 is located at the middle and lower part of outer barrel 1;
Space is provided between outer barrel 1 and inner cylinder 3, syngas outlet 4, syngas outlet 4 are provided with the side wall of outer barrel 1 Connected with the space, the outer of the upper port of inner cylinder 3 is arranged in the side wall of outer barrel 1, the lower port of inner cylinder 3 and the space Connection;
Inner cylinder 3 is followed successively by wide path 5, undergauge section 6, narrow footpath section 7 and extension diameter section 8 from top to bottom;
It is symmetrical arranged multiple Quench nozzles 9 in the side wall of outer barrel 1 ring week, Quench nozzle 9 is installed obliquely, and Quench nozzle The lower section that 9 jet is close to extension diameter section 8 is set.
In said structure, due to being symmetrical arranged multiple Quench nozzles in the side wall of outer barrel ring week, and Quench nozzle is obliquely Installation, so, when having shock chilling medium to be ejected into outer barrel in multiple Quench nozzles, the atomization screen of back taper will be formed Barrier.
The gasification furnace of said structure, its operation principle are:
Hydrogen and oxygen and coal dust enter gasification furnace from the substance nozzle on outer barrel top, and the wide path on inner cylinder top carries out anti- Should, generate high-temperature synthesis gas and semicoke product, high-temperature synthesis gas and semicoke product are passed through from the wide path of inner cylinder by undergauge section Narrow footpath section and expand through section enter outer barrel bottom, expand the lower section through section, semicoke product with from be arranged in ring week multiple Quench The taper barrier that the coal dust that is sprayed in nozzle is formed exchanges heat, after the heat of semicoke deviates from the fugitive constituent in coal dust, entrance Top wide path continues reaction generation methane with hydrogen, and the semicoke after heat exchange reaches the row that the requirement sent outside is set from outer barrel bottom Jiao Kou is discharged, and synthesis gas reaches syngas outlet, gone out from synthesis gas from expanding through entering the space between inner cylinder and outer barrel below section Mouth discharge.
In said structure, by being arranged in the taper barrier of the coal dust sprayed in multiple Quench nozzles in ring week formation, Heat exchange reaction occurs with semicoke, not only realizes cooling for semicoke, its temperature is reached the requirement sent outside, without using Semicoke cooling bed, and the semicoke product of high temperature is transported in semicoke cooling bed by control pressure, avoid pressure Power control is difficult, phenomena such as collaborating;The shock chilling medium in this process, used is additionally, since as coal dust, rather than it is cold Water, so that the heat in semicoke has obtained effective recycling.
In addition, by, through setting narrow footpath section between (heat exchanging segment) below section, not only increasing in wide path (conversion zone) and expansion The space of conversion zone and reaction residence time, while the structure of enlarging again after necking, can add semicoke and synthesis gas Diffused after speed, play a part of gas-solid (semicoke and synthesis gas) separation, therefore, the progress that said structure not only improves reaction has again Beneficial to gas solid separation, reduce and carry semicoke in synthesis gas secretly, reduce entrainment and carry heat-energy losses.
Therefore, using the present embodiment provide hydrogasification stove, while cooling by coal dust to semicoke coal dust by Hot devolatilization, both are mixed into the process of low temperature semicoke, and course of reaction is carried out inside gasification furnace, and reaction is gentle, operation letter Single, heat energy is utilized effectively.Gas solid separation time length in gasification furnace simultaneously, separating effect is preferable, and synthesis gas is sent in reduction outside Carry material secretly, reduce heat-energy losses.It generally can effectively reduce heat energy needed for gasification reaction and thing hydrogen and oxygen combustion are provided When consumption.
In the present embodiment, Quench nozzle 9 is installed with downward 45 ° of angle.
Consider that small nozzle itself has certain spray angle, if being horizontally mounted, then some coal dust meeting It is sprayed onto upwards on the outside of enlarging (synthesis gas side), in the present embodiment, selects 45° angle to install downwards, it is ensured that to be integrally formed downwards Taper barrier so that the abundant contact heat-exchanging of semicoke that coal dust can get off with top.
In the present embodiment, itself spray angle of each Quench nozzle 8 is 30 °.
According to current industrial atomizer requirement, nozzle angle is preferable in 30 ° of atomizing effects, while considers depositing for its angle It can just play a part of covering space, if small nozzle does not have angle, taper barrier cannot be formed in gasification furnace.
In the present embodiment, Quench nozzle 9 is arranged to 8-16.
According to the difference of gasification furnace size, Quench nozzle can set 8-16, such as 8,12,16, such as ability No matter field technique personnel according to the Quench nozzle of actual conditions setting other quantity it should be understood that still, can also set several It is individual, be required for being evenly distributed on the ring week of gasification furnace, while can longitudinally covered formation interface, reduce ring Zhou Wei as far as possible and cover Lid space.
In the present embodiment, the shock chilling medium used in Quench nozzle 9 is coal dust and hydrogen.
Using coal dust by the use of hydrogen as conveying gas, coal dust and hydrogen after Quench nozzle atomization by being ejected into gasification furnace In, and taper barrier is formed, after the semicoke that gasification furnace top is come runs into the taper barrier, mixed heat transfer is carried out with it, semicoke Cracking reaction occurs for the coal dust that heat energy is sparged into, and devolatilization and hydrogen return to gasification furnace top and continues heating generation hydrogasification Reaction, generates required synthesis gas, so, coal dust and hydrogen are used as shock chilling medium, can effectively reclaim semicoke heat energy, and In heat transfer process, semicoke is set to reach the temperature that can be arranged outside.
In the present embodiment, spatial altitude of the extension diameter section below 8 accounts for the 2/5 of gasification furnace total height.
Due to the space below extension diameter section, there occurs heat exchange between semicoke and coal ash, turn into heat exchanging segment, so, this In embodiment, using above-mentioned height ratio, it is ensured that heat exchanging segment has enough spaces, so as to it is abundant to exchange heat, with And ensure that the bottom of heat exchanging segment can store a certain amount of semicoke, if allowed, the ratio, heat transfer effect can also be increased Can more preferably.
By using above-mentioned technical proposal disclosed in the utility model, following beneficial effect has been obtained:The utility model A kind of hydrogasification stove with semicoke refrigerated separation function that embodiment provides, by setting upper and lower opening in the inside of outer barrel Inner cylinder, and inner cylinder set gradually from top to bottom for wide path, undergauge section, narrow footpath section and extension diameter section, and in the side wall of outer barrel Upper ring week is symmetrical arranged multiple Quench nozzles, and Quench nozzle is installed obliquely, not only realizes in gasification furnace bottom semicoke Cool, without using semicoke cooling bed, avoid in course of conveying that Stress control is difficult, occur collaborating etc. existing As, and the gas solid separation of semicoke and synthesis gas is realized, reduce and carry semicoke in synthesis gas secretly, reduce the heat that entrainment carries The loss of energy, generally effectively reduce consumption when heat energy needed for gasification reaction provides thing hydrogen and oxygen combustion.
Described above is only preferred embodiment of the present utility model, it is noted that for the common skill of the art For art personnel, on the premise of the utility model principle is not departed from, some improvements and modifications can also be made, these improve and Retouching should also regard the scope of protection of the utility model.

