CN206464339U - Detection system for electric repair device - Google Patents

Detection system for electric repair device Download PDF

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Publication number
CN206464339U
CN206464339U CN201720051723.3U CN201720051723U CN206464339U CN 206464339 U CN206464339 U CN 206464339U CN 201720051723 U CN201720051723 U CN 201720051723U CN 206464339 U CN206464339 U CN 206464339U
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soil
sensor
electro reclamation
detecting system
processing unit
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王新宇
陈明
余国强
陈华
张佳文
王蕊
刘冠男
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Institute of Mineral Resources of Chinese Academy of Geological Sciences
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Institute of Mineral Resources of Chinese Academy of Geological Sciences
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Abstract

The utility model discloses a detecting system for electronic prosthetic devices, this system contains: the device comprises a detection mechanism, a real-time sampling device, a transmission unit, a processing unit, a display device, a recording and storing device and a feedback device. The utility model realizes the detection, display and storage of the electric field intensity, the pH value, the Eh value, the water content, the temperature and the heavy metal concentration of soil gap water at any position in the electric repairing treatment box through the effective integration of various sensors, thereby facilitating the later data processing; and the automatic power-off and alarm functions are realized when the threshold value is exceeded. This a detecting system for electronic prosthetic devices is to understanding the soil repair condition in real time, improving electronic remediation efficiency, reduce the prosthetic artifical work load of control soil, reduce the maintenance cost and have the significance.

Description

Detecting system for electro reclamation device
Technical field
The utility model belongs to remediation of heavy metal-contaminated soil field.It is used for electronic repair in particular to one kind The detecting system of apparatus for coating.
Background technology
Research shows that China's soil pollution is main based on heavy metal pollution, and the wherein pollution such as cadmium, mercury, lead, arsenic is dashed forward the most Go out, for example, the soil that China there are about tens thousand of hectares at present is polluted by cadmium, mercury etc..At present cause heavy metal pollution of soil because Element mainly has:Mining activity, the stacking containing heavy metal waste, the dried wet deposition of the flue dust containing heavy metal, the row of heavy metal-containing waste water Put, Sewage Irrigation in Farmland and sludge fertilising etc..It is not easily decomposed, converts and is enriched with after enters soil due to heavy metal, and soil The complexity of the structure of system in itself so that the improvement of heavy metal pollution of soil is very difficult.
Electroremediation contaminated soil technology is that early 1980s Louisiana, United States university research comes out A kind of based technique for in-situ remediation of purification soil pollution.Its principle in contaminated soil both sides mainly by applying DC voltage, shape Into electric-force gradient, polluter is moved to electrode two ends in the way of electromigration, EOF and electrophoresis under electric field action, collect It is middle to collect to remove pollutant.At present, this method has been used to the improvement of heavy metal, and shows before huge application Scape, the important development direction as soil remediation.The advantage of electro reclamation mainly has:(1) hypotonicity soil can be handled The reparation of earth (due to hydraulic conductivity sex chromosome mosaicism, traditional technology application is restricted);(2) in-situ immobilization can be carried out, is polluted Pollution of the repair process to scene is minimum;(3) repair time is short, and laboratory research shows repair time not over one month; (4) handle cost per ton or every cubic metre of soil and want much less than other conventional arts.
In soil electromotion repairing technique, electric-field intensity, electrical conductivity, pH value, temperature, moisture content and a soil gap water huge sum of money Belong to the parameters such as concentration has material impact to repairing.Heavy metal contaminants are main with electriferous state(Such as ion, ionic complex Deng)Form is present, because the electromigration speed and its effective electrophoretic velocity of pollutant are directly proportional to electric-field intensity, electric-field intensity Remediation efficiency is determined to a certain extent, and electric-field intensity can be calculated by magnitude of voltage with distance;Potential change can reflect The change of soil area's point conductive capability, that is, reflect the change of the ionic strength of the point.Temperature rises meeting during electro reclamation Accelerate oxidation and heavy metal desorption rate, general soil temperature is increased to 35-45 DEG C and is conducive to soil remediation to carry out, and temperature is too high Can injury repair equipment;Anodes in electrolytic cells is also easy to produce in acidity, the too high perishable prosthetic appliance of acid concentration, negative electrode in alkalescence Alkaline band, which can hinder to repair, to be carried out.Moisture content height be easy to heavy metal ion migration, moisture content it is low or be repaired soil surface do Resistance can be increased by splitting.Therefore, in real time monitoring electro reclamation during electric-field intensity, electrical conductivity, pH value, temperature, moisture content and The Parameters variations such as soil gap water heavy metal concentration, it is possible to decrease unnecessary power consumption, improve heavy metal ion migration rate, accelerate Electrokinetic remediation efficiency.
