CN206182432U - A combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures - Google Patents
A combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures Download PDFInfo
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- CN206182432U CN206182432U CN201620983735.5U CN201620983735U CN206182432U CN 206182432 U CN206182432 U CN 206182432U CN 201620983735 U CN201620983735 U CN 201620983735U CN 206182432 U CN206182432 U CN 206182432U
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Abstract
The utility model provides a combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures, including base cloth layer (1) and protective layer, the protective layer by primer layer (2) rigidity particle (3) on primer layer (2) surface with coat and compound glue film (4) on rigidity particle (3) form behind solidification treatment, primer layer (2) coat in on base cloth layer (1). The utility model discloses a protection products such as cutting, needle -prick prevention gloves, anti -cutting armguard, anti -cutting apron, resistant cutting suitcase are applicablely prevented to the water -fast performance of washing that a combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures compliance can be good, mechanical properties is high, anti cutting performance is strong and good, and preparation method is simple, production efficiency is high in the preparation, the range of application extensively.
Description
Technical field
The utility model belongs to new material technology field, more particularly to one kind is for anti-cutting gloves, anti-cutting protector and prevents
Puncture the composite of clothes.
Background technology
With the development of modern society, people increasingly pay attention to inherently safe protection.In industrial circle, such as machinery, stone
The aspect such as oil, chemical industry, glass processing and physical culture, open air, people in the urgent need to the Protection Product with the anti-stab function of anti-cutting, but
Current product such as Anti-cut Gloves, anti-cutting armlet, apron are still largely made using the embedded stainless steel wire method in fabric
Standby, though this kind of product has certain effect, inconvenient operation, flexibility is very poor.
Based on this present situation, the special protection for having had been developed for being intended to provide protection for the injury of anti-stab anti-cutting at present is produced
Product, although these Protection Products can play corresponding effect to a certain extent, but be substantially all more heavy, shortage spirit
Activity and flexibility, it is impossible to be entirely satisfactory.
The stab-resistance body armor being made using kevlar fabric is described in such as patent WO-A91-06821, has metal on its surface
Plate, anti-stab effect is reached with this, but this kind of clothes is relatively bulky, it is impossible to flexibility and flexibility needed for providing.Specially
The similar method being also adopted by sharp DE-A4413969, the stab-resistance body armor that multilayer metal foil is made is combined with aramid fabric,
Certain anti-stab effect can be played, but metal foil cost is very high, and preparation to get up bother very much, and pliability is also poor.Patent
It is then to be coated in fabric face using plasma spray to spray one layer of ceramic coating in WO9603277, although fine and close ceramic layer can be with
Good protective action is played, but plasma spray coating process is relatively costly, and the production time is long, complex process, it is impossible to volume production.
Anti-cutting fabric is prepared by the way of fiber twisting braiding in patent US7127879B2, fibre compact is combined together, although energy
Anti-cutting effect is enough played, but because fiber is finer and close, the number of plies is more, causes comfortableness gas permeability poor, and long-term use,
Fiber is gradually damaged, and anti-cutting effect is greatly reduced, and causes potential safety hazard.
Utility model content
Technical problem to be solved in the utility model is：For the defect of prior art, there is provided one kind is used for anti-cutting
The composite of gloves, anti-cutting protector and anti-puncture clothes.
The utility model uses following technical scheme to solve above-mentioned technical problem：
The utility model provides a kind of composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes, bag
Base cloth layer 1 and protective layer are included, the protective layer is implanted into the rigid grain on the surface of primer layer 2 by primer layer 2, using implantation process of sand
Formation after the cured treatment of complex layer 4 on son 3 and coating and the rigid particles 3, the primer layer 2 is coated on the base fabric
On layer 1.
Further, the base cloth layer 1 is selected from glass fibre, basalt fibre, aramid fiber, high-strength nylon fiber, washs
The thread fabric of one or more fibers of synthetic fibre fiber, yarn, during the fabric is woven, knitting or non-woven fabric
It is a kind of.
Further, the fineness of yarn of the fabric is 50D-2100D, and grammes per square metre is 100-300g/m2, the fabric tissue
Form is woven fabric, looped fabric or non-weaving cloth.
Further, the primary raw material of the primer layer 2 be thermosetting resin, the thermosetting resin be selected from ureaformaldehyde and its
In modified resin, phenolic aldehyde and its modified resin, epoxy and its modified resin, acrylic acid and its modified resin or inorganic binder
One or more.
