CN206204065U - A kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus - Google Patents
A kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus Download PDFInfo
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- CN206204065U CN206204065U CN201621184923.8U CN201621184923U CN206204065U CN 206204065 U CN206204065 U CN 206204065U CN 201621184923 U CN201621184923 U CN 201621184923U CN 206204065 U CN206204065 U CN 206204065U
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- 239000002351 wastewater Substances 0.000 title claims abstract description 31
- 241000276438 Gadus morhua Species 0.000 title claims abstract description 30
- 235000019516 cod Nutrition 0.000 title claims abstract description 30
- 238000005039 chemical industry Methods 0.000 title claims abstract description 25
- -1 iron-carbon Chemical compound 0.000 claims abstract description 51
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances data:image/svg+xml;base64,PD94bWwgdmVyc2lvbj0nMS4wJyBlbmNvZGluZz0naXNvLTg4NTktMSc/Pgo8c3ZnIHZlcnNpb249JzEuMScgYmFzZVByb2ZpbGU9J2Z1bGwnCiAgICAgICAgICAgICAgeG1sbnM9J2h0dHA6Ly93d3cudzMub3JnLzIwMDAvc3ZnJwogICAgICAgICAgICAgICAgICAgICAgeG1sbnM6cmRraXQ9J2h0dHA6Ly93d3cucmRraXQub3JnL3htbCcKICAgICAgICAgICAgICAgICAgICAgIHhtbG5zOnhsaW5rPSdodHRwOi8vd3d3LnczLm9yZy8xOTk5L3hsaW5rJwogICAgICAgICAgICAgICAgICB4bWw6c3BhY2U9J3ByZXNlcnZlJwp3aWR0aD0nMzAwcHgnIGhlaWdodD0nMzAwcHgnIHZpZXdCb3g9JzAgMCAzMDAgMzAwJz4KPCEtLSBFTkQgT0YgSEVBREVSIC0tPgo8cmVjdCBzdHlsZT0nb3BhY2l0eToxLjA7ZmlsbDojRkZGRkZGO3N0cm9rZTpub25lJyB3aWR0aD0nMzAwLjAnIGhlaWdodD0nMzAwLjAnIHg9JzAuMCcgeT0nMC4wJz4gPC9yZWN0Pgo8dGV4dCB4PScxMDAuNScgeT0nMTcwLjAnIGNsYXNzPSdhdG9tLTAnIHN0eWxlPSdmb250LXNpemU6NDBweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID5IPC90ZXh0Pgo8dGV4dCB4PScxMjYuMScgeT0nMTg2LjAnIGNsYXNzPSdhdG9tLTAnIHN0eWxlPSdmb250LXNpemU6MjZweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID4yPC90ZXh0Pgo8dGV4dCB4PScxMzguMCcgeT0nMTcwLjAnIGNsYXNzPSdhdG9tLTAnIHN0eWxlPSdmb250LXNpemU6NDBweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID5PPC90ZXh0Pgo8L3N2Zz4K data:image/svg+xml;base64,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 O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 29
- 230000003647 oxidation Effects 0.000 claims abstract description 28
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 28
- 238000005273 aeration Methods 0.000 claims abstract description 27
- 238000005189 flocculation Methods 0.000 claims abstract description 14
- 230000016615 flocculation Effects 0.000 claims abstract description 14
- 239000003513 alkali Substances 0.000 claims abstract description 11
- 239000003054 catalyst Substances 0.000 claims abstract description 7
- 235000012773 waffles Nutrition 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 19