Detection, the sampling of conventional electric restoring polluted soil are generally artificial sample, reading and record data, both easily occur to touch Electric danger is wasted time and energy again, and can not still meet electronic repair applied to the research and development of display system and detecting system on other field The actual demand of multiple contaminated soil.
One kind full-automatic contaminated soil remediation device in situ of such as Application No. " 201310164736.8 ".The device It is arranged on delivery vehicle, including metal ion chelation agent and acid-base neutralization agent injection device in soil, metal ion is electronic repaiies Apparatus for coating, soil remediation microorganism spray equipment, rotary tillage are digged device and microcomputer control system, wherein metal ion in soil Chelating agent and acid-base neutralization agent injection device, soil remediation microorganism spray equipment, metal ion electro reclamation device and micro- electricity Brain control system is electrically connected, metal ion chelation agent and acid-base neutralization agent injection device, soil remediation microorganism in the soil Spray equipment carries out chemistry chelating to contaminated soil respectively and repaired and microorganism in situ reparation, the metal ion electro reclamation dress Put and electrokinetics reparation is carried out to contaminated soil, rotary tillage device of digging is digged the dynamic of transmission device and delivery vehicle by rotary tillage Power apparatus is connected, and the rotary tillage digs device to contaminated soil progress ventilation oxidation reparation.
A kind of such as experimental facilities and application method for electromotion repairing technique of Application No. " 201510745273.3 ", Experimental facilities includes experiment test unit, flow-gas detection cell and power supply supply unit, and experiment test unit includes test Body, potentiometric measuring probe and electrode assemblie, the positive pole of the anode and power supply supply unit of one of electrode assemblie are electrically connected, separately The negative pole of the negative electrode of one electrode assemblie and described power supply supply unit is electrically connected;Flow-gas detection cell includes being used to survey First test block of quantity of fluid flow and the second test block for testing gas flow;Application method includes:Fine sand is carried out Pretreatment;The clean fine sand particle of chamber interior filling is loaded in simulation soil;Irrigate saturation NaCl solution;By controlling variable, Determine the voltage change between potentiometric measuring probe.The invention can be by the wetland with saline-alkaline laboratory simulation of seawater invasion.
A kind of regional water environment heavy metal monitoring system and operation method of such as Application No. " 2013105373672 ". The invention is a kind of regional water environment heavy metal monitoring system and operation method, and the system includes management system for monitoring and through GPRS Associated multiple monitoring terminals.Management system for monitoring center processor connection data transmit-receive, Data Analysis Services and data Database management module, is also connected with display/user terminal, GPS, GIS of each monitoring terminal of data transmit-receive module connection storage and The database of heavy metals concentration.The main control module of each monitoring terminal includes embeded processor and clock and GPRS submodules Block, detection module includes temperature sensor and heavy-metal electrochemical sensor array.Operation method surveys water ring by monitoring terminal The temperature and heavy metal concentration in border are sent to management system for monitoring and store and show.Data Analysis Services module is by itself and standard value With historical data contrast, when being that polluted water or certain heavy metal concentration jump and skipped a grade, alarm.
For example a kind of automatic detection of Application No. " 201310164736.8 " and pH soil electro reclamation is controlled to fill Put.The utility model is related to a kind of heavy metal contaminants that are used for and purified and processing unit, and in particular to a kind of automatic detection is simultaneously controlled PH processed soil electro reclamation device, including electro reclamation module, soil pH value sensor, humidity sensor, ZigBee module And processor module;Electro reclamation module includes negative electrode, two electrodes of anode, soil pH meter, device for storing liquid, power supply and ZigBee Module, soil pH meter is connected by probe with negative electrode, two electrodes of anode, and soil pH meter is connected with the control valve on water inlet pipe Connect;Electro reclamation module, soil pH sensor, humidity sensor is connected with processor module respectively;Processor module passes through ZigBee module be connected with extraneous monitoring computer, simple in construction, easy to use, and pH is automatically controlled in achievable electrokinetic process, And then regulate and control the pH value of soil system, by adding ZigBee module, realize and preserved on the Real-time Network of data, facilitate experiment Personnel are checked at any time, improve the efficiency of whole repair.
