CN206628538U - A kind of water hydrogen generator that can be automatically injected raw material - Google Patents

A kind of water hydrogen generator that can be automatically injected raw material Download PDF

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Publication number
CN206628538U
CN206628538U CN201621456158.0U CN201621456158U CN206628538U CN 206628538 U CN206628538 U CN 206628538U CN 201621456158 U CN201621456158 U CN 201621456158U CN 206628538 U CN206628538 U CN 206628538U
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water
methanol
hydrogen
storage container
raw material
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CN201621456158.0U
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向华
马进
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Guangdong Hydrogen Energy Science and Technology Co Ltd
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Guangdong Hydrogen Energy Science and Technology Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

The utility model discloses a kind of water hydrogen generator that can be automatically injected raw material, including methanol-water reformation hydrogen production equipment, hydrogen fuel cell, main storage container;Methanol-water reformation hydrogen production equipment includes storage container, raw material conveying device, methanol-water transfer pipeline, reformer, separator, hydrogen delivery tube road, control board;Main storage container includes the first liquid level recognition unit, valve, the conveying pump housing, connecting line;Storage container is provided with the second liquid level identification mechanism, to identify the liquid level of storage container.The utility model proposes water hydrogen generator, using methanol-water reformation hydrogen production generate electricity, reduce the pollution to environment.Generating electricity by natural energy can be effectively utilized simultaneously, and unnecessary electric energy can be stored in a manner of methanol, can be generated electricity on power supply peak by methanol.The utility model can be automatically injected raw material, save human cost, improve the intelligent of equipment.