- MHAJPDPJQMAIIY-UHFFFAOYSA-N hydrogen peroxide Chemical compound data:image/svg+xml;base64,PD94bWwgdmVyc2lvbj0nMS4wJyBlbmNvZGluZz0naXNvLTg4NTktMSc/Pgo8c3ZnIHZlcnNpb249JzEuMScgYmFzZVByb2ZpbGU9J2Z1bGwnCiAgICAgICAgICAgICAgeG1sbnM9J2h0dHA6Ly93d3cudzMub3JnLzIwMDAvc3ZnJwogICAgICAgICAgICAgICAgICAgICAgeG1sbnM6cmRraXQ9J2h0dHA6Ly93d3cucmRraXQub3JnL3htbCcKICAgICAgICAgICAgICAgICAgICAgIHhtbG5zOnhsaW5rPSdodHRwOi8vd3d3LnczLm9yZy8xOTk5L3hsaW5rJwogICAgICAgICAgICAgICAgICB4bWw6c3BhY2U9J3ByZXNlcnZlJwp3aWR0aD0nMzAwcHgnIGhlaWdodD0nMzAwcHgnIHZpZXdCb3g9JzAgMCAzMDAgMzAwJz4KPCEtLSBFTkQgT0YgSEVBREVSIC0tPgo8cmVjdCBzdHlsZT0nb3BhY2l0eToxLjA7ZmlsbDojRkZGRkZGO3N0cm9rZTpub25lJyB3aWR0aD0nMzAwLjAnIGhlaWdodD0nMzAwLjAnIHg9JzAuMCcgeT0nMC4wJz4gPC9yZWN0Pgo8cGF0aCBjbGFzcz0nYm9uZC0wIGF0b20tMCBhdG9tLTEnIGQ9J00gMTA1LjcsMTUwLjAgTCAxOTUuNSwxNTAuMCcgc3R5bGU9J2ZpbGw6bm9uZTtmaWxsLXJ1bGU6ZXZlbm9kZDtzdHJva2U6I0U4NDIzNTtzdHJva2Utd2lkdGg6Mi4wcHg7c3Ryb2tlLWxpbmVjYXA6YnV0dDtzdHJva2UtbGluZWpvaW46bWl0ZXI7c3Ryb2tlLW9wYWNpdHk6MScgLz4KPHRleHQgeD0nMTAuMicgeT0nMTcwLjAnIGNsYXNzPSdhdG9tLTAnIHN0eWxlPSdmb250LXNpemU6NDBweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID5IPC90ZXh0Pgo8dGV4dCB4PSczNS44JyB5PScxNzAuMCcgY2xhc3M9J2F0b20tMCcgc3R5bGU9J2ZvbnQtc2l6ZTo0MHB4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO3RleHQtYW5jaG9yOnN0YXJ0O2ZpbGw6I0U4NDIzNScgPk88L3RleHQ+Cjx0ZXh0IHg9JzIzOS45JyB5PScxNzAuMCcgY2xhc3M9J2F0b20tMScgc3R5bGU9J2ZvbnQtc2l6ZTo0MHB4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO3RleHQtYW5jaG9yOnN0YXJ0O2ZpbGw6I0U4NDIzNScgPk88L3RleHQ+Cjx0ZXh0IHg9JzI2Ny41JyB5PScxNzAuMCcgY2xhc3M9J2F0b20tMScgc3R5bGU9J2ZvbnQtc2l6ZTo0MHB4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO3RleHQtYW5jaG9yOnN0YXJ0O2ZpbGw6I0U4NDIzNScgPkg8L3RleHQ+Cjwvc3ZnPgo= data:image/svg+xml;base64,PD94bWwgdmVyc2lvbj0nMS4wJyBlbmNvZGluZz0naXNvLTg4NTktMSc/Pgo8c3ZnIHZlcnNpb249JzEuMScgYmFzZVByb2ZpbGU9J2Z1bGwnCiAgICAgICAgICAgICAgeG1sbnM9J2h0dHA6Ly93d3cudzMub3JnLzIwMDAvc3ZnJwogICAgICAgICAgICAgICAgICAgICAgeG1sbnM6cmRraXQ9J2h0dHA6Ly93d3cucmRraXQub3JnL3htbCcKICAgICAgICAgICAgICAgICAgICAgIHhtbG5zOnhsaW5rPSdodHRwOi8vd3d3LnczLm9yZy8xOTk5L3hsaW5rJwogICAgICAgICAgICAgICAgICB4bWw6c3BhY2U9J3ByZXNlcnZlJwp3aWR0aD0nODVweCcgaGVpZ2h0PSc4NXB4JyB2aWV3Qm94PScwIDAgODUgODUnPgo8IS0tIEVORCBPRiBIRUFERVIgLS0+CjxyZWN0IHN0eWxlPSdvcGFjaXR5OjEuMDtmaWxsOiNGRkZGRkY7c3Ryb2tlOm5vbmUnIHdpZHRoPSc4NS4wJyBoZWlnaHQ9Jzg1LjAnIHg9JzAuMCcgeT0nMC4wJz4gPC9yZWN0Pgo8cGF0aCBjbGFzcz0nYm9uZC0wIGF0b20tMCBhdG9tLTEnIGQ9J00gMjYuMyw0Mi4wIEwgNTcuNyw0Mi4wJyBzdHlsZT0nZmlsbDpub25lO2ZpbGwtcnVsZTpldmVub2RkO3N0cm9rZTojRTg0MjM1O3N0cm9rZS13aWR0aDoxLjBweDtzdHJva2UtbGluZWNhcDpidXR0O3N0cm9rZS1saW5lam9pbjptaXRlcjtzdHJva2Utb3BhY2l0eToxJyAvPgo8dGV4dCB4PSczLjQnIHk9JzUwLjgnIGNsYXNzPSdhdG9tLTAnIHN0eWxlPSdmb250LXNpemU6MTdweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID5IPC90ZXh0Pgo8dGV4dCB4PScxNC42JyB5PSc1MC44JyBjbGFzcz0nYXRvbS0wJyBzdHlsZT0nZm9udC1zaXplOjE3cHg7Zm9udC1zdHlsZTpub3JtYWw7Zm9udC13ZWlnaHQ6bm9ybWFsO2ZpbGwtb3BhY2l0eToxO3N0cm9rZTpub25lO2ZvbnQtZmFtaWx5OnNhbnMtc2VyaWY7dGV4dC1hbmNob3I6c3RhcnQ7ZmlsbDojRTg0MjM1JyA+TzwvdGV4dD4KPHRleHQgeD0nNTguNycgeT0nNTAuOCcgY2xhc3M9J2F0b20tMScgc3R5bGU9J2ZvbnQtc2l6ZToxN3B4O2ZvbnQtc3R5bGU6bm9ybWFsO2ZvbnQtd2VpZ2h0Om5vcm1hbDtmaWxsLW9wYWNpdHk6MTtzdHJva2U6bm9uZTtmb250LWZhbWlseTpzYW5zLXNlcmlmO3RleHQtYW5jaG9yOnN0YXJ0O2ZpbGw6I0U4NDIzNScgPk88L3RleHQ+Cjx0ZXh0IHg9JzcwLjgnIHk9JzUwLjgnIGNsYXNzPSdhdG9tLTEnIHN0eWxlPSdmb250LXNpemU6MTdweDtmb250LXN0eWxlOm5vcm1hbDtmb250LXdlaWdodDpub3JtYWw7ZmlsbC1vcGFjaXR5OjE7c3Ryb2tlOm5vbmU7Zm9udC1mYW1pbHk6c2Fucy1zZXJpZjt0ZXh0LWFuY2hvcjpzdGFydDtmaWxsOiNFODQyMzUnID5IPC90ZXh0Pgo8L3N2Zz4K OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- 238000011001 backwashing Methods 0.000 claims description 13