However, above-mentioned prior art does not solve still during soil remediation due to relevant parameter monitoring, judges to repair Caused by effect sampling, measure content of beary metal the problems such as manual physical, time loss and financial cost increase.
Utility model content
Monitored by relevant parameter during electro reclamation in order to overcome, judge repairing effect sampling, determine content of beary metal Caused by manual physical, time loss and the problems such as financial cost increase, the utility model discloses a kind of electro reclamation weight Metallic pollution soil shows system, and the system can be realized during the visualization of electro reclamation, dynamic continuous monitoring electro reclamation Multinomial technical parameter, can realize to electric-field intensity, electrical conductivity, pH value, redox potential, temperature, moisture content and soil Detection, processing, display and the storage of Interstitial Water heavy metal concentration etc., and sampling is needed according to client.
The utility model takes following technical scheme to solve above-mentioned technical problem:
A kind of electro reclamation heavy-metal contaminated soil shows system, and it is single comprising testing agency, real-time sampling device, transmission Member, processing unit, display device, record memory device and feedback device;Transmission unit difference connecting detection mechanism, in real time Sampling apparatus and processing unit, the processing unit are connected with display device, and the display device is connected with record memory device; The feedback device connects processing unit and electro reclamation device respectively.
Further, the testing agency includes detection case, pH/Eh sensors, soil conductivity sensor, PT1000 temperature Spend sensor, soil moisture sensor, voltage sensor, heavy-metal electrochemical sensor array, current sensor and electric current mutual Sensor, the pH/Eh sensors, PT1000 temperature sensors and heavy-metal electrochemical sensor array apparatus in detection case, The soil conductivity sensor, soil moisture sensor, voltage sensor, current sensor, current transformer device are in inspection Measuring tank is external.
Further, the detection case includes offering on polytetrafluoroethylene (PTFE) shell and liner, the tetrafluoroethene shell Some a diameter of 3 millimeters of through hole, the liner is fitted on the inwall of polytetrafluoroethylene (PTFE) shell, and liner is that filter opening diameter is equal to 0.45 micron of filter membrane.
Further, described pH/Eh sensors include stainless steel material probe and built-in field-effect transistor ion sense Answer silicon, the built-in field-effect transistor ion sensing silicon of stainless steel material probe connection.
Further, the real-time sampling device includes timer, positioner, weighing scale device and sampling apparatus, The sampling apparatus connects timer, positioner and weighing scale device respectively.
Further, the processing unit includes data reception module, Data Integration processing module, database module sum According to sending module;The data reception module is connected at transmission unit and Data Integration processing module, the Data Integration respectively Reason module connects database module and data transmission blocks respectively, and the data transmission blocks connect display device and feedback respectively Device.
Further, the display device is touch display screen.
Further, the feedback device includes switch and warning device, and the switch and warning device distinguish junction Manage unit.
Technique effect of the present utility model is embodied in:
(1)A kind of detecting system for electro reclamation device is proposed first, is provided for contaminated soil electromotion repairing technique A kind of reparation situation for being easy to monitoring in real time and automatic record varying level and upright position soil, for understanding soil in real time Reparation situation, the labor workload for improving electrokinetic remediation efficiency, reducing monitoring soil remediation, reduction maintenance cost have important meaning Justice.
(2)The utility model can be realized by probe to optional position electric-field intensity in electro reclamation treatment box, pH value, Eh values, moisture content, the detection of temperature and soil gap water heavy metal concentration, display and are stored, and are easy to later data to handle;Automatically Sampling system realizes the real-time sampling in repair process, is easy to later stage test analysis.
(3)The utility model can set parameters threshold value in repair process, give and feed back more than threshold value, reduce electricity The loss of energy, extends electro reclamation device lifetime.
Brief description of the drawings
Fig. 1 is the utility model principle schematic diagram.
1. testing agency, 2. real-time sampling devices, 3. transmission units, 4. processing units, 5. display devices, 6. record storages Device, 7. feedback devices, 8. electro reclamation devices.
Embodiment
The utility model feature is described in further detail with accompanying drawing with reference to embodiments:
As shown in figure 1, the utility model is arranged on electro reclamation device 8, the utility model includes testing agency 1, reality When sampling apparatus 2, transmission unit 3, processing unit 4, display device 5, record memory device 6 and feedback device 7.Transmission unit 3 Difference connecting detection mechanism 1, real-time sampling device 2 and processing unit 4, processing unit 4 connects display device 5 respectively and feedback is filled 7 are put, display device 5 is connected with record memory device 6;Feedback device 7 is also connected with electro reclamation dress in addition to connecting processing unit 4 Put 8.