Description

A kind of water hydrogen generator that can be automatically injected raw material
Technical field
The utility model belongs to technical field of generators, is related to a kind of generator, more particularly to one kind can be automatically injected original The water hydrogen generator of material.
Background technology
Energy crisis and ecocrisis annoying countries in the world government always, equally also annoying Chinese Government.For many years Though exploration effect, never important breakthrough.
Existing electrical equipment usually requires to connect power network alternating current, can not then be used in the open air for being not switched on power network;Or Person is generated electricity by diesel-driven generator.Diesel-driven generator volume is big, and larger noise can be sent when generating electricity;Diesel oil not only consumes greatly The non-renewable resources such as the oil of amount, and nitrogen oxides contained in tail gas, hydrocarbons, carbon monoxide etc., can be to environment Cause larger pollution.
In view of this, nowadays there is an urgent need to design a kind of new power supply mode, to overcome the above-mentioned of existing power supply mode Defect.
Utility model content
Technical problem to be solved in the utility model is:A kind of water hydrogen generator that can be automatically injected raw material is provided, can Generated electricity using methanol-water reformation hydrogen production, small volume is easy to remove, saves the energy, reduces the pollution to environment;It can note automatically simultaneously Enter raw material, save human cost, improve the intelligent of equipment.
In order to solve the above technical problems, the utility model adopts the following technical scheme that:
A kind of water hydrogen generator that can be automatically injected raw material, the water hydrogen generator include:An at least methanol-water reforms system Hydrogen storage equipment, at least a hydrogen fuel cell, main storage container;
Storage container corresponding to each methanol-water reformation hydrogen production equipment connection, for storing methanol-water raw material, each storage container Main storage container is connected respectively;
The main storage container includes master controller, the conveying pump housing, connecting line, the master controller connection conveying pump housing;Institute State storage container and be provided with the first liquid level recognition unit, to identify the liquid level of storage container, the first liquid level recognition unit connection master Controller;Valve is respectively equipped between each storage container and main storage container, each valve connects the master controller respectively;
Hydrogen, hydrogen made from hydrogen fuel cell utilization is made in the methanol-water reformation hydrogen production equipment utilization methanol-water raw material Generate electricity.
Preferably, the storage container is provided with the first temperature sensor, liquid level sensor, and second temperature is provided with heat exchanger Sensor, first flow sensor, reformer is interior to be provided with three-temperature sensor, and air flow inlet, the air-flow of hydrogen fuel cell go out Mouth sets pressure sensor and magnetic valve respectively;
The control board connects delivery pump respectively, second temperature sensor, first flow sensor in heat exchanger, Three-temperature sensor in reformer, the pressure sensor and magnetic valve of hydrogen fuel cell, and control the work of all parts;
The methanol-water raw material of liquid is stored in the methanol-water storage container;The delivery pump is used to store methanol-water Methanol-water raw material in container is pumped to the reformer chamber of reformer by conveyance conduit;The heat exchanger is installed on methanol-water raw material Conveyance conduit on, methanol-water raw material in heat exchanger, with reformer output high-temperature hydrogen exchanged heat, methanol-water raw material temperature Degree rise, hydrogen temperature reduce;Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through film point Hydrogen is obtained from device;Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell;Hydrogen leads to the oxygen in air Cross hydrogen fuel cell and redox reaction generation electric energy occurs.
The beneficial effects of the utility model are:The utility model proposes water hydrogen generator, reformed using methanol-water Preparing hydrogen, generating power, small volume is easy to remove, saves the energy, reduces the pollution to environment.The utility model can be automatically injected raw material, Human cost is saved, improves the intelligent of equipment.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model water hydrogen generator.
Fig. 2 is the composition schematic diagram of part control unit in the utility model water hydrogen generator.
Fig. 3 is the structural representation of part control unit in the utility model water hydrogen generator.
Fig. 4 is the composition schematic diagram of the utility model methanol-water reformation hydrogen production equipment.
Fig. 5 is the structural representation of methanol-water reformation hydrogen production equipment.
Fig. 6 is the composition schematic diagram of methanol-water reformation hydrogen production equipment.
Embodiment
Describe preferred embodiment of the present utility model in detail below in conjunction with the accompanying drawings.
Embodiment one