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances 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OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 9
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- 229920002401 polyacrylamide Polymers 0.000 claims description 7
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- 229910052904 quartz Inorganic materials 0.000 claims description 4
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- 238000006731 degradation reaction Methods 0.000 abstract description 2
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- 230000035418 detection of UV Effects 0.000 abstract 1
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- 239000003795 chemical substances by application Substances 0.000 description 3
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- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
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- 238000010926 purge Methods 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 231100000614 Poison Toxicity 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000003197 catalytic Effects 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
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- 238000006011 modification reaction Methods 0.000 description 1
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- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
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- 238000004062 sedimentation Methods 0.000 description 1
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Abstract
The utility model provides a kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus, including passes sequentially through intermediate pool, iron-carbon micro-electrolysis reactor, aeration oxidation pool, flocculation tank, tube settler, ultraviolet reaction tank and clear water reserviors that aqueduct links together.PH online detection instruments, throwing dispensing equipment, automatic control equipment pooled applications are realized reacting iron carbon the precise control of PH by this patent, improve the efficiency of iron carbon reaction；Fe is removed by adding alkali, oxidation, flocculation sediment2+, it is lowered into the interference of turbidity and follow-up the COD detection of UV reactors；Air dissolved pump provides oxygen for UV reactions, while playing stirring homogenizing water quality；Waffle slab catalyst removes COD with uviol lamp collective effect depth, green, efficient.Structure of the present utility model and process efficient reliability, operation and easy maintenance, it is adaptable to the COD advanced treatings of difficult degradation wastewater from chemical industry.