Testing agency 1 is used for electric-field intensity during electro reclamation, electrical conductivity, pH value, redox potential, temperature, contained The data determination such as water rate and soil gap water heavy metal concentration.Real-time sampling device 2 for adopting during electro reclamation automatically Sample.Testing agency 1, real-time sampling device 2 are connected by transmission unit 3 with processing unit 4, by testing agency 1 and real-time sampling system The electric signal transmission of system 2 is to processing unit 4.Processing unit 4 completes following work:1)Processing detection signal and sampled signal simultaneously will These signals are converted to numerical value, chart and word, are shown on a display screen according to customer demand;2)By weight in the current aqueous solution Metal concentration data are contrasted with heavy metals concentration rank in the database stored, the aqueous solution during electro reclamation When middle concentration of heavy metal ion is less than setting concentration standard, signal is sent on a display screen, point out to repair successfully;3)Set soil Temperature, moisture content, the scope of pH value, when beyond threshold value, send a signal to feedback device 7 and display device 5 complete alarm, sound Bell and presentation of information.Display device 5 is used to show word or chart.Record memory device 6 be used for by Site Detection gather it is big Data storage is measured in mobile hard disk or mobile workstation, copy and post-processing is available for.Feedback device 7 is used to feed back electronic repair The information of multiple process.
(1)Testing agency 1 includes such as lower sensor:Detection case, pH/Eh sensors, soil conductivity sensor, PT1000 Temperature sensor, soil moisture sensor, voltage sensor, heavy-metal electrochemical sensor array 11, current sensor and electricity Current transformer.Detection case includes offering the logical of some a diameter of 3mm on polytetrafluoroethylene (PTFE) shell and liner, tetrafluoroethene shell Hole, liner is fitted on the inwall of tetrafluoroethene shell, and liner is the filter membrane of a diameter of 0.45 micron of filter opening.PH/Eh sensors, PT1000 temperature sensors, the sensor probe of heavy-metal electrochemical sensor array are inserted into detection case and detected;Soil Earth conductivity sensor, soil moisture sensor, voltage sensor, current sensor summation current transformer sensor probe are direct Detected in insertion soil.
Testing agency 1 determines direct current and AC current by current sensor summation current transformer;Passed by voltage Sensor determines direct current and alternating current voltage;Electric-field intensity is obtained by voltage and distance value conversion;Passed by soil conductivity Sensor determines electrical conductivity;Pass through PT1000 temperature sensor measurement temperature;Moisture content is determined by soil moisture sensor;Pass through PH/Eh sensors determine soil pH and oxidation-reduction potential;Soil gap is determined by heavy-metal electrochemical sensor array 11 Water heavy metal ion concentration.
Under electro reclamation device powering-off state, the pH/Eh sensors, soil conductivity sensor, PT1000 temperature Sensor, soil moisture sensor and heavy-metal electrochemical sensor array 11 bring into operation work;It is logical in electro reclamation device In the case of electricity, the voltage sensor, current sensor, current transformer operation work;Electric-field strength is determined at regular intervals Degree, electrical conductivity, pH value, redox potential, temperature, moisture content and soil gap water heavy metal concentration value.
Soil pH value and oxidation-reduction potential are determined by pH/Eh sensors, and the sensor is by stainless steel material probe With built-in field-effect transistor ion sense silicon group into.Soil gap water heavy metal ion concentration passes through heavy metal electrochemistry Sensor array is determined.Heavy-metal electrochemical sensor array include Signal-regulated kinase, data reception module and lead, cadmium, The heavy-metal electrochemical sensor array of mercury, cupric ion electrode.Lead, cadmium, mercury, copper ion in heavy-metal electrochemical sensor array The electrical signal access signal conditioning circuit of electrode, after the signal is filtered and nursed one's health through signal conditioning circuit, accesses data Receiving module.
(2)Real-time sampling device 2 is the sampling time and sampling quantity timing sampling set according to client.Real-time sampling device Including timer, positioner, weighing scale device and sampling apparatus.One of which sampling layouts set-up mode to be uniformly distributed In soil remediation treatment box, sampling time interval is set to 30min-2h, and sampling quantity is set to 50-100g.
(3)Testing agency 1, real-time sampling device 2 are connected by transmission unit 3 with processing unit 4, by testing agency 1 and in fact When sampling apparatus 2 electric signal transmission to processing unit 4.