Further, the rigid particles 3 be selected from aluminum oxide, silicon nitride, pink fused alumina, fused alumina zirconia, carborundum, diamond,
One or several mixture in glass, its particle diameter is between 10-500 μm.
Further, the primary raw material of the re-glue 4 is thermosetting resin, and the thermosetting resin is selected from ureaformaldehyde and its changes
In property resin, phenolic aldehyde and its modified resin, epoxy and its modified resin, acrylic acid and its modified resin or inorganic binder one
Plant or several.
Further, the plant sand thickness of the rigid particles is 0.1-2mm, and it is 30-500g/m to plant sand amount2。
Further, the thickness of the base cloth layer 1 is 0.1-1mm.
Further, the protective layer thickness is 0.1-2mm.
The preparation technology of the utility model composite is：Suitable high-performance fiber fabric is chosen, electrostatic is carried out to it
Treatment and the treatment of coated primer, make fabric possess resistance to hypertonic performance, and make the physical and mechanical properties of fabric coated with follow-up
Binder phase is matched；Rigid particles are bonded in one by the mode for planting sand or electrostatic sand-planting using gravity with the fabric of coated primer
Rise, being sent to solidification workshop using conveyer carries out primary solidification；After the solidification a period of time of solidification workshop, rigid grain
Son is stronger with fabric bonding, then carries out re-glue treatment, rigid particles is bonded more firmly with fabric, and rigid particles are caused
It is close to be evenly distributed on high-performance fiber fabric, high-performance protective layer is formed, rigid particles can be denuded, be passivated sharp instrument,
Weaken the shearing force of sharp instrument, high-performance fiber fabric then plays a part of to support and buffers, user formed and is effectively protected.
Further, the voltage of the Electrostatic Treatment is 20000V-40000V, and electric current is 1mA-10mA, temperature is 20 DEG C-
50℃。
Further, the composition of the primer layer 2 includes following components by weight percentage：Thermosetting resin：45-
85%, filler：10-40%, surfactant：0.4-1.8%, diluent：5-18%, defoamer：0.3-0.9%, the above is each
Component carton is 100%.
Preferably, described filler is the one kind in coarse whiting, fine particle calcium carbonate, chalky soil, diatomite, wollastonite powder, asbestos or diopside
Or more than one, particle diameter is 1-5 μm.
Preferably, described surfactant is aliphatic sulfonic compound, alkyl aryl sulphonic acid compound, alkyl naphthalene sulfonic acid
One or more in thing, Span or polyoxyethylene sorbitan fatty acid ester.
Preferably, described diluent is methyl alcohol, ethanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol second
One or more in ether or water.
Preferably, described defoamer is one or more during organosiloxane, polyethers, silicon or ether are grafted.
Preferably, the solidification temperature of the primer layer 2 is 55-75 DEG C, and hardening time is 50-55min.
Further, the composition of the complex layer 4 includes following components by weight percentage：Thermosetting resin：45-
85%, efficient levelling agent：1.3-4.7%, antistatic additive：0.5-4.5%, filler：9-35%, coupling agent：0.2-0.7, pigment：
2-6%, diluent：0.5-9%, fire retardant：0.5-0.8%, above each component sum is 100%.
Preferably, the efficient levelling agent be organic silicon modified by polyether, alkyl-modified organosilicon, fluorin modified crylic acid ester gather
In compound, alkyl diphenyl base oxide disulfonate, Span or polyoxyethylene sorbitan fatty acid ester
One or more.
Preferably, the antistatic additive is quiet for anionic antistatic agent, cationic antistatic agent or nonionic resist
One or more in electric agent.
Preferably, described filler is calcium carbonate, silicate, hexafluoro sodium aluminate, potassium fluoborate, sodium fluoborate, calcirm-fluoride, fluorine
Change one or more in sodium, calcium stearate or zinc stearate；Coupling agent is in silane coupler or zirconium class coupling agent
One or more；Diluent is methyl alcohol, ethanol, acetone, ethyl acetate, ethylene glycol monoethyl ether, diethylene glycol ether or water
In one or more；Fire retardant be red phosphorus, aluminium hydroxide or expansile graphite in one or more.
