CN206671589U - A kind of anti-microbial coating resin lens - Google Patents

A kind of anti-microbial coating resin lens Download PDF

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Publication number
CN206671589U
CN206671589U CN201720023595.1U CN201720023595U CN206671589U CN 206671589 U CN206671589 U CN 206671589U CN 201720023595 U CN201720023595 U CN 201720023595U CN 206671589 U CN206671589 U CN 206671589U
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CN
China
Prior art keywords
layer
coating
resin lens
tack coat
coated
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Active
Application number
CN201720023595.1U
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Chinese (zh)
Inventor
唐忆君
张盛元
陆承星
金松日
文春红
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Kang Naite Optical Co Ltd
SHANGHAI KANGNAITE OPTICS CO Ltd
Original Assignee
Jiangsu Kang Naite Optical Co Ltd
Shanghai Conant Optics Co Ltd
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Priority to CN201720023595.1U priority Critical patent/CN206671589U/en
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Abstract

The utility model is a kind of anti-microbial coating resin lens, including resin lens, dip-coating in resin lens surface wear-resisting stiffening layer, be sputtered at antireflective coating, antibiotic layer, tack coat and the top layer waterproof layer of the wear-resisting stiffening layer outer surface.Antibiotic layer and tack coat are sputtered at successively between antireflective coating and top layer waterproof layer, antibiotic layer is coated with antireflective coating surface by a kind of metal oxide in silver, copper, zinc, titanium and formed, and tack coat is coated with the antibacterial layer surface by a kind of oxide in silica, silicon monoxide, aluminum oxide, zirconium oxide and formed.The utility model uses vacuum coating technology and ion gun Aided Film Coating Technique, adds the caking ability of each film layer, and realizes obtained eyewear products and not only kept while original antireflective coating performance but also had the effect of permanently effective outstanding anti-microbial property.