(4)Processing unit 4 includes data reception module, Data Integration processing module, database module and data and sends mould Block;Data reception module connects transmission unit 3 and Data Integration processing module respectively, and Data Integration processing module connects number respectively According to library module and data transmission blocks, data transmission blocks connect display device 5 and feedback device 7 respectively.Data Integration processing Data Centralized Processing of the module to collection.Heavy metal concentration value or the standard No. that is stored with database both comprising history measure are GB38382002 chinese national standard《Water environment quality standard》The concentration value that middle heavy metals allow.
(5)Display device 5 uses the described unit of display for touch display screen, for showing electric-field intensity, voltage, electricity Concentration of heavy metal ion and other analyses in stream, electrical conductivity, pH value, redox potential, temperature, moisture content data, time, water Data, image or pattern information, can be achieved different display parameters changing interface functions.
(6)The mass data that record memory device 6 is used to gather Site Detection is stored in mobile hard disk or mobile work In standing.
(7)Feedback device 7 includes switch and warning device, is powered using alternating current 220V.Feedback device 7 is used for anti- The information of the dynamic repair process of feed, mainly including following several feedback informations:
1)Soil moisture optimal varied scope is 0-80 DEG C, and when temperature >=95 DEG C, processing unit 4 sends signal extremely respectively Display device 5 and feedback device 7, make to switch off electro reclamation device 8 automatically power off, warning device send " dichloro-diphenyl-dichlorothane " alarm Simultaneously " temperature is too high " printed words are presented in sound on a display screen;
2)Soil moisture content optimal varied scope is 30-80%, and when soil moisture content≤20%, processing unit 4 is sent out respectively Go out signal to display device 5 and feedback device 7, make to switch off that electro reclamation device is automatically powered off, warning device sends " drop drop Simultaneously " antecedent soil moisture please add water " printed words are presented in drop " alarm song on a display screen;
3)Soil pH value optimal varied scope in the 0-1/3 electrolytic cell length ranges near negative electrode is 4-8, works as soil During earth pH >=12.5, processing unit 4 sends signal to display device 5 and feedback device 7 respectively, makes to switch off electro reclamation dress Put automatically power off, warning device send " dichloro-diphenyl-dichlorothane " alarm song and display screen present " pH crosses alkali near negative electrode ";
4)The concentration of heavy metal ion of soil gap water reaches in the 0-1/5 electrolytic cell length ranges near negative electrode The reparation threshold value of setting, processing unit 4 sends signal to display device 5 and feedback device 7 respectively, makes to switch off electro reclamation Device is automatically powered off, warning device send " dichloro-diphenyl-dichlorothane " alarm song and display screen present " repair complete, please detect soil a huge sum of money Belong to concentration ".Wherein the concentration of heavy metal ion of soil gap water is repaired threshold value and referred to《Water environment quality standard GB3838-2002》Or the historical data that user has stored.
The detecting system one of which course of work for electro reclamation device is as follows:
1)According to user's request, qualitative repairing polluted soil is shown that default is:Electro reclamation system operation work 4 Hour after, testing agency 1 every 30 minutes determine electric-field intensity, electrical conductivity, pH value, redox potential, temperature, moisture content and The data such as soil gap water heavy metal concentration, real-time sampling device 2 was every 1 hour collection sample 50g.
2)By the electric signal transmission of testing agency 1 and real-time sampling device 2 to processing unit 4.Processing unit 4 is by electric-field strength Degree, electrical conductivity, pH value, redox potential, temperature, moisture content and soil gap water heavy metal concentration data split screen display available, and Heavy metal concentration data in the current aqueous solution are contrasted with heavy metals concentration rank in the database of storage.
3)When concentration of heavy metal ion is less than setting concentration standard in the aqueous solution during electro reclamation, sends signal and exist Show screen display reparation success.Meanwhile, the mass data that Site Detection is gathered is stored in mobile working by record memory device 6 In standing.
The utility model is realized to optional position electricity in electro reclamation treatment box by the effective integration to multiple sensors Field intensity, pH value, Eh values, moisture content, the detection of temperature and soil gap water heavy metal concentration, display and store, be easy to the later stage Data processing;Threshold value is achieved over to automatically power off and alarm function.This is used for the detecting system of electro reclamation device to real-time Solution soil remediation situation, the labor workload for improving electrokinetic remediation efficiency, reducing monitoring soil remediation, reduction maintenance cost have weight Want meaning.
