CN206814701U - A kind of preparation facilities of fuel reforming - Google Patents

Abstract

Originally it is practical to be newly related to a kind of preparation facilities of fuel reforming, technique prepared by the fuel reforming includes pretreatment procedure, modification process, mixes process, stabilization process, and the fuel reforming preparation facilities includes fuel oil drum, water pot, catalytic unit, modification accelerator tank, mixing stirring device, stabilization device and holding vessel.Fuel oil and water integrated fusion in fuel reforming through fuel reforming preparation facilities generation, without residual moisture, do not occur oil-water emulsion; quality is steady in a long-term; the flash-point and calorific power of gained fuel reforming are identical with the fuel oil put into as raw material, promotion environmental protection, and promotion prospect is wide.

Description

A kind of preparation facilities of fuel reforming

Technical field

Originally it is practical to be newly related to energy field, more particularly to the preparation method and device of a kind of fuel reforming.

Background technology

At present, the political situation of the oil-producing country, security of nuclear energy power generation, warmization of the earth, the equilibrium of supply and demand of fossil fuel, complete Caused by the use of the problems such as environment of ball, particularly fossil fuel the problems such as the discharge capacity of carbon dioxide, always cannot It is effective to solve；The release for the decree that control fossil fuel uses, will cause the stagnation of industry；Therefore, solve fossil fuel to supply Answer, be undecided always using the effective countermeasure of problem.

In order to solve fossil fuel supply, substitute fossil fuel using natural energy source using problem, now gradual trial, and The time and funds that really substitution fossil fuel is spent are not it is contemplated that therefore, fossil fuel is substituted using natural energy source It is unexpected.

Prior art forms new fuel, i.e. described emulsion fuel, and constantly by adding water in fuel oil The practicality for carrying out emulsion fuel is improved.By the technology, the basic structure of fossil fuel is constant, and because the addition of water, subtracts Lack the usage amount of fossil fuel, and reduce the discharge capacity of carbon dioxide etc..But due to the addition of water, inevitably cause The rising of flash-point, the decline of calorific power.The result that fossil fuel is substituted using emulsion fuel is unsatisfactory.

Initial emulsion fuel is only that surfactant is added in fuel oil and water, and by being simply stirred system Into.Japan Patent (JP spy 2006-028215) improves the quality of emulsion fuel by using the methods of electrolysis, ultrasonic wave, vibration, But still can't resolve flash-point rising, calorific power decline the problem of.

Due to the incompatibility of water and oil, the flash-point rising of the emulsion fuel of water formation, calorific power is added to decline in fuel oil The reason for problem is that the form of emulsion fuel reclaimed water is constant, causes the flash-point of emulsion fuel to rise, calorific power declines.Water solubility combustion Moisture causes to misfire once separation, frozen in cold district in the high combustion efficiency of material, poor, fuel fuel compared to base oil The application of emulsion fuel is caused to become narrow the problems such as moisture blocking filter in knot, waste gas.

The fuel oil and water of emulsion fuel are in a kind of highly unstable state by surfactant, easily cause oil Water separates, and composition water can hinder to burn.Therefore, in the case of without using emulsification method, fuel oil and water how to be completed Integration, and fuel oil and it is water integrated after fuel reforming in not residual component water, water-oil separating, flash-point and calorific power does not occur Equal numerical value is maintained with base oil, fuel reforming has the combustibility as base oil, is still the technical issues that need to address.

Utility model content

The shortcomings that for above-mentioned prior art or deficiency, this practical new technical problems to be solved are：

The preparation method and device of a kind of fuel reforming are provided, the preparation method is without using emulsifying technology, you can complete combustion Material oil is integrally formed with water, and the fuel stabilization after reformation, without composition water, no water-oil separating, occurs without flash-point and improves, blocks Value declines.

In order to solve the above technical problems, this practical new technical scheme is as follows：

A kind of preparation facilities of fuel reforming, including fuel oil drum, water pot, catalytic unit, modification accelerator tank, stirring are mixed Attach together put, stabilization device and holding vessel；

Pipeline is parallel to the catalytic unit, the catalytic unit pipeline communication respectively for the fuel oil drum and the water pot In the mixing stirring device, the mixing stirring device pipeline communication is in the stabilization device, the stabilizer pipeline It is communicated in the holding vessel；

The modification accelerator tank, the modification accelerator are set between the catalytic unit and the mixing stirring device Connecting pipe of the tank pipeline communication between the catalytic unit and the mixing stirring device；

The stabilization device is connected with ultrasonic generator；

Moisture monitoring device is provided between the stabilization device and the holding vessel, the entrance of the moisture monitoring device connects Lead to the outlet of the stabilization device, the entrance of holding vessel described in the outlet of the moisture monitoring device.