Preferably, the solidification temperature of the complex layer 4 is 85-100 DEG C, and hardening time is 70-100min.
The composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes prepared using this technique, surface
With specific floral designs, the outer layer of gloves and protector can be sewn to, it is also possible to be sewn between surface layer and nexine.
The utility model uses above technical scheme, compared with prior art, has the following technical effect that：
Composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes of the present utility model, its preparation method
Simply, production efficiency is high, can be continuously produced；The surface particles intensity of composite is high, with mechanical property higher；And
Particle adhesive fastness is high, with good wash durability；Softness is good, and anti-cut performance is strong；It is applicable to make anti-cutting
Cut, anti-acupuncture gloves, it is also possible to make the Protection Products such as anti-cutting armlet, anti-cutting apron, cut resistant suitcase, have a wide range of application.
Brief description of the drawings
Fig. 1 is that the section of the composite that the utility model is used for anti-cutting gloves, anti-cutting protector and anti-puncture clothes shows
It is intended to；
Fig. 2 is using the protector schematic diagram of the utility model composite；
Fig. 3 is using the apron schematic diagram of the utility model composite；
Fig. 4 is using the gloves schematic diagram of the utility model composite.
Specific embodiment
As shown in figure 1, the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes of the present utility model,
Including base cloth layer 1 and protective layer, protective layer is by primer layer 2, the and of rigid particles 3 using implantation process of sand implantation primer layer 2 surface
Formed after the cured treatment of complex layer 4 in coating and rigid particles 3, the primer layer 2 is coated on the base cloth layer 1.Tool
Body is, by implantation process of sand, rigid particles 3 first to be bonded in into the surface of base cloth layer 1 with primer layer 2, tentatively solid in workshop is solidified
Change, then rigid particles 3 is combined with high-performance fiber fabric 1 more firmly by complex layer 4, high-performance is obtained is used for anti-cutting
The composite of gloves, anti-cutting protector and anti-puncture clothes.
The technical solution of the utility model is described in further detail below in conjunction with the accompanying drawings.
Embodiment 1
Using aramid fiber plain fabric as base fabric, line density is 1000D, and surface density is 200g/m2, thread count is 110*
110/ (root/10cm)；The composition of the primer of selection includes following components by weight percentage：Phenolic resin：55%, filler：
38%, surfactant：0.9%, diluent：5.3%, defoamer：0.8%；The rigid particles of selection are carborundum, and particle diameter is
80μm；The composition of re-glue includes following components by weight percentage：Phenolic resin：65%, efficient levelling agent：2.8%, it is antistatic
Agent：3.5%, filler：20.5%, coupling agent：0.4%, pigment：3%, diluent：4%, fire retardant：0.8%.
The preparation process of the described composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes is as follows：
Electrostatic Treatment and the treatment of coated primer are carried out to kevlar fabric, the voltage of Electrostatic Treatment is 30000V, and electric current is
5mA, temperature is 30 DEG C, fabric is possessed resistance to hypertonic performance, and improve fabric face tackability；Using the side of electrostatic sand-planting
Silicon-carbide particle is coated in scrim surfaces by formula, and being sent to solidification workshop using conveyer carries out primary solidification, primer
Solidification temperature is 60 DEG C, and hardening time is 55min, and silicon-carbide particle is bonded in fabric substrate surface；Re-glue technique is carried out again, it is multiple
Adhesive curing temperature is 90 DEG C, and hardening time is 80min, silicon-carbide particle is bonded more firmly with fabric, and carborundum
It is solidificated on high-performance fiber fabric grain dense uniform, is prepared from for anti-cutting gloves, anti-cutting protector and anti-puncture clothes
The composite of dress.
Embodiment 2
Using polyster fibre twill fabric as base fabric, line density is 600D, and surface density is 230g/m2, thread count is
160*180/ (root/10cm)；The composition of the primer of selection includes following components by weight percentage：Phenolic resin：55%, fill out
Material：38%, surfactant：0.9%, diluent：5.3%, defoamer：0.8%；The rigid particles of selection are fused alumina zirconia, grain
Footpath is 120 μm；The composition of re-glue includes following components by weight percentage：Phenolic resin：65%, efficient levelling agent：2.8%,
Antistatic additive：3.5%, filler：20.5%, coupling agent：0.4%, pigment：3%, diluent：4%, fire retardant：0.8%.