Referring to Fig. 1, the utility model discloses a kind of water hydrogen generator, the water hydrogen generator is reformed including methanol-water Hydrogen producer 1, hydrogen fuel cell 2, storage container 130, main storage container 120 (methanol-water reformation hydrogen production equipment 1, hydrogen fuel electricity Pond 2, storage container 130 can set several, share a main storage container 120).Storage container 130, methanol-water reform system Hydrogen storage equipment 1, hydrogen fuel cell 2 are set gradually, and the top of storage container 130 is provided with solution adding mouth and lid.
Fig. 2, Fig. 3 are referred to, the main storage container 120 includes master controller 121, main radio communication unit 122, second Liquid level recognition unit 123, the conveying pump housing 124, connecting line 125, master controller 121 connect main radio communication unit 122, second Liquid level recognition unit 123, the conveying pump housing 124.The second liquid level recognition unit 123 is identifying the liquid of main storage container 120 Position.
The storage container 130 is provided with sub-controller 131, sub- radio communication unit 132, the first liquid level recognition unit 133, First liquid level recognition unit 133 is identifying the liquid level of storage container 130;Sub-controller 131 distinguishes connexon wireless telecommunications list First 132, first liquid level recognition unit 133.Valve 134 is respectively equipped between each storage container 130 and main storage container 120, respectively Valve 134 connects the master controller 121 (can also be by sub-controller 131 come the break-make of control valve 134) respectively.
Methanol-water reformation hydrogen production equipment 1, hydrogen fuel cell 2 (can be existing common hydrogen fuel cell, such as may include hydrogen Fuel cell system, buffered sources) basic composition be all prior art, some earlier applications of the applicant disclose above-mentioned Composition (the patent of invention of such as three mandates of part:Chinese patent CN201210339912.2, one kind prepare hydrogen using methanol-water The system and method for gas;Chinese patent CN201310578035.9, instant preparing hydrogen, generating power system and method;Chinese patent CN 201310520538.0 a kind of preparing hydrogen, generating power system and method immediately), do not do excessively repeat here.But in order to embody this Shen Abundant, also slightly basic introduction, and being further improved to part details here please be disclose.
Referring to Fig. 4, the Hydrogen Unit include raw material conveying device 11, methanol-water transfer pipeline 12, reformer 13, Separator 14, hydrogen delivery tube road 15, residual air discharge pipe 17, starter 18, control board 19.Raw material conveying device 11 connection storage containers 2, reformer 13 is delivered to by the raw material in storage container 2 by methanol-water transfer pipeline 12.
The control board 19 connects raw material conveying device 11, reformer 13, separator 14 respectively, and control is each Device works.The raw material conveying device 11 connects storage container 2 and reformer 13 respectively by methanol-water transfer pipeline 12, The raw material conveying device 11 is by the methanol-water feedstock transportation in storage container 2 to reformer 13.The reformer 13 connects Separator 14 is connect, separator 14 connects hydrogen delivery tube road 15, residual air discharge pipe 17 respectively;The separator 14 wraps Include membrane separation device.
In the present embodiment, the storage container 130 can be provided with the first temperature sensor, liquid level sensor, in heat exchanger Provided with second temperature sensor, first flow sensor, reformer chamber is provided with three-temperature sensor, the air-flow of hydrogen fuel cell Entrance, air stream outlet set pressure sensor and magnetic valve respectively.The control board connects delivery pump (feedstock transportation respectively Device 101), second temperature sensor, first flow sensor in heat exchanger, the three-temperature sensor in reformer, hydrogen The pressure sensor and magnetic valve of fuel cell, and control the work of all parts.
The methanol-water raw material of liquid is stored in the methanol-water storage container;The delivery pump is used to store methanol-water Methanol-water raw material in container is pumped to the reformer chamber of reformer by conveyance conduit;The heat exchanger is installed on methanol-water raw material Conveyance conduit on, methanol-water raw material in heat exchanger, with reformer output high-temperature hydrogen exchanged heat, methanol-water raw material temperature Degree rise, hydrogen temperature reduce;Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through film point Hydrogen is obtained from device;Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell;Hydrogen leads to the oxygen in air Cross hydrogen fuel cell and redox reaction generation electric energy occurs.
The application's further thes improvement is that:
Fig. 5, Fig. 6 are referred to, the reformer 13 includes heat exchanger, heating and gasifying pipeline 108, reformer chamber 107, described Membrane separation device is arranged at the top in reformer chamber 107.The heat exchanger includes methanol-water preheating pipeline, the heat exchanger installation In on the conveyance conduit (this section of conveyance conduit can be used as methanol-water preheating pipeline) of methanol-water raw material, methanol-water raw material is exchanging heat High-temperature hydrogen in device with reformer output is exchanged heat, and methanol-water material temperature rise, hydrogen temperature reduces.Methanol-water raw material Gasify after being exchanged heat in heat exchanger into heating and gasifying pipeline 108;Methanol steam and water vapour after gasification enter reformer chamber, weight Whole interior is provided with catalyst.
