CN206184422U - A polymeric kettle for vinylidene chloride production - Google Patents

A polymeric kettle for vinylidene chloride production Download PDF

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Publication number
CN206184422U
CN206184422U CN201620676500.1U CN201620676500U CN206184422U CN 206184422 U CN206184422 U CN 206184422U CN 201620676500 U CN201620676500 U CN 201620676500U CN 206184422 U CN206184422 U CN 206184422U
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China
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kettle
blade
vingon
chuck
diameter
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Inventor
王洁
汤阳
项伟
陈欣
楼敏
阙素华
吴志刚
祝龙信
余云飞
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ZHEJIANG QUZHOU JUSU CHEMICAL INDUSTRY Co Ltd
Zhejiang Juhua Co Ltd Electrochemical Plant
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ZHEJIANG QUZHOU JUSU CHEMICAL INDUSTRY Co Ltd
Zhejiang Juhua Co Ltd Electrochemical Plant
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Abstract

The utility model discloses a polymeric kettle for vinylidene chloride production, the cauldron body including perpendicular installation, the internal agitator that is provided with of cauldron, the agitator is become in the epaxial paddle fabric of stirring with setting up by the (mixing) shaft, the (mixing) shaft upper end is connected with transmission, the straight section of thick bamboo section of the cauldron body is provided with the screw clamp cover that can make the cooling water rise along the external wall spiral shell screwing in of cauldron, the screw clamp cover is provided with jacket water (J. W. ) export and jacket water (J. W. ) import, the jacket water (J. W. ) import sets up in cauldron body lower part, the jacket water (J. W. ) export sets up on cauldron body upper portion, the cauldron is internal to be provided with interior cold tub, interior cold pipe one end is stretched out to the outside of the cauldron body from the internal wall of cauldron. The utility model has the advantages of rational in infrastructure, mass transfer heat transmission effect is good, glue all right, the high -efficient economy of cauldron, product quality stable, unit volume output is high.

Description

A kind of polymeric kettle for Vingon production
Technical field
The utility model is related to Vingon field, and in particular, the utility model is related to a kind of for gathering inclined chlorine The polymeric kettle of ethylene production.
Background technology
The key component of polyvinylidene chloride (abbreviation PVDC) is vinylidene chloride (VDC), due to symmetrical molecule The presence of structure and hydrophobic group chlorine, makes it have crystallinity and fusing point higher, block water, oxygen resistance it is good, and to the obstruct of gas Property is not influenceed by ambient humidity, is widely used in the fields such as food, medicine, military project.
In Vingon production process, polymeric kettle is main production equipment, the direct shadow of quality of its technical performance Ring economy for the Yield and quality and operation for arriving Vingon etc..At present, the production of polyvinylidene chloride resin can be produced Business, only external DOW chemical companies of the U.S. and Wu Yu companies of Japan, the country is Zhejiang Juhua Co., Ltd., Electrochemical Plant.It is existing The annual production of global Vingon is about 100,000 tons, far can not also meet the market demand.What current above-mentioned manufacturer used Vingon polymeric kettle, DOW chemical companies of the U.S. are 40m3Polymeric kettle, Japanese Wu Yu companies are 60m3Polymeric kettle, Zhejiang hugeization The polymeric kettle that electrochemical factory of limited company uses is 30m3.In order to further improve Vingon yield, work life is improved Yield, in the urgent need to exploitation 60m3Large-scale Vingon polymeric kettle above.
In addition, in the production process of Vingon, exist that viscous kettle, product particle be uneven, mass-and heat-transfer always The problems such as difference, machine envelope are easily leaked, manhole opens difficult, has a strong impact on the quality and efficiency of Vingon production.Especially It is that viscous kettle is seriously open question all the time in Vingon production process, in general Vingon production process, Cleaning of the high intensity pressure (500bar) up to 4 hours will be carried out after being polymerized each time to kettle, polymeric kettle production capacity is influenceed Performance.And the generation of above mentioned problem, except having outside the Pass with polymerization technique, the structure design also with polymeric kettle is relevant.Particularly stir The structural shape for mixing device has a great impact to the effect of PVDC polymerization stirrings.The agitator of each structure is all only to a certain kind Or several stirring operations have good effect, any agitator can not possibly be adapted to the stirring operation of all PVDC polymerizations.Pin To specific stirring operation operating mode, select suitable agitator pattern particularly significant to PVDC polymerization techniques.Stirring in polymeric kettle Mixing type formula typically has anchor formula, paddle, turbine type, push type and frame.
