CN206544950U - It is a kind of that arsenic device is gone based on modified molecular screen filtrate - Google Patents

It is a kind of that arsenic device is gone based on modified molecular screen filtrate Download PDF

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Publication number
CN206544950U
CN206544950U CN201720031387.6U CN201720031387U CN206544950U CN 206544950 U CN206544950 U CN 206544950U CN 201720031387 U CN201720031387 U CN 201720031387U CN 206544950 U CN206544950 U CN 206544950U
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China
Prior art keywords
arsenic
water
arsenic removal
pipe
molecular screen
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Expired - Fee Related
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CN201720031387.6U
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Chinese (zh)
Inventor
邵志元
李长胜
邵佩
王雪飞
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Chi Feng (beijing) Environmental Technology Group Co Ltd
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Chi Feng (beijing) Environmental Technology Group Co Ltd
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Priority to CN201720031387.6U priority Critical patent/CN206544950U/en
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Abstract

The utility model is related to a kind of removes arsenic device based on modified molecular screen filtrate.Its purpose is to provide that a kind of simple in construction, cost is low, effect of removing arsenic is good removes arsenic device.The utility model includes intermediate pool, arsenic removal filter, activated carbon adsorber and clear water reserviors, the water inlet of intermediate pool is by the first water-supply-pipe with being connected in well, the water side of intermediate pool is connected by the second water-supply-pipe with the oral siphon of arsenic removal filter, the outlet pipe of arsenic removal filter and the water inlet of activated carbon adsorber are connected, and the delivery port of activated carbon adsorber and the water inlet of clear water reserviors are connected.Arsenic removal filter includes water tank and arsenic removal bucket again, arsenic removal bucket top end opening, arsenic removal bucket is internally provided with modified zeolite filter material layer, the water inlet of water tank is connected with the first blow-down pipe, first blow-down pipe is the oral siphon of arsenic removal filter, the open communication of the delivery port of water tank and arsenic removal bucket, arsenic removal bucket bottom is connected with the second blow-down pipe, and the second blow-down pipe is the outlet pipe of arsenic removal filter.