The entirety of a methanol-water reformation hydrogen production equipment substantially hollow cylinder 101, the top of hollow cylinder 101 are provided with gas Outlet 102;Heat-insulation layer 104, stainless steel inner casing 105 are sequentially provided with by outer in hollow cylinder 101, in stainless steel inner casing 105 The space of formation forms combustion chamber 106.The bottom of reformer 13 is provided with starter 18, and the starter 18 includes cup Seat 103, methanol-water preheating pipeline, a part for heating and gasifying pipeline, igniter and temperature sensing dress are installed on cup 103 Put.The raw material input channel inputs first alcohol and water raw material, and raw material input channel is connected with heating and gasifying pipeline, first alcohol and water Raw material exports after raw material input channel enters heating and gasifying pipeline from the end of heating and gasifying pipeline;The igniter Position is corresponding with the end of heating and gasifying pipeline, for being carried out a little to the first alcohol and water raw material exported in heating and gasifying pipeline Fire, first alcohol and water raw material are heated to heating and gasifying pipeline, made in heating and gasifying pipeline through ignition device after-combustion First alcohol and water material gasification and increase combustion intensity rapidly, and then for reformer heat;The temperature detection device is used to visit The temperature surveyed by heating and gasifying pipeline;After the reformer starts hydrogen manufacturing, hydrogen partial made from reformer or/and residual air Reformer is maintained to run by burning.
The bottom side of the cup 103 is provided with air intake cover plate, and the air intake cover plate is provided with air channel, and outside air can be through the air channel Enter in reformer;The raw material input channel is provided with magnetic valve, to control raw material input channel to open or close, The flow of raw material input channel is controlled simultaneously.After the hydrogen producer starts, hydrogen producer passes through hydrogen made from device for producing hydrogen The energy needed for operation is provided;At this point it is possible to close starter.Due to hydrogen partial made from device for producing hydrogen or/and residual air Hydrogen producer is maintained to run by burning, so as to reduce the dependence to extra power, adaptive ability is strong.
As shown in figure 5, the reformer chamber 107 includes hollow circuit cylinder housing, catalyst 109 is provided with hollow circuit cylinder housing; Heating and gasifying pipeline 108 is partly or entirely arranged in hollow circuit cylinder housing, wrapped up by catalyst 109, effectively protection heating Gasification pipe.By the improvement, the utility model can be preheated preferably for methanol water liquid, and avoid heating and gasifying pipeline from going out The situation that existing peeling departs from, effectively extend the service life of pipeline.
In addition, in order to effectively utilize the heat of residual air, methanol-water pre-add pipe line can exchange heat with residual air discharge pipe.Institute The part for stating methanol-water pre-add pipe line is shape of threads pipeline, is used to convey methanol-water raw material in shape of threads pipeline;Shape of threads Pipeline wraps the residual air discharge pipe of reformer;Residual air discharge pipe temperature after shape of threads pipeline reduces, shape of threads Pipeline temperature after residual air discharge pipe raises;One end of shape of threads pipeline is provided with input port, and the other end is defeated provided with two Exit port, each output port are provided with valve;The other parts of one output port connection methanol-water transfer pipeline, another is defeated Exit port is connected to input port by circulation line;Temperature sensor is set at the output port close to shape of threads pipeline, Temperature sensor connects pre-add heat controller;Pre-add heat controller is according to the temperature data of temperature sensor and the original of reformer apparatus The switch of material demand two valves of regulation and the aperture of valve.
In summary, the utility model proposes the water hydrogen generator that can be automatically injected raw material, reformed using methanol-water Preparing hydrogen, generating power, small volume is easy to remove, saves the energy, reduces the pollution to environment.The utility model can be automatically injected raw material, Human cost is saved, improves the intelligent of equipment.
Here description and application of the present utility model are illustrative, are not wishing to the scope of the utility model being limited in State in embodiment.The deformation and change of embodiments disclosed herein are possible, for the ordinary skill people of those this areas The replacement of embodiment and equivalent various parts are known for member.It should be appreciated by the person skilled in the art that do not taking off In the case of spirit or essential characteristics of the present utility model, the utility model can in other forms, structure, arrangement, ratio, And realized with other components, material and part., can be to this in the case where not departing from the scope of the utility model and spirit In disclosed embodiment carry out other deformations and change.