Anchor formula:The stirring of high viscosity fluid is generally used for, because the stirrer diameter is very big, therefore may be used only for low turn Under fast operating mode.
Common pusher and paddle:Shearing force to fluid matasomatism is relatively low, it is difficult to be thoroughly mixed high viscosity fluid. Resin viscosity rising particle is thicker in course of reaction, easy implode.
Turbine type:It is applied to rotating speed high stirring, rotating speed is too high to make the PVDC resin particles become irregular, phase between particle Mutually it is bonded, reaction heat is difficult to remove, and easily produces implode.
Frame:Shearing force is too strong, easily deforms resin particle, is unfavorable for processing.
As Chinese patent notification number CN203754627U discloses a kind of PVDC reactors, including shell, several discharges Ring group into discharge ring array and top cover, the inwall of the cylindrical and shell of discharge ring array contacts;Discharge ring includes discharge ring master Body and connecting tube, discharge ring body interior are provided with ring-like hollow cavity, have in the inner headed face annular array of discharge ring main body Some relief holes, relief hole is connected with annular hollow cavity;Connecting tube is fixed in discharge ring main body, the axis with discharge ring main body Parallel, feed pipe is connected with annular hollow cavity;A connecting hole, axis and the discharge ring master of connecting hole are provided with discharge ring Body axis are parallel, are fixed with the cooperation with connecting hole by feed pipe between discharge ring;Annular array is provided with top cover Some through holes for fixing feed pipe.Additive is realized by the discharge ring for reacting easy enclosure fixation stacking Add, can with according to the species of additive change discharge ring quantity, do not interfere with the intensity for reacting easy body.
And for example《Polyvinylidene chloride production technology and application progress》(fine chemical material and intermediate, 2012 the 4th Phase) polymeric kettle blade is mentioned to using oblique oar, when mixing speed is 2.0-5.3, polymerisation stable operation;《Gather inclined two chloroethene The research and development of alkene are in progress with application》The agitator that (synthetic resin and plastics, 2011,28 (4)) are mentioned to PVDC polymeric kettles is double whirlpools It is wheeled.
The content of the invention
The purpose of this utility model is directed to the deficiencies in the prior art, there is provided a kind of rational in infrastructure, mass-and heat-transfer effect is good, Glue the polymerization for Vingon production high of all right kettle, high-efficiency and economic, product quality stabilization, unit volume yield Kettle.
To achieve the above object, the technical solution adopted in the utility model is:A kind of gathering for Vingon production Close kettle, including vertically arranged kettle is provided with agitator in described kettle, described agitator is by agitating shaft and is arranged on Blade group on the agitating shaft is constituted, and described agitating shaft upper end is connected with transmission device, and described kettle direct tube section is set Having can make cooling water along the spiralling spiral chuck of kettle outer wall, and described screw clamp set is provided with jacket water (J.W.) outlet and presss from both sides Set water inlet, described chuck water inlet is arranged on described kettle bottom, and described chuck water out is arranged on described kettle Body top, is provided with inner cool tube in described kettle, described inner cool tube one end extend out to kettle from described inner wall of kettle It is outside.
Used as preferred embodiment of the present utility model, described spiral chuck includes chuck housing, described chuck shell Spiral plate is provided between body and described kettle.Described spiral angle α is preferably 3-8 °, and spiral plate thickness S is preferably 1- 6mm, chuck is preferably 80-100mm with kettle spacing W;Preferably more 5-6 ° of spiral angle α, spiral plate thickness S preferably more 3- 5mm, spiral plate spacing H preferably more 120-130mm, chuck and kettle spacing W preferably more 90-95mm.
Used as preferred embodiment of the present utility model, described blade group is by from top to bottom along described agitating shaft axial direction The first blade, the second blade and the 3rd blade composition for setting, described the first blade and the second described blade are four leaves 45 ° of oblique blades, the 3rd described blade is axial flow type agitating valve leaf.
Used as preferred embodiment of the present utility model, highly preferred in described kettle of described the first blade is 0.5-0.6 times of the kettle internal diameter, highly preferred in described kettle of described the second blade is the kettle internal diameter 0.2-0.3 times, described the 3rd blade is the 0.05-0.1 of the kettle internal diameter in highly preferred in described kettle Times.