The preparation process of the described composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes is as follows：
Electrostatic Treatment and the treatment of coated primer are carried out to dacron, the voltage of Electrostatic Treatment is 22000V, and electric current is
4mA, temperature is 30 DEG C, fabric is possessed resistance to hypertonic performance, and improve fabric face tackability；Using the side of electrostatic sand-planting
Fused alumina zirconia particle is coated in scrim surfaces by formula, and being sent to solidification workshop using conveyer carries out primary solidification, primer
Solidification temperature is 60 DEG C, and hardening time is 55min, and fused alumina zirconia particle is bonded in fabric substrate surface；Re-glue technique is carried out again, it is multiple
Adhesive curing temperature is 90 DEG C, and hardening time is 80min, rigid particles is bonded more firmly with fabric, and fused alumina zirconia particle
It is solidificated on high-performance fiber fabric dense uniform, is prepared from for anti-cutting gloves, anti-cutting protector and anti-puncture clothes
Composite.
Embodiment 3
Using Cordura plain fabrics as base fabric, line density is 500D, and surface density is 210g/m2, thread count is
162*174 (root/10cm)；The composition of the primer of selection includes following components by weight percentage：Phenolic resin：55%, filler：
38%, surfactant：0.9%, diluent：5.3%, defoamer：0.8%；The rigid particles of selection are alumina particle, grain
Footpath is 60 μm；The composition of re-glue includes following components by weight percentage：Phenolic resin：65%, efficient levelling agent：2.8%, resist
Electrostatic agent：3.5%, filler：20.5%, coupling agent：0.4%, pigment：3%, diluent：4%, fire retardant：0.8%.
The preparation process of the anti-anti- needle-punched composite of cutting of described discrete flexibility is as follows:
Electrostatic Treatment and the treatment of coated primer are carried out to dacron, the voltage of Electrostatic Treatment is 25000V, and electric current is
4mA, temperature is 30 DEG C, fabric is possessed resistance to hypertonic performance, and improve fabric face tackability；Using the side of electrostatic sand-planting
Alumina particle is coated in scrim surfaces by formula, and being sent to solidification workshop using conveyer carries out primary solidification, primer
Solidification temperature is 60 DEG C, and hardening time is 55min, and alumina particle is bonded in fabric substrate surface；Re-glue technique is carried out again, it is multiple
Adhesive curing temperature is 90 DEG C, and hardening time is 80min, rigid particles is bonded more firmly with fabric, and alumina particle
It is solidificated on high-performance fiber fabric dense uniform, is prepared from for anti-cutting gloves, anti-cutting protector and anti-puncture clothes
Composite.
As the anti-stab anti-cutting composite of high-performance flexible prepared by above-mentioned the present embodiment 1-3 has excellent barrier propterty,
The materials application extensively, can be used to preparing that anti-cutting protector is as shown in Figure 2, apron is as shown in Figure 3, anti-stab cut gloves such as Fig. 4 institutes
The Related product such as show.Flexibility anti-cutting gloves of new generation can be prepared using this individual layer anti-cutting composite, and can
To reach 5 grades of standards of anti-cutting property of European EN388 mechanicalness injuries protective gloves standard, 4 grades of standards of puncture-resistant are played well
Anti-cutting effect.10-50 layers of anti-cutting composite carries out lamination suture, and protection inner core, 0.3m are prepared according to human somatotype2's
A whole set of stab-resistance body armor weight is only 2.2kg, and thickness is 8mm, is tested according to China's public safety industry GA68-2008 standards,
Either normal temperature or low temperature, high temperature can be transferred through 24J energy and do not penetrate.And the stab-resistance body armor prepared using this composite
Anti-stab excellent performance, weight is light, soft flexible, there is competitive advantage higher.
Specific embodiment of the utility model has been described in detail above, but it is only used as example, the utility model
It is not restricted to particular embodiments described above.To those skilled in the art, it is any to being equal to that the practicality is carried out
Modifications and substitutions are also all among category of the present utility model.Therefore, the institute in the case where spirit and scope of the present utility model are not departed from
The impartial conversion and modification of work, should all cover in the range of the utility model.