Claims (6)

1. a kind of water hydrogen generator that can be automatically injected raw material, it is characterised in that the water hydrogen generator includes:An at least methanol Water reformation hydrogen production equipment, at least a hydrogen fuel cell, main storage container;
Storage container corresponding to each methanol-water reformation hydrogen production equipment connection, for storing methanol-water raw material, each storage container difference Connect main storage container;
The main storage container includes master controller, the conveying pump housing, connecting line, the master controller connection conveying pump housing;The storage Deposit container and be provided with the first liquid level recognition unit, to identify the liquid level of storage container, the connection main control of the first liquid level recognition unit Device;Valve is respectively equipped between each storage container and main storage container, each valve connects the master controller respectively;
Hydrogen is made in the methanol-water reformation hydrogen production equipment utilization methanol-water raw material, hydrogen hair made from hydrogen fuel cell utilization Electricity.
2. the water hydrogen generator according to claim 1 that raw material can be automatically injected, it is characterised in that:
The reformer chamber includes hollow housing, and catalyst is provided with hollow housing;The part or all of setting of heating and gasifying pipeline Wrapped up in hollow housing, by catalyst.
3. the water hydrogen generator according to claim 1 that raw material can be automatically injected, it is characterised in that:
The main storage container also includes the second liquid level recognition unit, to identify the liquid level of main storage container;Second liquid level is known Other unit connects master controller.
4. the water hydrogen generator according to claim 1 that raw material can be automatically injected, it is characterised in that:
The storage container is provided with sub-controller, sub- radio communication unit, and sub-controller connects the first liquid level recognition unit, sub- nothing Line communication unit;
The main storage container is provided with main radio communication unit, and master controller is led to by main radio communication unit with sub-controller News, obtain the liquid level data of each storage container.
5. the water hydrogen generator according to claim 1 that raw material can be automatically injected, it is characterised in that:
The methanol-water reformation hydrogen production equipment include raw material conveying device, methanol-water transfer pipeline, reformer, separator, Hydrogen delivery tube road, control board;The control board connects raw material conveying device, reformer, separator respectively, Each device is controlled to work;
The raw material conveying device connects storage container and reformer, the feedstock transportation respectively by methanol-water transfer pipeline Device is by the methanol-water feedstock transportation in storage container to reformer;
The reformer connects separator, separator connection hydrogen delivery tube road;The separator includes UF membrane Device.
6. the water hydrogen generator according to claim 1 that raw material can be automatically injected, it is characterised in that:
The storage container is provided with the first temperature sensor, liquid level sensor, and second temperature sensor, first are provided with heat exchanger Flow sensor, reformer is interior to be provided with three-temperature sensor, and air flow inlet, the air stream outlet of hydrogen fuel cell set pressure respectively Force snesor and magnetic valve;
The control board connects delivery pump respectively, second temperature sensor, first flow sensor in heat exchanger, reforms Three-temperature sensor in device, the pressure sensor and magnetic valve of hydrogen fuel cell, and control the work of all parts;
The methanol-water raw material of liquid is stored in the methanol-water storage container;The delivery pump is used for methanol-water storage container In methanol-water raw material the reformer chamber of reformer is pumped to by conveyance conduit;The heat exchanger is installed on the defeated of methanol-water raw material Send on pipeline, methanol-water raw material is exchanged heat in heat exchanger with the high-temperature hydrogen of reformer output, methanol-water material temperature liter Height, hydrogen temperature reduce;Methanol-water raw material carries out reformation hydrogen production reaction in reformer chamber and hydrogen-containing gas is made, and passes through membrane separator Obtain hydrogen;Air pump connects hydrogen fuel cell, pumps air into hydrogen fuel cell;Hydrogen passes through hydrogen with the oxygen in air Fuel cell occurs redox reaction and produces electric energy.
CN201621456158.0U 2016-12-28 2016-12-28 A kind of water hydrogen generator that can be automatically injected raw material Active CN206628538U (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109638316A (en) * 2018-11-06 2019-04-16 德州新动能铁塔发电有限公司 Vehicle-mounted water hydrogen machine methanol-water raw material is for method of completing the square and system
CN111509833A (en) * 2020-05-14 2020-08-07 广东能创科技有限公司 Conference center standby power system and power supply control method

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109638316A (en) * 2018-11-06 2019-04-16 德州新动能铁塔发电有限公司 Vehicle-mounted water hydrogen machine methanol-water raw material is for method of completing the square and system
CN111509833A (en) * 2020-05-14 2020-08-07 广东能创科技有限公司 Conference center standby power system and power supply control method

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Granted publication date: 20171110