Description
Technical field
The utility model is related to a kind of chemical wastewater treatment device, especially a kind of simple and reliable for structure, designs ingenious, work
Make the new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of efficiency high.
Background technology
Current country chemical industrial park enters that the universal smaller, product scope of scope of the enterprise is narrow, technology content is not high, due to life
Production. art level is not high, and waste water recycling device operation simply even lacks, and causes wastewater from chemical industry following characteristics：Water-quality constituents is answered
It is miscellaneous, it is often solvent material and cyclic structure compound；Poisonous and harmful substance is more, such as halogen compounds, nitro compound；B/
Than low, biodegradability is poor, bio-refractory for C；Chroma in waste water is high.
More to the processing method of low biodegradability wastewater from chemical industry both at home and abroad, general handling process is：Pretreatment-raw
Change treatment-advanced treating.Because B/C is than low, complicated component, there is the stronger suppression property made to microbial activity, biochemical treatment
Limitation, could will further reduce COD concentration in waste water by advanced treating, and conventional further treatment technique is mainly sweet smell
, iron-carbon micro-electrolysis, photochemical catalytic oxidation.
Fenton technology has the advantages that process is simple, reaction speed are fast, can produce flocculation, but chemical feeding quantity is big, work
Intensity is big；Sludge output is more, high cost；The corrosivity for the treatment of agent is big, and cement can all be corroded.Iron-carbon micro-electrolysis technology should
Wide with scope, processing cost is low, easy to operate, but it is low to there is filler utilization rate, easily hardened to produce passivation；Reaction condition is (main
If PH) bad control；The low shortcoming for the treatment of effect.The reaction condition of photocatalysis oxidation technique is simple, and the reaction time is short；Reaction
Efficiently, thoroughly (product is CO2、H2O, acid, inorganic salts etc.)；Consumption of chemical agent is few, it is to avoid secondary pollution；Cost of investment is low
Advantage.But exist (turbidity is very low) high to the water quality requirement intake；The efficiency of catalyst is not universal high, and light source selection does not conform to
Reason, the shortcomings of cause operating cost high.
Utility model content
To solve the above problems, the utility model provides a kind of simple structure, designs ingenious, high working efficiency new
Low biodegradability wastewater from chemical industry COD advanced treatment apparatus.
Realize a kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of the utility model purpose, including according to
The secondary intermediate pool linked together by aqueduct, iron-carbon micro-electrolysis reactor, aeration oxidation pool, flocculation tank, tiltedly
Pipe sedimentation basin, ultraviolet reaction tank and clear water reserviors.