Compared with prior art, the advantages of this is practical new is：

1st, by pretreatment procedure and modification process, promote degraded, easily realize Fusion Strain；Be stirred process and Stable process, realize that the generation of integrated fuel reforming can be achieved without emulsification for fuel oil and water.The fuel reforming of generation and Indifference between original fuel oil, does not occur water-oil separating, reach with base oil identical flash-point and calorific power, can realize and base oil Identical uses.

2nd, by fuel oil and water respectively through catalytic unit catalytic treatment, promote in fuel oil the aromatic compounds such as phenyl ring to The conversion of chain fatty class compound, promotion is degraded, i.e.,：Water decouples with the respective strand of oil；Meanwhile water generation is micro Hydrogen-oxygen water, namely：Hydrogen atom and oxygen atom in water are converted to free radical, and water oxygen reduction potential reduces；Therefore, fuel Oil and water reach the state for being easy to fusion.

3rd, modification accelerator is added in by the fuel oil of pretreatment procedure, strengthens the stability after profit combines, more It is scattered in fuel oil to be easy to composition water, fuel oil and water are more easy to merge, and promote the generation of fuel reforming.

4th, the fuel reforming preparation facilities of this practical new offer, in the preparation facilities breast does not occur for fuel oil and water Change, obtain the fuel reforming of stay in grade.

5th, there are kerosene, diesel oil, A heavy oil, B heavy oil, waste oil etc. herein as the fuel oil of raw material input, fire Material oil mixes with water and is free of residual moisture in the fuel reforming obtained, and water-oil separating does not occur, can reach the sudden strain of a muscle equal with base oil Point and calorific power.

Brief description of the drawings

Fig. 1：This practical new fuel reforming preparation facilities schematic diagram.

Embodiment

This practical new design, concrete structure and caused technique effect are made furtherly below with reference to accompanying drawing It is bright, to be fully understood from this practical new purpose, feature and effect.

This practical new fuel reforming preparation technology includes pretreatment procedure, modification process, mixes process, be stable Chemical industry sequence.

Pretreatment procedure, refer to allow fuel oil and water to carry out catalytic treatment respectively, realize the aromatics such as phenyl ring in fuel oil Conversion of the compound to chain fatty compounds of group, promote degraded；Realize that hydrogen atom and oxygen atom are converted to freedom in water Base, the oxidation-reduction potential of water is reduced, it is final to promote fuel oil and aqueous fusion to close.

Wherein, catalytic treatment uses catalytic unit, is by transition metal complex, alkaline-earth metal, rare earth metal and spy Different noble metal sintering smelting forms.The catalytic unit uses ceramic catalytic units, for photocatalyst pottery structure.

Any one combination in ruthenium, rhodium, platinum, lawrencium, cobalt, iron, nickel, manganese of transition metal complex.

Process is modified, is directed to add modification accelerator progress modifying process in the fuel oil after catalytic treatment, at modification Reason used in modification accelerator refer to containing 50% weight than carbon number 16-22 unrighted acid aliphatic acid or poly- hydroxyl The ester that the polyol condensating of base aliphatic acid and carbon number more than 4 is formed, adds modification accelerator, it is easier to fuel oil in fuel oil Middle hydrone is homogeneous scattered, promotes the fusion of fuel oil and water, it is easier to generate fuel reforming.

It is aliphatic acid, poly-hydroxy fatty acid, the mixture of polyol ester three to modify accelerator.

Wherein, unrighted acid is selected from any one or any one the group in palmitoleic acid, oleic acid, erucic acid etc. Close, polyalcohol be selected from sucrose, lactose, glucose, polyglycereol, D-sorbite, sorbitol anhydride etc. any one or arbitrarily A kind of combination.

Process is stirred, refers to the fuel oil after modifying process and the water after pre-treatment being placed in mixing stirring device Mixed processing is stirred, used agitating device uses the silent oscillation stirring mixer of static mixer technology, stirred in mixing Fuel oil and water are mixed in process still in emulsified state.

Stabilization process, refer to the ultrasonic wave for giving the more grades of mixed liquor for mixing fuel oil and water that process obtains Vibration, the fuel oil in emulsified state and water is set to be converted into stable Fusion Strain.

The ultrasonic activation of more grades refers to, 20~25 kilo hertzs, 30~40 kilo hertzs and 60~80 kilo hertzs of each cycle section Vibration of ultrasonic wave.

Ultrasonic activation, decompose oxygen and hydrogen in hydrone so that cavitation is produced in the mixed liquor of fuel oil and water, And trigger the pressure wave of strength.Pass through pretreatment procedure and modification process so that the fusion of fuel oil and the transposition of water stage of development. The ultrasonic vibration of the first estate is 20~25 kilo hertzs, then the vibration of ultrasonic wave given is 30~40 kilo hertzs, the ultrasound finally given Ripple vibrations are 60~80 kilo hertzs.