Description

It is a kind of that arsenic device is gone based on modified molecular screen filtrate
Technical field
The utility model is related to sewage treatment area, more particularly to a kind of to go arsenic to fill based on modified molecular screen filtrate Put.
Background technology
Arsenic is a kind of toxicity very strong heavy metal element, and it will exist in the environment to be produced to human body, aquatic animals and plants etc. Have a strong impact on.Naturally occurring arsenic in the form of inorganic compound to be widely distributed in soil, rock forming mineral.Arsenic compound is generation The carcinogenic substance that many authoritative institutions such as boundary's health organization are assert, the current whole world has more than 100,000,000 populations by drinking water arsenic pollution Threat, only China's arsenic poisoning harm lesion population of exposure just be up to 15,000,000 people, patient diagnosed exceed tens of thousands of people.For a long time Drink the exceeded water of arsenic, it would be possible to cause Skin pigmentation, skin keratin, cutaneum carcinoma, liver cancer, angiocardiopathy etc. one to be Row health problem.In order to control drinking water, grain, veterinary antibiotics, aquatic animal (such as fish) different approaches to cause human body etc. Arsenic exposure, China carried out strict regulation by the form of standard to different arsenic in water environment concentration limits.For example, Require that four classes and its above arsenic in water body concentration should be less than 50 μ g/L in quality standard of water environment;In industrial wastewater discharge standard Regulation, which drains into arsenic concentration in the industrial wastewater in water body, should be less than 0.50mg/L.China is newest《Standards for drinking water quality》 (GB5749-2006) more strict regulation is made that to arsenic concentration limit value, it is desirable to which Arsenic in Drinking Water Cmax have to be lower than 10μg/L。
The removal technology of arsenic is the focus and difficulties studied both at home and abroad in water.Many research and technology developments Eye develops substantial amounts of arsenic removal new technology and new method in the removal of Arsenic in Drinking Water, such as absorption, flocculation-precipitation-filtering, wadding Solidifying-direct filtering, electrodialysis, ion exchange, UF membrane etc..On except arsenic adsorbent material, develop activated alumina, red mud, Modified activated carbon, FeOOH,Manganese sand, hydration Mn oxide, ferric oxide-alumina are combined The materials such as nano material, iron-managanese compounded oxide/diatomite.For example, the ferro manganese composite oxides of Li Guibai et al. early stage applications/ Diatomite adsorbing material (number of patent application:200610008135.8) can fully realize the oxidation of trivalent arsenic (As (III)) with The absorption of pentavalent arsenic (As (V)), so as to show excellent absorption arsenic removal ability.Iron oxide-oxidation of Cai Ya qis et al. invention Aluminium composite nano materials (number of patent application:CN200710118307.1) grain diameter is tiny, specific surface area is very big, so as to show Go out the very strong ability for removing the pollutant such as arsenic in water removal.But above method early investment cost is high, can only be confined to make on a small scale With, therefore, exploitation arsenic removing apparatus efficient, with low cost, easy to use and that extensive arsenic removal demand can be met, it has also become at present The difficulties of urgent need to resolve in Research And Engineering application.
Utility model content
The technical problems to be solved in the utility model is to provide that a kind of simple in construction, cost is low, effect of removing arsenic it is good based on Modified molecular screen filtrate removes arsenic device.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein, including intermediate pool, arsenic removal filtering Device, activated carbon adsorber and clear water reserviors, the water inlet of intermediate pool in well by the first water-supply-pipe with connecting, and intermediate pool goes out Water end (W.E.) is connected by the second water-supply-pipe with the oral siphon of arsenic removal filter, the outlet pipe of arsenic removal filter and activated carbon adsorber Water inlet is connected, and the delivery port of activated carbon adsorber and the water inlet of clear water reserviors are connected,
Arsenic removal filter includes water tank and arsenic removal bucket again, and arsenic removal bucket top end opening, arsenic removal bucket is internally provided with modified zeolite Filter material layer, the water inlet of water tank is connected with the first blow-down pipe, the open communication of the delivery port and arsenic removal bucket of water tank, arsenic removal bucket bottom Connected with the second blow-down pipe.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein the delivery port of the clear water reserviors with it is anti- One end connection of flushing pipe, the other end of Backwash pipeline respectively with the outlet pipe of dust removal filter and activated carbon adsorber Delivery port is connected, and backwashing pump is provided with Backwash pipeline.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein being provided with first water-supply-pipe Deep well pump.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein being provided with second water-supply-pipe Intermediate lift pump.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein arsenic bucket is vertically to set The cylindrical structural put.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein on the side wall of arsenic removal bucket bottom Dosing mouth is offered, dosing mouth is connected with regeneration chemicals dosing plant.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein on the side wall on arsenic removal bucket top Offer overfall.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein on the side wall of arsenic removal bucket bottom Offer sample tap.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein delivery port and the arsenic removal of the water tank Connected between the opening of bucket by water inlet pipe, peristaltic pump and gate valve are provided with water inlet pipe.
The utility model is a kind of to remove arsenic device based on modified molecular screen filtrate, wherein in the modified zeolite filter material layer Filtrate uses particle diameter for 0.8-1.8mm magma zeolite;Activated carbon raw material in activated carbon adsorber is cocoanut shell.
The utility model is a kind of to go arsenic device difference from prior art to be based on modified molecular screen filtrate:This reality Adsorbed and removed with the arsenic in new arsenic removal bucket and activated carbon adsorber water, reached《Standards for drinking water quality》 (GB5749-2006) filtrate in arsenic≤0.01mg/L requirement, arsenic removal bucket is soaked using ferrous sulfate as medicament, arsenic Removal efficiency reaches 99.97%.Regeneration chemicals dosing plant ensure that the filtrate in arsenic removal bucket is recycled, and greatly improve the work of arsenic removal Make efficiency.Activated carbon raw material in activated carbon adsorber is made of cocoanut shell, with pore structure is flourishing, intensity is high, impurity The advantages of content is low, granularity is appropriate, resistance is small, there is fabulous effect to purification of water quality, can not only remove odor smell, improves The degree of purity of water, also has very high clearance to the harmful substance such as chlorine, phenol, arsenic, lead, cyanide, agricultural chemicals in water.