A number elevator pump is installed on the aqueduct between the intermediate pool and iron-carbon micro-electrolysis reactor；
An online PH meter and concentrated sulfuric acid adding set, the iron carbon are provided with above the iron-carbon micro-electrolysis reactor
The inside of micro-electrolysis reactor is filled with iron carbon filler, and the bottom of the iron-carbon micro-electrolysis reactor is provided with iron-carbon micro-electrolysis bottom
Portion's aerator, cushion is provided with the middle part of the iron-carbon micro-electrolysis reactor；
The side wall of the aeration oxidation pool is provided with air blower, the air blower connection iron-carbon micro-electrolysis bottom aeration dress
Put；
It is connected with by pipe-line mixer on aqueduct between the iron-carbon micro-electrolysis reactor and aeration oxidation pool
Alkali lye dosing apparatus；
No. two PH meters and hydrogen peroxide throwing device, the bottom of the aeration oxidation pool are provided with above the aeration oxidation pool
Portion is provided with the aeration head being connected with air blower；
The top of the flocculation tank is provided with agitator and polyacrylamide dosing apparatus；
The side wall that being delivered in the tube settler has tube settler filler, the tube settler is provided with spoil disposal
Pump；
Air dissolved pump is provided with aqueduct between the tube settler and ultraviolet reaction tank；
The bottom of the ultraviolet reaction tank is provided with the dissolved air release being connected with air dissolved pump, the ultraviolet reaction tank
Be internally provided with waffle slab catalyst, be provided with quartz burner in the middle part of the ultraviolet reaction tank；
The bottom of the clear water reserviors is provided with backwashing pump, and the backwashing pump connects iron carbon back washing device.
A kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus described in this patent, each part is connected simultaneously
PLC control cabinet is simultaneously uniformly controlled operation by it, and waste water is entered intermediate pool, squeezed into by an elevator pump after conventional pretreatment
The bottom of iron-carbon micro-electrolysis reactor, concentrated sulfuric acid adding set is respectively in bottom of pond and stage casing acid adding regulation PH, an online PH meter
Monitor in real time pH value, controls the dosage of sulfuric acid, conveys air by air blower and aeration head and stirs；The reaction water outlet of iron carbon is led to
Cross alkali lye dosing apparatus and add alkali, such as lime or caustic soda to pipe-line mixer, make the Fe of iron carbon water outlet2+It is changed into Fe (OH)2, alkali lye throwing
Dosage counts the data point reuse of feedback by No. 2 online PH, and in aeration oxidation pool by hydrogen peroxide throwing device, addition hydrogen peroxide will
Fe(OH)2It is oxidized to Fe (OH)3, by experiment calmly, the aeration head of air blower and aeration oxidation pool is passed through air oxidation and stirs chemical feeding quantity
Mix；Waste water after oxidation enters flocculation tank, and polyacrylamide dosing apparatus add polyacrylamide, and agitator is carried out at a slow speed
Stirring contributes to flco to be formed；Water after flocculation enters tube settler, and the mud for precipitating is delivered to sludge by sludge pump
Processing system, the water after precipitation is oxygen-enriched by air dissolved pump, is intake in bottom of pond dissolved air release into ultraviolet reaction tank, ultraviolet
Line fluorescent tube and waffle slab catalyst are lower generation redox reaction removal COD jointly；Light-catalysed water outlet enters outside clear water reserviors
Row or reuse.
The iron-carbon micro-electrolysis reactor need to periodically carry out combined water and air backwash, and air purge is supplied by air blower, in iron carbon
The bottom section of micro-electrolysis reactor and stage casing are aerated；Washing is supplied water by the backwashing pump installed in clear water reserviors and iron carbon back washing device,
Conveniently just washed and backwash, the frequency of backwash and time adjust according to influent quality.
This patent realizes to iron carbon reaction PH's PH online detection instruments, throwing dispensing equipment, automatic control equipment pooled applications
Precise control, improves the efficiency of iron carbon reaction；Fe is removed by adding alkali, oxidation, flocculation sediment2+, it is lowered into UV reactors
Turbidity and the interference of follow-up COD detections；Air dissolved pump provides oxygen for UV reactions, while playing stirring homogenizing water quality；Waffle slab is urged
Agent removes COD with uviol lamp collective effect depth, green, efficient.Structure of the present utility model and process efficient reliability, operation
And easy maintenance, it is adaptable to the COD advanced treatings of difficult degradation wastewater from chemical industry.