Claims (6)

  1. A kind of 1. hydrogasification stove with semicoke refrigerated separation function, it is characterised in that including:Outer barrel, the top of the outer barrel Portion is provided with substance nozzle, the inner cylinder for being internally provided with upper and lower opening of the outer barrel, and the inner cylinder is located in the outer barrel Bottom;
    Space is provided between the outer barrel and the inner cylinder, syngas outlet, the conjunction are provided with the side wall of the outer barrel Export into gas and connected with the space, the outer of the upper port of the inner cylinder is arranged in the side wall of the outer barrel, the inner cylinder Lower port connected with the space;
    The inner cylinder is followed successively by wide path, undergauge section, narrow footpath section and extension diameter section from top to bottom;
    It is symmetrical arranged multiple Quench nozzles in the side wall of the outer barrel ring week, the Quench nozzle is installed obliquely, and described sharp The lower section that the jet of cold nozzle is close to the extension diameter section is set.
  2. 2. the hydrogasification stove according to claim 1 with semicoke refrigerated separation function, it is characterised in that the Quench Nozzle is installed with downward 45 ° of angle.
  3. 3. the hydrogasification stove according to claim 1 with semicoke refrigerated separation function, it is characterised in that each described Itself spray angle of Quench nozzle is 30 °.
  4. 4. the hydrogasification stove according to claim 1 with semicoke refrigerated separation function, it is characterised in that the Quench Nozzle is arranged to 8-16.
  5. 5. the hydrogasification stove according to claim 1 with semicoke refrigerated separation function, it is characterised in that the Quench The shock chilling medium used in nozzle is coal dust.
  6. 6. the hydrogasification stove according to claim 1 with semicoke refrigerated separation function, it is characterised in that described expanding Spatial altitude below section accounts for the 2/5 of gasification furnace total height.
CN201721157546.3U 2017-09-11 2017-09-11 A kind of hydrogasification stove with semicoke refrigerated separation function Active CN207159159U (en)

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Application Number Priority Date Filing Date Title
CN201721157546.3U CN207159159U (en) 2017-09-11 2017-09-11 A kind of hydrogasification stove with semicoke refrigerated separation function

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110835553A (en) * 2019-11-05 2020-02-25 新奥科技发展有限公司 Hydro-gasification process
CN112705123A (en) * 2019-10-25 2021-04-27 中国石油化工股份有限公司 Hydrogenation reactor and hydrogenation method

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112705123A (en) * 2019-10-25 2021-04-27 中国石油化工股份有限公司 Hydrogenation reactor and hydrogenation method
CN112705123B (en) * 2019-10-25 2022-10-11 中国石油化工股份有限公司 Hydrogenation reactor and hydrogenation method
CN110835553A (en) * 2019-11-05 2020-02-25 新奥科技发展有限公司 Hydro-gasification process

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