As preferred embodiment of the present utility model, the first described blade and the diameter and kettle of the second described blade Body diameter ratio is both preferably 0.5, and the 3rd described diameter of propeller blade is preferably 0.3 with kettle diameter ratio.
Used as preferred embodiment of the present utility model, described kettle top is additionally provided with Butterworth Hatch and feeding mouth, institute The autoclave body bottom stated is additionally provided with discharging opening.
Used as preferred embodiment of the present utility model, described Butterworth Hatch is additionally provided with shower valve.
Used as preferred embodiment of the present utility model, described kettle draw ratio is preferably 1.2-1.8, and nominal diameter is excellent Elect 3.5-4.5 meters as.
Used as preferred embodiment of the present utility model, described kettle draw ratio is preferably 1.3-1.5, and nominal diameter is excellent Elect 3.8-4 meters as.
Due to PVDC polymerization techniques use alternating temperature polymerization, in reaction each period resin viscosity change very greatly, because This hardly results in granule regularizing, the PVDC resins of easy processing using traditional agitating paddle pattern.The present invention uses three layers again Blade group is closed, upper strata and middle level all use 45 ° of oblique blades of cross, and lower floor uses axial flow type agitating valve leaf, to ensure PVDC resins Regularity, complies with the requirement that post-production is used.Vingon polymeric kettle blade group of the present utility model by from upper and Agitating shaft described in lower edge is axially arranged to be made up of the first blade, the second blade and the 3rd blade, the first described blade and institute The second blade stated is the oblique blade of 45 ° of four leaf, and the 3rd described blade is axial flow type agitating valve leaf, and the first described blade exists 0.5-0.6 times for the kettle internal diameter of highly preferred in described kettle, the second described blade is in described kettle Highly preferred 0.2-0.3 times for the kettle internal diameter, the 3rd described blade is highly preferred in described kettle It is 0.05-0.1 times of the kettle internal diameter, the first described blade and the diameter of the second described blade and kettle diameter ratio Both preferably 0.5, the 3rd described diameter of propeller blade is preferably 0.3 with kettle diameter ratio.Polymerization can guarantee that using this structure The mass-and heat-transfer effect and less shearing force of reaction.
The spiral plate of the utility model use is jacket structured to be different from conventional jacket, spiral stream guidance type chuck and semicanal spiral Chuck, it is on the basis of conventional jacket, between chuck inside and kettle outside, to increase spiral plate structure, the spiral shell of spiral plate Rotation angle [alpha], spiral plate thickness S, chuck housing and kettle spacing W and spiral plate spacing H determine the heat transfer efficiency of kettle.Spiral Plate is full weld with chuck and kettle, allows cooling water along spiral plate spiral, can be obtained more preferably with little water Heat-transfer effect, while can be by the way of with many imports and multiple exit, preferably to improve heat transfer coefficient, heat transfer coefficient be reachable K=950W (m2.K), heat transfer coefficient is both improved, the intensity of kettle is increased again.Meanwhile, the temperature of polymeric kettle realizes that DCS is automated Control, polymeric kettle temperature change can be controlled at ± 0.1 DEG C, and the good heat-transfer of kettle, temperature control is accurate.
The utility model carries out being conducted heat in kettle using inner cool tube, to make up the deficiency of jacket heat transfer area, and heat-transfer effect It is good.Inner cool tube fixed form is unique, is extend out to outside bottom from kettle, then in the outer fixing seal of kettle, extracts inner cool tube out convenient, It is easy to the maintenance and cleaning of inner cool tube, it is to avoid the loss that top some area of penetration type inner cool tube is caused not in contact with heat transfer. Meanwhile, inner cool tube plays a part of baffle plate in kettle, coordinates agitator to make mass transfer effect more preferably, reaction is uniformly carried out.