Stable process carries out moisture monitoring after terminating, by the moisture in the fuel reforming monitored, and as raw material Moisture in the fuel oil (base oil) of dispensing compares, to ensure the quality of fuel reforming.

Fuel reforming preparation facilities as shown in Figure 1, including the water pot 2 of the fuel oil drum 1 of storage fuel oil, storage water, Carry out the catalytic unit 3 of catalytic treatment, storage modifies the modification accelerator tank 4 of accelerator, is stirred the stirring of mixed processing Mixing arrangement 5, the stabilization device 6 for carrying out stabilization processing and the holding vessel 9 for storing fuel reforming；

Pipeline is parallel to the catalytic unit 3, the pipeline of catalytic unit 3 respectively for the fuel oil drum 1 and the water pot 2 The mixing stirring device 5 is communicated in, the pipeline communication of mixing stirring device 5 is in the stabilization device 6, the stabilization The pipeline communication of device 6 is in the holding vessel 9；

The modification accelerator tank 4 is set between the catalytic unit 3 and the mixing stirring device 5, and the modification promotees Enter connecting pipe of the pipeline communication of agent tank 4 between the catalytic unit 3 and the mixing stirring device 5；

The stabilization device 6 is connected with ultrasonic generator 7；

Moisture monitoring device 8 is provided between the stabilization device 6 and the holding vessel 9, the moisture monitoring device 8 enters Mouth connects the outlet of the stabilization device 6, the entrance of holding vessel 9 described in the outlet of the moisture monitoring device 8.

Water in water tank 2 enters mixing stirring device 5 by pipeline through catalytic unit 3.The inside of catalytic unit 3 uses honeybee Nest shape structure, each channel interior of alveolate texture set spiral helicine subsidiary conduit structure.

Fuel oil in fuel oil drum enters mixing stirring device 5 by pipeline through catalytic unit 3, is urged through catalytic unit 3 Change the fuel oil of processing before mixing stirring device 5 is entered after flowing out catalytic unit 3, open modification accelerator tank, Xiang Ran Appropriate modification accelerator is added in material oil.The structure of catalytic unit 3 used in fuel oil catalytic treatment and water catalytic treatment institute The structure of the catalytic unit 3 used is identical.

Mixing stirring device 5 is opposite in mixing stirring device 5 using the silent oscillation mixer of static mixer technology Modified processing after fuel oil and the water after pre-treatment be stirred mixed processing, obtain mixed liquor.

Stabilization device 6 is connected to the ultrasonic generator 7 of 3 kinds of different cycles, to entering stirring for stabilization device 6 The mixed liquor for mixing the generation of mixing arrangement 5 carries out ultrasonic wave stabilization processing, obtains the fuel reforming of stay in grade.

Meanwhile in order to monitor the moisture in fuel reforming, moisture monitoring is provided between stabilizer 6 and holding vessel 9 Device 8, the fuel reforming by the generation of fuel reforming preparation section enter through moisture detector 8 and stored after the discharge of stabilizer 6 Tank 9 stores.

Being applicable the fuel oil of this practical newly-generated fuel reforming includes kerosene, diesel oil, A heavy oil, B heavy oil, C weights Waste oil oily, to be recycled etc..Using this practical new fuel reforming preparation technology and the fuel reforming moisture-free of device generation Residual, quality is steady in a long-term, and water-oil separating does not occur, thus, flash-point, calorific power and fuel oil (base oil) are identical, have and fuel The equal use value of oil, promotes environmental protection, and popularization and application has good prospects in industry.

Above example is only illustrating this practical new technical scheme, rather than to this practical new limitation.It is affiliated The those of ordinary skill of technical field should be understood：All timess made within the spirit and principle of this practical new solution What modification, equivalent substitution, improvement etc., should be included within this practical new protection domain.

Claims (1)

1. a kind of preparation facilities of fuel reforming, including fuel oil drum (1), water pot (2), catalytic unit (3), modification accelerator tank (4), mixing stirring device (5), stabilization device (6) and holding vessel (9)；The fuel oil drum (1) and the water pot (2) are respectively Pipeline is parallel to the catalytic unit (3), and catalytic unit (3) pipeline communication is described to stir in the mixing stirring device (5) Mixing arrangement (5) pipeline communication is mixed in the stabilization device (6), stabilization device (6) pipeline communication is in the storage Tank (9)；The modification accelerator tank (4) is set between the catalytic unit (3) and the mixing stirring device (5), it is described to change Connecting pipe of matter accelerator tank (4) pipeline communication between the catalytic unit (3) and the mixing stirring device (5)；Institute State stabilization device (6) and be connected with ultrasonic generator (7)；Set between the stabilization device (6) and the holding vessel (9) Moisture monitoring device (8) is equipped with, the entrance of the moisture monitoring device (8) connects the outlet of the stabilization device (6), the moisture The entrance of holding vessel (9) described in the outlet of monitor (8).