Description

A kind of anti-microbial coating resin lens
Technical field
A kind of film coating lense of spectacle manufacturing technology is the utility model is related to, particularly discloses a kind of anti-microbial coating resin lens, Belong to the manufacturing field of resin lens.
Background technology
As resin glasses market progressively expands, its resin lens also increasingly obtains the concern of consumer.Therefore with The diversification of customer demand, the various aspects of performance and technique of resin lens are all in continuous improve and perfect.At present, in the market Plated film resin lens, be all mainly on the basis of resin lens really up to the mark are added, by the method for vacuum coating, be coated with anti-reflection Penetrate film layer, top layer waterproof layer etc..To have the function that to strengthen percent of pass, protection eyeglass.
Various resin lens are as daily carrying articles for use in life, to provide vision correction, protection and fashion Etc. function, simultaneously because long periods of wear resin lens surface certainly exists the microorganisms such as various bacteriums, fungi, virus, The use eye health and health that serious threat the mankind are propagated and spread to wherein various harmful microbes.Therefore people's confrontation The product of bacterium function is also increasingly paid attention to, and has similar product in the market, but the defects of two aspects be present, ties first Structure is unstable, and being not provided with transition zone between the antibiotic layer and outermost layer protective layer of key is aided in, and is so easily produced The problem of film Coating combination is bad, influence the persistence of antibacterial effect.In addition, component is not abundant enough in its antibiotic layer, to that can rise Mushroom species to antibacterial action is limited in scope.
Utility model content
The purpose of this utility model is that solution prior art plated film resin lens antibacterial effect is limited or antibiotic layer plated film is imitated The problem of fruit is not permanent, a kind of anti-microbial coating resin lens are proposed, by vacuum sputtering coating and ion gun Aided Film Coating Technique, Antibiotic layer and tack coat are coated between antireflective coating and top layer waterproof layer, good optical property is both ensure that, also add Adhesive force between top layer waterproof layer and antibiotic layer, there is excellent anti-microbial property again, greatly reduce the infection probability of illness in eye.
What the utility model was realized in:A kind of anti-microbial coating resin lens, including resin lens, dip-coating are in resin mirror The wear-resisting stiffening layer on piece surface, antireflective coating, antibiotic layer, tack coat and the top layer for being sputtered at the wear-resisting stiffening layer outer surface are prevented Water layer, in described antibiotic layer and tack coat it is sputtered at successively between antireflective coating and top layer waterproof layer, described antibiotic layer It is coated with and is formed on antireflective coating surface by one or more metal oxides in silver, copper, zinc, titanium, described tack coat is by two One or more oxides in silica, silicon monoxide, aluminum oxide, zirconium oxide are coated with the antibacterial layer surface to be formed, and is used To increase the adhesive force between top layer waterproof layer and the antibiotic layer.
Further, described antibiotic layer and described tack coat are using vacuum sputtering coating technology and ion gun auxiliary plating Membrane technology, which is coated with, to be formed, and described waterproof layer is sputtered at described tie layer surface using vacuum sputtering coating.
Further, described antireflective coating is a kind of sandwich construction, and its each layer is by silica, zirconium oxide, oxidation One kind in indium tin, which is coated with, to be formed, and adjacent layer is coated with using different material and formed.
Further, the thickness control of described antireflective coating is in 150nm~600nm, the thickness control of the antibiotic layer In 1nm~100nm, the thickness control of the tack coat is in 1nm~20nm.
The beneficial effects of the utility model are:The utility model uses vacuum coating technology and ion gun assisted deposition skill Art, antireflective coating, antibiotic layer, tack coat, top layer are being coated with successively again to being coated with outside in the resin lens of wear-resisting stiffening layer Waterproof layer, adds the adhesive fastness of each film layer, and realizes obtained eyewear products and both kept original antireflective coating performance Effect with permanently effective outstanding anti-microbial property again simultaneously, to common microbiological, Escherichia coli, staphylococcus aureus, The antibiotic rate 99% of Candida albicans and saccharomycete, mould etc.(Antibacterial activity value 2)More than.And because antibiotic layer is located at multilayer Among film, the validity of its antibacterial ability can provide peace with permanently effective as the multiple membrane lifetime of its outer layer for user Full health protection, particularly greatly reduce the infection probability of illness in eye.
Brief description of the drawings
Fig. 1 is the utility model anti-microbial coating resin lens structural representation.
Label declaration in figure:1st, resin lens, 2, wear-resisting stiffening layer, 3, antireflective coating, 4, antibiotic layer, 5, tack coat, 6, Top layer waterproof layer.
Embodiment
With reference to the accompanying drawings 1, a kind of anti-microbial coating resin lens of the utility model, including resin lens 1, dip-coating are in resin lens The wear-resisting stiffening layer 2 on surface and be sputtered at successively the antireflective coating 3 on the surface of wear-resisting stiffening layer 2, antibiotic layer 4, tack coat 5, Top layer waterproof layer 6.Described antibiotic layer 4 is by one or more metal oxides in silver, copper, zinc, titanium on antireflective coating surface It is coated with and forms, described tack coat is existed by one or more oxides in silica, silicon monoxide, aluminum oxide, zirconium oxide The antibacterial layer surface, which is coated with, to be formed, to increase the adhesive force between top layer waterproof layer and the antibiotic layer.