Claims (9)
1. the composite of anti-cutting gloves, anti-cutting protector and anti-puncture clothes is used for, it is characterised in that including base cloth layer (1)
And protective layer, the protective layer is by primer layer (2), the rigid particles (3) on the primer layer (2) surface and coating and the rigidity
Formed after complex layer (4) cured treatment on particle (3), the primer layer (2) is coated on the base cloth layer (1).
2. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
Be, the base cloth layer (1) selected from glass fibre, basalt fibre, aramid fiber, high-strength nylon fiber, polyster fibre one
Plant or the thread fabric of more than one fibers, yarn, the fabric is the one kind in woven, knitting or non-woven fabric.
3. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 2, its feature
It is that the fineness of yarn of the fabric is 50D-2100D, and grammes per square metre is 100-300g/m2, the fabric tissue form is woven
Cloth, looped fabric or non-weaving cloth.
4. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
Be that the primary raw material of the primer layer (2) is thermosetting resin, the thermosetting resin be selected from ureaformaldehyde and its modified resin,
One kind or several in phenolic aldehyde and its modified resin, epoxy and its modified resin, acrylic acid and its modified resin or inorganic binder
Kind.
5. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
It is that the rigid particles (3) are selected from aluminum oxide, silicon nitride, pink fused alumina, fused alumina zirconia, carborundum, diamond, glass
Plant or several mixtures, its particle diameter is between 10-500 μm.
6. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
It is, the re-glueLayer(4) primary raw material is thermosetting resin, the thermosetting resin be selected from ureaformaldehyde and its modified resin,
One kind or several in phenolic aldehyde and its modified resin, epoxy and its modified resin, acrylic acid and its modified resin or inorganic binder
Kind.
7. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
It is that the plant sand thickness of the rigid particles is 0.1-2mm, it is 30-500g/m to plant sand amount2。
8. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
It is that the thickness of the base cloth layer (1) is 0.1-1mm.
9. the composite for anti-cutting gloves, anti-cutting protector and anti-puncture clothes according to claim 1, its feature
It is that the protective layer thickness is 0.1-2mm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620983735.5U CN206182432U (en) | 2016-08-30 | 2016-08-30 | A combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201620983735.5U CN206182432U (en) | 2016-08-30 | 2016-08-30 | A combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures |
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| Publication Number | Publication Date |
|---|---|
| CN206182432U true CN206182432U (en) | 2017-05-24 |
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ID=58729098
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| CN201620983735.5U Active CN206182432U (en) | 2016-08-30 | 2016-08-30 | A combined material for preventing cut gloves, anti -cutting protective equipment and prevent clothing that punctures |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019062047A1 (en) * | 2017-09-29 | 2019-04-04 | 汇鸿(南通)安全用品有限公司 | Anti-cutting rubber coating yarn |
| CN111005237A (en) * | 2019-12-25 | 2020-04-14 | 上海固甲新材料科技有限公司 | Anti-cutting and anti-radiation composite material and preparation method thereof |
| CN111418933A (en) * | 2020-03-05 | 2020-07-17 | 淮安坤宇劳保用品有限公司 | Preparation method of nylon gloves with wear-resistant coatings |
| CN113142721A (en) * | 2021-05-28 | 2021-07-23 | 嘉鸿手套实业有限公司 | Cutting-resistant and puncture-resistant industrial protective glove |
-
2016
- 2016-08-30 CN CN201620983735.5U patent/CN206182432U/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019062047A1 (en) * | 2017-09-29 | 2019-04-04 | 汇鸿(南通)安全用品有限公司 | Anti-cutting rubber coating yarn |
| US11396719B2 (en) | 2017-09-29 | 2022-07-26 | Huihong (Nantong) Safety Products Co., Ltd. | Anti-cutting rubber-coated yarn |
| CN111005237A (en) * | 2019-12-25 | 2020-04-14 | 上海固甲新材料科技有限公司 | Anti-cutting and anti-radiation composite material and preparation method thereof |
| CN111418933A (en) * | 2020-03-05 | 2020-07-17 | 淮安坤宇劳保用品有限公司 | Preparation method of nylon gloves with wear-resistant coatings |
| CN113142721A (en) * | 2021-05-28 | 2021-07-23 | 嘉鸿手套实业有限公司 | Cutting-resistant and puncture-resistant industrial protective glove |
| CN113142721B (en) * | 2021-05-28 | 2024-04-02 | 嘉鸿手套实业有限公司 | Cutting-resistant and puncture-resistant industrial protective glove |
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