It is a kind of to the utility model below in conjunction with the accompanying drawings to go arsenic device to be described further based on modified molecular screen filtrate.
Brief description of the drawings
Fig. 1 is a kind of structural representation for removing arsenic device based on modified molecular screen filtrate of the utility model;
Fig. 2 is a kind of structural representation for removing arsenic removal filter in arsenic device based on modified molecular screen filtrate of the utility model Figure.
Embodiment
As shown in figure 1, be a kind of structural representation for removing arsenic device based on modified molecular screen filtrate of the utility model, bag Intermediate pool 2, arsenic removal filter 4, activated carbon adsorber 6 and clear water reserviors 7 are included, deep-well is installed on the first water-supply-pipe in well Pump 1, one end of the first water-supply-pipe is stretched into water, and the other end of the first water-supply-pipe is connected with the water inlet of intermediate pool 2, middle water Intermediate lift pump 3 is installed, one end of the second water-supply-pipe extend into the bottom of intermediate pool 2 on the second water-supply-pipe inside pond 2, the Another list of two water-supply-pipes is connected with the oral siphon of arsenic removal filter 4, and dosing mouth 16, dosing mouth are provided with arsenic removal filter 4 16 are connected with regeneration chemicals dosing plant 5.The outlet pipe of arsenic removal filter 4 is connected with the water inlet of activated carbon adsorber 6, and activated carbon is inhaled The delivery port of attached tower 6 is connected with the water inlet of clear water reserviors 7, and the delivery port of clear water reserviors 7 is externally supplied water.The water outlet of clear water reserviors 7 Mouthful it is connected with one end of Backwash pipeline, the outlet pipe and activated carbon of the other end of Backwash pipeline respectively with dust removal filter 4 Backwashing pump 8 is provided with the delivery port connection of adsorption tower 6, Backwash pipeline.Activated carbon raw material in activated carbon adsorber 6 is Cocoanut shell.
As shown in Fig. 2 removing arsenic removal filter in arsenic device based on modified molecular screen filtrate for the utility model is a kind of Structural representation, arsenic removal filter 4 is again including water tank 9 and arsenic removal bucket 13, arsenic removal 13 cylinder vertically to set of bucket The lower portion in overfall 15, arsenic removal bucket 13 is further opened with structure, arsenic removal 13 top end openings of bucket, the side wall on 13 tops of arsenic removal bucket Install and be equipped with modified zeolite filter material layer 14, dosing mouth 16 and sample tap 17 are also offered respectively on the side wall of 13 bottoms of arsenic removal bucket. The water inlet of water tank 9 is connected with the first blow-down pipe 18, and the first blow-down pipe 18 is the oral siphon of arsenic removal filter 4.Water tank 9 goes out The mouth of a river is connected with one end of water inlet pipe 11, and peristaltic pump 10 and gate valve 12, the other end of water inlet pipe 11 are provided with water inlet pipe 11 It is extend at the opening on 13 tops of arsenic removal bucket inside arsenic removal bucket 13.13 bottoms of arsenic removal bucket are connected with the second blow-down pipe 19, and second Blow-down pipe 19 is the outlet pipe of arsenic removal filter 4.
Filtrate in the utility model in modified zeolite filter material layer 14 uses particle diameter for 0.8-1.8mm magma zeolite, filter It is 0.25mol/L and 0.35mol/L KMnO that material is used respectively4;And MnS04Solution carry out immersion 6 hours, it is soaking after zeolite Calcination two hours in 480 DEG C of smelting furnaces so that filtrate aperture rate reaches 50-60%.
The course of work of the present utility model is:Underground water in well directly lifts into intermediate pool 2 tune by deep well pump 1 Water-saving amount and water speed, and the pH value of waste water is adjusted between 6~8, the water in intermediate pool 2 is lifted by intermediate lift pump 3 Stored in the water tank 9 of arsenic removal filter 4, then remove what is contained in water by the absorption and metathesis of arsenic removal bucket 13 Arsenic, water is stopped 2.5 hours in arsenic removal bucket 13, then further removes impurities in water by activated carbon adsorber 6, water is in activity Charcoal adsorption tower 6 is stopped 1 hour, is finally drained into clear water reserviors 7.When the modified zeolite filter material layer 14 in arsenic removal bucket 13 reaches saturation When, regeneration chemicals dosing plant 5 is opened, copperas solution is passed through and immersion 4-5 hours is carried out to filtrate, to be regenerated to filtrate. After soak time is reached, regeneration chemicals dosing plant 5 is closed, while opening backwashing pump 8 carries out backwash 30 minutes, by remaining medicine Agent and flushing liquor discharge.Also need just washed 20 minutes to ensure clarification of water, after the completion of backwash, to water quality clarification, be System can be normally carried out arsenic removal processing.
The utility model is a kind of to remove arsenic device, arsenic removal bucket 13 and the water of activated carbon adsorber 6 based on modified molecular screen filtrate In arsenic adsorbed and removed, reach《Standards for drinking water quality》(GB5749-2006) arsenic≤0.01mg/L requirement, Filtrate in arsenic removal bucket 13 is soaked using ferrous sulfate as medicament, and separating by extraction reaches 99.97%.Regenerate chemicals dosing plant 5 ensure that the filtrate in arsenic removal bucket 13 is recycled, and greatly improve the operating efficiency of arsenic removal.Work in activated carbon adsorber 6 Property carbon feedstock be made of cocoanut shell, with pore structure is flourishing, intensity is high, impurity content is low, granularity is appropriate, resistance is small etc. Advantage, there is fabulous effect to purification of water quality, can not only remove odor smell, improves the degree of purity of water, also to chlorine in water, phenol, The harmful substances such as arsenic, lead, cyanide, agricultural chemicals have very high clearance.The utility model is simple in construction, cost is low, arsenic removal effect It is really good, compared with prior art with clear advantage.
Embodiment described above is only that preferred embodiment of the present utility model is described, not to this practicality New scope is defined, on the premise of the utility model design spirit is not departed from, and those of ordinary skill in the art are to this Various modifications and improvement that the technical scheme of utility model is made, all should fall into the protection of the utility model claims determination In the range of.