Wherein, it is then solid in high temperature by the way that the resin lens cleaned up are carried out into stiffened processing using dipping process It is melted into the wear-resisting stiffening layer of high rigidity.Again using vacuum sputtering coating technology and ion gun ancillary technique in wear-resisting stiffened layer surface Antireflective coating is coated with, thickness control is in 150nm~600nm.
Afterwards, antireflective coating surface is coated with antibiotic layer again, is coated with to combine during antibiotic layer and uses ion gun assisted deposition Technology, increase the adhesive force of antibiotic layer and anti-reflection film, the antibiotic layer thickness control being coated with is in 1nm~100nm.Then in antibiotic layer Surface is coated with tack coat, is coated with during tack coat with reference to ion gun Aided Film Coating Technique is used, increases tack coat and antibiotic layer Adhesive force, the adhesive layer thickness that is coated with controlled in 1nm~20nm.Finally, it is coated with top layer waterproof layer in tie layer surface.
The utility model is effective by vacuum sputtering coating and ion gun Aided Film Coating Technique with antibiotic layer by antireflective coating Antibacterial ability has been had concurrently while with reference to, all optical properties for maintaining original film layer, is that its antibacterial range is more extensive, antibacterial Effect is more longlasting.Tested through German HOHENSTEIN and Japanese SIAA certification authorities, eyes made from the utility model method Product is to Escherichia coli, the antibiotic rate 99% of staphylococcus aureus, Candida albicans and saccharomycete, mould etc.(Antibacterial activity value 2)More than, and antibacterial ability is permanently effective.
With reference to specific embodiment, the utility model is described in further detail, but these embodiments are not intended to To restriction of the present utility model.
Embodiment 1:
The utility model prepares a kind of anti-microbial coating resin lens combined with antireflective coating, specific as follows:
Resin lens select refractive index 1.60(MR-8), using dip-coating hardening process, obtain the wearability that thickness is 2.5 μm Good wear-resisting stiffening layer;Then silicon dioxide layer 49.22nm, titanium dioxide are coated with successively in stiffening layer using vacuum evaporatation Zirconium layer 21.70nm, silicon dioxide layer 44.89nm, titanium dioxide zirconium layer 67.10nm, indium tin oxide layer 5.00nm, silica The antireflective coating that 73.58nm layers are formed, total thickness are 261.49nm.
Plated again on obtained six layers of antireflective coating using vacuum sputtering coating technology and ion gun Aided Film Coating Technique again The antibiotic layer of 10nm thickness processed.Continue to be coated with tack coat SiO using vacuum sputtering coating technology in antibacterial layer surface2Layer, is coated with Combined during tack coat and use ion gun Aided Film Coating Technique, increase the adhesive force of tack coat and antibiotic layer.It is further continued in tack coat Surface is coated with top layer waterproof layer.
By above-mentioned anti-microbial coating eyeglass, send to German HOHENSTEIN and Japanese SIAA certification authorities are tested to large intestine The antibiotic rate 99% of bacillus, staphylococcus aureus etc.(Antibacterial activity value 2)More than, antibacterial ability validity is with multiple membrane lifetime Equally, it is permanently effective, while antireflective coating send national Glasses detection Spot detection, film quality to meet national standard, 380~ Visible ray mean transmissivity is more than 99% in the range of 780nm light waves.
Embodiment 2:
The utility model prepares a kind of anti-microbial coating resin lens combined with antireflective coating, specific as follows:
Resin lens select refractive index 1.74, using dip-coating hardening process, obtain thickness as good wear-resisting of 2.5 μm of wearabilities Stiffening layer.Then it is coated with silicon dioxide layer, titanium dioxide zirconium layer, silica successively in stiffening layer using vacuum sputtering coating method Layer, titanium dioxide zirconium layer, silicon dioxide layer, titanium dioxide zirconium layer, indium tin oxide layer, silicon dioxide layer form anti-reflection film film layer, each layer Thickness be respectively 35.19 nm, 15.72 nm, 53.24 nm, 52.86 nm, 76.40 nm, 50.94 nm, 5.00 nm, 32.52nm, total thick 321.87nm.
30nm antibiotic layers are coated with obtained eight layers antireflective coating in using vacuum sputtering coating, is coated with while uses Ion gun Aided Film Coating Technique, increase the adhesive force of antibiotic layer and anti-reflection film, continue to plate using vacuum sputtering in antibacterial layer surface Membrane technology is coated with tack coat one silica layer, is combined when being coated with tack coat and uses ion gun Aided Film Coating Technique, increases tack coat With the adhesive force of antibiotic layer.It is further continued for being coated with top layer waterproof layer in the tie layer surface for being coated with acquisition.
By above-mentioned anti-microbial coating eyeglass, send to German HOHENSTEIN and Japanese SIAA certification authorities are tested to large intestine The antibiotic rate 99% of bacillus, staphylococcus aureus etc.(Antibacterial activity value 2)More than, antibacterial ability validity is with multiple membrane lifetime Equally, it is permanently effective, while antireflective coating send national Glasses detection Spot detection, film quality to meet national standard, 380~ Visible ray mean transmissivity is more than 99% in the range of 780nm light waves
Embodiment described above is only used for explaining the technical solution of the utility model, not of the present utility model to limit Protection domain, the scope of protection of the utility model are all new according to this practicality to be defined described in claims of the present utility model Technology contents disclosed in type, any modification of the design number of plies and other material classifications by changing anti-reflection film or reflective coating, Equivalent substitution and there is no improvement of unexpected beneficial effect etc., should be included in the scope of protection of the utility model it It is interior.