Compared with prior art, the utility model has the following advantages that:
1st, good, the viscous kettle of rational in infrastructure, mass-and heat-transfer effect is all right, and polymerisation is ensured using three layers of compound blade group Mass-and heat-transfer effect and less shearing force;The spiral plate of use is jacket structured, can be obtained preferably with little water Heat-transfer effect, both improves heat transfer coefficient, and the intensity of kettle is increased again, and the temperature of polymeric kettle realizes DCS Automated condtrols, polymeric kettle Temperature change can be controlled at ± 0.1 DEG C, and the good heat-transfer of kettle, temperature control is accurate;Carry out being conducted heat in kettle using inner cool tube, To make up the deficiency of jacket heat transfer area, and heat-transfer effect is good, meanwhile, inner cool tube plays a part of baffle plate in kettle, and cooperation is stirred Mixing device makes mass transfer effect more preferably, reaction is uniformly carried out;
2nd, high-efficiency and economic, unit volume yield are high, and the polymeric kettle for Vingon production of the present utility model is new Volume 60-75m3, mass-and heat-transfer effect is good, and it is all right to glue kettle, reduces the clear kettle frequency, scavenging period foreshorten to 2 hours with Under, unit volume yield is high, substantially increases labor productivity;
3rd, small investment, low cost, polymeric kettle quantity and corresponding instrument equipment greatly reduce under identical production capacity, save equipment Investment, while reducing operation headcount, reduce further production cost;
4th, product quality stabilization, the temperature of polymeric kettle realizes DCS Automated condtrols, and polymeric kettle temperature change can be controlled ± 0.1 DEG C, the good heat-transfer of kettle, precisely, the error that feeds intake is smaller for temperature control, and reaction is more steady, and product quality is significantly carried Height, while product quality stability is greatly improved between different batches.
Brief description of the drawings
Fig. 1 is the structural representation of the polymeric kettle for Vingon production of the present utility model;
Fig. 2 is the structural representation of the polymeric kettle spiral plate chuck for Vingon production of the present utility model.
In figure, transmission device 1, feeding mouth 2, shower valve 3, chuck water out 4, kettle 5, spiral chuck 6, the first blade 7, Inner cool tube 8, the second blade 9, the 3rd blade 10, discharging opening 11, chuck water inlet 12, Butterworth Hatch 13, chuck housing 14, spiral plate 15, agitating shaft 16
Specific embodiment
As shown in Figure 1 and Figure 2, it is provided with stirring in the polymeric kettle kettle 5 for Vingon production of the present utility model Device, agitator is made up of agitating shaft 16 and the blade group being arranged on agitating shaft 16, and the upper end of agitating shaft 16 connects with transmission device 1 Connect, the direct tube section of kettle 5 is provided with can make cooling water along the spiralling spiral chuck 6 of the outer wall of kettle 5, and spiral chuck 6 includes Chuck housing 14, is provided with spiral plate 15 between chuck housing 14 and kettle 5.Spiral chuck 6 is provided with chuck water out 4 and folder Set water inlet 12, chuck water inlet 12 is arranged on the bottom of kettle 5, and chuck water out 4 is arranged in the top of kettle 5, kettle 5 and sets There is inner cool tube 8, the one end of inner cool tube 8 extend out to the outside of kettle 5 from the inwall of kettle 5.Blade group is by from top to bottom along agitating shaft 16 Axially arranged the first blade 7, the second blade 9 and the 3rd blade 10 are constituted, the first blade 7, the second blade 9 and the 3rd blade 10 It is the oblique blade of 45 ° of four leaf.The top of kettle 5 is provided with Butterworth Hatch 13 and feeding mouth 2, and the bottom of kettle 5 is provided with discharging opening 11.Clearly Wash mouth 13 and be provided with shower valve 3.
The utility model is further elaborated by the following examples, but the utility model is not limited in institute The embodiment stated.
Embodiment 1
Agitator is provided with polymeric kettle kettle 5 (kettle draw ratio is 1.8, and nominal diameter is 3.5 meters), agitator is by stirring The blade group mixed axle 16 and be arranged on agitating shaft 16 is constituted, and the upper end of agitating shaft 16 is connected with transmission device 1, the direct tube section of kettle 5 Being provided with can make cooling water along the spiralling spiral chuck 6 of the outer wall of kettle 5, and spiral chuck 6 includes chuck housing 14, chuck Spiral plate 15 is provided between housing 14 and kettle 5, and (the spiral angle α of spiral plate 15 is 3 °, and spiral plate thickness S is 1mm, spiral Plate spacing H is 100mm, and chuck housing 14 is 80mm with the spacing W of kettle 5).Spiral chuck 6 is provided with chuck water out 4 and chuck Water inlet 12, chuck water inlet 12 is arranged on the bottom of kettle 5, and chuck water out 4 is arranged in the top of kettle 5, kettle 5 and is provided with Inner cool tube 8, one end of inner cool tube 8 extend out to the outside of kettle 5 from the inwall of kettle 5.Blade group is by from top to bottom along the axle of agitating shaft 16 To set the first blade 7 (45 ° of oblique blades of cross, height of first blade 7 in kettle 5 is 0.5 times of kettle internal diameter, the The diameter of one blade 7 and the diameter ratio of kettle 5 for 0.5), (45 ° of oblique blades of cross, the second blade 9 is in kettle 5 for the second blade 9 Height be 0.2 times of kettle internal diameter, 0.5) and the 3rd blade 10 (uses axle the diameter of the second blade 9 and the diameter ratio of kettle 5 are for Streaming stirrer paddle, height of the 3rd blade 10 in kettle 5 is 0.05 times of kettle internal diameter, the diameter of the 3rd blade 10 and kettle 5 diameter ratios are 0.3) to constitute.The top of kettle 5 is provided with Butterworth Hatch 13 and feeding mouth 2, and the bottom of kettle 5 is provided with discharging opening 11. Butterworth Hatch 13 is provided with shower valve 3.