Brief description of the drawings
Fig. 1 is a kind of structural representation of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of the present utility model
Figure.
Specific embodiment
As shown in figure 1, the new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind of the present utility model, including
Pass sequentially through intermediate pool 1, iron-carbon micro-electrolysis reactor 2, aeration oxidation pool 3, flocculation reaction that aqueduct 8 links together
Pond 4, tube settler 5, ultraviolet reaction tank 6 and clear water reserviors 7.
A number elevator pump 9 is installed on the aqueduct 8 between the intermediate pool 1 and iron-carbon micro-electrolysis reactor 2；
The top of the iron-carbon micro-electrolysis reactor 2 is provided with an online PH and counts 13 and concentrated sulfuric acid adding set 14, institute
The inside of iron-carbon micro-electrolysis reactor 2 is stated filled with iron carbon filler 10, the bottom of the iron-carbon micro-electrolysis reactor 2 is provided with iron
Carbon micro-electrolysis bottom aerator 12, the middle part of the iron-carbon micro-electrolysis reactor 2 is provided with cushion 11；
The side wall of the aeration oxidation pool 3 is provided with air blower 15, and the connection iron-carbon micro-electrolysis of the air blower 15 bottom exposes
Device of air 12；
Connected by pipe-line mixer 16 on aqueduct 8 between the iron-carbon micro-electrolysis reactor 2 and aeration oxidation pool 3
It is connected to alkali lye dosing apparatus 17；
The top of the aeration oxidation pool 3 is provided with No. two PH and counts 18 and hydrogen peroxide throwing device 19, the aerating oxidation
The bottom in pond 3 is provided with the aeration head 20 being connected with air blower 15；
The top of the flocculation tank 4 is provided with agitator 21 and polyacrylamide dosing apparatus 22；
The side wall that being delivered in the tube settler 5 has tube settler filler 24, the tube settler 5 is provided with row
Dredge pump 23；
Air dissolved pump 25 is provided with aqueduct 8 between the tube settler 5 and ultraviolet reaction tank 6；
The bottom of the ultraviolet reaction tank 6 is provided with the dissolved air release 26 being connected with air dissolved pump 25, the ultraviolet
Reaction tank 6 is internally provided with waffle slab catalyst 28, and the middle part of the ultraviolet reaction tank 6 is provided with quartz burner 27；
The bottom of the clear water reserviors 7 is provided with backwashing pump 29, the connection iron carbon of the backwashing pump 29 back washing device 30.
A kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus described in this patent, each part is connected simultaneously
PLC control cabinet 31 is simultaneously uniformly controlled operation by it.
Waste water enters intermediate pool after conventional pretreatment, and the bottom of iron-carbon micro-electrolysis reactor is squeezed into by an elevator pump
Portion, concentrated sulfuric acid adding set in bottom of pond and stage casing acid adding regulation PH, an online PH meters monitor in real time pH value, controls sulfuric acid respectively
Dosage, air is conveyed by air blower and aeration head and is stirred；The reaction water outlet of iron carbon is by alkali lye dosing apparatus to pipeline
Blender adds alkali, such as lime or caustic soda, makes the Fe of iron carbon water outlet2+It is changed into Fe (OH)2, alkali lye dosage is by No. 2 online PH meters
The data point reuse of feedback, in aeration oxidation pool by hydrogen peroxide throwing device, adds hydrogen peroxide by Fe (OH)2It is oxidized to Fe
(OH)3, by experiment calmly, the aeration head of air blower and aeration oxidation pool is passed through air oxidation and stirs chemical feeding quantity；It is useless after oxidation
Water enters flocculation tank, and polyacrylamide dosing apparatus add polyacrylamide, and agitator carries out low rate mixing contributes to wadding
Body is formed；Water after flocculation enters tube settler, and the mud for precipitating is delivered to sludge treating system by sludge pump, precipitation
Water afterwards is oxygen-enriched by air dissolved pump, is intake in bottom of pond dissolved air release into ultraviolet reaction tank, in quartz burner and grid
Plate catalyst is lower generation redox reaction removal COD jointly；Light-catalysed water outlet enters row or reuse outside clear water reserviors.