Claims (10)

1. a kind of remove arsenic device based on modified molecular screen filtrate, it is characterised in that:Including intermediate pool (2), arsenic removal filter (4), activated carbon adsorber (6) and clear water reserviors (7), the water inlet of intermediate pool (2) by the first water-supply-pipe with being connected in well, in Between the water side in pond (2) be connected by the second water-supply-pipe with the oral siphon of arsenic removal filter (4), arsenic removal filter (4) go out Water pipe is connected with the water inlet of activated carbon adsorber (6), the delivery port of activated carbon adsorber (6) and the water inlet of clear water reserviors (7) Connection,
Arsenic removal filter (4) includes water tank (9) and arsenic removal bucket (13) again, and arsenic removal bucket (13) top end opening, arsenic removal bucket (13) is internal Modified zeolite filter material layer (14) is provided with, the water inlet of water tank (9) is connected with the first blow-down pipe (18), the delivery port of water tank (9) With the open communication of arsenic removal bucket (13), arsenic removal bucket (13) bottom is connected with the second blow-down pipe (19).
A kind of arsenic device is gone based on modified molecular screen filtrate 2. according to claim 1, it is characterised in that:The clear water One end of the delivery port in pond (7) and Backwash pipeline is connected, and the other end of Backwash pipeline goes out with dust removal filter (4) respectively Backwashing pump (8) is provided with the delivery port connection of water pipe and activated carbon adsorber (6), Backwash pipeline.
A kind of arsenic device is gone based on modified molecular screen filtrate 3. according to claim 1, it is characterised in that:Described first Deep well pump (1) is installed on water-supply-pipe.
A kind of arsenic device is gone based on modified molecular screen filtrate 4. according to claim 1, it is characterised in that:Described second Intermediate lift pump (3) is installed on water-supply-pipe.
A kind of arsenic device is gone based on modified molecular screen filtrate 5. according to claim 1, it is characterised in that:The arsenic removal Bucket (13) is the cylindrical structural vertically set.
A kind of arsenic device is gone based on modified molecular screen filtrate 6. according to claim 5, it is characterised in that:The arsenic removal Dosing mouth (16) is offered on the side wall of bucket (13) bottom, dosing mouth (16) is connected with regeneration chemicals dosing plant (5).
A kind of arsenic device is gone based on modified molecular screen filtrate 7. according to claim 5, it is characterised in that:The arsenic removal Overfall (15) is offered on the side wall on bucket (13) top.
A kind of arsenic device is gone based on modified molecular screen filtrate 8. according to claim 5, it is characterised in that:The arsenic removal Sample tap (17) is offered on the side wall of bucket (13) bottom.
A kind of arsenic device is gone based on modified molecular screen filtrate 9. according to claim 1, it is characterised in that:The water tank (9) it is connected between delivery port and the opening of arsenic removal bucket (13) by water inlet pipe (11), water inlet pipe is provided with peristaltic pump on (11) And gate valve (12) (10).
A kind of arsenic device is gone based on modified molecular screen filtrate 10. according to claim 1, it is characterised in that:It is described to change Property zeolite filler layer (14) in filtrate use particle diameter for 0.8-1.8mm magma zeolite;Activity in activated carbon adsorber (6) Carbon feedstock is cocoanut shell.
CN201720031387.6U 2017-01-11 2017-01-11 It is a kind of that arsenic device is gone based on modified molecular screen filtrate Expired - Fee Related CN206544950U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107973362A (en) * 2017-12-22 2018-05-01 中国地质大学(武汉) A kind of method and device for removing removing fluorine in water and arsenate at the same time based on hydrocalumite

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107973362A (en) * 2017-12-22 2018-05-01 中国地质大学(武汉) A kind of method and device for removing removing fluorine in water and arsenate at the same time based on hydrocalumite

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20171010

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