Embodiment 2
Agitator is provided with polymeric kettle kettle 5 (kettle draw ratio is 1.5, and nominal diameter is 4 meters), agitator is by stirring Axle 16 and the blade group being arranged on agitating shaft 16 are constituted, and the upper end of agitating shaft 16 is connected with transmission device 1, and the direct tube section of kettle 5 sets Being equipped with can make cooling water along the spiralling spiral chuck 6 of the outer wall of kettle 5, and spiral chuck 6 includes chuck housing 14, chuck shell Spiral plate 15 is provided between body 14 and kettle 5, and (the spiral angle α of spiral plate 15 is 5 °, and spiral plate thickness S is 3mm, spiral plate Spacing H is 130mm, and chuck housing 14 is 90mm with the spacing W of kettle 5).Spiral chuck 6 is provided with chuck water out 4 and jacket water (J.W.) Import 12, chuck water inlet 12 is arranged on the bottom of kettle 5, in chuck water out 4 is arranged in the top of kettle 5, kettle 5 and is provided with Cold pipe 8, one end of inner cool tube 8 extend out to the outside of kettle 5 from the inwall of kettle 5.Blade group is by from top to bottom along the axial direction of agitating shaft 16 (45 ° of oblique blades of cross, height of first blade 7 in kettle 5 is 0.55 times of kettle internal diameter, first to the first blade 7 for setting The diameter of blade 7 and the diameter ratio of kettle 5 for 0.5), (45 ° of oblique blades of cross, the second blade 9 is in kettle 5 for the second blade 9 It highly it is 0.25 times of kettle internal diameter, the diameter of the second blade 9 is 0.5) with the diameter ratio of kettle 5 and the 3rd blade 10 (uses axle Streaming stirrer paddle, height of the 3rd blade 10 in kettle 5 is 0.08 times of kettle internal diameter, the diameter of the 3rd blade 10 and kettle 5 diameter ratios are 0.3) to constitute.The top of kettle 5 is provided with Butterworth Hatch 13 and feeding mouth 2, and the bottom of kettle 5 is provided with discharging opening 11. Butterworth Hatch 13 is provided with shower valve 3.
Embodiment 3
Agitator is provided with polymeric kettle kettle 5 (kettle draw ratio is 1.2, and nominal diameter is 4.5 meters), agitator is by stirring The blade group mixed axle 16 and be arranged on agitating shaft 16 is constituted, and the upper end of agitating shaft 16 is connected with transmission device 1, the direct tube section of kettle 5 Being provided with can make cooling water along the spiralling spiral chuck 6 of the outer wall of kettle 5, and spiral chuck 6 includes chuck housing 14, chuck Spiral plate 15 is provided between housing 14 and kettle 5, and (the spiral angle α of spiral plate 15 is 8 °, and spiral plate thickness S is 6mm, spiral Plate spacing H is 150mm, and chuck housing 14 is 100mm with the spacing W of kettle 5).Spiral chuck 6 is provided with chuck water out 4 and folder Set water inlet 12, chuck water inlet 12 is arranged on the bottom of kettle 5, and chuck water out 4 is arranged in the top of kettle 5, kettle 5 and sets There is inner cool tube 8, the one end of inner cool tube 8 extend out to the outside of kettle 5 from the inwall of kettle 5.Blade group is by from top to bottom along agitating shaft 16 Axially arranged first blade 7 (45 ° of oblique blades of cross, height of first blade 7 in kettle 5 is 0.6 times of kettle internal diameter, The diameter of the first blade 7 and the diameter ratio of kettle 5 for 0.5), (45 ° of oblique blades of cross, the second blade 9 is in kettle 5 for the second blade 9 Interior height is 0.3 times of kettle internal diameter, and the diameter of the second blade 9 is 0.5) (to be used with the 3rd blade 10 with the diameter ratio of kettle 5 Axial flow type agitating valve leaf, height of the 3rd blade 10 in kettle 5 is 0.1 times of kettle internal diameter, the diameter of the 3rd blade 10 and kettle The diameter ratio of body 5 is 0.3) to constitute.The top of kettle 5 is provided with Butterworth Hatch 13 and feeding mouth 2, and the bottom of kettle 5 is provided with discharging opening 11.Butterworth Hatch 13 is provided with shower valve 3.