The iron-carbon micro-electrolysis reactor need to periodically carry out combined water and air backwash, and air purge is supplied by air blower, in iron carbon
The bottom section of micro-electrolysis reactor and stage casing are aerated；Washing is supplied water by the backwashing pump installed in clear water reserviors and iron carbon back washing device,
Conveniently just washed and backwash, the frequency of backwash and time adjust according to influent quality.
Embodiment described above is only that preferred embodiment of the present utility model is described, not to this practicality
New scope is defined, under the premise of the utility model design spirit is not departed from, this area ordinary skill technical staff couple
Various modifications and improvement that technical solutions of the utility model are made, all should fall into the guarantor that claims of the present utility model determine
In the range of shield.
Claims (11)
1. a kind of new low biodegradability wastewater from chemical industry COD advanced treatment apparatus, it is characterised in that including passing sequentially through water-supply-pipe
It is intermediate pool that road links together, iron-carbon micro-electrolysis reactor, aeration oxidation pool, flocculation tank, tube settler, ultraviolet
Line reaction tank and clear water reserviors.
2. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In being provided with an elevator pump on the aqueduct between the intermediate pool and iron-carbon micro-electrolysis reactor.
3. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In being provided with an online PH meter and concentrated sulfuric acid adding set, the micro- electricity of iron carbon above the iron-carbon micro-electrolysis reactor
The inside for solving reactor is filled with iron carbon filler, and the bottom of the iron-carbon micro-electrolysis reactor is provided with the exposure of iron-carbon micro-electrolysis bottom
Device of air, cushion is provided with the middle part of the iron-carbon micro-electrolysis reactor.
4. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In the side wall of the aeration oxidation pool is provided with air blower, the air blower connection iron-carbon micro-electrolysis bottom aerator.
5. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In, on the aqueduct between the iron-carbon micro-electrolysis reactor and aeration oxidation pool by pipe-line mixer be connected with alkali lye throw
With device.
6. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In, No. two PH meters and hydrogen peroxide throwing device are provided with above the aeration oxidation pool, the bottom of the aeration oxidation pool sets
It is equipped with the aeration head being connected with air blower.
7. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In the top of the flocculation tank is provided with agitator and polyacrylamide dosing apparatus.
8. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In the side wall that being delivered in the tube settler has tube settler filler, the tube settler is provided with sludge pump.
9. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In being provided with air dissolved pump on the aqueduct between the tube settler and ultraviolet reaction tank.
10. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
The bottom of, the ultraviolet reaction tank is provided with the dissolved air release being connected with air dissolved pump, the ultraviolet reaction tank it is interior
Portion is provided with waffle slab catalyst, and quartz burner is provided with the middle part of the ultraviolet reaction tank.
The 11. new low biodegradability wastewater from chemical industry COD advanced treatment apparatus of one kind according to claim 1, its feature exists
In the bottom of the clear water reserviors is provided with backwashing pump, and the backwashing pump connects iron carbon back washing device.
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|---|---|---|---|
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107399799A (en) * | 2017-07-28 | 2017-11-28 | 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 | A kind of method for eliminating fracturing outlet liquid measure COD disturbing factors |
| CN109179811A (en) * | 2018-10-17 | 2019-01-11 | 四川凯沃环保科技有限公司 | A kind of advanced synergistic oxidation reaction unit of industrial wastewater and technique |
-
2016
- 2016-10-28 CN CN201621184923.8U patent/CN206204065U/en active Active
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107399799A (en) * | 2017-07-28 | 2017-11-28 | 中国石油集团川庆钻探工程有限公司长庆井下技术作业公司 | A kind of method for eliminating fracturing outlet liquid measure COD disturbing factors |
| CN109179811A (en) * | 2018-10-17 | 2019-01-11 | 四川凯沃环保科技有限公司 | A kind of advanced synergistic oxidation reaction unit of industrial wastewater and technique |
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