Above example is only explanation technological thought of the present utility model, it is impossible to limit protection model of the present utility model with this Enclose, it is every according to the utility model proposes technological thought, any change done on the basis of technical scheme each falls within this reality Within the scope of novel protected.Embodiment of the present utility model is explained in detail above in conjunction with accompanying drawing, but this practicality It is new to be not limited to above-mentioned embodiment, in the knowledge that those of ordinary skill in the art possess, can also or else it take off Made a variety of changes on the premise of from the utility model objective.

Claims (8)

1. a kind of detecting system for electro reclamation device, it is characterised in that:It includes testing agency(1), real-time sampling dress Put(2), transmission unit(3), processing unit(4), display device(5), record memory device(6)And feedback device(7);It is described to pass Defeated unit(3)Difference connecting detection mechanism(1), real-time sampling device(2)And processing unit(4), the processing unit(4)With showing Showing device(5)Connection, the display device(5)With record memory device(6)Connection;The feedback device(7)Difference junction Manage unit(4)With electro reclamation device(8).
2. the detecting system according to claim 1 for electro reclamation device, it is characterised in that:The testing agency (1)Including detection case, pH/Eh sensors, soil conductivity sensor, PT1000 temperature sensors, soil moisture sensor, electricity Pressure sensor, heavy-metal electrochemical sensor array, current sensor summation current transformer, the pH/Eh sensors, PT1000 Temperature sensor and heavy-metal electrochemical sensor array apparatus are in detection case, the soil conductivity sensor, the soil water Sub-sensor, voltage sensor, current sensor, that current transformer is arranged on detection case is external.
3. the detecting system according to claim 2 for electro reclamation device, it is characterised in that:The detection case includes Some a diameter of 3 millimeters of through hole, the liner patch are offered on polytetrafluoroethylene (PTFE) shell and liner, the tetrafluoroethene shell Close on the inwall of polytetrafluoroethylene (PTFE) shell, liner is the filter membrane that filter opening diameter is equal to 0.45 micron.
4. the detecting system according to claim 2 for electro reclamation device, it is characterised in that:Described pH/Eh is passed Sensor includes stainless steel material probe and built-in field-effect transistor ion sensing silicon, the stainless steel material probe connection Built-in field-effect transistor ion senses silicon.
5. the detecting system according to claim 1 for electro reclamation device, it is characterised in that:The real-time sampling dress Put(2)Including timer, positioner, weighing scale device and sampler, the sampling apparatus connects timer, positioning respectively Device and weighing scale device.
6. the detecting system according to claim 1 for electro reclamation device, it is characterised in that:The processing unit (4)Including data reception module, Data Integration processing module, database module and data transmission blocks;The data reception Block connects transmission unit respectively(3)With Data Integration processing module, the Data Integration processing module connects database mould respectively Block and data transmission blocks, the data transmission blocks connect display device respectively(5)And feedback device(7).
7. the detecting system according to claim 1 for electro reclamation device, it is characterised in that:The display device (5)For touch display screen.
8. the detecting system according to claim 1 for electro reclamation device, it is characterised in that:The feedback device (7)Comprising switch and warning device, the switch and warning device connect processing unit respectively(4).
CN201720051723.3U 2017-01-17 2017-01-17 Detection system for electric repair device Active CN206464339U (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108746183A (en) * 2018-03-30 2018-11-06 中冶华天南京工程技术有限公司 Heavy-metal contaminated soil in-situ intelligent repair system
CN109304361A (en) * 2018-10-11 2019-02-05 西安科技大学 Heavy-metal contaminated soil electro reclamation analogy method
CN111842456A (en) * 2020-07-28 2020-10-30 吉林省环境科学研究院 Novel soil treatment system
CN113477698A (en) * 2020-11-27 2021-10-08 苏州精英环保有限公司 Intelligent monitoring platform of normal temperature desorption repair equipment

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108746183A (en) * 2018-03-30 2018-11-06 中冶华天南京工程技术有限公司 Heavy-metal contaminated soil in-situ intelligent repair system
CN109304361A (en) * 2018-10-11 2019-02-05 西安科技大学 Heavy-metal contaminated soil electro reclamation analogy method
CN111842456A (en) * 2020-07-28 2020-10-30 吉林省环境科学研究院 Novel soil treatment system
CN113477698A (en) * 2020-11-27 2021-10-08 苏州精英环保有限公司 Intelligent monitoring platform of normal temperature desorption repair equipment
CN113477698B (en) * 2020-11-27 2022-03-29 苏州精英环保有限公司 Intelligent monitoring platform of normal temperature desorption repair equipment

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