Claims (10)

1. a kind of polymeric kettle for Vingon production, including vertically arranged kettle, it is characterised in that described kettle Agitator is inside provided with, described agitator is made up of agitating shaft and the blade group being arranged on the agitating shaft, and described stirs Mix axle upper end to be connected with transmission device, described kettle direct tube section is provided with can make cooling water spiralling along kettle outer wall Spiral chuck, described screw clamp set is provided with jacket water (J.W.) outlet and chuck water inlet, and described chuck water inlet is arranged on institute The kettle bottom stated, described chuck water out is arranged on described kettle top, and inner cool tube, institute are provided with described kettle The inner cool tube one end stated extend out to the outside of kettle from described inner wall of kettle.
2. it is according to claim 1 for Vingon production polymeric kettle, it is characterised in that described spiral chuck Including chuck housing, spiral plate is provided between described chuck housing and described kettle.
3. it is according to claim 2 for Vingon production polymeric kettle, it is characterised in that described spiral plate Spiral angle is 3-8 °, and described spiral plate thickness is 1-6mm, and described chuck housing and described kettle spacing is 80- 100mm。
4. it is according to claim 1 for Vingon production polymeric kettle, it is characterised in that described blade group by Constituted along the first axially arranged blade of described agitating shaft, the second blade and the 3rd blade from top to bottom, the first described oar Leaf and the second described blade are the oblique blade of 45 ° of four leaf, and the 3rd described blade is axial flow type agitating valve leaf.
5. it is according to claim 4 for Vingon production polymeric kettle, it is characterised in that the first described blade Height in described kettle is 0.5-0.6 times of the kettle internal diameter, and the second described blade is in described kettle It it is highly the kettle internal diameter 0.2-0.3 times, the height of described the 3rd blade in described kettle is in the kettle 0.05-0.1 times of footpath.
6. it is according to claim 4 for Vingon production polymeric kettle, it is characterised in that the first described blade 0.5 is with the diameter of the second described blade and kettle diameter ratio, the 3rd described diameter of propeller blade and kettle diameter ratio It is 0.3.
7. it is according to claim 1 for Vingon production polymeric kettle, it is characterised in that described kettle top Butterworth Hatch and feeding mouth are provided with, described autoclave body bottom is provided with discharging opening.
8. it is according to claim 7 for Vingon production polymeric kettle, it is characterised in that described Butterworth Hatch sets It is equipped with shower valve.
9. it is according to claim 1 for Vingon production polymeric kettle, it is characterised in that described kettle major diameter Than being 1.2-1.8, nominal diameter is 3.5-4.5 meters.
10. it is according to claim 1 for Vingon production polymeric kettle, it is characterised in that described kettle major diameter Than being 1.3-1.5, nominal diameter is 3.8-4 meters.
CN201620676500.1U 2016-06-27 2016-06-27 A polymeric kettle for vinylidene chloride production Active CN206184422U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105964203A (en) * 2016-06-27 2016-09-28 浙江巨化股份有限公司电化厂 Polymerizing kettle and method for producing polyvinylidene chloride
CN107670625A (en) * 2017-11-20 2018-02-09 江门市英豪农科有限公司 A kind of fully automatic integral reactor
CN107694504A (en) * 2017-11-20 2018-02-16 江门市英豪农科有限公司 A kind of reactor for being used to produce liquid fertilizer

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105964203A (en) * 2016-06-27 2016-09-28 浙江巨化股份有限公司电化厂 Polymerizing kettle and method for producing polyvinylidene chloride
CN107670625A (en) * 2017-11-20 2018-02-09 江门市英豪农科有限公司 A kind of fully automatic integral reactor
CN107694504A (en) * 2017-11-20 2018-02-16 江门市英豪农科有限公司 A kind of reactor for being used to produce liquid fertilizer

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