Claims (4)

1. a kind of anti-microbial coating resin lens, including resin lens(1), dip-coating is in resin lens(1)The wear-resisting stiffening layer on surface (2), be sputtered at the wear-resisting stiffening layer(2)The antireflective coating of outer surface(3), antibiotic layer(4), tack coat(5)With top layer waterproof Layer(6), it is characterised in that:In described antibiotic layer(4)And tack coat(5)It is to be sputtered at antireflective coating successively(3)Prevent with top layer Water layer(6)Between, described antibiotic layer(4)By a kind of metal oxide in silver, copper, zinc, titanium in antireflective coating(3)Plate on surface System forms, described tack coat(5)By a kind of oxide in silica, silicon monoxide, aluminum oxide, zirconium oxide described anti- Bacterium layer(4)Surface, which is coated with, to be formed, to increase top layer waterproof layer(6)With the antibiotic layer(4)Between adhesive force.
A kind of 2. anti-microbial coating resin lens according to claim 1, it is characterised in that:Described antibiotic layer(4)And institute The tack coat stated(5)It is coated with and forms using vacuum sputtering coating technology and ion gun Aided Film Coating Technique, described waterproof layer(6) Described tack coat is sputtered at using vacuum sputtering coating(5)Surface.
A kind of 3. anti-microbial coating resin lens according to claim 1, it is characterised in that:Described antireflective coating(3)It is A kind of sandwich construction, its each layer are to be coated with to form by one kind in silica, zirconium oxide, tin indium oxide, and adjacent layer uses Different material, which is coated with, to be formed.
A kind of 4. anti-microbial coating resin lens according to claim 1, it is characterised in that:Described antireflective coating(3)'s Thickness control is in 150nm~600nm, the antibiotic layer(4)Thickness control in 1nm~100nm, the tack coat(5)Thickness Degree control is in 1nm~20nm.
CN201720023595.1U 2017-01-10 2017-01-10 A kind of anti-microbial coating resin lens Active CN206671589U (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110646871A (en) * 2019-10-08 2020-01-03 苏州鑫河镜业有限公司 High-strength waterproof antibacterial automobile sun visor lens and production process thereof
CN111338006A (en) * 2020-01-03 2020-06-26 江苏奥天光学有限公司 Anti-reflection yellow jade film and preparation method thereof
CN112649904A (en) * 2020-12-29 2021-04-13 江苏淘镜有限公司 Vacuum coating antifogging lens and preparation method thereof
WO2021234030A1 (en) * 2020-05-19 2021-11-25 Carl Zeiss Vision Technical Service (Guangzhou) Ltd. Transparent article, in particular a spectacle lens, with antibacterial and/or antiviral properties and method for manufacturing thereof
CN114637059A (en) * 2022-02-15 2022-06-17 江苏全真光学科技股份有限公司 Lens with strong antibacterial and antistatic properties

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110646871A (en) * 2019-10-08 2020-01-03 苏州鑫河镜业有限公司 High-strength waterproof antibacterial automobile sun visor lens and production process thereof
CN111338006A (en) * 2020-01-03 2020-06-26 江苏奥天光学有限公司 Anti-reflection yellow jade film and preparation method thereof
WO2021234030A1 (en) * 2020-05-19 2021-11-25 Carl Zeiss Vision Technical Service (Guangzhou) Ltd. Transparent article, in particular a spectacle lens, with antibacterial and/or antiviral properties and method for manufacturing thereof
CN112649904A (en) * 2020-12-29 2021-04-13 江苏淘镜有限公司 Vacuum coating antifogging lens and preparation method thereof
CN112649904B (en) * 2020-12-29 2022-05-10 江苏淘镜有限公司 Vacuum coating antifogging lens and preparation method thereof
CN114637059A (en) * 2022-02-15 2022-06-17 江苏全真光学科技股份有限公司 Lens with strong antibacterial and antistatic properties

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GR01 Patent grant
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20180622

Address after: 226200 Jiangsu Nantong Qidong Binhai Industrial Park No. 18, Jiang Feng Road.

Co-patentee after: Shanghai Kangnaite Optics Co., Ltd.

Patentee after: Jiangsu Kang Naite Optical Co., Ltd

Address before: 226200 Jiangsu Nantong Qidong Binhai Industrial Park No. 18, Jiang Feng Road.

Co-patentee before: Shanghai Conant Optics Co., Ltd.

Patentee before: Jiangsu Kang Naite Optical Co., Ltd

TR01 Transfer of patent right